CN103937370A - Electrophoretic paint - Google Patents

Electrophoretic paint Download PDF

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Publication number
CN103937370A
CN103937370A CN201410153646.3A CN201410153646A CN103937370A CN 103937370 A CN103937370 A CN 103937370A CN 201410153646 A CN201410153646 A CN 201410153646A CN 103937370 A CN103937370 A CN 103937370A
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CN
China
Prior art keywords
product
electrocoating paint
ether
mass percent
pigment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410153646.3A
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Chinese (zh)
Inventor
彭德琼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUANGDE ZHONGYIN CHEMICAL CO Ltd
Original Assignee
GUANGDE ZHONGYIN CHEMICAL CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GUANGDE ZHONGYIN CHEMICAL CO Ltd filed Critical GUANGDE ZHONGYIN CHEMICAL CO Ltd
Priority to CN201410153646.3A priority Critical patent/CN103937370A/en
Publication of CN103937370A publication Critical patent/CN103937370A/en
Pending legal-status Critical Current

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Abstract

The invention provides an electrophoretic paint, comprising the following raw materials by weight percent: 95% of epoxy resin and 5% of special assistant for the electrophoretic paint. The 5% of special assistant for the electrophoretic paint is added to the 95% of epoxy resin, and the electrophoretic paint is prepared by adopting the existing mature technology and equipment, and the prepared product has a smooth and flat surface, and meanwhile, the dull and heavy surface of a paint film is avoided. Therefore, the requirements of the product are met.

