CN103923397A - High-strength anticorrosive plastic - Google Patents

High-strength anticorrosive plastic Download PDF

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Publication number
CN103923397A
CN103923397A CN201410184685.XA CN201410184685A CN103923397A CN 103923397 A CN103923397 A CN 103923397A CN 201410184685 A CN201410184685 A CN 201410184685A CN 103923397 A CN103923397 A CN 103923397A
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CN
China
Prior art keywords
plastics
plastic
parts
photostabilizer
light absorber
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201410184685.XA
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Chinese (zh)
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CN103923397B (en
Inventor
周听昌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KUNMING PURETOWN ENVIRONMENTAL TECH Inc Co
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KUNMING PURETOWN ENVIRONMENTAL TECH Inc Co
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Publication of CN103923397A publication Critical patent/CN103923397A/en
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Publication of CN103923397B publication Critical patent/CN103923397B/en
Expired - Fee Related legal-status Critical Current
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/04Ingredients characterised by their shape and organic or inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/15Heterocyclic compounds having oxygen in the ring
    • C08K5/151Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1535Five-membered rings
    • C08K5/1539Cyclic anhydrides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/10Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/14Glass
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L25/00Constructive types of pipe joints not provided for in groups F16L13/00 - F16L23/00 ; Details of pipe joints not otherwise provided for, e.g. electrically conducting or insulating means
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L47/00Connecting arrangements or other fittings specially adapted to be made of plastics or to be used with pipes made of plastics
    • F16L47/14Flanged joints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)
  • Laying Of Electric Cables Or Lines Outside (AREA)

Abstract

The invention relates to development of pipe joints, and also relates to a new synthetic plastic material, namely a high-strength anticorrosive plastic. The formula of the plastic comprises the following components by weight: 100 parts of PP (polypropylene) plastic, 0.15-0.22 part of glass fiber 988A, 0.08-0.13 part of light stabilizer UV-9, 0.08-0.12 part of ultraviolet absorbent UV531, 0.05 part of nucleating agent NAP-53F and 0.16-0.25 part of antioxidant 1010; or 100 parts of PE (polyethylene) plastic, 0.15-0.22 part of silicon carbide whisker, 0.28-0.33 part of maleic anhydride, 0.16-0.22 part of coupling agent KH550, 0.08-0.13 part of light stabilizer UV-9, 0.08-0.12 part of ultraviolet absorbent UV531, 0.05 part of nucleating agent NAP-53F and 0.16-0.25 part of antioxidant 168. The plastic is simple and readily available in raw materials, low in cost, excellent in performance and good in injection molding property. The practicability of the plastic is wider than that of the pipe joints, and the plastic can be widely used for manufacturing industrial parts. The plastic is particularly suitable for occasions of being buried in underground engineering.

