CN103904034A - P-BiCS structure and formation method thereof - Google Patents

P-BiCS structure and formation method thereof Download PDF

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CN103904034A
CN103904034A CN201410078622.6A CN201410078622A CN103904034A CN 103904034 A CN103904034 A CN 103904034A CN 201410078622 A CN201410078622 A CN 201410078622A CN 103904034 A CN103904034 A CN 103904034A
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layer
forming
sacrificial layer
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tubular channel
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吴华强
王博
钱鹤
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Tsinghua University
GigaDevice Semiconductor Beijing Inc
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Tsinghua University
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B43/00EEPROM devices comprising charge-trapping gate insulators
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D64/00Electrodes of devices having potential barriers
    • H10D64/01Manufacture or treatment
    • H10D64/031Manufacture or treatment of data-storage electrodes
    • H10D64/037Manufacture or treatment of data-storage electrodes comprising charge-trapping insulators

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Abstract

本发明公开了P-BiCS结构及其形成方法,该方法包括:提供衬底和衬垫层;在衬垫层顶部光刻出管形通道图案并刻蚀出凹槽;在凹槽中淀积第一材料以形成管形通道牺牲层;在衬垫层之上交替淀积第二材料和第三材料以形成绝缘层和控制栅牺牲层的叠层结构;在叠层结构中形成垂直刻蚀孔,垂直刻蚀孔的底部与管形通道牺牲层的端部接触;去除管形通道牺牲层,以使管形通道牺牲层两端的垂直刻蚀孔连通;填充多晶硅以形成U形导电通道;在叠层结构中刻蚀中央沟槽,以将U形导电通道的两个垂直段的各自周围的叠层结构分隔开;去除控制栅牺牲层;淀积形成电荷俘获复合层;淀积形成控制栅极。本发明可以得到具有金属栅极和电荷俘获复合层结构的P-BiCS结构,电学性能良好。

The invention discloses a P-BiCS structure and a forming method thereof. The method includes: providing a substrate and a pad layer; photoetching a tubular channel pattern and etching a groove on the top of the pad layer; depositing The first material is used to form a tubular channel sacrificial layer; the second material and the third material are alternately deposited on the liner layer to form a stacked structure of an insulating layer and a control gate sacrificial layer; vertical etching is formed in the stacked structure hole, the bottom of the vertically etched hole is in contact with the end of the sacrificial layer of the tubular channel; the sacrificial layer of the tubular channel is removed so that the vertically etched holes at both ends of the sacrificial layer of the tubular channel are connected; polysilicon is filled to form a U-shaped conductive channel; Etching the central trench in the stack structure to separate the respective surrounding stack structures of the two vertical segments of the U-shaped conductive channel; removing the sacrificial layer of the control gate; depositing and forming a charge trapping composite layer; depositing and forming control grid. The invention can obtain a P-BiCS structure with a metal gate and a charge-trapping composite layer structure, and has good electrical performance.

Description

P-BiCS structure and forming method thereof
Technical field
The invention belongs to memory manufacturing technology field, be specifically related to a kind of P-BiCS structure and forming method thereof.
Background technology
Because 2D nand flash memory exists micro bottleneck, 3D NAND becomes the developing direction in memory technology field.Researcher proposes a kind of U-shaped vertical-channel 3D and NOT-AND flash (pipe-shaped bit cost scalable, P-BiCS) structure that combines silicon through hole technology.The technology that this P-BiCS adopts is: after alternately laminated gate electrode film and interlayer dielectric, by being embedded in polysilicon passage from the superiors to undermost through hole, carry out stacked multiple memory cell., P-BiCS is linkage unit on U-shaped NAND string.
Existing P-BiCS structure preparation method is: deposit SiO in silicon base 2insulating barrier; Make annular channel pattern by lithography, etch groove; Deposit sacrificial layer material is filled the groove of tubular channel pattern; Planarization, removes the sacrificial layer material at non-annular channel pattern place; Alternating deposition SiO 2insulating barrier and polysilicon control grid layer; Vertical etching laminated construction, to bottom annular channel sacrifice layer, is overlooked etched hole rounded; Etching is removed annular channel sacrifice layer; Deposit electric charge capture composite bed successively; Fill polysilicon as conducting channel; On laminated construction, etch groove, so that the adjacent through-holes being connected by bottom annular channel control grid is around separated.
