CN103917116B - Smoking article with color change segmentation - Google Patents
Smoking article with color change segmentation Download PDFInfo
- Publication number
- CN103917116B CN103917116B CN201280054562.3A CN201280054562A CN103917116B CN 103917116 B CN103917116 B CN 103917116B CN 201280054562 A CN201280054562 A CN 201280054562A CN 103917116 B CN103917116 B CN 103917116B
- Authority
- CN
- China
- Prior art keywords
- cystidium
- smoking article
- fluid
- segmentation
- color change
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 230000008859 change Effects 0.000 title claims abstract description 99
- 230000000391 smoking effect Effects 0.000 title claims abstract description 93
- 230000011218 segmentation Effects 0.000 title claims abstract description 84
- 239000012530 fluid Substances 0.000 claims abstract description 95
- 235000019504 cigarettes Nutrition 0.000 claims abstract description 66
- 230000003993 interaction Effects 0.000 claims abstract description 7
- 239000011248 coating agent Substances 0.000 claims abstract description 5
- 238000000576 coating method Methods 0.000 claims abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 26
- 238000001914 filtration Methods 0.000 claims description 23
- 238000004040 coloring Methods 0.000 claims description 19
- 239000000654 additive Substances 0.000 claims description 11
- 125000003118 aryl group Chemical group 0.000 claims description 10
- 238000011144 upstream manufacturing Methods 0.000 claims description 10
- 230000000996 additive effect Effects 0.000 claims description 9
- 238000007639 printing Methods 0.000 claims description 7
- 239000002966 varnish Substances 0.000 claims description 2
- 238000010422 painting Methods 0.000 claims 1
- 239000000463 material Substances 0.000 description 39
- 239000000443 aerosol Substances 0.000 description 16
- 241000208125 Nicotiana Species 0.000 description 13
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 13
- 239000000123 paper Substances 0.000 description 13
- 230000000694 effects Effects 0.000 description 10
- 239000000796 flavoring agent Substances 0.000 description 9
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 7
- 230000008901 benefit Effects 0.000 description 7
- 235000013355 food flavoring agent Nutrition 0.000 description 7
- 239000003205 fragrance Substances 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 239000011159 matrix material Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 229920002301 cellulose acetate Polymers 0.000 description 6
- 239000003546 flue gas Substances 0.000 description 6
- 238000007599 discharging Methods 0.000 description 5
- 239000000945 filler Substances 0.000 description 5
- 239000000779 smoke Substances 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229920002678 cellulose Polymers 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 3
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 3
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000010408 film Substances 0.000 description 3
- 229940041616 menthol Drugs 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229960002715 nicotine Drugs 0.000 description 3
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 3
- 230000002093 peripheral effect Effects 0.000 description 3
- 235000019505 tobacco product Nutrition 0.000 description 3
- 239000012780 transparent material Substances 0.000 description 3
- 238000009423 ventilation Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 244000246386 Mentha pulegium Species 0.000 description 2
- 235000016257 Mentha pulegium Nutrition 0.000 description 2
- 235000004357 Mentha x piperita Nutrition 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000008034 disappearance Effects 0.000 description 2
- CBOQJANXLMLOSS-UHFFFAOYSA-N ethyl vanillin Chemical compound CCOC1=CC(C=O)=CC=C1O CBOQJANXLMLOSS-UHFFFAOYSA-N 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 235000001050 hortel pimenta Nutrition 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000010019 resist printing Methods 0.000 description 2
- 235000013599 spices Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000005418 vegetable material Substances 0.000 description 2
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 1
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 1
- 241000522254 Cassia Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 235000019501 Lemon oil Nutrition 0.000 description 1
- 244000024873 Mentha crispa Species 0.000 description 1
- 235000014749 Mentha crispa Nutrition 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000009470 Theobroma cacao Nutrition 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000001926 citrus aurantium l. subsp. bergamia wright et arn. oil Substances 0.000 description 1
- 239000000549 coloured material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
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- 238000013461 design Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229940073505 ethyl vanillin Drugs 0.000 description 1
- -1 gaultherolin Substances 0.000 description 1
- 239000010648 geranium oil Substances 0.000 description 1
- 235000019717 geranium oil Nutrition 0.000 description 1
- 239000010649 ginger oil Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000010501 lemon oil Substances 0.000 description 1
- 229930007744 linalool Natural products 0.000 description 1
- 230000004807 localization Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000001771 mentha piperita Substances 0.000 description 1
- ZYDGQQTXLBNSGJ-UHFFFAOYSA-N oxonan-2-one Chemical compound O=C1CCCCCCCO1 ZYDGQQTXLBNSGJ-UHFFFAOYSA-N 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 235000019615 sensations Nutrition 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/04—Tobacco smoke filters characterised by their shape or structure
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/061—Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/02—Cigars; Cigarettes with special covers
- A24D1/025—Cigars; Cigarettes with special covers the covers having material applied to defined areas, e.g. bands for reducing the ignition propensity
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/04—Cigars; Cigarettes with mouthpieces or filter-tips
- A24D1/042—Cigars; Cigarettes with mouthpieces or filter-tips with mouthpieces
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/04—Tobacco smoke filters characterised by their shape or structure
- A24D3/048—Tobacco smoke filters characterised by their shape or structure containing additives
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
- Manufacture Of Tobacco Products (AREA)
Abstract
The present invention relates to a kind of smoking article (9), including the segmentation of cigarette holder (1), color change and the rupturable cystidium (5) containing fluid.Color change segmentation be suitable to the fluid interaction for coming from the rupturable cystidium containing fluid, when the cystidium is ruptured, based on interaction, the color change segmentation shows color change.The smoking article includes permeable outer wrapping part, and the outer wrapping part is coated with impermeable coating in the first region, therefore the first area is impermeable, wherein not being permeable by the second area that impermeable coating is covered.
