CN103911056A - Antibacterial paint - Google Patents

Antibacterial paint Download PDF

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Publication number
CN103911056A
CN103911056A CN201210594512.6A CN201210594512A CN103911056A CN 103911056 A CN103911056 A CN 103911056A CN 201210594512 A CN201210594512 A CN 201210594512A CN 103911056 A CN103911056 A CN 103911056A
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CN
China
Prior art keywords
kilograms
paint
antibiotic paint
mixture
propylene glycol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201210594512.6A
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Chinese (zh)
Inventor
李玉明
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Individual
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Individual
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Publication date
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Priority to CN201210594512.6A priority Critical patent/CN103911056A/en
Publication of CN103911056A publication Critical patent/CN103911056A/en
Pending legal-status Critical Current

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Abstract

The invention relates to antibacterial paint harmless to human body health. The paint is composed of the following compositions in parts by weight: 18-29% of titanium dioxide, 15-30% of acrylic acid copolymerization emulsion, 5-10% of polyethylene wax emulsion, 3-5% of butyldiglycol, 1-3% of a thickening agent, 2-5% of a dispersant, 0.5-3% of an antifoaming agent, 16-28% of deionized water, 3.5-8% of propylene glycol, 2-3% of a coalescing solvent and 10-20% of a castor oil-inorganic metal ion complex. The antibacterial paint is prepared by employing a routine paint preparation method. The paint is simple in preparation technology and convenient to use, and has good inhibiting and killing effect on multiple bacteria and fungi.

Description

Antibiotic paint
Technical field
The invention belongs to building material field, be specifically related to a kind of harmless antibacterial bacteriostatic coating.
Background technology
Along with people's standard of living constantly improves, people are also more and more higher to the requirement of living-hygienic quality, and how effectively antibacterial, degerming is the challenge that people propose the modern life.Antibiotic paint industry is still in developmental stage at present, solves the application art of anti-biotic material in coating, is pendulum common problem in face of coating industry.The coating with anti-microbial effect is called antibiotic paint, is generally in coating, to add sterilant.
Modal commercial sterilization agent is based on following several activeconstituentss: ZPT (ZPT), 3-iodo propinyl-n-normal-butyl carbamate (IPBC), 2-n-n-octyl-4-isothiazoline-3-ketone (OIT), 4, the chloro-2-of 5-bis-(n-octyl group)-4-isothiazoline-3-ketone (DCOIT), derosal (CBZ) and m-tetrachlorophthalodinitrile (CTL).Above-mentioned sterilant is knownly can effectively stop fungi and part algal grown mostly, but its effect for bacterium is completely unclear.And because it is chemosynthesis composition, human body is had to injury in various degree, particularly derosal and m-tetrachlorophthalodinitrile, European sterilant instruction (BPD) more has strict restrictive clause to it.Derosal is strictly reclassified as: in the time containing this active ingredient that exceedes 1000ppm in paint, must indicate " toxicant R46 " (may cause the infringement of heredity gene), and corresponding posting " raw and bloody bones " symbol, emphasize " being only limited to professional person uses ".In the chemical producting safety specification sheets of paint, must show " causing transgenation classification 2 ".M-tetrachlorophthalodinitrile will have R40 label (minority evidence shows carcinogenic consequence).
Money base sterilant is the antibacterial and protective method that another kind is widely known by the people, and in the technical literature of many medical facilities and other polymkeric substance, all has and relates to.But its using method in paint is not still by people is known.Because it has anti-microbial activity, therefore money base sterilant uses as benchmark under study for action.At the isothiazoline base sterilant of U.S.'s new registration, n-butyl-1,2-benzisothiazole-3-ketone is also in research range.
And along with the development of biotechnology, increasing natural radioactivity antimicrobial substance is found, this also provides new thinking for people seek a kind of non-harmful natural antibacterial coating.Viscotrol C is a kind of natural antiseptic-germicide, and its anti-microbial activity has obtained experiment and confirmed, and its application in coating is rarely seen.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of coating that contains natural radioactivity antimicrobial factors, harmless, manufactures simple, easy to use.
Antibiotic paint of the present invention is grouped into by the one-tenth of following weight part:
Titanium dioxide 18~29%, acrylate copolymer emulsion 15~30%, polythene wax emulsion 5~10%, butyl carbitol 3~5%, thickening material 1~3%, dispersion agent 2~5%, defoamer 0.5~3%, deionized water 16~28%, propylene glycol 3.5~8%, agglomerated solvent 2~3%, Viscotrol C-inorganic metal ion title complex 10~20%.
Described film coalescence aid is selected from a kind of in ethylene glycol phenyl ether, phenylcarbinol, propylene glycol phenylate or their mixture.
Described thickening material is selected from a kind of in polyacrylic acid, BK-887A, WT-105A or their mixture.
Described dispersion agent is selected from a kind of in lithium magnesium silicate, OP-5035, OP-8146 or their mixture.
Described defoamer is selected from a kind of in SP-202, XP-1273, F-111, NXZ or their mixture.
The preparation method of antibiotic paint of the present invention is general preparation method in the industry.
The invention has the beneficial effects as follows: adopt crude substance Viscotrol C as antiseptic-germicide, the amount of the harmful chemical in coating is dropped to minimum, can not be detrimental to health.Meanwhile, this coating can kill airborne mould and other bacteriums effectively.This fungicidal paint is easy to use, both can brush with common brush, also can be sprayed on building or decoration surface.
Embodiment
Below in conjunction with specific embodiment, the present invention will be further described, but do not limit the present invention.
Embodiment 1
24 kilograms of titanium dioxides, 20 kilograms of acrylate copolymer emulsions, 6 kilograms of polythene wax emulsions, 4 kilograms of butyl carbitols, 1.5 kilograms of thickening materials, 3 kilograms of dispersion agents, 1 kilogram of defoamer, 19 kilograms of deionized waters, 5 kilograms of propylene glycol, 2.5 kilograms of agglomerated solvents, 14 kilograms of Viscotrol C-inorganic metal ion title complexs.
Embodiment 2
28 kilograms of titanium dioxides, 17 kilograms of acrylate copolymer emulsions, 8 kilograms of polythene wax emulsions, 3 kilograms of butyl carbitols, 3 kilograms of thickening materials, 2 kilograms of dispersion agents, 0.5 kilogram of defoamer, 17 kilograms of deionized waters, 4 kilograms of propylene glycol, 1.5 kilograms of agglomerated solvents, 16 kilograms of Viscotrol C-inorganic metal ion title complexs.
Embodiment 3
20 kilograms of titanium dioxides, 15 kilograms of acrylate copolymer emulsions, 5 kilograms of polythene wax emulsions, 3.5 kilograms of butyl carbitols, 3 kilograms of thickening materials, 3 kilograms of dispersion agents, 1 kilogram of defoamer, 20 kilograms of deionized waters, 7 kilograms of propylene glycol, 2.5 kilograms of agglomerated solvents, 20 kilograms of Viscotrol C-inorganic metal ion title complexs.
Embodiment 4
18 kilograms of titanium dioxides, 28 kilograms of acrylate copolymer emulsions, 6 kilograms of polythene wax emulsions, 4 kilograms of butyl carbitols, 1 kilogram of thickening material, 4 kilograms of dispersion agents, 1 kilogram of defoamer, 22 kilograms of deionized waters, 3.5 kilograms of propylene glycol, 2.5 kilograms of agglomerated solvents, 10 kilograms of Viscotrol C-inorganic metal ion title complexs.
Embodiment 5
22 kilograms of titanium dioxides, 25 kilograms of acrylate copolymer emulsions, 6 kilograms of polythene wax emulsions, 4 kilograms of butyl carbitols, 1.5 kilograms of thickening materials, 3 kilograms of dispersion agents, 1 kilogram of defoamer, 18 kilograms of deionized waters, 5 kilograms of propylene glycol, 2.5 kilograms of agglomerated solvents, 12 kilograms of Viscotrol C-inorganic metal ion title complexs.
The antibiotic paint that above-mentioned 5 embodiment obtain has all carried out antibacterial detection, adopts inhibition zone method, and the fungistatic effect of streptococcus aureus, intestinal bacteria, Pseudomonas aeruginosa, Salmonella hog cholera bacillus and Cray Bai Shi pneumobacillus is evaluated and tested.All see obvious inhibition zone, antibacterial efficient reaching more than 99%.

