CN1039063A - New processing technology for high ice nickel - Google Patents
New processing technology for high ice nickel Download PDFInfo
- Publication number
- CN1039063A CN1039063A CN 88105087 CN88105087A CN1039063A CN 1039063 A CN1039063 A CN 1039063A CN 88105087 CN88105087 CN 88105087 CN 88105087 A CN88105087 A CN 88105087A CN 1039063 A CN1039063 A CN 1039063A
- Authority
- CN
- China
- Prior art keywords
- nickel
- high ice
- processing technology
- new processing
- ice nickel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 87
- 229910052759 nickel Inorganic materials 0.000 title claims abstract description 43
- 238000005516 engineering process Methods 0.000 title claims abstract description 10
- 238000006477 desulfuration reaction Methods 0.000 claims abstract description 10
- 230000023556 desulfurization Effects 0.000 claims abstract description 10
- 230000006698 induction Effects 0.000 claims abstract description 5
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical group [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 15
- 239000002893 slag Substances 0.000 claims description 14
- 239000011734 sodium Substances 0.000 claims description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- 230000018044 dehydration Effects 0.000 claims description 7
- 238000006297 dehydration reaction Methods 0.000 claims description 7
- 235000010265 sodium sulphite Nutrition 0.000 claims description 7
- 238000005266 casting Methods 0.000 claims description 6
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 5
- 238000013467 fragmentation Methods 0.000 claims description 5
- 238000006062 fragmentation reaction Methods 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims description 4
- 229910001634 calcium fluoride Inorganic materials 0.000 claims description 4
- 239000010439 graphite Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 238000003723 Smelting Methods 0.000 abstract description 14
- 238000000034 method Methods 0.000 abstract description 12
- 229910001220 stainless steel Inorganic materials 0.000 abstract description 6
- 239000010935 stainless steel Substances 0.000 abstract description 6
- 238000009628 steelmaking Methods 0.000 abstract description 6
- 229910000831 Steel Inorganic materials 0.000 abstract description 5
- 239000010959 steel Substances 0.000 abstract description 5
- 229910000863 Ferronickel Inorganic materials 0.000 abstract description 3
- 239000002699 waste material Substances 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 229910004261 CaF 2 Inorganic materials 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910005347 FeSi Inorganic materials 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 229910000570 Cupronickel Inorganic materials 0.000 description 1
- 238000006124 Pilkington process Methods 0.000 description 1
- 240000003936 Plumbago auriculata Species 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 description 1
- 238000005188 flotation Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- UGKDIUIOSMUOAW-UHFFFAOYSA-N iron nickel Chemical compound [Fe].[Ni] UGKDIUIOSMUOAW-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
Landscapes
- Manufacture And Refinement Of Metals (AREA)
Abstract
The invention relates to the novel process that high ice nickel is handled, belong to the Metal smelting technology, smelting stainless steel and what contain that nickel steel adopts is electrolytic nickel, this smelting process wastes energy and the cost height.The present invention adopts the non-vacuum induction furnace decopper(ing) and handles through desulfurization, height ice nickel is become the ferronickel that meets steel-making requirements be used for smelting stainless steel, is characterized in saving the energy, reduces cost.
Description
The invention belongs to the Metal smelting technology, is a kind of novel process of handling high ice nickel.
Domestic smelting stainless steel and other nickel steel all adopt highly purified electrolytic nickel, the smelting process of electrolytic nickel is at first to obtain high ice nickel by the nickel minerals powder after the flotation through roasting → electrosmelting → blowing than more complicated, high ice nickel adopts layering smelting process or mill float glass process to carry out copper-nickel separation again, form anode nickel again, but, containing nickel steel with electrolytic nickel smelting stainless steel and other is a kind of great waste, and does not still have a way with nickel-iron smelting is domestic.
The objective of the invention is to solve smelting stainless steel and other and contain nickel steel and use the electrolytic nickel problems such as cost height that waste energy, a kind of novel process of directly smelting into ferronickel from height ice nickel is provided from economic angle.
Technological process of the present invention can be summarized in following steps:
1. height is iced the nickel fragmentation and 2. delivered to decopper(ing) in the non-vacuum induction furnace, used slag charge is sodium sulphite (Na
2S) 3. bottom ingot casting and 4. desulfurization of fragmentation, ingot casting.
Sodium sulphite (Na
2S) through processed, its degree of dehydration reaches each hundred kilograms and obtains 75 kilograms of dehydration sulfureted sodium (Na in (kg) left and right sides
2S);
What desulfurization was adopted is that lining electroslag furnace or electric furnace are arranged;
It is to use the graphite matter that is knotted into by Graphite Powder 99 and tar as furnace lining that lining electroslag furnace or electric furnace are arranged.