The P-BiCS structure that above-mentioned prior art obtains has following shortcoming: (1) is owing to having high-temperature technology in follow-up flow process, the alternately etching process prior art of simultaneous oxidation silicon and metal cannot solve, so directly deposited metal is as controlling grid, so just cannot utilize that high-work-function metal grid can bring as more excellent memory electrology characteristics such as higher erasing speeds.(2) owing to also having many high-temperature step after deposit electric charge capture composite bed, and the high-k materials such as hafnium oxide at high temperature can crystallization cause device electrology characteristic to decline, therefore also cannot use high-k material as electric charge capture composite bed, affect the electric property of device.
Summary of the invention
The present invention is intended at least solve cannot adopting metal gate, cannot using the technical problem of high-k material as electric charge capture composite bed of existing in prior art.
For this reason, one object of the present invention is to propose that a kind of metal gate is replaced, high-k material is as the formation method of the P-BiCS structure of electric charge capture composite bed.
Another object of the present invention is to propose a kind of P-BiCS structure of the electric charge capture composite bed with metal gate and high-k material.
To achieve these goals, according to the formation method of the P-BiCS structure of the embodiment of one aspect of the invention, can comprise the following steps: substrate is provided, and forms laying on described substrate; Carve annular channel pattern and etch groove in described laying top light; In described groove, deposit the first material is to form annular channel sacrifice layer; On described laying, alternating deposition the second material and the 3rd material are to form the laminated construction of insulating barrier and control gate sacrifice layer; In described laminated construction, form vertical etched hole, the bottom of described vertical etched hole contacts with the end of described annular channel sacrifice layer; Remove described annular channel sacrifice layer, so that the described vertical etched hole at described annular channel sacrifice layer two ends is communicated with; Fill polysilicon to form U-shaped conductive channel; Etching central authorities groove in described laminated construction, to separate the described laminated construction around separately of two vertical sections of described U-shaped conductive channel; Remove described control gate sacrifice layer; Deposit forms electric charge capture composite bed, and described electric charge capture composite bed covers the surface of two vertical sections of described insulating barrier and described U-shaped conductive channel; Deposited metal gate material is with formation control grid.
According to the formation method of the P-BiCS structure of the embodiment of the present invention, can form the P-BiCS structure with metal gates and the electric charge capture lamination layer structure that contains high-k material, the higher erasing speed of bringing that can make 3D and NOT-AND flash utilize metal gates, larger memory window value, the advantage of better charge-retention property; Can utilize high-k material as electric charge capture composite bed, device is had and be better than traditional SONOS(Si/SiO simultaneously 2/ SiN/SiO 2/ Si) flash memory charge storage density, better the electric charge blocking capability on barrier layer.
In addition, can also there is following additional technical feature according to the formation method of the P-BiCS structure of the embodiment of the present invention:
In an example of the present invention, adopt the first corrosive liquid wet etching to remove described annular channel sacrifice layer, wherein, described the first corrosive liquid is greater than the corrosion rate to described the second material to the corrosion rate of described the first material, and is greater than the corrosion rate to described the 3rd material.
In an example of the present invention, adopt the second corrosive liquid wet etching to remove described control gate sacrifice layer, wherein, described the second corrosive liquid is greater than the corrosion rate to described the second material to the corrosion rate of described the 3rd material, and is greater than the corrosion rate to described polysilicon.
In an example of the present invention, described deposit forms electric charge capture composite bed and comprises: deposit electric charge tunnel layer material, charge storage layer material and electric charge barrier layer material successively.
In an example of the present invention, described the first material is aluminium oxide or cupric oxide.
In an example of the present invention, described the second material is silicon dioxide.
In an example of the present invention, described the 3rd material is silicon nitride.
In an example of the present invention, overlook described vertical etched hole rounded.
In an example of the present invention, described metal gate material is tungsten.
The P-BiCS structure of embodiment according to a further aspect of the invention, this P-BiCS structure is to make by above-mentioned method.
According to the P-BiCS structure of the embodiment of the present invention, there is the electric charge capture lamination layer structure of metal gates and high-k material, the higher erasing speed that can make 3D and NOT-AND flash utilize metal gates to bring, larger memory window value, the better advantage of charge-retention property; Can utilize high-k material as electric charge capture composite bed, device is had and be better than traditional SONOS(Si/SiO simultaneously 2/ SiN/SiO 2/ Si) flash memory charge storage density, better the electric charge blocking capability on barrier layer.
Additional aspect of the present invention and advantage in the following description part provide, and part will become obviously from the following description, or recognize by practice of the present invention.
Accompanying drawing explanation
Above-mentioned and/or additional aspect of the present invention and advantage accompanying drawing below combination is understood becoming the description of embodiment obviously and easily, wherein:
Fig. 1 to Figure 11 is the process schematic diagram of the formation method of the P-BiCS structure of the embodiment of the present invention.
Embodiment
Describe embodiments of the invention below in detail, the example of described embodiment is shown in the drawings, and wherein same or similar label represents same or similar element or has the element of identical or similar functions from start to finish.Be exemplary below by the embodiment being described with reference to the drawings, be intended to for explaining the present invention, and can not be interpreted as limitation of the present invention.
First aspect present invention proposes a kind of formation method of P-BiCS structure, comprises the following steps:
S1., substrate is provided, and on substrate, forms laying.
As shown in Figure 1, provide single crystal silicon material substrate 101, and form SiO on substrate 101 2laying 102.
S2. carve annular channel pattern and etch groove in laying top light.
As shown in Figure 2, carve annular channel pattern and etch groove 102a in the top light of laying 102.
It should be noted that, although only show a groove in figure, in practical application, on a wafer, can etch several parallel grooves.
S3. in groove deposit the first material to form annular channel sacrifice layer.
As shown in Figure 3, deposition the first material, to fill full groove 102a, then carries out planarization, removes first material at non-tubular pattern place, has obtained the annular channel sacrifice layer 103 of the first material.Wherein, the first material can be the materials such as aluminium oxide or cupric oxide.
S4. on laying alternating deposition the second material and the 3rd material to form the laminated construction of insulating barrier and control gate sacrifice layer.
As shown in Figure 4, on laying 102 alternating deposition the second material and the 3rd material to form the laminated construction of insulating barrier 104 and control gate sacrifice layer 105.The second material can be SiO 2deng material.The 3rd material can be the materials such as SiN.
S5. in laminated construction, form vertical etched hole, the bottom of vertical etched hole contacts with the end of annular channel sacrifice layer.
As shown in Figure 5 a, in the laminated construction of insulating barrier 104 and control gate sacrifice layer 105, form vertical etched hole 106.The bottom of this vertical etched hole 106 contacts with the end of annular channel sacrifice layer 103.Vertical etched hole 106 can be circular port.Fig. 5 b is the vertical view of the structure shown in Fig. 5 a, and Fig. 5 b has demonstrated the situation on a wafer with multipair vertical etched hole.
S6. remove annular channel sacrifice layer, so that the vertical etched hole at annular channel sacrifice layer two ends is communicated with.
As shown in Figure 6, remove annular channel sacrifice layer 103, so that the vertical etched hole 106 at annular channel sacrifice layer 103 two ends is communicated with.Alternatively, adopt the first corrosive liquid wet etching to remove annular channel sacrifice layer 106.Wherein, the first corrosive liquid is greater than the corrosion rate to the second material to the corrosion rate of the first material, and is greater than the corrosion rate to the 3rd material.In one embodiment, the first corrosive liquid can be hydrochloric acid.
S7. fill polysilicon to form U-shaped conductive channel.
As shown in Figure 7a, fill polysilicon to form U-shaped conductive channel 107.This U-shaped conductive channel 107 has occupied the locus of the vertical etched hole 106 at original annular channel sacrifice layer 103 and two ends thereof.Fig. 7 b is the vertical view of the structure shown in Fig. 7 a, and Fig. 7 b has demonstrated the situation on a wafer with multiple U-shaped conductive channels.
S8. etching central authorities groove in laminated construction, to separate the laminated construction around separately of two vertical sections of U-shaped conductive channel.
As shown in Figure 8 a, etching central authorities groove 108 in the laminated construction of insulating barrier 104 and control gate sacrifice layer 105, to separate the laminated construction around separately of two vertical sections of U-shaped conductive channel 107.At this moment, expose the part side of insulating barrier 104 and control gate sacrifice layer 105, be convenient to the follow-up wet etching that carries out.Fig. 8 b is the vertical view of the structure shown in Fig. 8 a, and Fig. 8 b has demonstrated on a wafer and formed strip groove by the separated situation in multiple U-shaped conductive channels both sides.
S9. remove control gate sacrifice layer.
As shown in Figure 9, remove control gate sacrifice layer 105, now in original laminated construction, be only left insulating barrier 104.Alternatively, adopt the second corrosive liquid wet etching to remove control gate sacrifice layer 105, wherein, the second corrosive liquid is greater than the corrosion rate to the second material to the corrosion rate of the 3rd material, and is greater than the corrosion rate to polysilicon.In one embodiment, the second corrosive liquid can be phosphoric acid.
S10. deposit forms electric charge capture composite bed, and electric charge capture composite bed covers the surface of two vertical sections of insulating barrier and U-shaped conductive channel.
As shown in figure 10, deposit forms electric charge capture composite bed 109, and this electric charge capture composite bed 109 covers the surface of two vertical sections of insulating barrier 104 and U-shaped conductive channel 107.Alternatively, deposit formation electric charge capture composite bed 109 specifically comprises: deposit electric charge tunnel layer material, charge storage layer material and electric charge barrier layer material successively.
S11. deposited metal gate material is with formation control grid.
As shown in figure 11, plated metal grid material is to be full of control grid part, and then etching is removed excess metal grid material, and different control between grid 110 is not connected mutually.In addition, can also between multiple control grids 110, fill insulating layer material isolates.Alternatively, metal gate material is tungsten.
In sum, the formation method of P-BiCS structure of the present invention can form the P-BiCS structure with metal gates and the electric charge capture lamination layer structure that contains high-k material, the higher erasing speed of bringing that can make 3D and NOT-AND flash utilize metal gates, larger memory window value, the advantage of better charge-retention property; Can utilize high-k material as electric charge capture composite bed, device is had and be better than traditional SONOS(Si/SiO simultaneously 2/ SiN/SiO 2/ Si) flash memory charge storage density, better the electric charge blocking capability on barrier layer.
Second aspect present invention also proposes a kind of P-BiCS structure, this P-BiCS structure is to make by the formation method of above-disclosed any P-BiCS structure of the present invention, therefore also there is the electric charge capture lamination layer structure of metal gates and high-k material, the higher erasing speed that can make 3D and NOT-AND flash utilize metal gates to bring, larger memory window value, the better advantage of charge-retention property; Can utilize high-k material as electric charge capture composite bed, device is had and be better than traditional SONOS(Si/SiO simultaneously 2/ SiN/SiO 2/ Si) flash memory charge storage density, better the electric charge blocking capability on barrier layer.
In description of the invention, it will be appreciated that, term " " center ", " longitudinally ", " laterally ", " length ", " width ", " thickness ", " on ", D score, " front ", " afterwards ", " left side ", " right side ", " vertically ", " level ", " top ", " end " " interior ", " outward ", " clockwise ", " counterclockwise ", " axially ", " radially ", orientation or the position relationship of indications such as " circumferentially " are based on orientation shown in the drawings or position relationship, only the present invention for convenience of description and simplified characterization, rather than device or the element of indication or hint indication must have specific orientation, with specific orientation structure and operation, therefore can not be interpreted as limitation of the present invention.