Description

High-strength corrosion-resisting plastics
The application is that application number is: 201210046219.6, and patent name is: the divisional application of the patent of invention of " a kind of tube stub ", the original bill applying date: 2012-02-28.
Technical field
The present invention relates to public works or fluid transfer facilities, is exactly a kind of tube stub that connects the interface on body and equipment specifically; Also relate to new synthetic plastics material simultaneously.
Background technology
Tube stub is to realize that body is connected with body or web member that body is connected with the interface on interface or other parts on container, equipment.Existing tube stub is all one-piece construction, and the size of the interface that conventionally can connect is less, is not also applicable to the tube stub being connected with the corresponding large interface on container compared with extra heavy pipe body.
Summary of the invention
Main purpose of the present invention is to provide the tube stub that a kind of applicable large size body is connected with the corresponding interface.
Concrete technical scheme of the present invention is: a kind of tube stub, it is characterized in that: described tube stub comprises the linker that multiple entirety is curved, multiple linkers enclose and form closed circle region, on linker along caliber to the web plate that is provided for connecting interface, a side relative with interface arranges the jack panel arranging along pipe side face, and the jack panel on multiple linkers encloses the bell and spigot that forms grafting body.
In such technical scheme, tube stub is enclosed and is formed by multiple linkers, has so just solved the processing of large size tube stub, inconvenient problem with use.Simultaneously tube stub one side connects by flange with web plate or the mode such as splicing or heat seal is connected with interface, and opposite side is for the termination of socket joint body, and realization is connection reliably.The termination of body can be plugged on bell and spigot inner side or all can in outside.
Brief description of the drawings
Fig. 1 is the perspective view of linker;
Fig. 2 be tube stub perspective view.
Embodiment
The preferred implementation of tube stub of the present invention is as shown in Figure 1, 2: tube stub comprises the curved linker of multiple entirety 10, multiple linkers 10 enclose and form closed circle region, on linker 10 along caliber to the web plate 11 that is provided for connecting interface, a side relative with interface arranges the jack panel 12 arranging along pipe side face, and the jack panel 12 on multiple linkers 10 encloses the bell and spigot that forms grafting body.Described web plate 11 outer rims arrange flange 13 to jack panel 12 1 sides, between described jack panel 12 and flange 13 along caliber to gusset 14 is set.So further reinforced company's fishplate bar 11 and structural strength whole tube stub, avoids the body weight connecting to cause too greatly tube stub to damage.
Uniform connecting hole 15 on described web plate 11, web plate 11 can utilize bolt or screw to be connected with the connecting hole of interface and periphery thereof with whole tube stub like this, and such syndeton also can be referred to as flange and connect.
The side that described linker 10 is connected with interface arranges multiple double wedges 16, coincide with the bore of the tangent circumferential size of double wedge 16 outer rims and interface.Double wedge 16 can be inserted in interface inside like this, its firm degree that reinforced pipe joint is connected with interface on the one hand, be convenient to again on the other hand linker 10 and can in interface, realize easily location when mounted, be convenient to wall of container and grafting body with flange connecting interface side.
Tube stub can be metal material.Also can be other synthetic materials.
But because large-sized like this body and tube stub general size are larger, again usually used as underground works facilities such as cable distribution pipes, so in order to reach reduction manufacturing cost, there is acid-fast alkali-proof simultaneously, etch-proof performance, to adapt to its use occasion, the present invention has also developed specially and has been suitable for the plastic material that tube stub is manufactured.
Composite plastic, formula (by weight) comprising:
Plastics: 100 parts, photostabilizer: 0.08-0.13 part, UV light absorber: 0.08-0.12 part, nucleator: 0.05 part, oxidation inhibitor: 0.16-0.25 part; Acceptable enhancing or toughening material: 0.2-0.8 part.
Preferably, described plastics are PP plastics, and enhancing or toughening material comprise glass 988A:0.15-0.22 part.
Or described plastics are PE plastics, enhancing or toughening material comprise SiC whisker: 0.15-0.22 part, maleic anhydride: 0.28-0.33 part, coupling agent KH550:0.16-0.22 part.
Above-mentioned two kinds is the preferred material combination obtaining through overtesting.Two kinds of preferred embodiments are provided below.
Embodiment mono-
Described PP plastics: 100 parts, glass 988A:0.2 part, photostabilizer UV-9:0.1 part, UV light absorber UV531:0.1 part, nucleant agent N AP-53F:0.05 part, antioxidant 1010: 0.2 part.
Embodiment bis-
Described PE plastics: 100 parts, SiC whisker: 0.2 part, maleic anhydride: 0.3 part, coupling agent KH550:0.2 part, irgasfos 168: 0.2 part, photostabilizer UV-9:0.1 part, nucleant agent N AP-53F:0.05 part, UV light absorber UV531:0.1 part.
Such plastics are raw materials used simple and easy to get, with low cost, superior performance, and injection molding is good.Its practicality is even more extensive compared with tube stub itself, can be widely used in making industrial part.Especially be suitable for burying underground the occasion of underground works.Parts are although it is so embedded in and undergroundly itself can be subject to illumination, but find through research, and add after photostabilizer and UV light absorber, the performances such as its intensity significantly improve, and the mechanical property can ensure as the product such as cable shaft, tube stub time is reliable.