Description
Technical field
The present invention relates to a kind of smoking article, including cigarette holder, the rupturable cystidium containing fluid and can change
The color change segmentation of color.The invention further relates to a kind of cigarette holder for this smoking article.
Background technology
Some smoking articles, such as cigarette with filter tip, generally include by wrapping paper surround tobacco filler material cylindrical bar and
With wrapped tobacco rods with the axially aligned cylindrical filter of end-to-end abutting relation.Wrapped tobacco boom end and mistake
Filter tip is connected typically by tipping paper, and the tipping paper is typically whole length and wrapped tobacco by limiting filter tip
What the paper material band of the adjacency section of bar was formed.
Many wherein tobaccos are also proposed in this area to be heated rather than burned smoking article.In heated hair
In tobacco product, aerosol is produced by heating the matrix of the generation fragrance of such as tobacco etc.Known heated smoke
Product for example includes electrically heated smoking article and wherein by from combustible thermal source to the formation aerosol being physically discrete from
Material heat transfer and produce the smoking article of aerosol.During smoking, volatile compound is by the warm from thermal source
Transmit and discharged from the matrix of aerosol is formed and be carried in the air by smoking article suction.With what is discharged
Compound is cooled down, and they condense the aerosol for being formed and being sucked by consumer.
Smoking article including discharging the cystidium of the fluid of such as menthol etc is known.
WO2011/077141A1 discloses a kind of filter tip for smoking article, and it passes through the cystidium in filter tip
There should be enhanced biodegradation rate, the wherein cystidium includes strengthening the liquid of smoking article decomposition.Cystidium
In liquid can carry color, in order to be able to user is confirmed that the cystidium has ruptured.
EP-A-1895863 describes a kind of cigarette, wherein being absorbed in the first absorbent component of filter element and second
Cystidium is set between agent component.The cystidium is suitable to be discharged when the cystidium bears the such as external force of consumer's extruding etc
At least a portion fluid.
However, the change that can be only made up of the fragrance of smoking article or flue gas of the release of the fluid of this cystidium come
Detection.
Additionally, whether this limited approach for being capable of identify that fluid release know the fluid for consumers
When storage (such as) release is difficult unintentionally because the release of the fluid of such as menthol etc a few days or a few weeks it
After will be not necessarily it is detectable.
The content of the invention
Therefore it provides for recognizing that the attachment device of fluid release is required.Offer can make consumer use except
Sensation outside hearing or tasting determines that the technical scheme of fluid release is especially required.
Offer makes the release of fluid to the device that consumer indicates can be also required in visible mode.
Therefore, according to the present invention, there is provided a kind of smoking article, it includes the cigarette holder being segmented with color change and can break
The cystidium containing fluid for splitting, wherein color change segmentation is suitable to and comes from the rupturable cystidium containing fluid
The fluid interaction so that when the cystidium ruptures based on the color change segmentation that interacts show from
The externally visible color change of the smoking article.
The color change mode entirely different for consumer provides confirm fluid release and have it is other
Advantage, the additional advantage is independently of the ability that consumer recognizes the release by taste or flavor change.
Term " color change segmentation " represent smoking article with come from the rupturable cystidium containing fluid
Change the part of color when the fluid is contacted.This color change can include:Produce and be different from smoking article peripheral part
Color;With the disappearance of smoking article peripheral part color identical color;Segmentation is never transparent to transparent change;Segmentation from
Transparent to opaque change;The appearance of pattern, mark or other images;Segmentation is from any color or blend color to another
The change of kind of color or blend color and it is whether identical with the color of smoking article peripheral part with these colors unrelated;Or appoint
The appearance of the color of the part of what its detectable change, including smoking article, disappear or change or mark, image or
Appearance, disappearance or the change of pattern.The color change segmentation is preferably cigarette holder segmentation, such as filter sections, or parcel
Part, such as internal or external wrap member.
Term " color change " represents visible in the color change segmentation when the fluid is contacted with the segmentation
As a result.
Color change is preferably occur in the outer layer of smoking article.Depositing in the case of multiple layers, color change can be with
Occur in not being outermost layer.So this have the advantage that the fluid for being preferably prevented from interacting with color change segmentation
With the lip or finger directly contact of consumer.
Therefore, outermost layer is that impermeable barrier is especially required.This further reduces fluid and the mouth of consumer
The chance of lip or finger directly contact.Therefore, especially preferably impermeable barrier is not permeable.
The color change segmentation preferably includes a part for layer, therefore this layer of part when it is contacted with certain fluid
Experience color change.
Preferably described color change segmentation includes at least a portion of one of outer layer of cigarette holder.
The cigarette holder of wherein position color change segmentation can be opaque or transparent.Preferably described cigarette holder is not
Transparent.This enables consumers to be more easily seen color change, because opaque background is provided than transparent background
Bigger contrast.