In the sweetening process, the slag charge proportioning is calcium oxide (CaO): Calcium Fluoride (Fluorspan) (CaF
2): firebrick piece=5: 2: 1, the slag charge amount is worked as with processing material (high ice nickel) heavy phase.
The present invention utilizes the non-vacuum induction furnace decopper(ing), and copper can take off to below 2.00%, and utilizing has lining electroslag furnace or electric furnace desulfurization, and sulphur can take off to below 0.5%.Because high ice nickel adopts above-mentioned technology to obtain meeting the ferronickel of steel-making requirements, and can be directly used in steel-making, therefore can reduce steel-making cost greatly, saves the energy, and found an effective way for smelting stainless steel.
Accompanying drawing is a process flow sheet of the present invention.
In the accompanying drawing, high ice nickel is delivered in the non-vacuum induction furnace through after the fragmentation, adds sodium sulphite (Na simultaneously
2S), at a certain temperature, the way of employing plumbago crucible operate continuously reaches and removes contained copper in the high ice nickel.The sodium sulphite that adopts must be through processed, and its degree of dehydration obtains the dehydration sulfureted sodium in the 75kg left and right sides with each hundred kilograms and is advisable.Dehydration postcure sodium (Na
2S) consumption accounts for about 20% of high ice nickel weight; The high ice of dress nickel along with fusing, is treated to add after fusion sodium sulphite moisture content purifies high-power again earlier.Smelting temperature will be controlled at below 1000 ℃, and after decopper(ing) finished, slag was advisable with blood red, and nickel liquid and slag all injected ingot mould, be divided into upper and lower two-layerly after the cooling, the compound of the cupric sulfide-sodium sulphite on upper strata is removed, remaining lower floor ingot casting changes next step over to.
With the fragmentation of the ice of the height behind decopper(ing) nickel ingot casting, be put into lining electroslag furnace or electric furnace then and carried out desulfurization, it is to adopt graphite matter as furnace lining.It is formed by Graphite Powder 99 and tar knotting, and the slag charge proportioning is calcium oxide (CaO): Calcium Fluoride (Fluorspan) (CaF
2): firebrick piece=5: 2: 1, the quantity of slag and processing material (high ice nickel) heavy phase is worked as.Adopt FeSi piece and FeSi powder to carry out deoxidation, adopting skims and make new slag method increases the quantity of slag, until sulphur is taken off qualified till.In case of necessity, can adopt powder-spraying intensified desulfurization, promptly spray into calcium oxide (CaO): Calcium Fluoride (Fluorspan) (CaF
2The pulvis of)=4: 1, straying quatity 250 kg/ton adopt argon gas or nitrogen to spray into, and the pressure that dusts is 3 pressure.
Sulphur is with Ni in the high ice nickel
3S
2, Cu
2S, forms such as FeS, CoS exist, and employing CaO powder decopper(ing) generates CaS and is dissolved in the slag, and this method is better than roasting method, does not have SO
2Effusion, can avoid polluting.Based on this, similar with steel desulfurization, have following reaction formula:
The height ice nickel major ingredient of handling through the present invention is:
Alloying element (%): S P Fe Cu Ni Si
Before high ice nickel is handled: 22.0-4/5 〉=8 58/65-
High ice nickel is handled the back: surplus the 0.004/0.5 0.04 〉=2 75,/91 5/12
Height ice nickel ingot after this processing can satisfy steel-making requirements, and replace electrolytic nickel to be used for steel-making, and the rate of recovery of nickel reaches more than 85%.
Claims (5)
1, new processing technology for high ice nickel is characterized in that it is through following step:
1) height is iced the nickel fragmentation;
2) deliver to decopper(ing) in the non-vacuum induction furnace, slag charge is sodium sulphite (Na
2S);
3) bottom ingot casting and broken;
4) desulfurization, ingot casting.
2, according to the described new processing technology for high ice nickel of claim 1, it is characterized in that in the decopper(ing) slag charge sodium sulphite (Na
2S) through processed, its degree of dehydration reaches each hundred kilograms and obtains 75 kilograms of dehydration sulfureted sodium (Na in the left and right sides
2S).
3, according to claim 1 or 2 described new processing technology for high ice nickel, what it is characterized in that the desulfurization employing is that lining electroslag furnace or electric furnace are arranged.
4, according to the described new processing technology for high ice nickel of claim 3, it is characterized in that having lining electroslag furnace or electric furnace is to use the graphite matter that is knotted into by Graphite Powder 99 and tar as furnace lining.