In addition, term " first ", " second " be only for describing object, and can not be interpreted as indication or hint relative importance or the implicit quantity that indicates indicated technical characterictic.Thus, one or more these features can be expressed or impliedly be comprised to the feature that is limited with " first ", " second ".In description of the invention, the implication of " multiple " is two or more, unless otherwise expressly limited specifically.
In the present invention, unless otherwise clearly defined and limited, the terms such as term " installation ", " being connected ", " connection ", " fixing " should be interpreted broadly, and for example, can be to be fixedly connected with, and can be also to removably connect, or integral; Can be mechanical connection, can be also electrical connection; Can be to be directly connected, also can indirectly be connected by intermediary, can be the connection of two element internals or the interaction relationship of two elements.For the ordinary skill in the art, can understand as the case may be above-mentioned term concrete meaning in the present invention.
In the present invention, unless otherwise clearly defined and limited, First Characteristic Second Characteristic " on " or D score can be that the first and second features directly contact, or the first and second features are by intermediary indirect contact.And, First Characteristic Second Characteristic " on ", " top " and " above " but First Characteristic directly over Second Characteristic or oblique upper, or only represent that First Characteristic level height is higher than Second Characteristic.First Characteristic Second Characteristic " under ", " below " and " below " can be First Characteristic under Second Characteristic or tiltedly, or only represent that First Characteristic level height is less than Second Characteristic.
In the description of this specification, the description of reference term " embodiment ", " some embodiment ", " example ", " concrete example " or " some examples " etc. means to be contained at least one embodiment of the present invention or example in conjunction with specific features, structure, material or the feature of this embodiment or example description.In this manual, to the schematic statement of above-mentioned term not must for be identical embodiment or example.And, specific features, structure, material or the feature of description can one or more embodiment in office or example in suitable mode combination.In addition, those skilled in the art can carry out combination and combination by the different embodiment that describe in this specification or example.
Although illustrated and described embodiments of the invention above, be understandable that, above-described embodiment is exemplary, can not be interpreted as limitation of the present invention, and those of ordinary skill in the art can change above-described embodiment within the scope of the invention, modification, replacement and modification.

Claims (10)

1.一种P-BiCS结构的形成方法,其特征在于,包括以下步骤:1. A method for forming a P-BiCS structure, comprising the following steps: 提供衬底,并在所述衬底上形成衬垫层;providing a substrate, and forming a liner layer on the substrate; 在所述衬垫层顶部光刻出管形通道图案并刻蚀出凹槽;Photoetching a tubular channel pattern and etching a groove on the top of the liner layer; 在所述凹槽中淀积第一材料以形成管形通道牺牲层;depositing a first material in the groove to form a tubular channel sacrificial layer; 在所述衬垫层之上交替淀积第二材料和第三材料以形成绝缘层和控制栅牺牲层的叠层结构;Alternately depositing a second material and a third material on the liner layer to form a stack structure of an insulating layer and a sacrificial control gate layer; 在所述叠层结构中形成垂直刻蚀孔,所述垂直刻蚀孔的底部与所述管形通道牺牲层的端部接触;forming a vertical etching hole in the stacked structure, the bottom of the vertical etching hole is in contact with the end of the tubular channel sacrificial layer; 去除所述管形通道牺牲层,以使所述管形通道牺牲层两端的所述垂直刻蚀孔连通;removing the sacrificial layer of the tubular channel, so that the vertical etching holes at both ends of the sacrificial layer of the tubular channel communicate; 填充多晶硅以形成U形导电通道;Fill polysilicon to form a U-shaped conductive channel; 在所述叠层结构中刻蚀中央沟槽,以将所述U形导电通道的两个垂直段的各自周围的所述叠层结构分隔开;etching a central trench in the stack to separate the stack around each of the two vertical segments of the U-shaped conductive channel; 去除所述控制栅牺牲层;removing the control gate sacrificial layer; 淀积形成电荷俘获复合层,所述电荷俘获复合层覆盖所述绝缘层和所述U形导电通道的两个垂直段的表面;Depositing a charge-trapping recombination layer covering the surfaces of the insulating layer and the two vertical segments of the U-shaped conductive channel; 淀积金属栅极材料以形成控制栅极。