CN103909658B - Composite material connecting skirt forming method and mold and inner rubber core mold forming mold - Google Patents

Composite material connecting skirt forming method and mold and inner rubber core mold forming mold Download PDF

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Publication number
CN103909658B
CN103909658B CN201410121135.3A CN201410121135A CN103909658B CN 103909658 B CN103909658 B CN 103909658B CN 201410121135 A CN201410121135 A CN 201410121135A CN 103909658 B CN103909658 B CN 103909658B
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Prior art keywords
mold
inner core
internal model
resin
external mold
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CN103909658A (en
Inventor
张国喜
邓德凤
黄泽勇
曾甜甜
高李帅
霍文静
谭云水
魏虹
姚桂平
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Hubei Sanjiang Space Jiangbei Mechanical Engineering Co Ltd
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Hubei Sanjiang Space Jiangbei Mechanical Engineering Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/30Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
    • B29C70/36Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and impregnating by casting, e.g. vacuum casting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/38Moulds or cores; Details thereof or accessories therefor characterised by the material or the manufacturing process
    • B29C33/3842Manufacturing moulds, e.g. shaping the mould surface by machining
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/30Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
    • B29C70/34Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation
    • B29C70/342Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation using isostatic pressure

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Manufacturing & Machinery (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)

Abstract

The invention discloses a composite material containing skirt forming method and mold and an inner rubber core mold forming mold. The method comprises the following steps: (1) manufacturing the forming mold, namely manufacturing an outer mold, an inner mold and the inner rubber core mold and sheathing the inner rubber core mold on the outer wall of the inner mold; (2) laying up; (3) preheating and vacuumizing the forming mold; (4) carrying out resin pretreatment; (5) injecting glue and solidifying, namely solidifying resin after glue injection, wherein the inner rubber core mold is expanded along with the increase of temperature to uniformly pressing a preform and enable the resin to fully infiltrate the preform; and (6) demolding and trimming. The forming mold structure adopts the inner rubber core mold; silicone rubber is adopted and a resin transfer molding (RTM) process is assisted to form the composite material containing skirt, and a double-sided mold is adopted, so that a product has the advantages of stable dimension, good quality consistence, controllable fiber and resin contents and the like; measures such as co-solidification and the adoption of the expandable core mold are adopted to reduce the porosity, increase the volume content of the fibers of the product and improve the mechanical property.

Description

Composite joint skirt forming method, mould and its rubber inner core mould
Technical field
The present invention relates to solid rocket motor case forming technique, in particular to a kind of molding of composite joint skirt Method, mould and its rubber inner core mould.
Background technology
Solid rocket motor case joint skirt is the overall extension of housing, for realize guided missile interstage section connect or and its The connection of his part, joint skirt need to undergo axle pressure, moment of flexure, shearing, and various load such as intrinsic pressure, and stressing conditions are more complicated, such as In the case of where not increasing joint skirt weight, simplify moulding process, and improve its performance, to whole motor body performance Raising it is most important.
At present, composite joint skirt generally carries out molding using " prepreg overlay+winding " forming method, the molding Method exposes in process of production following problem:1)Only one of which rigidity formpiston in forming process, and product external surfaces adopt Pressurizeed with silvalin winding, when have Le trace, a projection, and depression etc. occurs, it is impossible to ensures the fineness of product external surfaces, and then produces Product overall dimensions are difficult to ensure that;2), using manual frictioning control, which is larger to fibre damage, and frictioning degree for resin content It is wayward, very big is affected on motor body gross weight and specific impulse;3)Cannot composite of the molding with reinforcing rib structure Joint skirt, product structure is less efficient;4)Joint skirt corner fiber is easily maked somebody a mere figurehead, is layered and fold, at present using increasing peace The conservative design mode of overall coefficient does not produce breakage guaranteeing that this is under service load, but this mode reduce further it is multiple Close structure efficiency of skirt etc..
The content of the invention
Present invention aim to provide a kind of forming method of composite joint skirt, mould and its rubber inner core mould Mould, with composite joint skirt excellent in mechanical performance obtained in the forming method and its mould, fiber volume fraction is high, Simultaneously moulding process is simple, easy to operate.
