CN103931634B - Containing herbicide and the purposes of penoxsuam - Google Patents
Containing herbicide and the purposes of penoxsuam Download PDFInfo
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- CN103931634B CN103931634B CN201410125764.3A CN201410125764A CN103931634B CN 103931634 B CN103931634 B CN 103931634B CN 201410125764 A CN201410125764 A CN 201410125764A CN 103931634 B CN103931634 B CN 103931634B
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Abstract
The present invention relates to herbicide field, specifically, relate to a kind of rice terrace herbicides special that contains penoxsuam, comprise active component penoxsuam, symetryne and 2 first 4 chlorine or derivatives thereofs, the weight ratio of three kinds of active components is: penoxsuam: symetryne: 2 first 4 chlorine or derivatives thereof=1～10:1～50:1～50; Herbicide activity of weeding of the present invention significantly improves, and amount of application reduces simultaneously, has wider weeds control spectrum, and prevention effect is more lasting; Environmental protection more, amount of application is few, is easy to degraded, safe to succession crop, and lasting medicine.
Description
Technical field
The present invention relates to herbicide field, specifically, relate to a kind of rice terrace that contains penoxsuam specialUse herbicide.
Background technology
Using chemical herbicide is the most effective means during farmland weed is prevented and kill off, but long-term, continuous high doseThe chemical herbicide of using single variety or the single mode of action, easily cause weeds resistance and resistance development,And the herbicide weeding narrow range of single-activity component, chronic administration weighting ring environment pollution, and developing new product varietyHerbicide also can make the problems referred to above go round and begin again, simultaneously developing new product variety herbicide cost is constantly soaring. PhaseThan under, exploitation is efficient, the composite and mixture kind of low toxicity, low-residual has small investment, the lead time is shortEtc. advantage, be subject to domestic and international scientific research person's attention.
Summary of the invention
For addressing the above problem, the invention provides a kind of rice field weeding containing penoxsuam of efficient, environmental protectionAgent, and for the purposes of killing weeds in rice field.
Herbicide containing penoxsuam of the present invention, comprise active component penoxsuam, symetryne withAnd containing the compound (2 first 4 chlorine or derivatives thereofs) of formula (I) structure, the weight ratio of three kinds of active components is:Penoxsuam: symetryne: formula (I) structural compounds=1～10:1～50:1～50;
Wherein, R is-COOH ,-COONa ,-COOK ,-C2H4COOH、-COON(CH3)2、-COOC4H9、-COOC8H17、-COOC2H4OC4H9、-COON(CH2CH2OH)2、-COOC3H7、-COOCH3、-COONH2C2H4OH、-COSC2H5、 -COOC2H4N(CH2CH2OH)2、-COOC8H19；
X is-H or-CH3。
Preferably, the weight ratio of three kinds of described active components is: penoxsuam: symetryne: formula (I)Structural compounds=1～10:1～30:1～30.
Preferably, the weight ratio of three kinds of described active components is: penoxsuam: symetryne: formula (I)Structural compounds=1～5:1～20:1～25.
Preferably, three kinds of described active components account for 1～80% in herbicide, itsRemaining is pesticidal preparations auxiliary element, and shared percentage by weight is more in herbicide for three kinds of described active componentsFor preferably 30～50%.
Described pesticidal preparations auxiliary element comprise water, carrier, surfactant, adhesive, dispersant orThickener, also can contain various other components, as protecting colloid, adhesive, thickener, thixotropic agent, oozeAgent thoroughly, stabilizing agent, chelating agent, dyestuff, colouring agent and polymer, herbicide of the present invention can be with existingThere are solid conventional in technology or liquid additive to mix.
Described formulation of herbicide is suspending agent, suspension emulsion, dispersible oil-suspending agent, water dispersible granules orGranula.
The invention still further relates to a kind of purposes of the herbicide containing penoxsuam, for preventing and kill off rice field class cropWeeds.
Compared with prior art, the invention has the beneficial effects as follows:
1, activity of weeding significantly improves, and amount of application reduces simultaneously, has wider weeds control spectrum, control effectFruit is more lasting;
2, environmental pollution is few: the one, and amount of application reduces, and the 2nd, each component is easy to degraded, residual few, to rearStubble crop safety is high;
3, use cost low: the one, lasting medicine, has reduced spraying times, and the 2nd, desinsection control spectrum width can subtractThe use of few other herbicides.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further explained.
