CN103904034A - P-BiCS structure and formation method thereof - Google Patents
P-BiCS structure and formation method thereof Download PDFInfo
- Publication number
- CN103904034A CN103904034A CN201410078622.6A CN201410078622A CN103904034A CN 103904034 A CN103904034 A CN 103904034A CN 201410078622 A CN201410078622 A CN 201410078622A CN 103904034 A CN103904034 A CN 103904034A
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- China
- Prior art keywords
- layer
- forming
- sacrificial layer
- bics
- tubular channel
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- 238000000034 method Methods 0.000 title claims abstract description 27
- 230000015572 biosynthetic process Effects 0.000 title claims description 13
- 239000000463 material Substances 0.000 claims abstract description 79
- 229910052751 metal Inorganic materials 0.000 claims abstract description 23
- 239000002184 metal Substances 0.000 claims abstract description 23
- 239000002131 composite material Substances 0.000 claims abstract description 21
- 238000005530 etching Methods 0.000 claims abstract description 16
- 238000000151 deposition Methods 0.000 claims abstract description 13
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims abstract description 11
- 229920005591 polysilicon Polymers 0.000 claims abstract description 11
- 239000000758 substrate Substances 0.000 claims abstract description 9
- 238000001259 photo etching Methods 0.000 claims abstract 2
- 238000005260 corrosion Methods 0.000 claims description 15
- 230000007797 corrosion Effects 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 13
- 238000003860 storage Methods 0.000 claims description 7
- 238000001039 wet etching Methods 0.000 claims description 7
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 5
- 230000000903 blocking effect Effects 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 239000010937 tungsten Substances 0.000 claims description 3
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 2
- 239000005751 Copper oxide Substances 0.000 claims 1
- 229910000431 copper oxide Inorganic materials 0.000 claims 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 1
- 238000005215 recombination Methods 0.000 claims 1
- 230000006798 recombination Effects 0.000 claims 1
- 230000005641 tunneling Effects 0.000 claims 1
- 239000010410 layer Substances 0.000 description 46
- 230000004888 barrier function Effects 0.000 description 18
- 238000010276 construction Methods 0.000 description 15
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- 229910004298 SiO 2 Inorganic materials 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 230000008021 deposition Effects 0.000 description 5
- 238000003475 lamination Methods 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229960004643 cupric oxide Drugs 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 229910000449 hafnium oxide Inorganic materials 0.000 description 1
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 238000001459 lithography Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
Images
Classifications
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B43/00—EEPROM devices comprising charge-trapping gate insulators
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/01—Manufacture or treatment
- H10D64/031—Manufacture or treatment of data-storage electrodes
- H10D64/037—Manufacture or treatment of data-storage electrodes comprising charge-trapping insulators
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- Non-Volatile Memory (AREA)
- Semiconductor Memories (AREA)
Abstract
本发明公开了P-BiCS结构及其形成方法,该方法包括:提供衬底和衬垫层;在衬垫层顶部光刻出管形通道图案并刻蚀出凹槽;在凹槽中淀积第一材料以形成管形通道牺牲层;在衬垫层之上交替淀积第二材料和第三材料以形成绝缘层和控制栅牺牲层的叠层结构;在叠层结构中形成垂直刻蚀孔,垂直刻蚀孔的底部与管形通道牺牲层的端部接触;去除管形通道牺牲层,以使管形通道牺牲层两端的垂直刻蚀孔连通;填充多晶硅以形成U形导电通道;在叠层结构中刻蚀中央沟槽,以将U形导电通道的两个垂直段的各自周围的叠层结构分隔开;去除控制栅牺牲层;淀积形成电荷俘获复合层;淀积形成控制栅极。本发明可以得到具有金属栅极和电荷俘获复合层结构的P-BiCS结构,电学性能良好。
The invention discloses a P-BiCS structure and a forming method thereof. The method includes: providing a substrate and a pad layer; photoetching a tubular channel pattern and etching a groove on the top of the pad layer; depositing The first material is used to form a tubular channel sacrificial layer; the second material and the third material are alternately deposited on the liner layer to form a stacked structure of an insulating layer and a control gate sacrificial layer; vertical etching is formed in the stacked structure hole, the bottom of the vertically etched hole is in contact with the end of the sacrificial layer of the tubular channel; the sacrificial layer of the tubular channel is removed so that the vertically etched holes at both ends of the sacrificial layer of the tubular channel are connected; polysilicon is filled to form a U-shaped conductive channel; Etching the central trench in the stack structure to separate the respective surrounding stack structures of the two vertical segments of the U-shaped conductive channel; removing the sacrificial layer of the control gate; depositing and forming a charge trapping composite layer; depositing and forming control grid. The invention can obtain a P-BiCS structure with a metal gate and a charge-trapping composite layer structure, and has good electrical performance.
Description
Claims (10)
Priority Applications (1)
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CN201410078622.6A CN103904034A (en) | 2014-03-05 | 2014-03-05 | P-BiCS structure and formation method thereof |
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CN201410078622.6A CN103904034A (en) | 2014-03-05 | 2014-03-05 | P-BiCS structure and formation method thereof |
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CN103904034A true CN103904034A (en) | 2014-07-02 |
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CN201410078622.6A Pending CN103904034A (en) | 2014-03-05 | 2014-03-05 | P-BiCS structure and formation method thereof |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102623458A (en) * | 2008-12-24 | 2012-08-01 | 海力士半导体有限公司 | Vertical channel type nonvolatile memory device and manufacturing method thereof |
US20120217564A1 (en) * | 2011-02-25 | 2012-08-30 | Tang Sanh D | Semiconductor charge storage apparatus and methods |
US20130221423A1 (en) * | 2012-02-29 | 2013-08-29 | Kabushiki Kaisha Toshiba | Nonvolatile semiconductor memory device and method for manufacturing same |
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2014
- 2014-03-05 CN CN201410078622.6A patent/CN103904034A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102623458A (en) * | 2008-12-24 | 2012-08-01 | 海力士半导体有限公司 | Vertical channel type nonvolatile memory device and manufacturing method thereof |
US20120217564A1 (en) * | 2011-02-25 | 2012-08-30 | Tang Sanh D | Semiconductor charge storage apparatus and methods |
US20130221423A1 (en) * | 2012-02-29 | 2013-08-29 | Kabushiki Kaisha Toshiba | Nonvolatile semiconductor memory device and method for manufacturing same |
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Legal Events
Date | Code | Title | Description |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C41 | Transfer of patent application or patent right or utility model | ||
CB03 | Change of inventor or designer information |
Inventor after: Wu Huaqiang Inventor after: Wang Bo Inventor after: Qian He Inventor after: Zhu Yiming Inventor before: Wu Huaqiang Inventor before: Wang Bo Inventor before: Qian He |
|
COR | Change of bibliographic data | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20160715 Address after: 100084 Haidian District 100084-82 mailbox Beijing Applicant after: Tsinghua University Applicant after: GigaDevice Semiconductor (Beijing) Inc. Address before: 100084 Haidian District 100084-82 mailbox Beijing Applicant before: Tsinghua University |
|
RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140702 |