For achieving the above object, the technical solution used in the present invention is:A kind of composite joint skirt forming method, including Following steps:
1)Make mould:Make external mold, internal model, and rubber inner core mould, the profile of the rubber inner core mould with it is compound The interior shape cooperation of material joint skirt, the interior shape of the external mold and the form fit of composite joint skirt, the profile of the internal model Coordinate with the interior shape of the rubber inner core mould;Then the uniform application releasing agent on the internal model outer wall, by the rubber inner core Die sleeve is loaded on the internal model outer wall;
2)Laying:Fibre reinforced materials are cut into into different size and angle and painting is spread after setting agent, it is successively spread It is overlying on the rubber inner core mould, is coated with to certain thickness compacting, until corrugationless, obtains preform;
3)Mould is preheated and evacuation:The external mold and internal model are carried out into matched moulds assembling, then adds mould Heat simultaneously carries out evacuation process;
4)Resin pretreatment:By the uniform rear evacuation of resin agitating;
5)Injecting glue and solidification:Pretreated resin is injected in die cavity carries out molding;Injecting glue is carried out resin after finishing Elevated cure, rubber inner core mould expands as temperature is raised, and uniform pressurization is carried out to preform, so that resin fully soaks Profit preform;
6)The demoulding and pruning:After the demoulding, overlap pruning is carried out to molded body, obtain composite joint skirt.
Further, the step 1)In, the forming method of the rubber inner core mould is comprised the following steps:
A, preparation rubber glue:By rubber latex:Vulcanizing agent=90~99%:1~10% mass ratio prepares rubber glue Liquid, by rubber liquid cement agitation it is uniform after be evacuated to -10~-20Kpa, 30~60min of pressurize, to no longer occurring compared with after gross blow hole Take out stand-by;
B, rubber inner core mold forming:Rubber glue is injected in rubber inner core mould carries out molding;
C, sulfuration and the demoulding:By rubber glue 22~26h of natural vulcanization at room temperature, 95~100 DEG C of guarantors are then heated to 1.0~1.5h of temperature, is finally warming up to 195~205 DEG C of 1.0~1.5h of insulation;The demoulding after room temperature is cooled to, rubber inner core is obtained Mould.
Further, the step 2)In, laying angle is 0 °, ± 15 °, ± 30 °, ± 45 °, ± 60 ° and 90 °.
Further, the step 5)In, resin implantation temperature is 20~150 DEG C, and injection pressure is 0.1~0.8MPa.
Further, the step 5)In, resin curing conditions are:100~150 DEG C of 1~4h of insulation, then heat to 180~200 DEG C of 1~4h of insulation, are finally warming up to 210~250 DEG C of 2~10h of insulation.
Further, the step 1)In, the moulding material of the rubber inner core mould is R10301 silicone rubber;The demoulding Agent is silicone grease or PMR-70.
Further, the step 2)In, the fibre reinforced materials are glass fabric or carbon cloth.
Further, the step 4)In, the resin is bismaleimide resin or epoxy resin.
A kind of composite joint skirt mould designed to realize said method, including internal model and external mold, it is described Coaxial laminating on internal model outer wall is set with rubber inner core mould, and the external mold coaxial package is in the periphery of the rubber inner core mould, institute State internal model top and be connected with pressing plate, the top surface of the pressing plate is connected with the top of the external mold, and the bottom of the internal model is connected with water conservancy diversion Plate, the bottom of deflector is connected with cover plate, the periphery of the cover plate along be connected with the bottom of the external mold, the rubber inner core mould and The external mold, internal model, pressing plate, and deflector surrounds joint skirt shaping mold cavity, is provided with what is connected with the die cavity on the cover plate Gum-injecting port, the outer mold top is provided with the gum exudation mouth connected with the die cavity.
A kind of rubber inner core mould of the composite joint skirt molding designed to realize said method, including Molding internal model, the periphery coaxial sleeve of the molding internal model is equipped with the first external mold, and molding internal model top outer is connected with outside second Mould, the internal model, the first external mold, and the second external mold surround rubber inner core mold forming die cavity, and second external mold is provided with discharging Mouthful.