Embodiment 1
Herbicides for use in paddy containing penoxsuam of the present invention, is suspending agent, comprises active component and helpsAgent, its active component be penoxsuam, symetryne and 2 first 4 chlorine dimethylamine salts (in formula (I), RFor-COON (CH3)2, X is-H), the weight proportion of each component is: 18%2 first 4 chlorine dimethylamine salt+16% west grassOnly+1.6% penoxsuam+5% dispersant sodium lignin sulfonate+2% wetting agent pulls open powder+0.3% thickener xanthanGlue+5% antifreezing agent glycerine, surplus is water.
Embodiment 2
Herbicides for use in paddy containing penoxsuam of the present invention, is suspending agent, comprises active component and helpsAgent, its active component be penoxsuam, symetryne and 2 first 4 chlorine dimethylamine salts (in formula (I), RFor-COON (CH3)2, X is-H), the weight proportion of each component is: 18%2 first 4 chlorine dimethylamine salt+16% west grassOnly+2.2% penoxsuam+5% dispersant sodium lignin sulfonate+2% wetting agent pulls open powder+0.3% thickener xanthanGlue+5% antifreezing agent glycerine, surplus is water.
Embodiment 3
Herbicides for use in paddy containing penoxsuam of the present invention, is suspending agent, comprises active component and helpsAgent, its active component is that (in formula (I), R is for penoxsuam, symetryne and 2 first 4 chlorine dimethylamine salts-COON(CH3)2, X is-H), the weight proportion of each component is: 16%2 first 4 chlorine dimethylamine salt+19% symetrynes+ 2.5% penoxsuam+5% dispersant sodium lignin sulfonate+2% wetting agent pulls open powder+0.3% thickener xanthans+ 5% antifreezing agent glycerine, excess water is supplied.
Embodiment 4
Herbicides for use in paddy containing penoxsuam of the present invention, is suspending agent, comprises active component and helpsAgent, its active component is that (in formula (I), R is for penoxsuam, symetryne and 2 first 4 chlorine dimethylamine salts-COON(CH3)2, the X compound that is H), the weight proportion of each component is: 10%2 first 4 chlorine dimethylamine salt+46%Symetryne+2.5% penoxsuam+5% dispersant sodium lignin sulfonate+2% wetting agent pulls open powder+0.3% thickenerXanthans+2% antifreezing agent glycerine, excess water is supplied.
Embodiment 1 ∽ 4 is suspending agent, and preparation method is: all materials are dropped in mixing kettle, be uniformly mixedThe rear colloid mill of crossing, enters three grades of grindings of sand mill afterwards, finally in cutter, shears and is evenly finished product.
Embodiment 5
Herbicides for use in paddy containing penoxsuam of the present invention, is suspension emulsion, comprises active component and helpsAgent, its active component be penoxsuam, symetryne and the different monooctyl ester of 2 first 4 chlorine (R is in formula (I)--COOC8H17、X is-H), the weight proportion of each component is: different monooctyl ester+19% symetryne+2% of 21.5%2 first 4 chlorine penoxsulamAmine+4% phenethyl phenol polyoxyethylene phosphonate triethanolamine salt+3% AEO+3% castor-oil plantOil APEO+0.25% thickener xanthans+4% antifreeze glycol, excess water is supplied.
Embodiment 6
Herbicides for use in paddy containing penoxsuam of the present invention, is suspension emulsion, and active component is five fluorine sulphursGrass amine, symetryne and 2 first 4 chloroethene thioesters (in formula (I) R be-COSC2H5, X be-H), each componentWeight proportion be: 18%2 first 4 chloroethene thioesters+19% symetryne+2.2% penoxsuam+4% phenethyl phenolPolyoxyethylene ether phosphate triethanolamine salt+3% AEO+3% castor oil polyoxyethylene ether+ 0.25% thickener xanthans+4% antifreeze glycol, excess water is supplied.
Embodiment 7
Herbicides for use in paddy containing penoxsuam of the present invention, is suspension emulsion, and active component is five fluorine sulphursGrass amine, symetryne and 2 first 4 chloroethene thioesters (in formula (I) R be-COSC2H5, X be-H), each componentWeight proportion be: 28%2 first 4 chloroethene thioesters+30% symetryne+2% penoxsuam+2% phenethyl phenol are poly-Oxygen vinethene phosphate triethanolamine salt+1% AEO+3% castor oil polyoxyethylene ether+0.25%Thickener xanthans+4% antifreeze glycol, excess water is supplied.
