CN103937945B - Technology for Heating Processing of spheroidal graphite cast-iron Piston Casting and application thereof - Google Patents

Technology for Heating Processing of spheroidal graphite cast-iron Piston Casting and application thereof Download PDF

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Publication number
CN103937945B
CN103937945B CN201410113626.3A CN201410113626A CN103937945B CN 103937945 B CN103937945 B CN 103937945B CN 201410113626 A CN201410113626 A CN 201410113626A CN 103937945 B CN103937945 B CN 103937945B
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spheroidal graphite
graphite cast
iron piston
piston casting
iron
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CN103937945A (en
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杨志刚
潘多龙
封雪平
张军
鲍飞
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CRRC Qishuyan Institute Co Ltd
CRRC Changzhou Auto Parts Co Ltd
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CRRC Qishuyan Institute Co Ltd
Changzhou CSR Auto Parts Co Ltd
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Abstract

The present invention relates to the Technology for Heating Processing of a kind of spheroidal graphite cast-iron Piston Casting, a, the spheroidal graphite cast-iron Piston Casting that will be in room temperature load electric furnace, are heated to 620~680 DEG C, insulation 1~2h;B, be again heated to 920 ± 10 DEG C, insulation 2 ± 0.5h;C, be cooled to 850~880 DEG C, insulation 1 ± 0.1h;D, come out of the stove after put into rapidly in aqueous solvent cooling medium, chilling period controls, 10~20s, to make spheroidal graphite cast-iron Piston Casting be cooled to 600~750 DEG C, from aqueous solvent cooling medium take out;E, spheroidal graphite cast-iron Piston Casting is placed in air, natural cooling;G, the spheroidal graphite cast-iron Piston Casting after air cooling to room temperature is carried out temper, it is thus achieved that the content of pearlite in alloy of spheroidal graphite cast-iron piston matrix spheroidal graphite cast-iron Piston Casting more than 90%.The Technology for Heating Processing of the nodular iron casting that the present invention is complicated for structure, wall unevenness is even and content of pearlite in alloy requirement is high.

Description

Technology for Heating Processing of spheroidal graphite cast-iron Piston Casting and application thereof
Technical field
The present invention relates to Technology for Heating Processing of a kind of spheroidal graphite cast-iron Piston Casting and application thereof, belong to ductile cast iron casting heat treatment Technology field.
Background technology
Pearlite type spheroidal graphite cast-iron has higher-strength, wearability, low toughness, is suitable to the parts higher to requirement of strength, The structural member of vehicle is used widely.
The pearlite strengthening of conventional spheroidal graphite cast-iron generally uses normalizing process, i.e. after the austenitizing of G. Iron Castings, passes through The insulation of a period of time, after coming out of the stove immediately air cooling, air-cooled or mist is cold, making basic body transforms is pearlitic structrure, reaches to improve hard Degree, intensity and the effect of wearability.Ink cast iron normalizing heating-up temperature general control at 800~900 DEG C, too high normalizing temperature Degree can not increase pearlite fraction, causes austenite crystal thick on the contrary, makes carbon dissolve in the quantity of austenite too much, during cooling Easily separate out net secondary cementite at crystal boundary, make intensity and the degraded toughness of G. Iron Castings, and too low normalizing temperature cannot Obtain the austenite of uniformity.
Being the internal combustion engine of QT700-2 for material, its matrix content of pearlite in alloy requires >=90%, hardness requirement HB225~305, therefore spray need to be carried out the Technology for Heating Processing of pearlite strengthening.Due to spheroidal graphite cast-iron Piston Casting structure Complicated, wall thickness great disparity, and thick large part core cooling is extremely slow, additionally blowing or spray process easily occur blowing or The position, dead angle of spraying.Therefore traditional normalizing process, no matter air cooling, air-cooled or mist is cold, owing to its cooling capacity is the most limited, Make matrix medium pearlite content extremely unstable after spheroidal graphite cast-iron Piston Casting heat treatment, same foundry goods different parts with And cast(ing) surface is uneven with the content of pearlite in alloy of core, is mostly between 40% to 80%, it is impossible to meet high pearly-lustre The requirement of body burden.