Description

A kind of electrocoating paint
Technical field
The present invention relates to electrophoretic paint production field, be specifically related to a kind of electrocoating paint.
Background technology
Electrocoating paint is divided into ability cathode electrophoresis and anodic electrophoresis; electrophoretic paint as the novel low pollution of a class, economize the energy, resource-saving, rise and protect and the coating of non-corrosibility; there is smooth coating; the features such as water tolerance and chemical resistant properties are good; easily realize mechanize and the automatization of application industry; applicable complex-shaped, there are edge corner angle, hole Workpiece coating, be widely used at present the application of the handwares such as automobile, automatic vehicle, electromechanics, household electrical appliances.Electrophoretic paint and finishing obtain industrial application after the sixties in 20th century, adopt electrophoretic paint can carry out the operation of closed circulating system, and coating almost 100% utilizes.Electrophoretic paint is taking water-soluble or water dispersible Ionomer as film forming matter, and being coated with workpiece can be that anode also can be used as negative electrode; Existing coating surface unfairness, and surface ratio is more dull and heavy, does not reach attractive in appearance and practical requirement.
Summary of the invention
For above problems of the prior art, the invention provides a kind of electrocoating paint, make the surface ratio of product more smooth, avoided the dull and heavy of coating surface simultaneously.
The present invention is achieved by the following technical solutions:
A kind of electrocoating paint, formed by epoxy resin, electrocoating paint special assistant, compound alcohol ether, pigment and filler, the mass percent of wherein said epoxy resin is 75-81%, the mass percent of electrocoating paint special assistant is 4-5%, the mass percent of compound alcohol ether is 1%, the mass percent of pigment is 12-17%, and the mass percent of filler is 2%.
Electrocoating paint special assistant is propyl carbinol and compound alcohol ether, and the mass ratio of propyl carbinol and compound alcohol ether is 3:2.
Compound alcohol ether is propylene glycol monomethyl ether, butyl glycol ether |, Diethylene Glycol butyl ether or diethylene glycol dimethyl ether.
Pigment is carbon black or titanium dioxide; Filler is kaolin and matting agent.
Preparation method:
1) epoxy resin and electrocoating paint special assistant are mixed to thick, form work in-process;
2) use shredder to grind fully the work in-process in step 1 and compound alcohol ether, pigment and filler;
3) product after grinding fully in step 2 is mixed with water as required, obtain required finished product.
The temperature that step 1 stirs is 40-50 DEG C, and pressure is normal pressure.
Beneficial effect of the present invention is: in the epoxy resin that is 95% in mass percent, adding mass percent is 5% electrocoating paint special assistant, adopt existing proven technique equipment to be prepared, kaolin can suspend the product of grinding and be difficult for precipitation, therefore product can be kept to the state mixing, also more even in adhering to product; Therefore the product of preparing makes the surface ratio of product more smooth, has avoided the dull and heavy of coating surface simultaneously.
Embodiment
Below in conjunction with embodiment, the present invention is described in further details.
The invention provides a kind of electrocoating paint, formed by epoxy resin, electrocoating paint special assistant, compound alcohol ether, pigment and filler, the mass percent of wherein said epoxy resin is 75-81%, the mass percent of electrocoating paint special assistant is 4-5%, the mass percent of compound alcohol ether is 1%, the mass percent of pigment is 12-17%, and the mass percent of filler is 2%; Electrocoating paint special assistant is propyl carbinol and compound alcohol ether, and the mass ratio of propyl carbinol and compound alcohol ether is 3:2; Compound alcohol ether is propylene glycol monomethyl ether, butyl glycol ether |, Diethylene Glycol butyl ether or diethylene glycol dimethyl ether; Pigment is carbon black or titanium dioxide; Filler is kaolin and matting agent.
Preparation method:
1) epoxy resin and electrocoating paint special assistant are mixed to thick, form work in-process;
2) use shredder to grind fully the work in-process in step 1 and compound alcohol ether, pigment and filler;
3) product after grinding fully in step 2 is mixed with water as required, obtain required finished product.
The temperature that step 1 stirs is 40-50 DEG C, and pressure is normal pressure.
Embodiment mono-
Being prepared as of product:
1) be 3 kilograms by propyl carbinol, epoxy resin is 80 kilograms, and propylene glycol monomethyl ether is 2 kilograms, mix mix to thick, form work in-process;
2) use shredder to grind fully with the propylene glycol monomethyl ether of 1 kilogram, pigment and 2 kilograms of fillers of 12 kilograms 85 kilograms of the work in-process in step 1;
3) product after grinding fully in step 2 is mixed with water as required, obtain required finished product.
Kaolin in step 2 can suspend the product of grinding and be difficult for precipitation, therefore product can be kept to the state mixing, also more even in adhering to product; Therefore the product of preparing makes the surface ratio of product more smooth, has avoided the dull and heavy of coating surface simultaneously, has therefore just met the requirement of product.
Embodiment bis-
Being prepared as of product:
1) be 3 kilograms by propyl carbinol, epoxy resin is 75 kilograms, and butyl glycol ether is 2 kilograms, mix mix to thick, form work in-process;
2) 80 kilograms of the work in-process in step 1 are ground fully with 1 kilogram of butyl glycol ether, 17 kilograms of pigment and 2 kilograms of use shredders of filler;
3) product after grinding fully in step 2 is mixed with water, obtain required finished product.
Kaolin in step 2 can suspend the product of grinding and be difficult for precipitation, therefore product can be kept to the state mixing, also more even in adhering to product; Therefore the product of preparing makes the surface ratio of product more smooth, has avoided the dull and heavy of coating surface simultaneously, has therefore just met the requirement of product.
Embodiment tri-
Being prepared as of product: propyl carbinol is 3 kilograms, epoxy resin is 78 kilograms, Diethylene Glycol butyl ether is 2 kilograms, mix mix to thick, form work in-process;
2) 50.000 kilograms of the work in-process in step 1 are ground fully with 1 kilogram of Diethylene Glycol butyl ether, 14 kilograms of pigment and 2 kilograms of use shredders of filler;
3) product after grinding fully in step 2 is mixed with water, obtain required finished product.
Kaolin in step 2 can suspend the product of grinding and be difficult for precipitation, therefore product can be kept to the state mixing, also more even in adhering to product; Therefore the product of preparing makes the surface ratio of product more smooth, has avoided the dull and heavy of coating surface simultaneously, has therefore just met the requirement of product.
Embodiment tetra-
Being prepared as of product: propyl carbinol is 2.7 kilograms, epoxy resin is 77 kilograms, diethylene glycol dimethyl ether is 1.8 kilograms, mix mix to thick, form work in-process;
2) 81.5 kilograms of the work in-process in step 1 are ground fully with 1 kilogram of diethylene glycol dimethyl ether, 15.5 kilograms of pigment and 2 kilograms of use shredders of filler;
3) product after grinding fully in step 2 is mixed with water, obtain required finished product.
Kaolin in step 2 can suspend the product of grinding and be difficult for precipitation, therefore product can be kept to the state mixing, also more even in adhering to product; Therefore the product of preparing makes the surface ratio of product more smooth, has avoided the dull and heavy of coating surface simultaneously, has therefore just met the requirement of product.
Embodiment five
Being prepared as of product: propyl carbinol is 3 kilograms, epoxy resin is 76 kilograms, Diethylene Glycol butyl ether is 2 kilograms, mix mix to thick, form work in-process;
2) 81 kilograms of the work in-process in step 1 are ground fully with 1 kilogram of Diethylene Glycol butyl ether, 16 kilograms of pigment and 2 kilograms of use shredders of filler;
3) product after grinding fully in step 2 is mixed with water, obtain required finished product.
Kaolin in step 2 can suspend the product of grinding and be difficult for precipitation, therefore product can be kept to the state mixing, also more even in adhering to product; Therefore the product of preparing makes the surface ratio of product more smooth, has avoided the dull and heavy of coating surface simultaneously, has therefore just met the requirement of product.
In the epoxy resin that the present invention is 95% in mass percent, adding mass percent is 5% electrocoating paint special assistant, adopt existing proven technique equipment to be prepared, kaolin can suspend the product of grinding and be difficult for precipitation, therefore product can be kept to the state mixing, also more even in adhering to product; Therefore the product of preparing makes the surface ratio of product more smooth, has avoided the dull and heavy of coating surface simultaneously.