Compared with prior art, the invention has the advantages that:
First, the present invention carries out the molding of composite joint skirt using silicone rubber assisted RTM technique, due to using two-sided Making mold so that product has dimensionally stable, quality conformance good, and the advantages of fiber and controllable resin content, solves The wayward problem of frictioning degree that manual frictioning is caused, it also avoid built on stilts joint skirt corner fiber, layering and fold Phenomenon;Simultaneously product porosity is reduced using the means such as co-curing and expandable rubber core, improve the corpus fibrosum of product Product content and mechanical property.
Second, this forming method integrated molding, the apparent color and luster of product is homogeneous, and internal bonding is good, high precision, without the need for right The fibrous layer machine of carrying out adds, it is to avoid machine adds the damage to fiber;And the composite joint skirt that reinforcing rib structure can be carried with molding, Improve product structure efficiency compared with.
Third, mould adopts rubber pattern as inner core die, in the curing process, with temperature rising, rubber inner core Mould expands, and carries out uniform pressurization to preform in whole process so that resin fully infiltrates preform, it is ensured that in product Portion's resin is uniformly distributed, and improves the fiber volume fraction of product, while substantially increasing the mechanical property of material.
Description of the drawings
Fig. 1 is a kind of cross-sectional view of composite joint skirt mould.
Fig. 2 is a kind of cross-sectional view of rubber inner core mould.
Specific embodiment
With reference to the accompanying drawings and examples the present invention is described in further detail, is easy to more clearly understand this It is bright, but they do not constitute restriction to the present invention.
It is a kind of composite joint skirt mould used in following examples shown in Fig. 1, including internal model 1 and outer Mould 2, coaxial laminating on the outer wall of internal model 1 is set with rubber inner core mould 3, and the coaxial package of external mold 2 is interior in the periphery of rubber inner core mould 3 The top of mould 1 is connected with pressing plate 4, and the top surface of pressing plate 4 is connected with the top of external mold 2, and the bottom of internal model 1 is connected with deflector 5, deflector 5 Bottom be connected with cover plate 6, the periphery of cover plate 6 along be connected with the bottom of external mold 2, rubber inner core mould 3 and external mold 2, internal model 1, pressing plate 4, and deflector 5 surrounds joint skirt shaping mold cavity 7, and the gum-injecting port 8 connected with die cavity 7 is provided with cover plate 6, the top of external mold 2 is provided with The gum exudation mouth 9 connected with die cavity 7, is provided with the seal groove 10 for installing sealing strip between the top surface of internal model 1 and the bottom surface of pressing plate 4, lead Seal groove is also had between stream plate 5 and cover plate 6, between deflector 5 and the bottom surface of internal model 1.
It is a kind of rubber inner core mould used in following examples shown in Fig. 2, including molding internal model 14, into The periphery coaxial sleeve of type internal model 14 is equipped with the first external mold 15, and the top outer of molding internal model 14 is connected with the second external mold 16, internal model 14, the One external mold 15, and the second external mold 16 surrounds rubber inner core mold forming die cavity 17, the second external mold 16 is provided with discharge port 18.
Embodiment 1
The motor body manufactured in the present embodiment size and performance parameter such as table 1 below of composite joint skirt:
Table 1
Sequence number Project Unit Index
1 Flange inner diameter mm φ400.0
2 End face wall thickness mm 6.0
3 Skirt height mm 100.0
4 Cylinder section wall thickness mm 3.0
5 Axle pressure kN ≥500.0
6 Fiber volume fraction % ≥60
Should
The forming method of composite joint skirt is comprised the following steps:
1)Make mould:Make external mold, internal model, and rubber inner core mould, the profile of the rubber inner core mould with it is compound The interior shape cooperation of material joint skirt, the interior shape of the external mold and the form fit of composite joint skirt, the profile of the internal model Coordinate with the interior shape of the rubber inner core mould;Then one layer of releasing agent of uniform application on the internal model outer wall, releasing agent is silicon Fat or PMR-70, by the rubber inner core die sleeve internal model outer wall is loaded on;
Wherein, the process using rubber inner core mould molded rubber inner core die is as follows:
A, preparation rubber glue:Using R10301 rubber, according to rubber latex:Vulcanizing agent=90~99%:1~10%, preferably 90%:10% mass ratio prepares 5kg rubber glues, stirs, and at ambient temperature rubber glue is put into into vacuum tank, takes out Vacuum to vacuum is -10~-20Kpa, preferably -10Kpa, 30~60min of pressurize, preferred 30min, to no longer occurring compared with air Take out behind hole stand-by;
B, rubber inner core mold forming:Molding inner mould surface is cleaned out into rear uniform application silicone grease, then respectively with first External mold and the second external mold are assembled, and rubber glue is carried out into molding from discharge port injection rubber inner core mould;
C, sulfuration and the demoulding:Injecting glue is finished, by rubber glue 22~26h of natural vulcanization, preferred 24h at room temperature;Then 95~100 DEG C are warming up to, preferably 100 DEG C, 1.0~1.5h, preferred 1.0h is incubated;Finally it is warming up to 195~205 DEG C, preferably 200 DEG C, it is incubated 1.0~1.5h, preferred 1h;The demoulding after room temperature is naturally cooled to, rubber inner core mould is obtained;
2)Preform laying:40 blocks of carbon cloths of cutting or glass fabric apply spread after setting agent according to(0°)2/ (± 15 °, ± 30 °, ± 45 °, ± 60 °)9/90°2Order, be successively coated with from the inside to the outside on rubber inner core mould(Fiber laying 0 ° of direction is defined as internal model ring), it is coated with to end face wall thickness 6.0mm, cylinder section wall thickness 3.0mm, prune away excess fiber cloth, adopts Vacuum bag coated after evacuation compacting, until all of fiber be compacted, corrugationless, that is, obtain preform;
3)Mould is preheated and evacuation:The external mold 2 and internal model 1 are carried out into matched moulds assembling, i.e.,:First in internal model 1 Sealing strip is loaded onto in seal groove 10, then pressing plate 4 and internal model 1 fastened by the first screw 11 successively, by external mold 2 with press Plate 4 is fastened, is fastened deflector 5 with internal model 1 by the second screw 12, finally cover plate 6 and external mold 2 is passed through into the 3rd Screw 13 is fastened;Then mould is heated to into 130 DEG C, and carries out evacuation process;
4)Resin pretreatment:By bismaleimide resin at 20~150 DEG C, evacuation after stirring at preferably 130 DEG C;
5)Injecting glue and solidification:By pretreated bismaleimide resin in 0.1~0.8MPa, from two under preferred 0.5MPa pressure Injecting in die cavity simultaneously in gum-injecting port carries out molding, after injecting glue is finished, resin is solidified according to following curing cycle:100 ~150 DEG C, preferably 150 DEG C, it is incubated 1~4h, preferred 4h;180~200 DEG C are then heated to, preferably 180 DEG C, 1~4h is incubated, It is preferred that 2h;210~250 DEG C are finally warming up to, preferably 220 DEG C, 2~10h, preferred 6h is incubated, rubber inner core mould is with temperature liter It is high and expand, uniform pressurization is carried out to preform, so that resin fully infiltrates preform;
6)The demoulding and pruning:Overlap pruning is carried out to composite joint skirt product, composite joint skirt finished product is obtained.
After testing, the performance indications such as table 2 below of the composite joint skirt of above-mentioned molding:
Table 2
Sequence number Project Unit As a result
1 Axle pressure kN 620.7
2 Fiber volume fraction % 65.0
From the data in table 2, it can be seen that obtained composite joint skirt mechanical property is good, fiber volume fraction is big.