" opaque " material for describing to prevent the incident light of at least notable ratio from passing through of term, therefore can not possibly understand thoroughly
The material.Preferably, it is " opaque " to represent as using about the 40% of Hunterlab Colorquest XE spectrometer, measures
Or less light transmission percent of total, more preferably about 30% or less, even more preferably about 25% or less, it is optimal
Selection of land 15% or less.
The outer layer of cigarette holder can be wrap member, and it at least partially wraps up at least part of cigarette holder.
The smoking article of the invention being segmented including cigarette holder and color change can be cigarette with filter tip form or
Person be wherein tobacco filler material or other can smoking material be burned the form of other smoking articles to form flue gas.The present invention is in addition
Also include wherein forming aerosol by the matrix of heating (rather than burning) tobacco-containing material or other generation aerosol
Smoking article, and aerosol (the especially aerosol containing nicotine) is by cigarette wherein in the case where not burning or heating
The smoking article that the matrix of careless material, tobacco extract or substituting source of nicotine or another generation aerosol is produced.
In the following description, term " main flume " is used to describe by the incendivity smoke of such as cigarette with filter tip etc
The main flume that product is produced, and heating by such as type described above or non-heated smoking article etc on-fuel hair
The main flow aerosol that tobacco product is produced.
As used herein, term " upstream " and " downstream " are used to describing cigarette holder of the invention and smoking article
Each several part or element are relative in the relative of the direction of its main flume for being aspirated by the cigarette holder and smoking article during use
Position.For example, in cigarette holder of the color change segmentation in mouth end segmentation upstream, main flume is drawn through color change first
Segmentation, is then segmented by mouth end.
As used herein, term " length " represents fragrance release segmentation of the invention, cigarette holder and smoking article
Longitudinal direction on size.
In a preferred aspect, the cigarette holder includes filter tip, and the color change can occur in the filtering
In mouth.
Therefore, when fluid is discharged from the cystidium, consumer sees the color change on filter tip outside, and because
This knows that fluid has discharged.The release of fluid can be triggered by applying pressure on filter tip, such as by extruding
Filter tip, it is damaged in order to cystidium and discharge fluid.
Preferably, the color change can be realized in predetermined areas so that consumer can see that predetermined form,
Such as trade mark, mark or other patterns.
In an aspect, the fluid of cystidium carries color.Therefore, when fluid is discharged from the cystidium, stream
Body most starts colouring agent that can be comprising consumer needed for visible in itself.In this case, it is preferable that color change point
Section includes absorbing the material of colored fluid and therefore changes color.
In another aspect, the fluid can interact with the colouring agent of setting in color change segmentation.Therefore,
The fluid and the colouring agent of setting in color change segmentation that itself can not include colouring agent interact so that coloring
Agent is functioned to so that consumer can see that color change.Such benefit is only in some regions of filter element
Need to set colouring agent, and it is not colored in other regions of filter cell from the fluid of cystidium release.
In another aspect, fluid and color change segmentation not include colouring agent, but when the fluid with it is described
When color change segmentation contacts with each other, their interaction produces color.
The cystidium can be rupturable fluid reservoir, and it includes about 0.1ml to the fluid of about 1.0ml.
Suitable cystidium is preferably spherical or ellipse.Preferred diameter is from about 2.9mm to about 6.2mm.
In in a preferred aspect, the color change segmentation can be arranged on the wrap member for limiting at least a portion cigarette holder
On.Smoking article of the invention can include more than one wrap member.In this embodiment, the color change point
Section can be arranged on the inner side of outer wrapping part.
In some embodiments, the cystidium can include changing the additive of smoking article flue gas characteristic.It is this
Additive can include flavouring agent, nertralizer or other flue gas modifying agent, such as chemical reagent.In addition, these additives are also
Diluent, solvent or treatment adjuvant can be included.In a preferred embodiment, these additives can include it is a kind of or
Multiple scents, such as liquid or solid flavouring agent and fragrance formula or containing dulcet material.Suitable flavouring agent include but
It is not limited to menthol, the peppermint of such as peppermint and spearmint etc, cocoa, Radix Glycyrrhizae, lemon and other fruit fragrant
Taste agent, gamma caprylolactone, vanillic aldehyde, ethyl vanillin, the flavouring agent for making breath freshening, the spices fragrance of such as Chinese cassia tree etc
Agent, gaultherolin, linalool, bergamot oil, geranium oil, lemon oil, ginger oil and tobacco flavor agent.
Preferably, the cystidium comprising the fluid for realizing color change is arranged in the porous segmentation of cigarette holder, so as to
The outside of porous segmentation is accessible in the fluid being included in when cystidium ruptures in the cystidium.In this case,
Believe that the fluid is advanced by capillary effect in the porous segmentation.If the color change segmentation is located near simultaneously
In limiting the layer of the porous segmentation, then the fluid occurs color change once reaching porous segmented external.
The porous segmentation can be porous filtering segmentation.Suitable porous filtering segmentation can be by cellulose acetate structure
Into, it is therefore preferred to have low filter efficiency, with adsorptivity high.The porous filtering segmentation can especially be had by every 9km
The material of the height list denier type of about 8.0g weight is made.
The low filter efficiency of porous filtering segmentation enables that the fluid flows to the layer including color change segmentation
Inner surface, can realize color change and show that the cystidium has discharged the fluid.
In one embodiment, the cigarette holder only can be segmented including porous filtering.