Quenching is spheroidal graphite cast-iron austenitizing, at held for some time, then inserts in oil groove or other media, the most sufficiently fast Speed cools down, suppression pearlite and ferritic formation so that low temperature austenite is transformed into martensite below Ms point temperature, Obtain highest hardness.
And isothermal hardening be foundry goods heating is made its austenite homogenization after, be allowed to be as cold as soon bainite temperature range (260~ 400 DEG C), to put in the isothermal medium of temperature a little higher than Ms point, isothermal keeps certain time, generally in bath during insulation Between be 30~60min, be allowed to austenite and be changed into bainite, then take out and be placed in air cooling, although isothermal hardening energy It is suitable for cast shape complicated, deformation and the cracking of foundry goods can be prevented, but need the huge bath waiting thermohaline circulation to carry out accurately Temperature control, Equipment for Heating Processing is costly, and cost is the highest.
But use traditional quenching and same temperature hardening heat treatment technique, heat treatment is carried out for spheroidal graphite cast-iron Piston Casting, exists Problems with:
1, after heat treatment the matrix of spheroidal graphite cast-iron Piston Casting equal non-pearlite tissue, its tissue and performance with require phase Difference is very remote, not enough because of content of pearlite in alloy due to Piston Casting, causes Piston Casting annular groove portion faces high frequency after semifinishing Impewdance matching hardness generally less than required standard, reduces piston abrasion-proof performance.
2, complicated due to spheroidal graphite cast-iron Piston Casting structure, wall unevenness is even, quenching process deforms and the tendency that ftractures very Greatly, easily produce hardening flaw, cause spheroidal graphite cast-iron Piston Casting qualification rate to decline.
Summary of the invention
It is an object of the invention to provide a kind of heat treatment low cost, the content of pearlite in alloy of spheroidal graphite cast-iron piston matrix can be stablized Ensure the Technology for Heating Processing of spheroidal graphite cast-iron Piston Casting more than 90%.
The present invention is that the technical scheme reaching above-mentioned purpose is: the Technology for Heating Processing of a kind of spheroidal graphite cast-iron Piston Casting, its feature It is: according to the following steps,
A kind of Technology for Heating Processing of spheroidal graphite cast-iron Piston Casting, it is characterised in that: according to the following steps,
A, the spheroidal graphite cast-iron Piston Casting that will be in room temperature load electric furnace, and are heated to 620~680 DEG C, are incubated 1~2h, Spheroidal graphite cast-iron Piston Casting is preheated, makes spheroidal graphite cast-iron Piston Casting equalizing temperature;
B, again spheroidal graphite cast-iron Piston Casting is heated to 920 ± 10 DEG C, is incubated 2 ± 0.5h, makes spheroidal graphite cast-iron Piston Casting base Body is completely reformed into austenite homogenization;
C, spheroidal graphite cast-iron Piston Casting is cooled to 850~880 DEG C, is incubated 1 ± 0.1h;
D, spheroidal graphite cast-iron Piston Casting is come out of the stove after put into rapidly in aqueous solvent cooling medium, chilling period control 10~ 20s, makes spheroidal graphite cast-iron Piston Casting be cooled to 600~750 DEG C, takes out from aqueous solvent cooling medium;
E, spheroidal graphite cast-iron Piston Casting is placed in air, natural cooling;
G, finally the spheroidal graphite cast-iron Piston Casting after air cooling to room temperature is carried out temper, it is thus achieved that spheroidal graphite cast-iron piston matrix The content of pearlite in alloy of tissue spheroidal graphite cast-iron Piston Casting more than 90%.
Wherein: in b walks, spheroidal graphite cast-iron Piston Casting is heated to 920 ± 5 DEG C, it is incubated 2h.