A metal gate material is deposited to form the control gate. 2.根据权利要求1所述的P-BiCS结构的形成方法,其特征在于,采用第一腐蚀液湿法刻蚀去除所述管形通道牺牲层,其中,所述第一腐蚀液对所述第一材料的腐蚀速率大于对所述第二材料的腐蚀速率,并且大于对所述第三材料的腐蚀速率。2. the formation method of P-BiCS structure according to claim 1 is characterized in that, adopts the first corrosive liquid wet etching to remove described tubular channel sacrificial layer, wherein, described first corrosive liquid is to the described first corrosive liquid The corrosion rate of the first material is greater than the corrosion rate of the second material and greater than the corrosion rate of the third material. 3.根据权利要求1所述的P-BiCS结构的形成方法,其特征在于,采用第二腐蚀液湿法刻蚀去除所述控制栅牺牲层,其中,所述第二腐蚀液对所述第三材料的腐蚀速率大于对所述第二材料的腐蚀速率,并且大于对所述多晶硅的腐蚀速率。3. The forming method of the P-BiCS structure according to claim 1, characterized in that, the control grid sacrificial layer is removed by wet etching with a second corrosive solution, wherein the second corrosive solution is used for the first The etch rate of the three materials is greater than the etch rate of the second material and greater than the etch rate of the polysilicon. 4.根据权利要求1所述的P-BiCS结构的形成方法,其特征在于,所述淀积形成电荷俘获复合层包括:依次淀积电荷隧穿层材料、电荷存储层材料和电荷阻挡层材料。4. The method for forming the P-BiCS structure according to claim 1, wherein said depositing and forming the charge trapping composite layer comprises: sequentially depositing charge tunneling layer material, charge storage layer material and charge blocking layer material . 5.根据权利要求1所述的P-BiCS结构的形成方法,其特征在于,所述第一材料为氧化铝或氧化铜。5. The method for forming the P-BiCS structure according to claim 1, wherein the first material is aluminum oxide or copper oxide. 6.根据权利要求1所述的P-BiCS结构的形成方法,其特征在于,所述第二材料为二氧化硅。6. The method for forming the P-BiCS structure according to claim 1, wherein the second material is silicon dioxide. 7.根据权利要求1所述的P-BiCS结构的形成方法,其特征在于,所述第三材料为氮化硅。7. The method for forming the P-BiCS structure according to claim 1, wherein the third material is silicon nitride. 8.根据权利要求1所述的P-BiCS结构的形成方法,其特征在于,俯视所述垂直刻蚀孔呈圆形。8 . The method for forming the P-BiCS structure according to claim 1 , wherein the vertical etching hole is circular in plan view. 9.根据权利要求1所述的P-BiCS结构的形成方法,其特征在于,所述金属栅极材料为钨。9. The method for forming the P-BiCS structure according to claim 1, wherein the metal gate material is tungsten. 10.一种P-BiCS结构,其特征在于,是通过权利要求1-9中任一项所述的方法制得的。10. A P-BiCS structure, characterized in that it is prepared by the method according to any one of claims 1-9.
CN201410078622.6A 2014-03-05 2014-03-05 P-BiCS structure and formation method thereof Pending CN103904034A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102623458A (en) * 2008-12-24 2012-08-01 海力士半导体有限公司 Vertical channel type nonvolatile memory device and manufacturing method thereof
US20120217564A1 (en) * 2011-02-25 2012-08-30 Tang Sanh D Semiconductor charge storage apparatus and methods
US20130221423A1 (en) * 2012-02-29 2013-08-29 Kabushiki Kaisha Toshiba Nonvolatile semiconductor memory device and method for manufacturing same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102623458A (en) * 2008-12-24 2012-08-01 海力士半导体有限公司 Vertical channel type nonvolatile memory device and manufacturing method thereof
US20120217564A1 (en) * 2011-02-25 2012-08-30 Tang Sanh D Semiconductor charge storage apparatus and methods
US20130221423A1 (en) * 2012-02-29 2013-08-29 Kabushiki Kaisha Toshiba Nonvolatile semiconductor memory device and method for manufacturing same

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