Embodiment 2
The motor body manufactured in the present embodiment size and performance parameter such as table 3 below of composite joint skirt:
Table 3
Sequence number Project Unit Index
1 Flange inner diameter mm φ1200
2 End face wall thickness mm 12.0
3 Skirt height mm 250.0
4 Cylinder section wall thickness mm 8.0
5 Axle pressure kN ≥1000.0
6 Fiber volume fraction % ≥60
The forming method of the composite joint skirt is comprised the following steps:
1)Make mould:Make external mold, internal model, and rubber inner core mould, the profile of the rubber inner core mould with it is compound The interior shape cooperation of material joint skirt, the interior shape of the external mold and the form fit of composite joint skirt, the profile of the internal model Coordinate with the interior shape of the rubber inner core mould;Then one layer of releasing agent of uniform application on the internal model outer wall, by the rubber Inner core die is set in the internal model outer wall;
Wherein, the process using rubber inner core mould molded rubber inner core die is as follows:
A, preparation rubber glue:Using R10301 rubber, according to rubber latex:Vulcanizing agent=95%:5% mass ratio is matched somebody with somebody 5kg rubber glue processed, stirs, and at ambient temperature rubber glue is put into into vacuum tank, be evacuated to vacuum for- 20Kpa, pressurize 45min, to no longer occurring compared with taking out stand-by after gross blow hole;
B, rubber inner core mold forming:By the removing surface of molding internal model 14 it is clean after uniform application silicone grease, then respectively with the One external mold 15 and the second external mold 16 are assembled, and rubber glue is injected in rubber inner core mould from discharge port 18 to be carried out Molding;
C, sulfuration and the demoulding:Injecting glue is finished, and by rubber glue natural vulcanization 24h at room temperature, then heats to 100 DEG C of guarantors Warm 1.0h, is finally warming up to 200 DEG C of insulation 1h;The demoulding after room temperature is naturally cooled to, rubber inner core mould is obtained;
2)Preform laying:80 blocks of carbon cloths of cutting, painting spread after setting agent according to(0°)4/(± 15 °, ± 30 °, ± 45 °, ± 60 °)18/90°4Order, be successively coated with from the inside to the outside on rubber inner core mould(0 ° of direction of fiber laying is defined as Internal model ring), it is coated with to end face wall thickness 12.0mm, cylinder section wall thickness 8.0mm, prune away excess fiber cloth, is carried out using vacuum bag After cladding evacuation compacting, until all of fiber be compacted, corrugationless, that is, obtain preform;
3)Mould evacuation:The external mold and internal model are carried out into matched moulds assembling, i.e.,:It is built-in in internal model seal groove first Upper sealing strip, then successively pressing plate and internal model fastened by screw 2, external mold and pressing plate are fastened by screw 1, Deflector is fastened with internal model, finally cover plate is fastened by screw 3 with external mold;Then mould is taken out Application of vacuum;
4)Resin pretreatment:Epoxy resin is stirred at room temperature into uniform rear evacuation;
5)Injecting glue and solidification:Pretreated epoxy resin is injected simultaneously under 0.3MPa pressure from two gum-injecting ports Molding is carried out in die cavity, after injecting glue is finished, resin is solidified according to following curing cycle:80 DEG C of insulation 4h, then heat up To 100 DEG C of insulation 4h, 120 DEG C of insulation 6h are finally warming up to, rubber inner core mould expands as temperature is raised, preform is entered Row uniform pressurization, so that resin fully infiltrates preform;
6)The demoulding and pruning:Overlap pruning is carried out to composite joint skirt product, composite joint skirt finished product is obtained.
After testing, the performance indications such as table 4 below of the composite joint skirt of above-mentioned molding:
Table 4
Sequence number Project Unit As a result
1 Axle pressure kN 1427.0
2 Fiber volume fraction % 72.1
From the data in table 4, it can be seen that obtained composite joint skirt mechanical property is good, fiber volume fraction is big.