Claims (6)

1. an electrocoating paint, it is characterized in that: formed by epoxy resin, electrocoating paint special assistant, compound alcohol ether, pigment and filler, the mass percent of wherein said epoxy resin is 75-81%, the mass percent of electrocoating paint special assistant is 4-5%, the mass percent of compound alcohol ether is 1%, the mass percent of pigment is 12-17%, and the mass percent of filler is 2%.
2. a kind of electrocoating paint according to claim 1, is characterized in that: electrocoating paint special assistant is propyl carbinol and compound alcohol ether, and the mass ratio of propyl carbinol and compound alcohol ether is 3:2.
3. a kind of electrocoating paint according to claim 1, is characterized in that: compound alcohol ether is propylene glycol monomethyl ether, butyl glycol ether |, Diethylene Glycol butyl ether or diethylene glycol dimethyl ether.
4. a kind of electrocoating paint according to claim 1, is characterized in that: pigment is carbon black or titanium dioxide; Filler is kaolin and matting agent.
5. the preparation method of a kind of electrocoating paint according to claim 1, is characterized in that: preparation method:
1) epoxy resin and electrocoating paint special assistant are mixed to thick, form work in-process;
2) use shredder to grind fully the work in-process in step 1 and compound alcohol ether, pigment and filler;
3) product after grinding fully in step 2 is mixed with water as required, obtain required finished product.
6. the preparation method of a kind of electrocoating paint according to claim 4, is characterized in that: the temperature that step 1 stirs is 40-50 DEG C, and pressure is normal pressure.
CN201410153646.3A 2014-04-16 2014-04-16 Electrophoretic paint Pending CN103937370A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410153646.3A CN103937370A (en) 2014-04-16 2014-04-16 Electrophoretic paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410153646.3A CN103937370A (en) 2014-04-16 2014-04-16 Electrophoretic paint