The main namely injection molding of linker of tube stub production process: the present invention adopts single injection-molded.
Concrete be exactly: raw material is joined and in container, is heated to gradually 180-220 DEG C and keep at least 30 minutes by hopper, and evenly plasticizing under the stirring intensity of 40-70r/min;
Then under the hydraulic flow that is 50-100L/mim in 50-100Mpa thrust, speed, inject injection moulding in mould; Pressure and the flow velocity of temperature, degree of uniformity and the lodging of plasticizing must strictly be controlled, and just can reach good quality product.
And under 40 ± 1Mpa pressure-acting, pressurize is carried out coolingly, controls the plastics cooling about 300S of time that reaches 50 DEG C; Then die sinking, finally also slower soon after first slow when die sinking, be namely divided into three sections of die sinkings, speed is respectively: 40L/min, 70L/min, 30L/min; Then slowly firmly equably by work in-process ejection die; Work in-process on inspection, repair deburring, material can be packaged as finished product after handle.Bolt nut, pad and connecting sewing embedding sealing bar with dimension when use assemble into septic tank.Fast after die sinking is first slow is finally the edge that damages plastic plate during for fear of die sinking more slowly.Dwell time and control speed of cooling are in order to ensure that plastics are evenly distributed in grinding tool, plastic plate performance structure homogeneous, stable.
Tube stub using method of the present invention, the occasion being connected with cable distribution pipe taking the interface being embedded on underground cable shaft is as example, installation method is: first excavation hole groove, then installing cables well, cable shaft can be the structure that is connected of polylith plate body can be also integral molded plastic processing, then connecting joint is fixed on by double wedge 16 on the interface of cable shaft, then with bolt, web plate 11 and the connecting hole of cable shaft interface is fixed.Again body is plugged on the bell and spigot on tube stub.Backfill earthing again.
The cable shaft and the tube stub that utilize plastics of the present invention to make, on August 5th, 2011, contriver carried out the test of the aspects such as strength property to it, and its mechanical property is made to evaluation to August 31.Situation is as follows:
Test points two groups is carried out, and tested cable shaft, tube stub are the plastic warp processing method of the present invention of the screening formulation of embodiment 2 and make, and the tube stub of test group 1 is connected with modular cable well, the tube stub of test group 2 and the cable shaft of integral molded plastic are connected.
Testing tool:
(1) the two-way resistance strain gage of Br120-2AA
(2) YE2539 high speed static strain gage
(3) AZ216R data collecting system
On the cable shaft of test group 1 and tube stub, be uniformly distributed altogether 28 monitoring points, test group 2 is uniformly distributed 18 check points.In test, whether the main intensity of investigating two test group products can meet service requirements, test has mainly gathered the strain value of cable shaft under the different backfill degree of depth, namely the STRESS VARIATION situation of monitoring point in the different situation of the back fill course thickness of cable shaft top.
By actual road conditions, in the time having vehicle to pass through, the stress-strain situation of test-based examination well, obtains the STRESS VARIATION situation of inspection chamber under moving load.
Particular case is as follows:
(1) the each measuring point stress value of buried depth process
The measuring point stress (MPa) of the each measuring point of table 1 modular cable well under different buried depth
The measuring point stress (MPa) of the each measuring point of table 2 monoblock type cable well under different buried depth
(2) the each measuring point stress value of observation process
The measuring point stress (MPa) of the each measuring point of table 3 modular cable well in the time of monitoring
Remarks: starting to put each detection time from 26.3h has the truck of load-carrying 20T process.
The measuring point stress (MPa) of the each measuring point of table 4 monoblock type cable well in the time of monitoring
Remarks: starting to put each detection time from 26.3h has the truck of load-carrying 20T process.
Can find out by above-mentioned testing data:
(1), in all measuring points of modular cable well, the point that stress is larger mainly occurs in the interface of body and cable shaft, tube stub periphery namely, i.e. the position of measuring point 9,10,11,12, and wherein measuring point 11,12 is positioned on the web plate of tube stub.Along with the increase of the buried depth degree of depth, the stress of this position rises obvious.The stress of other position measuring points is all smaller, in 4MPa left and right.Therefore, the soil matrix below pipeline should be first tamped in suggestion in the time of construction, avoids pipeline unsettled, reduces the impact of load downward on pipeline on pit shaft.
(2) in monoblock type cable well, the stress of all measuring points is all little, mostly in 4MPa left and right.Wherein, the ladle body of comparing of the measuring point stress value on access flap is slightly bigger than normal.
(3) there iing car little through out-of-date STRESS VARIATION.
(4) the aboveground maximum stress load of modular cable reaches 22.523, maximum stress load 23.707 on tube stub.But cable shaft and tube stub, all not by outside destroy, prove that cable shaft of the present invention and pipe joint structure are firm, dependable performance.