In a preferred embodiment, the smoking article includes being located at respectively in the segmentation of the first and second porous filterings
The first and second cystidiums, wherein it is described first segmentation described second segmentation upstream.First cystidium can be wrapped
Containing the fluid for realizing color change, second cystidium can include the additive of such as aromatic etc.At one
In preferred aspect, second filter sections have the adsorptivity lower than the described first segmentation so that from second cryptomere
The fluid that body is discharged comes from the fluid of first cystidium rapidly very slowly by second filter sections
Reach the outer surface of the first filter sections.So this have the advantage that, consumer can in aromatic reaches consumer mouthful it
It is preceding or notice the instruction for discharging aromatic simultaneously.
The additional advantage so having be realize color change fluid will not reach substantially in the mouth of consumer or
The color at the mouth end of the second porous filtering segmentation will not be changed.
Preferably, second filter sections have the minimum length of about 7mm and are cellulose filter materials, such as
Cellulose acetate.Other absorbing material, such as activated carbon can be provided with the segmentation.
Second filter sections preferably have filter efficiency high, i.e., low adsorptivity.So this have the advantage that
Prevent or reduce suction-operated of the fluid for discharging in the second filter sections.
In one embodiment, the second porous filtering segmentation is a mouthful end filter sections.Preferably it has about
10mm or longer length.
In particular it is preferred that in causing the fluid of color change to remain substantially in the first filter sections.It is therefore preferable that
Ground at least about 80%, more preferably about 90% fluid is retained in the first filter sections.
In one embodiment, the cigarette holder includes the impermeable interior wrap member of fluid.Therefore, color change is realized
The fluid will realize reaching but being not passed through the interior wrap member once cystidium ruptures.This prevent with consumer's
Contact, especially with the contact of consumer's finger, so as to maintain dry tactile, this is typically needed for consumer.
Preferably, interior wrap member is the wrap member of at least one filter sections for limiting filter element.The interior wrap member
Multiple filter sections of filter element, preferably up to five segmentations can be connected.These single filter sections especially may be used
With including absorbent, flavouring agent, vegetable material, plant or spices.Some or all these segmentation can be by interior parcels
The transparent part of one or more of part is visible at least in part.These transparent parts can rush cut out portion.
In one embodiment, filter element includes at least opaque permeable interior wrap member.Especially, institute
Stating interior wrap member can have adsorptivity higher than the filter sections of corresponding border.Therefore, the interior wrap member absorb by
The high concentration fluid that the cystidium is provided, is thus provided that color change is segmented.Opaque permeable interior parcel
Part can be made up of every square metre of about 20 grams of (gsm) weight to the wrapping paper of about 30gsm weight.
The interior wrap member can be provided with colouring agent.The colouring agent can be arranged on the inner side of interior wrap member.For
Permeable interior wrap member, the colouring agent can be distributed in whole on wrap member.
In one embodiment, the outer wrapping part is opaque and including otch.The otch can be appointed
The opening of what type, but die-cut openings are preferred.The outer wrapping part can be made up of standard tipping paper, especially with big
About 40 to about 60gsm weight.By and the combination of substantially impermeable interior wrap member typically prevent by outer wrapping
The uncontrolled air stream of the opening in part.
In one embodiment, the outer wrapping part is transparent and is partly printed or imprinted.By printing
Or impressing, outer wrapping part only can be in predetermined areas transparent, i.e., in the region that color change occurs wherein.Printing can
To present sales message or can be used for the design of smoking article.Additionally, the outer wrapping part can be stamped, wherein described
Imprint the purpose for providing the consumer with similar mouthfeel for standard outer wrapping part.Additionally, printing can be with color change
Effect interacts so that color change effect changes the shape of the image printed before in color change effect region.
Preferably, the outer wrapping part is impermeable.
Alternatively, the outer wrapping part is permeable, and is provided with impermeable coating in the first region (such as
Varnish), to make the first area be substantially impermeable.Therefore, the permeable region of outer wrapping part includes color change
Segmentation, the fluid will realize color change in the outer wrapping part in permeable region.
The inside of filter tip generally includes at least one and wherein arranges cystidiate filter sections, wherein the cystidium
Fluid is packaged with, the fluid is discharged when applying pressure on the cystidium.
In a preferred embodiment, at least one filter sections are limited by interior wrap member, the interior wrap member by
Transparent impermeable thin-film material is constituted, especially cellulosic material, and it uses resist printing colored paint to process.It is hinged with by standard made of paper
Into outer wrapping part be arranged in around interior wrap member, outer wrapping part includes die-cut openings, so as to setting window in tipping paper.
The window enables the customer to see the color change effect being arranged on interior wrap member inner side after cystidium breakage.In the reality
Apply in mode, color change is realized when the fluid of cystidium reaches transparent interior wrap member.Consumer can be by outer wrapping
Die-cut openings on part observe the color change.For example, the color of the cellulose acetate of filter sections will be due to having released
Release the fluid color and change.
In further preferred embodiment, at least one filter sections are limited by transparent film, described outer
Wrap member is made up of transparent tipping film.The transparent tipping film can at least in part be printed or imprint.Therefore,
The color change on the inside of interior wrap member can be seen at least through the non-printing zone of outer wrapping part.In this embodiment, mistake
Filter segmentation changes its color when with for realizing that the fluid of color change is contacted.Consumer can be by transparent inner and outer bag
Wrap up in part and see color change.Preferably, transparent window is only set in outer wrap member, and remaining outer wrapping part is stamped and/
Or printing causes that it is opaque.Outer wrapping part or interior wrap member may each be impermeable for the fluid of cystidium.
In further preferred embodiment, at least one filter sections are with permeable opaque interior parcel
Part and transparent impermeable outer wrapping part parcel.Therefore, when interior wrap member and the fluid interaction of the cystidium of rupture
When, color change can be seen by transparent outer wrapping part.In this embodiment, when the fluid is reached in permeable
Wrap member and when interacting therewith it can be seen that color change effect because in this region at least provided with outer wrapping part not
The transparent part of printing.Therefore, the coloring of porous interior wrap member confirms to have sent out flavouring agent.
In further preferred embodiment, permeable opaque interior wrap member limits at least one filtering
Segmentation, permeable opaque outer wrapping part is wrapped in around interior wrap member at least in part.The part of outer wrapping part can ooze
Permeability only can process the part of outer wrapping part to realize by using resist printing colored paint.Therefore, outer wrapping part is not processed
Part be permeable and absorb the fluid, so as to color change will be realized on the outside of outer wrap member.In the reality
In applying mode, when the fluid is disperseed by permeable interior wrap member and is then partially absorbed by the permeable of outer wrapping part
Shi Shixian color changes.Therefore, the permeable part of outer wrapping part will change its color, and consumer sees that flavouring agent is passed
Send out.
Cigarette holder used in this invention can be unistage type cigarette holder or filter tip.
Alternatively, cigarette holder used in this invention can also include one or more in addition to color change is segmented
The multipart cigarette holder of segmentation.
Cigarette holder used in this invention can be included in one or more segmentations of color change segmentation upstream.
Alternatively or additionally, cigarette holder used in this invention can be included in one of color change section downstream or
Multiple segmentation.So desirably reduce the machine of the fluid and mouth directly contact of consumer interacted with color change segmentation
Meeting.
Cigarette holder in smoking article of the invention can be included with such as cellulose acetate tow etc
The other segmentation of one or more of cellulose filter material.
The mouth end segmentation of cigarette holder can include hollow tube or groove.The hollow tube or groove can pass through example in the cigarette holder
As tipping paper be attached to can the bar of smoking material formed during smoking article of the invention with being formed.Preferably, the groove
Also include increasing the cylindrical elements of the tubular construction intensity, for example, wrap up the paper tube or paperboard tube of tipping material above.Groove
Filter tip is well known in the art, such as in european patent application WO-A-2004/089124.
The cigarette holder can be segmented including current limiter.The draw resistance and other fluids of current limiter segmentation influence smoking article
Power, has an effect on the formation of carbon monoxide and carbon dioxide.Current limiter in smoking article is well known in the art, for example
Can know from international patent application WO-A2-2008/059377.
The cigarette holder can be included in the mouth end segmentation of color change section downstream, and the color change segmentation includes acetic acid
Cellulose tow or other cellulosic material plugs.
Cigarette holder used in this invention can include one or more other segmentations, and the other segmentation includes absorbing
Agent (such as activated carbon or silica gel), vegetable material (such as piece cigarette), aromatic and other flue gas modifying agent.
One or more of other segmentations can be used for obtaining the total content of plasticizing agent needed for cigarette holder.
Alternatively or additionally, one or more of other segmentations can be used for the required total of acquisition cigarette holder
Draw resistance (RTD).
Cigarette holder used in this invention can have for example as according to ISO6565:The 2002 about 100mm for measuring
Draw resistance (RTD) between WG (water meter) to about 180mm WG.
Cigarette holder used in this invention can have the external diameter between such as about 5mm to about 8.5mm.
Cigarette holder used in this invention can have the length between such as about 20mm to about 50mm.
In the case where the mouth end that cigarette holder used in this invention is included in color change section downstream is segmented, the segmentation of mouth end
Length can for example between about 3mm to about 15mm, for example between about 6mm to about 12mm.
In the case where mouth end segmentation includes hollow tube or groove, the length of this mouthful of end segmentation can for example about
Between 3mm to about 8mm.
Cigarette holder used in this invention can be incorporated into the different types of smoking article of many kinds.For example, used in this hair
Cigarette holder in bright can be incorporated into combustible smoking article, such as cigarette with filter tip, and it includes wrapped tobacco filler material
Bar or during aspirating be burned other can be with sucked material bar.
Alternatively, cigarette holder used in this invention can be incorporated into the on-fuel heating smoke system of type described above
In product, wherein material is heated to form aerosol, rather than burned.For example, cigarette holder used in this invention can be combined
To including incendivity thermal source and incendivity thermal source downstream generation aerosol matrix heating smoking article in, such as WO-
Disclosed in A-2009/022232.Cigarette holder used in this invention can be combined with including the heating smoke of non-burning thermal source
In product, such as chemical heat source or electric heat source.
Alternatively, during cigarette holder used in this invention can be incorporated into the non-burning smoking article of type described above,
Wherein aerosol be by generation aerosol matrix produce rather than burning or heat, such as WO-A-2008/121610 and
Those described in WO-A-2010/107613.
In one embodiment, smoking article of the invention can include being attached to by tipping paper the quilt of cigarette holder
The tobacco filler material bar of parcel or other can smoking material bar.
In another embodiment, smoking article of the invention can be included in the generation aerosol of cigarette holder upstream
Matrix.
Smoking article of the invention can include with ventilation unit cigarette holder, in order to during smoking by around
Air is mixed with consumer by the main flume that cigarette holder is aspirated.For example, can be at the position along cigarette holder along the circumferential direction
A row or multi-row perforation is set, in order to mix surrounding air by the main flume that cigarette holder is aspirated with consumer during smoking
Close.Preferably, the peripherally disposed a row or multi-row perforation or other ventilation units apart from cigarette holder mouthful end at least
12mm is positioned.
Smoking article of the invention can have the ventilation level between such as about 20% to about 80%, such as root
According to ISO9512:2002 measurements.
Smoking article of the invention can have the total length between such as about 60mm to about 128mm.
Smoking article of the invention can have such as about 5mm to about 8.5mm between external diameter, for example for
External diameter between the smoking article of very thin size about 5mm to about 7.1mm, or for stock size smoking article about
External diameter between 7.1mm to about 8.5mm.
Cigarette holder used in this invention can include filter tip.The filter tip can include one or more cellulose filters
Segmentation.
In the case where filter tip includes multistage, it can be produced by forming single continuous lever, and the bar includes
Multiple units of each single section of filter tip.Then in one or more stages by these single bars in known manner
Include the continuous filter rods of multiple units of filter tip with reference to formation.Cutting mechanism be may then pass through by the continuous mistake
Filter rod is successively switched off at regular intervals, to produce a series of scattered filter tips of the invention.
Preferably, smoking article of the invention includes wrapped tobacco filler material bar.Preferably, it is of the invention
There is smoking article the dry granule phase substance of the nicotine (NFDPM) or " tar " that always goes up to about 10mg to measure.It is highly preferred that " tar "
Between amount about 1mg to 10mg, more preferably about 6mg.
Preferably, during color change segmentation is if located in the cigarette holder, then with it is wrapped can smoking material bar support
Connect.
Brief description of the drawings
The present invention is further described now with reference to the illustrative embodiments as shown in in figure.
Fig. 1 shows the viewgraph of cross-section of filter element according to the first embodiment of the invention.
Fig. 2 shows the viewgraph of cross-section of filter element second embodiment of the invention.
Fig. 3 shows the viewgraph of cross-section of smoking article according to the first embodiment of the invention.
Fig. 4 shows the viewgraph of cross-section of smoking article second embodiment of the invention.
Fig. 5 shows the perspective view of the smoking article of an implementation method of the invention.
Specific embodiment
In fig. 1 it is shown that the cigarette holder of the form in filter element 1 according to the first embodiment of the invention.Should
Filter element 1 is generally made up of the first filter sections 2, rod end filter sections 3 and mouth end filter sections 4.These filterings point
The arrangement adjacent to each other on longitudinal direction 100 of section 4,2,3.The longitudinal direction 100 corresponds to the axle of cylindrical filter element 1
To direction.The rod end filter sections 3 be arranged so that its by with smoking article in smoking material bar border, and mouth end filter
Segmentation 4 is arranged in downstream at the mouth end of smoking article.
Cystidium 5 is set in the first filter sections 2.The cystidium 5 is packaged with fluid, when the cystidium 5 bears pressure
The fluid is discharged during so as to rupturing.The cystidium 5 is embedded in the filtering material (i.e. cellulose acetate) of the first filter sections 2
In.The rod end filter sections 3 and mouth end filter sections 4 can also be manufactured by cellulose acetate.
Preferably, the adsorptivity of the first filter sections 2 is higher than mouth end filter sections 4 or the adsorptivity of rod end filter sections 3.
Therefore, the fluid for being discharged by cystidium 5 is remained substantially in the first filter sections 2, and is rapidly distributed to outside it
Week.
Fluid in cystidium 5 includes aromatic, therefore, when it discharges, change the fragrance of smoking article.However,
In other embodiments, the fluid being included in cystidium 5 can only include additive, and the additive changes by smoke components
The composition of the flue gas of offer.
Fluid in cystidium 5 includes colouring agent, therefore when fluid discharges, by the dyeing material of the first filter sections 2.
First filter sections 2, rod end filter sections 3 and mouth end filter sections 4 are limited by interior wrap member 6, so as to by they
It is connected to each other.The interior wrap member 6 can be made up of impermeable transparent material or is made up of permeable opaque material.
However, under any circumstance, the fluid for discharging will realize color change, and this color change is in the outside of filter element 1
On be visible.In the fluid being included in cystidium 5 not those implementation methods including colouring agent, colouring agent can be set
In the first filter sections 2 or on interior wrap member 6, so as to when the fluid reaches colouring agent, color change will be realized.
It should be emphasized that rod end filter sections 3 are optional, the first filter sections 2 can also be arranged on filter element
On 1 end, thus its directly with smoking material bar border.In other implementation method, can be in filter element only
Set one and wherein have cystidiate filter sections.
In fig. 2 it is shown that the cigarette holder of the form in filter element 1 of the invention.The filter element 1 includes
First filter sections 2, first filter sections 2 have the cystidium 5 for being arranged in upstream side, and the upstream side is filter element 1
Rod end side.The second filter sections 7 with the second cystidium 8, the second filter sections 7 are arranged on downstream position and the first mistake
Filter 2 borders of segmentation.
In some embodiments, the second filter sections 7 are shorter than the first filter sections 2 on longitudinal direction 100.Shorter
Length is feasible, because the filtering material of the second filter sections 7 includes the suction lower than the filtering material of the first filter sections 2
Attached property, therefore, come from the cystidium 5 of the fluid without the first filter sections 2 of the second cystidium 8 fluid dispersion it is remote.
Additionally, being provided with downstream direction the mouth end filter sections 4 with the border of the second filter sections 7.These filter sections
4th, 7,2 on longitudinal direction 100 arrangement adjacent to each other.Each filter sections 2,7,4 is limited by interior wrap member 6.The cystidium 5
Including the fluid with colouring agent, wherein the second cystidium 8 includes the fluid with additive, such as aromatic.Work as consumer
During extruding filter element 1, the first cystidium 5 and the second cystidium 8 are damaged.First filter sections 2 have than the second filtering point
7 adsorptivities higher of section, so that dispersion ratio fluid of the fluid of the first cystidium 5 in the first filter sections 2 is in the second filtering
The dispersion of segmentation 7 is faster.Therefore, the fluid of the first cystidium 5 reaches interior wrap member 6 and provides color change thereon quickly
Effect.The interior wrap member 6 can be impermeable transparent material or permeable opaque material, as before
Described in detail in implementation method.Because color change function and aromatic release function are provided by different cystidiums,
So the more localization of color change effect can be realized, while in preventing the mouth that colouring agent reaches consumer.Additionally, mouth end mistake
Filter segmentation prevents aromatic to be distributed in liquid form in consumer mouthful.
In fig. 3 it is shown that the first embodiment of smoking article of the invention 9.The smoking article 9 includes basis
The filter element 1 of second embodiment as shown in Figure 2.Especially, the smoking article 9 includes smoking material bar 10, hair
Cigarette material bar 10 is connected to filter element 1 by outer wrapping part 11.The outer wrapping part limits the downstream part of smoking material bar
With filter element 1.The outer wrapping part 11 is made up of opaque material, especially standard tipping paper.The outer wrapping part 11 includes
Otch 12 in the region of the first filter sections 2.Interior wrap member 6 is transparent impermeable wrap member.Therefore, when in filtering
When extruding smoking article 9 in the region of mouth element 1, cystidium 5,7 is damaged and their fluid is released, wherein the first cryptomere
The fluid of body 5 is soon distributed by the first filter sections 2 of high adsorption, the coloured material of band of the first filter sections 2
Otch 12 by transparent interior wrap member 6 and outer wrapping part 11 is visible.However, the remaining mouth end of filter element 1
There is provided common the look and feel of standard tipping paper.
Figure 4 illustrates the second embodiment of smoking article of the invention 9.According to the hair of second embodiment
Tobacco product 9 equally includes the filter element 1 according to second embodiment as shown in Figure 2.However, with smoking article 9
Wrap member 6 and outer wrapping part 11 are made up of transparent material in unlike first embodiment.Outer wrapping part 11 it is saturating
Bright material can be printed or imprint.However, in the region of the first cystidium 5, transparent window is set in outer wrap member 11,
The transparent window realizes the observability of the color change that the fluid by being provided by the first cystidium 5 is realized.Smoking article 9
Interior wrap member 6 in second embodiment can be opaque permeable wrap member or transparent impermeable wrap member,
Because outer wrapping part 11 provides necessary impenetrability to prevent the fluid for including colouring agent from reaching outside.
The construction and arrangement of the inside and outside wrap member described as reference picture 3 and 4 go for appointing in filter element
The filter sections structure of which kind of class.The filter element 1 according to Fig. 1 can for example be set, or only have one includes cryptomere
The filter element of the filter sections of body, the stream of cystidium additive of the encapsulation with colouring agent or such as aromatic etc
Body.
In Figure 5, illustrate in perspective view the smoking article 9 of an implementation method of the invention.As can be seen that
, the color change effect of the form of image 13 can be seen on the outside of outer wrap member 11.Therefore, cystidium is made to rupture it
Before can't see such mark 13, once rupture, the mark quickly manifests.The mark 13 can represent the fragrance for discharging
The type of agent, such as dried peppermint leaf or the like.
Claims (13)
1. a kind of smoking article, including cigarette holder, color change segmentation and the rupturable cystidium containing fluid, wherein the face
Color change segmentation is suitable to and the fluid interaction for coming from the rupturable cystidium containing fluid so that described when making
When cystidium ruptures, based on interaction, the color change segmentation shows color change, wherein the smoking article includes
Permeable outer wrapping part, the outer wrapping part is coated with impermeable coating in the first region, so that the first area is not
It is permeable, wherein not be permeable by the second area that impermeable coating is covered, and wherein described impermeable painting
Layer is varnish.
2. smoking article according to claim 1, wherein permeable second area includes the color change point
Section.
3. smoking article according to claim 1 and 2, including outer wrapping part opaque and with otch.
4. smoking article according to claim 1 and 2, including transparent outer wrapping part.
5. smoking article according to claim 1 and 2, wherein the fluid of rupturable cystidium is with color
's.
6. smoking article according to claim 1 and 2, wherein the fluid be arranged in a part for the cigarette holder
Colouring agent interacts.
7. smoking article according to claim 1 and 2, wherein rupturable cystidium is arranged in porous segmentation.