Embodiment 5 ∽ 7 are suspension emulsion, and preparation method is: symetryne, penoxsuam and part of auxiliary are thrownEnter in mixing kettle, be uniformly mixed the rear colloid mill of crossing, enter afterwards three grades of sand millings of sand mill, obtain product I standbyWith; The different monooctyl ester of 2 first 4 chlorine, all the other auxiliary agents are mixed and obtain product II, after product I and product II are mixedIn cutter, shear and obtain finished product.
Embodiment 8
Herbicides for use in paddy containing penoxsuam of the present invention, is granule, comprises active component and helpsAgent, its active component is that (in formula (I), R is-COOK, X for penoxsuam, symetryne and 2 first 4 chlorine potassiumFor-H), each composition weight proportioning is: 3.6%2 first 4 chlorine potassium+3.4% symetryne+0.4% penoxsuam+3.5%Polyethylene glycol+2%30# machine oil, surplus is supplied by carrier coal gangue particle.
Embodiment 9
Herbicides for use in paddy containing penoxsuam of the present invention, is granule, comprises active component and helpsAgent, its active component be penoxsuam, symetryne and 2 first 4 chlorine sodium (in (I) R for-COONa, X be-H), the weight proportion of each component is: 2%2 first 4 chlorine sodium+1.5% symetryne+0.22% penoxsuam+3.5%Polyethylene glycol+2%30# machine oil, surplus is supplied by carrier coal gangue particle.
Embodiment 8 ∽ 9 are granule, and preparation method is: after coal gangue particle is sieved with screening machine, by instituteThere is material to mix in cone-type mixer, after being dried, can obtain finished product.
Embodiment 10
Herbicides for use in paddy containing penoxsuam of the present invention, is water dispersible granules, comprises active componentAnd auxiliary agent, its active component be penoxsuam, symetryne and 2 first 4 chlorine sodium (in formula (I) R for-COONa,X is-H), each composition weight proportioning is: 21%2 first 4 chlorine sodium+17% symetryne+2.5% penoxsuam+10%Dispersant naphthalenesulfonate+5% wetting agent pulls open powder+1% disintegrant polyvinyl alcohol, and surplus is mended by filler diatomiteFoot.
Embodiment 11
Herbicides for use in paddy containing penoxsuam of the present invention, is water dispersible granules, comprises active componentAnd auxiliary agent, its active component be penoxsuam, symetryne and 2 first 4 chlorine sodium (in formula (I) R for-COONa,X is-H), each composition weight proportioning is: 25%2 first 4 chlorine sodium+50% symetryne+2.6% penoxsuam+10%Dispersant naphthalenesulfonate+5% wetting agent pulls open powder+1% disintegrant polyvinyl alcohol, and surplus is diatomite.
Embodiment 10 ∽ 11 are for dispersibling granula, and preparation method is: all materials are mixed and pass through air-flowPulverizer, adds kneading, and dry after granulation, final sizing obtains finished product.
Embodiment 12
Herbicides for use in paddy containing penoxsuam of the present invention, for dispersibling oil suspending agent, comprises active groupDivide and auxiliary agent, its active component is that (in formula (I), R is for penoxsuam, symetryne and 2 first 4 neoprene esters-COOC3H7, X is-H), each composition weight proportioning is: 22.6%2 first 4 neoprene ester+19.2% symetryne+2% 5Penoxsulam+5% dispersant phenethyl phenol polyoxyethylene phosphonate triethanolamine salt+5% emulsifying agent aliphatic acidPolyoxyethylene ester+8% emulsifying agent castor oil polyoxyethylene ether+2% thickener organobentonite, surplus is by oleic acid firstEster is supplied.
Embodiment 13
Herbicides for use in paddy containing penoxsuam of the present invention, for dispersibling oil suspending agent, comprises active groupDivide and auxiliary agent, its active component is that (in formula (I), R is for penoxsuam, symetryne and 2 first 4 neoprene esters-COOC3H7, X is-H), each composition weight proportioning is: 30%2 first 4 neoprene ester+20% symetryne+2% 5 fluorine sulphursGrass amine+5% dispersant phenethyl phenol polyoxyethylene phosphonate triethanolamine salt+5% emulsifying agent aliphatic acid polyoxyVinyl acetate+8% emulsifying agent castor oil polyoxyethylene ether+2% thickener organobentonite, surplus is methyl oleate.
