CN103937543A - Decoloring and deodorizing method of pyrolysis oil of waste tyres - Google Patents

Decoloring and deodorizing method of pyrolysis oil of waste tyres Download PDF

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Publication number
CN103937543A
CN103937543A CN201410159427.6A CN201410159427A CN103937543A CN 103937543 A CN103937543 A CN 103937543A CN 201410159427 A CN201410159427 A CN 201410159427A CN 103937543 A CN103937543 A CN 103937543A
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CN
China
Prior art keywords
oil
pyrolysis oil
refining
cracked oil
sorbent
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Pending
Application number
CN201410159427.6A
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Chinese (zh)
Inventor
王康洲
邱碧宁
韩笑
张翔
李婉宁
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Shenyang University of Chemical Technology
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Shenyang University of Chemical Technology
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Publication date
Application filed by Shenyang University of Chemical Technology filed Critical Shenyang University of Chemical Technology
Priority to CN201410159427.6A priority Critical patent/CN103937543A/en
Publication of CN103937543A publication Critical patent/CN103937543A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a decoloring and deodorizing method of pyrolysis oil of waste tyres, and relates to a method of preparing pyrolysis oil. The method comprises the following steps: first, pre-treating the pyrolysis oil of waste tyres; them, mixing the pyrolysis oil with an adsorbent in proportion; heating the mixture to a certain temperature, and continuously stirring for a certain time at the temperature; then, entering into a filter device to separate the oil and the adsorbent; after regenerating filter residues, re-using the oil; distilling and refining the filtrate; and refining for a certain time to obtain a light component which is the product. The method can remove nitrides and non-ideal components such as other thiol and thioether in oil so as to improve the oxidizing stability of the oil. The pyrolysis oil treatment is simple in process, low in cost, easy to operate, simple in post-treatment and less in environmental pollution.

Description

The method of the decolouring of junked tire cracked oil, deodorization
technical field
The present invention relates to method prepared by cracked oil, particularly relate to the method for the decolouring of junked tire cracked oil, deodorization.
Background technology
Work the mischief to environment taking junked tire as the increase suddenly of main waste rubber goods at present, very important stage has been arrived in the recycling of junked tire and utilization.Industrial expansion needs increasing fuel and Chemicals, but global fixed resource is limited, so advocate recycling economy, realizes utilization of waste as resource, and it is very effective aspect addressing this problem that damaged tire cracking produces oil.Can be by waste tyre pyrolytic oil and petroleum crude oil are carried out to comparative study, realized comprehensive and reasonable and utilized the object of solid waste to seek a kind of reasonable approach.Some thermal treatment units are set up both at home and abroad, as adopted vulcanization bed or revolving brickkiln etc.
Although damaged tire cracking oil product out can directly use, because its color is crossed dark and gives an offensive smell, can bring inconvenience to user.Therefore can take decoloration and deodorization refining, remove sulphur hydrogen peculiar smell, and remove oxidation sediment, colloid, makes pitch black, muddy oil product become as clear as crystal, improves oil product outward appearance, transparency, purity, reaches higher use standard, improves economic worth.
At present, the main method of processing damaged tire cracked oil has hydrofining, acid-alkali refining and quadric catalysis refining, wherein these several refining losses that all can nearly 10%, because the sulfide wherein containing mainly exists with sulphur, hydrogen sulfide, mercaptan, thioether, these sulphur are all called active sulphur, wherein mercaptan accounts for 60% left and right, and in quadric catalysis cracking, mercaptan also can make poisoning of catalyst, affects refining effect.
Summary of the invention
The object of the invention is to propose a kind of method of junked tire cracked oil decolouring, deodorization, this law processing cracked oil technique is simple, cost is low, easy to operate, last handling process is easy, environmental pollution is little.
The object of the invention is to be achieved through the following technical solutions:
The method of the decolouring of junked tire cracked oil, deodorization, the method comprises following process:
First cracked oil is carried out to pre-treatment, then cracked oil and sorbent material are mixed in proportion, mixture heating, and at this temperature continuously stirring, then enter filtration unit, oil product is separated with sorbent material, after filter residue regeneration, can reuse, filtrate is distilled refining, gets light constituent and be product after refining.
Described junked tire cracked oil decolouring, the method for deodorization, its temperature of reaction is 30-100 DEG C.
Described junked tire cracked oil decolouring, the method for deodorization, its reaction times is 10 minutes-150 minutes.
Advantage of the present invention and effect are:
The sorbent used method for refining of the present invention, in decolouring, deodorization, does not need High Temperature High Pressure, has reduced the requirement to equipment intensity, and equipment is simple, cost is low, easy to operate, last handling process is easy, environmental pollution is little, better economic benefit.
Brief description of the drawings
Fig. 1 is technological process block-diagram of the present invention.
Embodiment
Below in conjunction with embodiment, the present invention is described in detail.
The present invention relates to be utilize sorbent material to the stronger adsorption of polar compound to junked tire cracked oil decolour, deodorizing and refining, remove the imperfect compositions such as nitride in oil product and other mercaptan, thioether, to improve the oxidative stability of oil product; Its sorbent material is general molecular sieve.
Embodiment 1:
Be 2:50 by sorbent material and cracked oil by agent-oil ratio, measure respectively and get 10 grams, sorbent material, 250 milliliters of cracked oils, add in 500 ml beakers in the water bath with thermostatic control that is placed on 40 DEG C, stir after 100 minutes standing sedimentation, filter, filtrate is put into 500 ml flasks, adds thermal distillation in electric food warmer, obtains the product of light constituent.Recording product colourity is 11, and absorbancy is 2.480.
Embodiment 2:
Be 3:50 by sorbent material and cracked oil by agent-oil ratio, measure respectively and get 12 grams, sorbent material, 200 milliliters of cracked oils, add in 500 ml beakers in the water bath with thermostatic control that is placed on 40 DEG C, stir after 120 minutes standing sedimentation, filter, filtrate is put into 500 ml flasks, adds thermal distillation in electric food warmer, obtains the product of light constituent.Recording product colourity is 8, and absorbancy is 2.003.
Embodiment 3:
Be 3:50 by sorbent material and cracked oil by agent-oil ratio, measure respectively and get 12 grams, sorbent material, 200 milliliters of cracked oils, add in 500 ml beakers in the water bath with thermostatic control that is placed on 60 DEG C, stir after 100 minutes standing sedimentation, filter, filtrate is put into 500 ml flasks, adds thermal distillation in electric food warmer, obtains the product of light constituent.Recording product colourity is 11, and absorbancy is 3.461.
Embodiment 4:
Be 2:50 by sorbent material and cracked oil by agent-oil ratio, measure respectively and get 10 grams, sorbent material, 250 milliliters of cracked oils, add in 500 ml beakers in the water bath with thermostatic control that is placed on 60 DEG C, stir after 120 minutes standing sedimentation, filter, filtrate is put into 500 ml flasks, adds thermal distillation in electric food warmer, obtains the product of light constituent.Recording product colourity is 8, and absorbancy is 2.003.

Claims (3)

1. the method for junked tire cracked oil decolouring, deodorization, is characterized in that: the method comprises following process:
First cracked oil is carried out to pre-treatment, then cracked oil and sorbent material are mixed in proportion, mixture heating, and at this temperature continuously stirring, then enter filtration unit, oil product is separated with sorbent material, after filter residue regeneration, can reuse, filtrate is distilled refining, gets light constituent and be product after refining.
2. the method for junked tire cracked oil decolouring according to claim 1, deodorization, is characterized in that: its temperature of reaction is 30-100 DEG C.
3. the method for junked tire cracked oil decolouring according to claim 1, deodorization, is characterized in that: its reaction times is 10 minutes-150 minutes.
CN201410159427.6A 2014-04-21 2014-04-21 Decoloring and deodorizing method of pyrolysis oil of waste tyres Pending CN103937543A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410159427.6A CN103937543A (en) 2014-04-21 2014-04-21 Decoloring and deodorizing method of pyrolysis oil of waste tyres

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410159427.6A CN103937543A (en) 2014-04-21 2014-04-21 Decoloring and deodorizing method of pyrolysis oil of waste tyres

Publications (1)

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CN103937543A true CN103937543A (en) 2014-07-23

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107227170A (en) * 2017-07-27 2017-10-03 华东理工大学 The system of sulfide in a kind of eddy flow reinforcing removing oil product
CN112011364A (en) * 2020-08-31 2020-12-01 广州世朗普力斯绿色环保科技有限公司 High-efficiency non-hydrodesulfurization method for waste tire pyrolysis oil

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1174881A (en) * 1996-05-23 1998-03-04 Ohmi研究和工程技术有限公司 Method and apparatus for adsorptive cleaning of substances
CN1488710A (en) * 2002-10-08 2004-04-14 蒋志山 Environmental-protection process for refining fuel oil from waste rubber (waste plastic or waste oil)
CN101597541A (en) * 2009-07-03 2009-12-09 豆远奎 Acid and alkali free quick regeneration method for waste oil
CN101768511A (en) * 2010-01-27 2010-07-07 卢玉胜 Low-temperature refining method for tea seed oil and refining adsorbent
CN101921612A (en) * 2009-06-15 2010-12-22 尉氏县挺凯植物胶化工厂有限公司 Method for decoloring and deodorizing diesel fuel oil and increasing yield
CN102311751A (en) * 2010-07-05 2012-01-11 青岛福安伯环保能源有限公司 Method for producing oil by degrading waste tires

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1174881A (en) * 1996-05-23 1998-03-04 Ohmi研究和工程技术有限公司 Method and apparatus for adsorptive cleaning of substances
CN1488710A (en) * 2002-10-08 2004-04-14 蒋志山 Environmental-protection process for refining fuel oil from waste rubber (waste plastic or waste oil)
CN101921612A (en) * 2009-06-15 2010-12-22 尉氏县挺凯植物胶化工厂有限公司 Method for decoloring and deodorizing diesel fuel oil and increasing yield
CN101597541A (en) * 2009-07-03 2009-12-09 豆远奎 Acid and alkali free quick regeneration method for waste oil
CN101768511A (en) * 2010-01-27 2010-07-07 卢玉胜 Low-temperature refining method for tea seed oil and refining adsorbent
CN102311751A (en) * 2010-07-05 2012-01-11 青岛福安伯环保能源有限公司 Method for producing oil by degrading waste tires

Non-Patent Citations (1)

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Title
死明师范学院化学系树脂组: "使用沸石分子筛对油脂脱色", 《油脂科技》, no. 5, 28 October 1982 (1982-10-28) *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107227170A (en) * 2017-07-27 2017-10-03 华东理工大学 The system of sulfide in a kind of eddy flow reinforcing removing oil product
CN110760332A (en) * 2017-07-27 2020-02-07 华东理工大学 System for removing sulfide in oil product through cyclone reinforcement
CN112011364A (en) * 2020-08-31 2020-12-01 广州世朗普力斯绿色环保科技有限公司 High-efficiency non-hydrodesulfurization method for waste tire pyrolysis oil

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Application publication date: 20140723

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