Claims (5)

1. an antibiotic paint, it is characterized in that being grouped into by the one-tenth of following weight part: titanium dioxide 18~29%, acrylate copolymer emulsion 15~30%, polythene wax emulsion 5~10%, butyl carbitol 3~5%, thickening material 1~3%, dispersion agent 2~5%, defoamer 0.5~3%, deionized water 16~28%, propylene glycol 3.5~8%, agglomerated solvent 2~3%, Viscotrol C-inorganic metal ion title complex 10~20%.
2. antibiotic paint according to claim 1, is characterized in that described film coalescence aid is selected from a kind of in ethylene glycol phenyl ether, phenylcarbinol, propylene glycol phenylate or their mixture.
3. antibiotic paint according to claim 1, is characterized in that described thickening material is selected from a kind of in polyacrylic acid, BK-887A, WT-105A or their mixture.
4. antibiotic paint according to claim 1, is characterized in that described dispersion agent is selected from a kind of in lithium magnesium silicate, OP-5035, OP-8146 or their mixture.
5. antibiotic paint according to claim 1, is characterized in that described defoamer is selected from a kind of in SP-202, XP-1273, F-111, NXZ or their mixture.
CN201210594512.6A 2012-12-31 2012-12-31 Antibacterial paint Pending CN103911056A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201210594512.6A CN103911056A (en) 2012-12-31 2012-12-31 Antibacterial paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201210594512.6A CN103911056A (en) 2012-12-31 2012-12-31 Antibacterial paint

Publications (1)

Publication Number Publication Date
CN103911056A true CN103911056A (en) 2014-07-09

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201210594512.6A Pending CN103911056A (en) 2012-12-31 2012-12-31 Antibacterial paint

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CN (1) CN103911056A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0848917A (en) * 1994-05-31 1996-02-20 Kansai Paint Co Ltd Antibacterial coating composition
CN1563575A (en) * 2004-03-25 2005-01-12 贵州工业大学 Method for preparing antibiosis paper
CN102086327A (en) * 2009-12-07 2011-06-08 戚冬梅 Exterior wall coating
CN102086328A (en) * 2009-12-07 2011-06-08 戚冬梅 Exterior wall coating
CN102757702A (en) * 2012-08-01 2012-10-31 南宁亚多制漆有限公司 Water-based natural biological composite antibacterial coating and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0848917A (en) * 1994-05-31 1996-02-20 Kansai Paint Co Ltd Antibacterial coating composition
CN1563575A (en) * 2004-03-25 2005-01-12 贵州工业大学 Method for preparing antibiosis paper
CN102086327A (en) * 2009-12-07 2011-06-08 戚冬梅 Exterior wall coating
CN102086328A (en) * 2009-12-07 2011-06-08 戚冬梅 Exterior wall coating
CN102757702A (en) * 2012-08-01 2012-10-31 南宁亚多制漆有限公司 Water-based natural biological composite antibacterial coating and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
商成杰: "《纺织品抗菌及防螨整理》", 31 January 2009, 中国纺织出版社 *

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Application publication date: 20140709