Described in c walks, spheroidal graphite cast-iron Piston Casting is cooled to 860~870 DEG C, is incubated 1h.
Described in d walks, spheroidal graphite cast-iron Piston Casting is put into rapidly in aqueous solvent cooling medium after coming out of the stove, and chilling period exists 12~18s, make spheroidal graphite cast-iron Piston Casting be cooled to 650~720 DEG C.
The temperature of described aqueous solvent cooling medium is at 20 DEG C ± 15 DEG C.
The temperature of described temper is 550~620 DEG C, is incubated 2~4h, air cooling of coming out of the stove afterwards.
The purposes of the instantaneous quenching technical of spheroidal graphite cast-iron Piston Casting of the present invention, it is characterised in that: it is used for obtaining spheroidal graphite cast-iron and lives The content of pearlite in alloy of plug matrix spheroidal graphite cast-iron Piston Casting more than 90%.
Spheroidal graphite cast-iron Piston Casting is first carried out the pre-heat treatment in the heat temperature raising stage by the present invention, is heated to from room temperature by foundry goods 620~680 DEG C of insulations 1~2h, owing to spheroidal graphite cast-iron is more slow at cryogenic conditions heat transfer rate, are allowed to by the pre-heat treatment Being heated evenly of each position of foundry goods.The spheroidal graphite cast-iron Piston Casting that the present invention is complicated by structure, wall unevenness is even is carried out at preheating Reason energy, can reduce the thermal stress of spheroidal graphite cast-iron Piston Casting, prevents casting deformation, solves spheroidal graphite cast-iron Piston Casting direct By producing bigger thermal stress when being warming up to austenitizing temperature, the problem of casting portion structure gross distortion will be caused.
The present invention is by after spheroidal graphite cast-iron Piston Casting preheating insulation 1~2h, then is warmed up to 920 ± 10 DEG C, is incubated 2 ± 0.5h, Being down to 850~880 DEG C of insulation 1h again, after spheroidal graphite cast-iron Piston Casting reaches austenitizing temperature, insulation guarantees that foundry goods is complete Austenite homogenization, simultaneously because spheroidal graphite cast-iron Piston Casting be heated to 920 ± 10 DEG C be incubated after, also make foundry goods matrix It is completely reformed into austenite homogenization, eliminates cementite.
The present invention uses quickly cooling, makes spheroidal graphite cast-iron Piston Casting top layer and core temperature be rapidly decreased to 600~750 DEG C, Accelerate austenite eutectoid reaction by quickly cooling, restrained effectively C in austenite and spread in globular graphite and free ferrum The precipitation of ferritic, is carried out so that diffused eutectoid reaction forms direction to pearlite.Simultaneously cooling under conditions of rapidly also Same foundry goods different parts, cast(ing) surface to core can be made all to reach austenite transformation temperature, thus ensure that foundry goods is each Position all reaches the content of pearlite in alloy of more than 90%, it is ensured that cast(ing) surface and the uniformity of core matrix, refines pearlite, Improve spheroidal graphite cast-iron Piston Casting intensity.The present invention uses quickly cooling, and by the temperature before cooling by 920 DEG C ± 10 DEG C It is reduced to 850~880 DEG C, the stress produced when significantly reducing quickly cooling, make spheroidal graphite cast-iron Piston Casting depart from water-soluble Agent cooling medium, to natural cooling, prevents stress excessive the most further and causes deformation and the cracking of spheroidal graphite cast-iron Piston Casting Problem, improve Piston Casting heat treatment qualification rate.The present invention can use existing common Equipment for Heating Processing, it is not necessary to special Equipment, heat treatment low cost.
Accompanying drawing explanation
Below in conjunction with the accompanying drawings embodiments of the invention are described in further detail.
Fig. 1 is the heat treatment cycle curve figure of spheroidal graphite cast-iron Piston Casting of the present invention.
Fig. 2 is that existing spherical iron piston uses the Technology for Heating Processing of conventional normalizing to obtain matrix (500X).
Fig. 3 is that spheroidal graphite cast-iron Piston Casting uses the Technology for Heating Processing of the present invention to obtain matrix (100X).
Fig. 4 is that spheroidal graphite cast-iron Piston Casting uses the Technology for Heating Processing of the present invention to obtain matrix (500X).
Detailed description of the invention
As shown in Figure 1, the Technology for Heating Processing of the spheroidal graphite cast-iron Piston Casting of the present invention, according to the following steps,
A, the spheroidal graphite cast-iron Piston Casting that will be in room temperature load electric furnace, and are heated to 620~680 DEG C, are incubated 1~2h, Logical spheroidal graphite cast-iron Piston Casting is preheated, makes spheroidal graphite cast-iron Piston Casting equalizing temperature, by complicated to structure, The even spheroidal graphite cast-iron Piston Casting of wall unevenness carries out the pre-heat treatment, the effective thermal stress reducing spheroidal graphite cast-iron Piston Casting, Prevent Piston Casting from deforming.The present invention is shown in Table 1 institute to the specific embodiment of spheroidal graphite cast-iron Piston Casting preheating temperature and time Show.
Table 1
Project Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6 Embodiment 7 Embodiment 8
Temperature (DEG C) 630 640 650 660 665 670 675 680
Time (h) 2 1.8 1.6 1.5 1.5 1.2 1.2 1
B, again spheroidal graphite cast-iron Piston Casting is heated to 920 ± 10 DEG C, is incubated 2 ± 0.5h, makes spheroidal graphite cast-iron Piston Casting base Body is completely reformed into austenite homogenization, eliminates carbide, preferably spheroidal graphite cast-iron Piston Casting and is heated to 920 ± 5 DEG C, Insulation 2h, can use constant-speed heating.The specific embodiment of spheroidal graphite cast-iron Piston Casting acid extraction is shown in by the present invention Shown in table 2.
Table 2
Project Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6 Embodiment 7 Embodiment 8
Temperature (DEG C) 910 915 915 920 925 930 910 930
Time (h) 2.5 2.2 2 2 1.5 2 1.8 1.5
C, spheroidal graphite cast-iron Piston Casting is cooled to 850~880 DEG C, is incubated 1 ± 0.1h, preferably spheroidal graphite cast-iron Piston Casting It is cooled to 860~870 DEG C, is incubated 1h, the stress produced during to reduce quickly cooling.The present invention is to spheroidal graphite cast-iron Piston Casting The specific embodiment of cooling temperature and time is shown in Table 3.
Table 3
Project Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6 Embodiment 7 Embodiment 8
Temperature (DEG C) 850 860 865 870 868 870 880 875
Time (h) 1.1 1 1 1 1 0.95 0.9 0.95
D, spheroidal graphite cast-iron Piston Casting is come out of the stove after put into rapidly in aqueous solvent cooling medium, chilling period control 10~ 20s, makes spheroidal graphite cast-iron Piston Casting be cooled to 600~750 DEG C, takes out from aqueous solvent cooling medium, and solvent of the present invention is cold But the temperature of medium is at 20 DEG C ± 15 DEG C, makes the temperature of aqueous solvent cooling medium be maintained under room temperature environment, and the present invention passes through Quickly cooling is with austenite eutectoid reaction in acceleration matrix, it is suppressed that in austenite, C spreads and free ferrum element in globular graphite The precipitation of body, thus increase pearlite fraction, and refine pearlite, improve intensity, also solve because cooling stress is excessive simultaneously And cause the problem that foundry goods ftractures.The best chilling period of the present invention controls in the 12~18s temperature making spheroidal graphite cast-iron Piston Casting It is down to 650~720 DEG C, takes out from aqueous solvent cooling medium, have more and fixed in spheroidal graphite cast-iron Piston Casting can be made Pearlite fraction, the pearlite fraction in spheroidal graphite cast-iron Piston Casting matrix is more than 95%, and the spheroidal graphite cast-iron piston of the present invention is cast The chilling temperature of part can be obtained by thermometric, the aqueous solvent cooling medium of the present invention can use PAG coolant or Aqua-Quench 251 Water Soluble Cooling Liquid.The cool time of spheroidal graphite cast-iron Piston Casting of the present invention and being embodied as of temperature Example is shown in Table 4.
Table 4
E, spheroidal graphite cast-iron Piston Casting is placed in air, natural cooling, Piston Casting can be placed in void spaces and carry out sky Cold.
G, finally the spheroidal graphite cast-iron Piston Casting after air cooling to room temperature is carried out temper, to obtain spheroidal graphite cast-iron piston base The content of pearlite in alloy of soma spheroidal graphite cast-iron Piston Casting more than 90%, by temper to improve spheroidal graphite cast-iron piston Toughness and eliminate stress, the tempering process of the present invention, its temperature is 550~620 DEG C, be incubated 2~4h, go out afterwards Stove air cooling.The specific embodiment of temper of the present invention is shown in Table 5.
Table 5
Project Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6 Embodiment 7 Embodiment 8
Temperature (DEG C) 550 560 570 580 590 600 610 620
Time (h) 4 3 3.5 2.5 2.1 2.2 2.2 2
The spheroidal graphite cast-iron Piston Casting of the present invention is QT700-2 spheroidal graphite cast-iron, and chemical composition is joined and is by mass percentage: 3.7%C, 2.5%Si, 0.48%Mn, 0.6%Cu ,≤0.08%P ,≤0.02%S, with medium-frequency induction furnace melting the general of 3t Base iron is through sufficient nodularization and breeds, and nodulizing grade is 2 grades, and sphere diameter size rank is 6 grades, and matrix is 55% Ferrite+pearlite, tensile strength Rm is 582Mpa, it is stipulated that plasticity prolongs raw intensity Rp0.2For 401Mpa, have no progeny and stretch Long rate is the spheroidal graphite cast-iron Piston Casting of 7%.Spheroidal graphite cast-iron Piston Casting after the heat treatment of the present invention, according to GB/T9441-2009 and GB/T228.1-2010 and have GB/T231.1-2009 standard-required to make sample, and to each reality The sample executing example is tested, and each specific performance index is shown in Table 6,
Table 6
The purposes of the instantaneous quenching technical of spheroidal graphite cast-iron Piston Casting of the present invention, for obtaining spheroidal graphite cast-iron piston matrix Content of pearlite in alloy spheroidal graphite cast-iron Piston Casting more than 90%.
It can be seen that the Technology for Heating Processing of the spheroidal graphite cast-iron Piston Casting for preparing of the present invention and conventional normalizing obtains from Fig. 2~4 Comparing to matrix, the present invention can obtain and fully meet the requirement of QT700-2 material and the spheroidal graphite of more than 90% pearlite requirement Cast-iron piston foundry goods.The Technology for Heating Processing of the present invention cannot be only used for spheroidal graphite cast-iron Piston Casting, it may also be used for other structure is multiple Miscellaneous ductile cast iron casting.

Claims (7)

1. the Technology for Heating Processing of a spheroidal graphite cast-iron Piston Casting, it is characterised in that: according to the following steps,
A, the spheroidal graphite cast-iron Piston Casting that will be in room temperature load electric furnace, and are heated to 620~680 DEG C, are incubated 1~2h, Spheroidal graphite cast-iron Piston Casting is preheated, makes spheroidal graphite cast-iron Piston Casting equalizing temperature;
B, again spheroidal graphite cast-iron Piston Casting is heated to 920 ± 10 DEG C, is incubated 2 ± 0.5h, makes spheroidal graphite cast-iron Piston Casting base Body is completely reformed into austenite homogenization;
C, spheroidal graphite cast-iron Piston Casting is cooled to 850~880 DEG C, is incubated 1 ± 0.1h;
D, spheroidal graphite cast-iron Piston Casting is come out of the stove after put into rapidly in aqueous solvent cooling medium, chilling period control 10~ 20s, makes spheroidal graphite cast-iron Piston Casting be cooled to 600~750 DEG C, takes out from aqueous solvent cooling medium;
E, spheroidal graphite cast-iron Piston Casting is placed in air, natural cooling;
G, finally the spheroidal graphite cast-iron Piston Casting after air cooling to room temperature is carried out temper, it is thus achieved that spheroidal graphite cast-iron piston matrix The content of pearlite in alloy of tissue spheroidal graphite cast-iron Piston Casting more than 90%.
The Technology for Heating Processing of spheroidal graphite cast-iron Piston Casting the most according to claim 1, it is characterised in that: in b walks, Spheroidal graphite cast-iron Piston Casting is heated to 920 ± 5 DEG C, is incubated 2h.
The Technology for Heating Processing of spheroidal graphite cast-iron Piston Casting the most according to claim 1, it is characterised in that: described at c In step, spheroidal graphite cast-iron Piston Casting is cooled to 860~870 DEG C, is incubated 1h.
The Technology for Heating Processing of spheroidal graphite cast-iron Piston Casting the most according to claim 1, it is characterised in that: described at d In step, spheroidal graphite cast-iron Piston Casting is put into rapidly in aqueous solvent cooling medium after coming out of the stove, and chilling period, 12~18s, makes ball Ink cast-iron piston foundry goods is cooled to 650~720 DEG C.
The Technology for Heating Processing of spheroidal graphite cast-iron Piston Casting the most according to claim 1, it is characterised in that: described water-soluble The temperature of agent cooling medium is at 20 DEG C ± 15 DEG C.
The Technology for Heating Processing of spheroidal graphite cast-iron Piston Casting the most according to claim 1, it is characterised in that: described returns The temperature that fire processes is 550~620 DEG C, is incubated 2~4h, air cooling of coming out of the stove afterwards.
The purposes of the Technology for Heating Processing of spheroidal graphite cast-iron Piston Casting the most according to claim 1, it is characterised in that: use In the content of pearlite in alloy spheroidal graphite cast-iron Piston Casting more than 90% obtaining spheroidal graphite cast-iron piston matrix.
CN201410113626.3A 2014-03-25 Technology for Heating Processing of spheroidal graphite cast-iron Piston Casting and application thereof Active CN103937945B (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5789423A (en) * 1980-11-26 1982-06-03 Kubota Ltd Heat treatment of spherical graphite cast iron pipe
JPH036319A (en) * 1989-05-31 1991-01-11 Otai Iron Works Co Ltd Method and device for remelting and hardening of cast iron casting
CN1088997A (en) * 1992-12-30 1994-07-06 华东工学院 The thermal treatment process of low-alloy spheroidal graphite cast-iron and foundry goods thereof
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CN102978360A (en) * 2012-12-29 2013-03-20 滨州海得曲轴有限责任公司 Heat treatment process for QT850-5 nodular cast iron
CN103451393A (en) * 2013-08-19 2013-12-18 宁国市华丰耐磨材料有限公司 Heat treatment process of austempered ductile iron grinding balls

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5789423A (en) * 1980-11-26 1982-06-03 Kubota Ltd Heat treatment of spherical graphite cast iron pipe
JPH036319A (en) * 1989-05-31 1991-01-11 Otai Iron Works Co Ltd Method and device for remelting and hardening of cast iron casting
CN1088997A (en) * 1992-12-30 1994-07-06 华东工学院 The thermal treatment process of low-alloy spheroidal graphite cast-iron and foundry goods thereof
CN1827795A (en) * 2004-03-01 2006-09-06 株式会社小松制作所 Ferrous seal sliding parts and producing method thereof
CN102978360A (en) * 2012-12-29 2013-03-20 滨州海得曲轴有限责任公司 Heat treatment process for QT850-5 nodular cast iron
CN103451393A (en) * 2013-08-19 2013-12-18 宁国市华丰耐磨材料有限公司 Heat treatment process of austempered ductile iron grinding balls

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