Claims (3)

1. plastics, the weight of formula consists of:
PP plastics: 100 parts, glass 988A:0.15-0.22 part, photostabilizer UV-9:0.08-0.13 part, UV light absorber UV531:0.08-0.12 part, nucleant agent N AP-53F:0.05 part, antioxidant 1010: 0.16-0.25 part;
Or PE plastics: 100 parts, silicon carbide whisker: 0.15-0.22 part, maleic anhydride: 0.28-0.33 part, coupling agent KH550:0.16-0.22 part, photostabilizer UV-9:0.08-0.13 part, UV light absorber UV531:0.08-0.12 part, nucleant agent N AP-53F:0.05 part, irgasfos 168: 0.16-0.25 part;
Procedure of processing comprises:
Raw material is heated to 180-220 DEG C gradually and also keeps at least 30 minutes, evenly plasticizing under the stirring intensity of 40-70r/min;
Under the hydraulic flow that is 50-100L/mim in 50-100Mpa thrust, speed, inject injection moulding in mould;
Under 40 ± 1Mpa pressure-acting, pressurize is carried out coolingly, controls the plastics cooling time 300S that reaches 50 DEG C;
Die sinking: finally also slower soon after first slow when die sinking, speed is respectively: 40L/min, 70L/min, 30L/min;
Then slowly firmly equably by work in-process ejection die; Work in-process on inspection, repair deburring, material obtains plastic product after handle.
2. a kind of plastics according to claim 1, is characterized in that: described PP plastics: 100 parts, glass 988A:0.2 part, photostabilizer UV-9:0.1 part, UV light absorber UV531:0.1 part, nucleant agent N AP-53F:0.05 part, antioxidant 1010: 0.2 part.
3. a kind of plastics according to claim 1, is characterized in that: described PE plastics: 100 parts, silicon carbide whisker: 0.2 part, maleic anhydride: 0.3 part, coupling agent KH550:0.2 part, irgasfos 168: 0.2 part, photostabilizer UV-9:0.1 part, nucleant agent N AP-53F:0.05 part, UV light absorber UV531:0.1 part.
CN201410184685.XA 2012-02-28 2012-02-28 High-strength corrosion-resisting plastics Expired - Fee Related CN103923397B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201210046219.6A CN102585372B (en) 2012-02-28 2012-02-28 Pipe joint

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CN201210046219.6A Division CN102585372B (en) 2012-02-28 2012-02-28 Pipe joint

Publications (2)

Publication Number Publication Date
CN103923397A true CN103923397A (en) 2014-07-16
CN103923397B CN103923397B (en) 2016-01-20

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ID=46474652

Family Applications (4)

Application Number Title Priority Date Filing Date
CN201410184330.0A Expired - Fee Related CN103937074B (en) 2012-02-28 2012-02-28 Novel corrosion resistant tube stub
CN201210046219.6A Expired - Fee Related CN102585372B (en) 2012-02-28 2012-02-28 Pipe joint
CN201410183260.7A Expired - Fee Related CN103951890B (en) 2012-02-28 2012-02-28 Joint for plastic tube
CN201410184685.XA Expired - Fee Related CN103923397B (en) 2012-02-28 2012-02-28 High-strength corrosion-resisting plastics

Family Applications Before (3)

Application Number Title Priority Date Filing Date
CN201410184330.0A Expired - Fee Related CN103937074B (en) 2012-02-28 2012-02-28 Novel corrosion resistant tube stub
CN201210046219.6A Expired - Fee Related CN102585372B (en) 2012-02-28 2012-02-28 Pipe joint
CN201410183260.7A Expired - Fee Related CN103951890B (en) 2012-02-28 2012-02-28 Joint for plastic tube

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107400276A (en) * 2017-07-31 2017-11-28 苏州坤阳机械科技有限公司 A kind of resistance to chemical attack vinyon for laboratory pipette frame

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Publication number Priority date Publication date Assignee Title
CN103937074B (en) * 2012-02-28 2016-04-13 昆明普尔顿环保科技股份有限公司 Novel corrosion resistant tube stub
CN103407055B (en) * 2013-08-15 2015-07-29 杭州宏升塑胶有限公司 A kind of preparation method of large-scale polyethylene tube
CN110396238A (en) * 2019-08-07 2019-11-01 河南天铁环保科技有限公司 A kind of septic tank PP Pipe Compound and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN107400276A (en) * 2017-07-31 2017-11-28 苏州坤阳机械科技有限公司 A kind of resistance to chemical attack vinyon for laboratory pipette frame

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Publication number Publication date
CN103937074B (en) 2016-04-13
CN102585372A (en) 2012-07-18
CN102585372B (en) 2014-11-05
CN103951890B (en) 2016-05-18
CN103923397B (en) 2016-01-20
CN103937074A (en) 2014-07-23
CN103951890A (en) 2014-07-30

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Denomination of invention: High-strength anticorrosive plastic

Effective date of registration: 20200313

Granted publication date: 20160120

Pledgee: Kunming Industrial Development and Investment Co.,Ltd.

Pledgor: KUNMING PURETOWN ENVIRONMENTAL TECH Co.,Ltd.

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