Embodiment 14
Herbicides for use in paddy containing penoxsuam of the present invention, for dispersibling oil suspending agent, comprises active groupDivide and auxiliary agent, its active component is that (in formula (I), R is for penoxsuam, symetryne and Vi par -C2H4COOH, X are-H), the weight proportion of each component is: 18%2 first 4 neoprene ester+16% symetryne+2.2%Penoxsuam+5% dispersant phenethyl phenol polyoxyethylene phosphonate triethanolamine salt+5% emulsifying agent fatAcid polyoxyethylene ester+8% emulsifying agent castor oil polyoxyethylene ether+2% thickener organobentonite, surplus is by oleic acidMethyl esters is supplied.
Embodiment 15
Herbicides for use in paddy containing penoxsuam of the present invention, for dispersibling oil suspending agent, comprises active groupDivide and auxiliary agent, its active component is that (in formula (I), R is for penoxsuam, symetryne and 2 first 4 neoprene esters-COOC3H7, X is-H), the weight ratio of each component is: 19%2 first 4 neoprene ester+17% symetryne+5% 5 fluorine sulphursGrass amine+5% dispersant phenethyl phenol polyoxyethylene phosphonate triethanolamine salt+5% emulsifying agent aliphatic acid polyoxyVinyl acetate+8% emulsifying agent castor oil polyoxyethylene ether+2% thickener organobentonite, surplus is mended by methyl oleateFoot.
Embodiment 16
Herbicides for use in paddy containing penoxsuam of the present invention, for dispersibling oil suspending agent, comprises active groupDivide and auxiliary agent, its active component is that (in formula (I), R is for penoxsuam, symetryne and 2 first 4 neoprene esters-COOC3H7, X is-H), the weight ratio of each component is: 50%2 first 4 neoprene ester+8% symetryne+2% 5 fluorine sulphursGrass amine+3% dispersant phenethyl phenol polyoxyethylene phosphonate triethanolamine salt+3% emulsifying agent aliphatic acid polyoxyVinyl acetate+2% emulsifying agent castor oil polyoxyethylene ether+1% thickener organobentonite+2% is by methyl oleate.
Test of pesticide effectiveness example 1
Composition of the present invention can be by spraying, spread fertilizer over the fields, the method for pesticide-clay mixture is applied to grass cutting blade or rhizomeUpper, the application dosage of active component is conventionally at 240-2000 gram/ha, preferably 300-1500 gram/ha.
The herbicidal composition that utilizes embodiment 1,3,5-6,8-10,12,14-15 to make is prevented and kill off paddy riceField weed test.
Test method: weed seed is unified to vernalization, broadcast sowing for examination weed seed equal and quantitative pretreatedIn soil surface, convert by germination percentage, ensure the density of control treatment weeds, water 2-3 in field before dispenserCentimetre, and water conservation. Medicament is made into pesticide-clay mixture and evenly spreads fertilizer over the fields, and measures weeds overground part germination quantity, calculates weedsGermination quantity inhibiting rate, statistical test situation after testing 45 days, result is as table 1.
Table 1, the preventive effect of herbicide of the present invention to paddy field weed
The quantity of germinateing in table is to repeat mean value 4 times, and from table, result of the test can be found out, of the present invention groupCompound has good preventive effect to preventing and kill off paddy field weed. Effective one-tenth of individualized compound in complex preparationDivide consumption all lower than the consumption in each single dose, the composition after mixture, with respect to each single dose processing, is all carried greatlyThe high preventive effect to weeds, shows significant synergistic effect, especially to moleplant seed, and Paspalum distichum performance effectFruit is particularly evident. In single dose, 56%2 first 4 chlorine soluble powders, 25% symetryne wettable powder uses high agentAmount not only has certain poisoning to paddy rice, and because its residual accumulation of unit in soil increases, to rearCorn, cotton and some vegetables of stubble all produce certain poisoning, and the present composition has reduced bothConsumption, obviously improves the security to paddy rice and has reduced the pollution to environment. In closed soil treatment processIn, embodiment 15 has shown great convenience in dispenser process, and outstanding to the preventive effect of weeds,Greatly improve crop safety simultaneously.
Test of pesticide effectiveness example 2
2013 in Changsha, 5, Changde, Yingkou, Liaoning, Qiqihar, Heilungkiang, Jing Zhou, Hubei etc.Exemplary test is promoted in testing site, 25Ge Dao district, area.
Weed community type in each demonstration pilot project: Changsha: barnyard grass+moleplant seed+Monochoria vaginalis+short arrowhead+angustifolia arrowhead herb+brokenMeter Sha Cao; Changde: barnyard grass+moleplant seed+Monochoria vaginalis+short arrowhead+cyperus iria+wild water chestnut; Yingkou: barnyard grass+Angustifolia arrowhead herb+Monochoria vaginalis+Monochoria korsakowii+short arrowhead+difformed galingale herb; Qiqihar: angustifolia arrowhead herb+barnyard grass+Monochoria vaginalis+shortArrowhead+Monochoria korsakowii+difformed galingale herb+cyperus iria; Jing Zhou: barnyard grass+moleplant seed+short arrowhead+Monochoria vaginalis+Sha cracks riceGrass+rhizome of nutgrass flatsedge+wild water chestnut.
Test method: 5-7 days after rice transplanting, water conservation 3-5 centimetre in field, adopts in pesticide-clay mixture method fieldEvenly spread fertilizer over the fields, use 300 grams/ha of the present compositions (a.i.) of active ingredient, be watered 30 public affairs for every muJin, 50 square metres of community areas, every processing repeats 4 times, and rice varieties is for connecting No. 7, round-grained rice. In process of the testContrast medicament mcpa sodium in region, Qiqihar because local low temperature causes the certain poisoning of rice seedling, westGrass has certain poisoning in region, Changsha to rice leaf only.
Contrast medicament: 56%2 first 4 chlorine soluble powder of sodium agent 40 grams/acre of (a.i.), 25% symetryne solubilitiesPulvis 50 grams/acre of (a.i.), 2.2 grams/acre of 22% penoxsuams (a.i.), investigation in 48 days after dispenserPreventive effect, result of the test is in table 2.
The field demonstration test of table 2 present composition
Claims (6)
1. containing a herbicide for penoxsuam, it is characterized in that, comprise active component penoxsuam, west grassClean and containing the compound of formula (I) structure, the weight ratio of three kinds of active components is: penoxsuam: westGrass is clean: formula (I) structural compounds=1～5:1～20:1～25;
Wherein, R is-COOH ,-COONa ,-COOK ,-C2H4COOH、-COON(CH3)2、-COOC4H9、-COOC8H17、-COOC2H4OC4H9、-COON(CH2CH2OH)2、-COOC3H7、-COOCH3、-COONH2C2H4OH、-COSC2H5、-COOC2H4N(CH2CH2OH)2、-COOC8H19；
X is-H or-CH3。
2. the herbicide containing penoxsuam according to claim 1, is characterized in that three kinds of described workProperty composition accounts for 1～80% in herbicide, and all the other are pesticidal preparations auxiliary element.
3. the herbicide containing penoxsuam according to claim 2, is characterized in that three kinds of described workProperty composition accounts for 30～50% in herbicide.
4. according to the herbicide containing penoxsuam described in claim 2 or 3, it is characterized in that described agricultureMedicine preparation auxiliary element comprises water, carrier, surfactant, adhesive, dispersant or thickener.
5. the herbicide containing penoxsuam according to claim 1, is characterized in that described herbicideFormulation is suspending agent, suspension emulsion, dispersible oil-suspending agent, water dispersible granules or granule.
6. described in claim 1, contain a herbicide for penoxsuam, for preventing and kill off the assorted of rice field class cropGrass.
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| CN106070267A (en) * | 2016-07-13 | 2016-11-09 | 山东奥坤生物科技有限公司 | A kind of Herbicidal combinations containing symetryne and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103037695A (en) * | 2010-02-03 | 2013-04-10 | 陶氏益农公司 | Synergistic herbicidal composition containing penoxsulam and flazasulfuron |
| CN103548860A (en) * | 2013-11-12 | 2014-02-05 | 王艳梅 | Herbicide composition |
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| JP5336741B2 (en) * | 2008-01-16 | 2013-11-06 | 協友アグリ株式会社 | Stable suspension formulation with reduced phytotoxicity |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103037695A (en) * | 2010-02-03 | 2013-04-10 | 陶氏益农公司 | Synergistic herbicidal composition containing penoxsulam and flazasulfuron |
| CN103548860A (en) * | 2013-11-12 | 2014-02-05 | 王艳梅 | Herbicide composition |
Non-Patent Citations (1)
| Title |
|---|
| 无."농약품목명표준화내역".《권말부록》.2007, * |
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Effective date of registration: 20170120 Address after: The Northern District of Huangdao Bo Li Zhen Bo Yao road 266000 Shandong city of Qingdao Province Patentee after: Qingdao Qingyuan nongguan resistant weed control Co Ltd Address before: 266000 Shandong Province, Qingdao city Nanjing Road No. 100 Patentee before: QINGDAO KING AGROOT PLANT PROTECTION SERVICES CO., LTD. |