5,, it is characterized in that used slag charge proportioning is calcium oxide (CaO) in the desulfurization: Calcium Fluoride (Fluorspan) (CaF according to the described new processing technology for high ice nickel of claim 4
2): firebrick piece=5: 2: 1, the slag charge amount is worked as with processing material (high ice nickel) heavy phase.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 88105087 CN1039063A (en) | 1988-07-07 | 1988-07-07 | New processing technology for high ice nickel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 88105087 CN1039063A (en) | 1988-07-07 | 1988-07-07 | New processing technology for high ice nickel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1039063A true CN1039063A (en) | 1990-01-24 |
Family
ID=4833317
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 88105087 Pending CN1039063A (en) | 1988-07-07 | 1988-07-07 | New processing technology for high ice nickel |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1039063A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105177307A (en) * | 2015-09-06 | 2015-12-23 | 中南大学 | Method for recycling copper-nickel-cobalt from low grade nickel matte through abrasive flotation separation |
| CN106636613A (en) * | 2016-11-16 | 2017-05-10 | 中南大学 | Preparation method of high-grade matte nickel oxidized calcined sand |
| CN107245643A (en) * | 2017-04-19 | 2017-10-13 | 广西盛隆冶金有限公司 | A kind of sea sand ore deposit and lateritic nickel ore preprocess method |
| CN111394597A (en) * | 2020-04-01 | 2020-07-10 | 河套学院 | A method for nickel-containing sludge sulfidation roasting-alkaline smelting to separate nickel |
-
1988
- 1988-07-07 CN CN 88105087 patent/CN1039063A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105177307A (en) * | 2015-09-06 | 2015-12-23 | 中南大学 | Method for recycling copper-nickel-cobalt from low grade nickel matte through abrasive flotation separation |
| CN106636613A (en) * | 2016-11-16 | 2017-05-10 | 中南大学 | Preparation method of high-grade matte nickel oxidized calcined sand |
| CN107245643A (en) * | 2017-04-19 | 2017-10-13 | 广西盛隆冶金有限公司 | A kind of sea sand ore deposit and lateritic nickel ore preprocess method |
| CN111394597A (en) * | 2020-04-01 | 2020-07-10 | 河套学院 | A method for nickel-containing sludge sulfidation roasting-alkaline smelting to separate nickel |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106399692B (en) | A kind of concentration smelting method that cupric solid wastes recycling utilizes | |
| US5865872A (en) | Method of recovering metals and producing a secondary slag from base metal smelter slag | |
| CA1084719A (en) | Process for treating lead-copper-sulphur charges | |
| Guo et al. | Element distribution in oxygen-enriched bottom-blown smelting of high-arsenic copper dross | |
| CN114381606A (en) | Recycling harmless treatment method for copper smelting lead-and zinc-containing intermediate product | |
| CN1167819C (en) | Method for production of blister copper in suspension reactor | |
| CN101113486A (en) | A kind of hot metal desulfurization pretreatment slag modifier and preparation method thereof | |
| CN86104384A (en) | The dc arc furnace method | |
| CN1039063A (en) | New processing technology for high ice nickel | |
| CN103937992A (en) | Method for recycling copper scum during top-blown furnace smelting lead refining process | |
| US4135912A (en) | Electric smelting of lead sulphate residues | |
| CN210122585U (en) | Pyrometallurgical zinc smelting system | |
| CN107739841A (en) | A kind of method for separating arsenic from containing the high copper dross slag of arsenic, reclaiming copper | |
| EP0117325A1 (en) | A method of zinc smelting by injection smelting | |
| CN1023610C (en) | Electroslag induction refining process as one special smelting process | |
| RU2169202C1 (en) | Method of continuous processing of copper concentrate into blister copper | |
| CN112143908B (en) | Smelting process for treating complex gold ore | |
| CN1023718C (en) | Method for treating nickel oxide ore | |
| FI73741C (en) | Process for continuous production of raw cups. | |
| CN110106531A (en) | A kind of molten-salt electrolysis copper sulfide synchronizes the method for preparing metallic copper and sulphur | |
| CN108559854A (en) | A kind of copper ashes method of comprehensive utilization being vacuum-treated based on the more atmosphere of RH stoves | |
| CA1060217A (en) | Process for separating nickel, cobalt and copper | |
| US4021235A (en) | Operating method for slag cleaning furnace in copper refining | |
| CN101189351B (en) | Method for reducing and/or refining a metal-containing slag | |
| CN116179868B (en) | Method, device and application for recycling rare noble metals in coordination with lead and zinc smelting |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |