CN103917551A - 通过二氧化碳与氢气反应制备甲酸的方法 - Google Patents

通过二氧化碳与氢气反应制备甲酸的方法 Download PDF

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Publication number
CN103917551A
CN103917551A CN201280054841.XA CN201280054841A CN103917551A CN 103917551 A CN103917551 A CN 103917551A CN 201280054841 A CN201280054841 A CN 201280054841A CN 103917551 A CN103917551 A CN 103917551A
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CN
China
Prior art keywords
alkyl
phase
formic acid
mixture
tertiary amine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201280054841.XA
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English (en)
Chinese (zh)
Inventor
T·绍布
M·帕齐基
D·M·弗莱斯
R·帕切洛
A·迈尔
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BASF SE
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BASF SE
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Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of CN103917551A publication Critical patent/CN103917551A/zh
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C07F15/0053—Ruthenium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/15—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction of organic compounds with carbon dioxide, e.g. Kolbe-Schmitt synthesis

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201280054841.XA 2011-11-10 2012-11-07 通过二氧化碳与氢气反应制备甲酸的方法 Pending CN103917551A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11188591 2011-11-10
EP11188591.9 2011-11-10
PCT/EP2012/072013 WO2013068389A1 (de) 2011-11-10 2012-11-07 Verfahren zur herstellung von ameisensäure durch umsetzung von kohlendioxid mit wasserstoff

Publications (1)

Publication Number Publication Date
CN103917551A true CN103917551A (zh) 2014-07-09

Family

ID=47146398

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201280054841.XA Pending CN103917551A (zh) 2011-11-10 2012-11-07 通过二氧化碳与氢气反应制备甲酸的方法

Country Status (11)

Country Link
EP (1) EP2776448A1 (https=)
JP (1) JP2015502922A (https=)
KR (1) KR20140090183A (https=)
CN (1) CN103917551A (https=)
BR (1) BR112014010923A2 (https=)
CA (1) CA2854047A1 (https=)
IN (1) IN2014DN03469A (https=)
RU (1) RU2014123397A (https=)
SG (1) SG11201401103YA (https=)
WO (1) WO2013068389A1 (https=)
ZA (1) ZA201404151B (https=)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9428438B2 (en) 2012-11-27 2016-08-30 Basf Se Process for preparing formic acid
EP3936498A4 (en) * 2019-03-08 2022-12-14 Nitto Denko Corporation PROCESS FOR THE PRODUCTION OF FORMIC ACID
JP7405594B2 (ja) * 2019-03-08 2023-12-26 日東電工株式会社 ギ酸の製造方法
WO2021187057A1 (ja) * 2020-03-17 2021-09-23 日東電工株式会社 ギ酸塩の製造方法及びギ酸塩製造システム

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0035724A2 (de) * 1980-03-12 1981-09-16 Bayer Ag Verfahren zur Herstellung von 1,1-Dihalogen-alkenen
EP0095321A2 (en) * 1982-05-22 1983-11-30 BP Chemicals Limited Production of formate salts
EP0151510B1 (en) * 1984-01-14 1987-08-05 BP Chemicals Limited Production of formate salts
CN101663259A (zh) * 2007-03-23 2010-03-03 巴斯夫欧洲公司 制备甲酸的方法
CA2765430A1 (en) * 2009-06-26 2010-12-29 Basf Se Method for producing formic acid

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3681481A (en) 1969-11-12 1972-08-01 Hooker Chemical Corp Catalytic addition of compounds having a p-h bond to acetylene
JPS591140A (ja) * 1982-06-23 1984-01-06 Matsushita Electric Ind Co Ltd 同心加工機
GB8424672D0 (en) 1984-09-29 1984-11-07 Bp Chem Int Ltd Production of formic acid
DE68920933T2 (de) * 1988-08-20 1995-05-24 Bp Chem Int Ltd Produktion von Formiat-Salzen von Stickstoffbasen.
DE19702025A1 (de) * 1997-01-23 1998-07-30 Studiengesellschaft Kohle Mbh Verwendung perfluoralkylsubstituierter Phosphorverbindungen als Liganden für die homogene Katalyse in überkritischem Kohlendioxid
DE102004040789A1 (de) 2004-08-23 2006-03-02 Basf Ag Verfahren zur Herstellung von Ameisensäure

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0035724A2 (de) * 1980-03-12 1981-09-16 Bayer Ag Verfahren zur Herstellung von 1,1-Dihalogen-alkenen
EP0095321A2 (en) * 1982-05-22 1983-11-30 BP Chemicals Limited Production of formate salts
EP0151510B1 (en) * 1984-01-14 1987-08-05 BP Chemicals Limited Production of formate salts
CN101663259A (zh) * 2007-03-23 2010-03-03 巴斯夫欧洲公司 制备甲酸的方法
CA2765430A1 (en) * 2009-06-26 2010-12-29 Basf Se Method for producing formic acid

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
CARL CHRISTOPH TZSCHUCKE，等: "Assessment of the Reusability of Pd Complexes Supported on Fluorous Silica Gel as Catalysts for Suzuki Couplings", 《EUROPEAN JOURNAL OF ORGANIC CHEMISTRY》, vol. 2005, 31 October 2005 (2005-10-31), pages 5248 - 5261, XP055049613, DOI: doi:10.1002/ejoc.200500281 *
EKKEHARD LINDNER等: "Catalytic activity of cationic diphospalladium(II) complexes in the alkene:CO copolymerization in organic solvents and water in dependence on the length of the alkyl chain at the phosphine ligands", 《JOURNAL OF ORGANOMETALLIC CHEMISTRY》, vol. 602, 15 May 2000 (2000-05-15), pages 173 - 187 *
KARL S. A. VALLIN等: "A New Regioselective Heck Vinylation with Enamides. Synthesis and Investigation of Fluorous-Tagged Bidentate Ligands for Fast Separation", 《THE JOURNAL OF ORGANIC CHEMISTRY》, vol. 68, 24 July 2003 (2003-07-24), pages 6639 - 6645, XP055049615, DOI: doi:10.1021/jo034265i *

Also Published As

Publication number Publication date
JP2015502922A (ja) 2015-01-29
RU2014123397A (ru) 2015-12-20
ZA201404151B (en) 2015-12-23
BR112014010923A2 (pt) 2017-04-18
WO2013068389A1 (de) 2013-05-16
SG11201401103YA (en) 2014-08-28
EP2776448A1 (de) 2014-09-17
CA2854047A1 (en) 2013-05-16
KR20140090183A (ko) 2014-07-16
IN2014DN03469A (https=) 2015-06-05

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Application publication date: 20140709