8. smoking article according to claim 1 and 2, the wherein smoking article include being located at the porous mistake in the first upstream respectively
The first cystidium and the second cystidium in filter segmentation and the second downstream porous filtering segmentation, first cystidium is included to be used for
The fluid of color change is realized, second cystidium includes additive, wherein porous filtering segmentation in second downstream has
Lower adsorptivity is segmented than the first upstream porous filtering, so as to more slowly be moved by the from the fluid of the second cystidium release
Two downstream porous filtering segmentations, when ruptured, the fluid for coming from the first cystidium passes through more quickly the first upstream porous filtering
Segmentation.
9. smoking article according to claim 1 and 2, wherein the cigarette holder includes being arranged in the filtering point in cystidium downstream
Section.
10. smoking article according to claim 1 and 2, wherein the outer wrapping part is partially provided with Printing Department and/or pressure
Print portion.
11. smoking articles according to claim 1 and 2, including permeable opaque interior wrap member.
12. smoking articles according to claim 1 and 2, including impermeable transparent interior wrap member.
13. smoking articles according to claim 8, wherein the additive is aromatic.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11008825 | 2011-11-07 | ||
EP11008825.9 | 2011-11-07 | ||
PCT/EP2012/004521 WO2013068081A1 (en) | 2011-11-07 | 2012-10-29 | Smoking article with colour change segment |
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Publication Number | Publication Date |
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CN103917116A CN103917116A (en) | 2014-07-09 |
CN103917116B true CN103917116B (en) | 2017-06-06 |
Family
ID=47143823
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201280054562.3A Active CN103917116B (en) | 2011-11-07 | 2012-10-29 | Smoking article with color change segmentation |
Country Status (17)
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US (1) | US9497991B2 (en) |
EP (1) | EP2775867B1 (en) |
JP (1) | JP6145104B2 (en) |
KR (1) | KR20140088549A (en) |
CN (1) | CN103917116B (en) |
AU (1) | AU2012334405B2 (en) |
BR (1) | BR112014010877B1 (en) |
ES (1) | ES2677468T3 (en) |
HK (1) | HK1200661A1 (en) |
MX (1) | MX349118B (en) |
MY (1) | MY168127A (en) |
PL (1) | PL2775867T3 (en) |
RU (1) | RU2564600C1 (en) |
SG (1) | SG11201402068YA (en) |
TR (1) | TR201809842T4 (en) |
UA (1) | UA115432C2 (en) |
WO (1) | WO2013068081A1 (en) |
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2012
- 2012-10-29 PL PL12783120T patent/PL2775867T3/en unknown
- 2012-10-29 JP JP2014540344A patent/JP6145104B2/en active Active
- 2012-10-29 MY MYPI2014701125A patent/MY168127A/en unknown
- 2012-10-29 KR KR1020147012030A patent/KR20140088549A/en not_active Application Discontinuation
- 2012-10-29 WO PCT/EP2012/004521 patent/WO2013068081A1/en active Application Filing
- 2012-10-29 BR BR112014010877-3A patent/BR112014010877B1/en active IP Right Grant
- 2012-10-29 UA UAA201405240A patent/UA115432C2/en unknown
- 2012-10-29 RU RU2014123363/12A patent/RU2564600C1/en active
- 2012-10-29 SG SG11201402068YA patent/SG11201402068YA/en unknown
- 2012-10-29 US US14/355,635 patent/US9497991B2/en active Active
- 2012-10-29 CN CN201280054562.3A patent/CN103917116B/en active Active
- 2012-10-29 TR TR2018/09842T patent/TR201809842T4/en unknown
- 2012-10-29 ES ES12783120.4T patent/ES2677468T3/en active Active
- 2012-10-29 AU AU2012334405A patent/AU2012334405B2/en not_active Ceased
- 2012-10-29 EP EP12783120.4A patent/EP2775867B1/en active Active
- 2012-10-29 MX MX2014005577A patent/MX349118B/en active IP Right Grant
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2015
- 2015-02-10 HK HK15101465.7A patent/HK1200661A1/en not_active IP Right Cessation
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Also Published As
Publication number | Publication date |
---|---|
HK1200661A1 (en) | 2015-08-14 |
UA115432C2 (en) | 2017-11-10 |
MX2014005577A (en) | 2014-12-05 |
WO2013068081A1 (en) | 2013-05-16 |
BR112014010877A2 (en) | 2017-06-13 |
AU2012334405B2 (en) | 2015-10-01 |
SG11201402068YA (en) | 2014-06-27 |
KR20140088549A (en) | 2014-07-10 |
AU2012334405A1 (en) | 2014-05-29 |
RU2564600C1 (en) | 2015-10-10 |
JP2014534818A (en) | 2014-12-25 |
PL2775867T3 (en) | 2019-04-30 |
MX349118B (en) | 2017-07-12 |
ES2677468T3 (en) | 2018-08-02 |
US9497991B2 (en) | 2016-11-22 |
CN103917116A (en) | 2014-07-09 |
US20140290678A1 (en) | 2014-10-02 |
MY168127A (en) | 2018-10-11 |
BR112014010877B1 (en) | 2020-12-01 |
TR201809842T4 (en) | 2018-07-23 |
JP6145104B2 (en) | 2017-06-07 |
EP2775867A1 (en) | 2014-09-17 |
EP2775867B1 (en) | 2018-06-13 |
BR112014010877A8 (en) | 2017-06-20 |
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