Claims (7)

1. a kind of composite joint skirt forming method, comprises the following steps:
1) mould is made:Make external mold, internal model, and rubber inner core mould, the profile and composite of the rubber inner core mould The interior shape cooperation of joint skirt, the interior shape of the external mold and the form fit of composite joint skirt, the profile of the internal model and institute The interior shape for stating rubber inner core mould coordinates;Then the uniform application releasing agent on the internal model outer wall, by the rubber inner core die sleeve Loaded on the internal model outer wall;
2) laying:By fibre reinforced materials be cut into different size and angle and painting spread after setting agent, it is successively coated with On the rubber inner core mould, compacting is coated with to certain thickness, until corrugationless, obtains preform;Laying angle is 0 °, ± 15 °, ± 30 °, ± 45 °, ± 60 ° and 90 °;
3) mould preheating and evacuation:The external mold and internal model are carried out into matched moulds assembling, then mould is heated simultaneously Carry out evacuation process;
4) resin pretreatment:By the uniform rear evacuation of resin agitating;
5) injecting glue and solidification:Pretreated resin is injected in die cavity carries out molding;Injecting glue is heated up resin after finishing Solidification, rubber inner core mould expands as temperature is raised, and uniform pressurization is carried out to preform, so that resin fully infiltrates pre- Molded body;Resin curing conditions are:100~150 DEG C of 1~4h of insulation, then heat to 180~200 DEG C of 1~4h of insulation, finally It is warming up to 210~250 DEG C of 2~10h of insulation;
6) demoulding and pruning:After the demoulding, overlap pruning is carried out to molded body, obtain composite joint skirt;
The step 1) in, the forming method of the rubber inner core mould is comprised the following steps:
A, preparation rubber glue:By rubber latex:Vulcanizing agent=90~99%:1~10% mass ratio prepares rubber glue, By rubber liquid cement agitation it is uniform after be evacuated to -10~-20Kpa, 30~60min of pressurize, to no longer occurring being taken compared with after gross blow hole Go out stand-by;
B, rubber inner core mold forming:Rubber glue is injected in rubber inner core mould carries out molding;
C, sulfuration and the demoulding:By rubber glue 22~26h of natural vulcanization at room temperature, 95~100 DEG C of insulations 1.0 are then heated to ~1.5h, is finally warming up to 195~205 DEG C of 1.0~1.5h of insulation;The demoulding after room temperature is cooled to, rubber inner core mould is obtained.
2. composite joint skirt forming method according to claim 1, it is characterised in that:The step 5) in, resin Implantation temperature is 20~150 DEG C, and injection pressure is 0.1~0.8MPa.
3. composite joint skirt forming method according to claim 1, it is characterised in that:The step 1) in, it is described The moulding material of rubber inner core mould is R10301 silicone rubber;The releasing agent is silicone grease or PMR-70.
4. composite joint skirt forming method according to claim 1, it is characterised in that:The step 2) in, it is described Fibre reinforced materials are glass fabric or carbon cloth.
5. composite joint skirt forming method according to claim 1, it is characterised in that:The step 4) in, it is described Resin is bismaleimide resin or epoxy resin.
6. a kind of composite joint skirt mould designed to realize claim 1 methods described, including internal model (1) and External mold (2), it is characterised in that:Coaxial laminating on internal model (1) outer wall is set with rubber inner core mould (3), and the external mold (2) is same Axle sleeve is mounted in the periphery of the rubber inner core mould (3), and internal model (1) top is connected with pressing plate (4), the top surface of the pressing plate (4) It is connected with the top of the external mold (2), the bottom of the internal model (1) is connected with deflector (5), and the bottom of the deflector (5) connects Have a cover plate (6), the periphery of the cover plate (6) along being connected with the bottom of the external mold (2), the rubber inner core mould (3) with it is described External mold (2), internal model (1), pressing plate (4), and deflector (5) surrounds joint skirt shaping mold cavity (7), be provided with the cover plate (6) with The gum-injecting port (8) of die cavity (7) connection, external mold (2) top is provided with the gum exudation mouth (9) connected with the die cavity (7).
7. a kind of rubber inner core mold forming mould of the composite joint skirt molding designed to realize claim 1 methods described Tool, it is characterised in that:Including molding internal model (14), the periphery coaxial sleeve of the molding internal model (14) is equipped with the first external mold (15), Molding internal model (14) top outer is connected with the second external mold (16), the internal model (14), the first external mold (15), and the second external mold (16) rubber inner core mold forming die cavity (17) is surrounded, second external mold is provided with discharge port (18).
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