Publications (1)

Publication Number Publication Date
CN103937370A true CN103937370A (en) 2014-07-23

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CN201410153646.3A Pending CN103937370A (en) 2014-04-16 2014-04-16 Electrophoretic paint

Country Status (1)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104893395A (en) * 2015-06-05 2015-09-09 浩力森涂料(上海)有限公司 Cathode electrophoresis paint
CN106634443A (en) * 2016-12-29 2017-05-10 重庆博延汽车部件制造有限公司 Formula and preparation process of electrophoretic paint
CN107641392A (en) * 2017-09-29 2018-01-30 江苏皓月涂料有限公司 A kind of electrophoresis paint for priming paint and top lacquer
CN107987705A (en) * 2017-12-18 2018-05-04 枣阳市旺前电泳涂料有限公司 A kind of cathode electrodip painting
CN108546974A (en) * 2018-06-06 2018-09-18 佛山市南海区大沥永太五金丝网制品有限公司 A kind of steel wire electrophoresis formula of liquid and technological process
CN109127962A (en) * 2018-09-12 2019-01-04 佛山市南海区大沥永太五金丝网制品有限公司 A kind of steel wire electrophoresis formula of liquid and process flow

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5559174A (en) * 1988-12-22 1996-09-24 Basf Corporation Electrocoating composition of a polyamine self-condensed epoxy adduct and coatings produced thereby
CN1167794A (en) * 1996-06-12 1997-12-17 神东涂料株式会社 Resin composition for cationic electrodeposition coating
CN102702925A (en) * 2012-06-20 2012-10-03 南通优尼科化工有限公司 Cationoid epoxy electrophoretic paint
CN102942835A (en) * 2012-11-21 2013-02-27 广东科德化工实业有限公司 High throwing power cathode electrophoresis paint and preparation method and using method thereof
CN103059694A (en) * 2012-12-28 2013-04-24 大连金洁建筑材料科技发展有限公司 Anodic electrophoretic coating

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5559174A (en) * 1988-12-22 1996-09-24 Basf Corporation Electrocoating composition of a polyamine self-condensed epoxy adduct and coatings produced thereby
CN1167794A (en) * 1996-06-12 1997-12-17 神东涂料株式会社 Resin composition for cationic electrodeposition coating
CN102702925A (en) * 2012-06-20 2012-10-03 南通优尼科化工有限公司 Cationoid epoxy electrophoretic paint
CN102942835A (en) * 2012-11-21 2013-02-27 广东科德化工实业有限公司 High throwing power cathode electrophoresis paint and preparation method and using method thereof
CN103059694A (en) * 2012-12-28 2013-04-24 大连金洁建筑材料科技发展有限公司 Anodic electrophoretic coating

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
刘益军: "《聚氨酯原料及助剂手册 第二版》", 31 January 2013, 化学工业出版社 *
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104893395A (en) * 2015-06-05 2015-09-09 浩力森涂料(上海)有限公司 Cathode electrophoresis paint
CN106634443A (en) * 2016-12-29 2017-05-10 重庆博延汽车部件制造有限公司 Formula and preparation process of electrophoretic paint
CN107641392A (en) * 2017-09-29 2018-01-30 江苏皓月涂料有限公司 A kind of electrophoresis paint for priming paint and top lacquer
CN107987705A (en) * 2017-12-18 2018-05-04 枣阳市旺前电泳涂料有限公司 A kind of cathode electrodip painting
CN108546974A (en) * 2018-06-06 2018-09-18 佛山市南海区大沥永太五金丝网制品有限公司 A kind of steel wire electrophoresis formula of liquid and technological process
CN109127962A (en) * 2018-09-12 2019-01-04 佛山市南海区大沥永太五金丝网制品有限公司 A kind of steel wire electrophoresis formula of liquid and process flow

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Application publication date: 20140723

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