CN103898790A - Beating enzyme preparation, and preparation method and application thereof - Google Patents
Beating enzyme preparation, and preparation method and application thereof Download PDFInfo
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Abstract
The invention discloses a beating enzyme preparation, and a preparation method and application thereof. The beating enzyme preparation is prepared from the following components in percentage by weight: 10%-15% of endo-cellulase, 5%-7.5% of cellobiohydrolase, 0-5% of xylanase, 0.2%-1% of fatty alcohol-polyoxyethylene ether, 0.2%-1% of Tween-80, 0.01%-0.05% of potassium sorbate and the balance being deionized water. Due to the synergistic effect of a plurality of enzymes in the beating enzyme preparation, the power consumption of grinding is greatly reduced, a high fibrillation degree of the fiber surface is achieved, the excessive cutting of strong fibers is avoided, a large fiber length is retained and the folding strength and the tearing strength of paper are improved; meanwhile, a fine fiber retention rate can also be effectively improved, and thus the utilization rate of fiber raw materials can be improved.
Description
Technical field
The present invention relates to pulp technology for making paper, relate in particular to a kind of making beating enzyme preparation and its preparation method and application.
Background technology
Along with people require to improve environment, conserve forests, save the energy and raw material, the cry of reduction papermaking cost grows to even greater heights; add that environmental requirement is more and more stricter, paper making raw material price rises steadily and Pressure on Energy, the energy-saving and emission-reduction of papermaking enterprise have caused the attention of countries in the world government and enterprise.The energy-saving and emission-reduction of papermaking enterprise can promote the raising of paper industry concentration degree, promote industry restructuring, are conducive to the future development of the modernization paper industry of environmentally friendly, resource-conserving.
Making beating, is a very important operation of paper-making process, and making beating needs to consume a large amount of energy, accounts for from timber to becoming paper to produce 15% ~ 18% of total energy consumption.Account for the sulfate wood pulp of global chemical pulp annual production 89%, it is difficult for making beating, needs to consume a large amount of energy, all power consumption 200 ~ 300kWh/ ton slurries, and high shiny beating average power consumption is 250 ~ 500kWh/ ton slurry.Reducing the particularly beating energy consumption of sulfate wood pulp of paper pulp, is a strategic problem of paper industry energy-saving and emission-reduction.Paper industry is energy-conservation two kinds of approach: reduce energy consumption of unit product from management aspect; Utilize new technology to reduce energy consumption of unit product.But the amount of increase of the rise of commercial pulp price and paper product price is less, make the reduction of paper product profit margin, the existence of part papermaking enterprise is more and more difficult, can only replace import slurry by the relatively cheap domestic slurry of buying, for enterprise creates profit.But use domestic slurry to have risk, the especially impact on art paper intensity that strength ratio import slurry is poor, cause paper strength to decline.Because folding explosion problem becomes large and medium-sized art paper manufacturing enterprise urgent need to solve the problem after part halftone paper printing always, if produce pulp strength variation again, that problem will be more serious.More much type art paper paper machines is gone into operation and is discharged the current of production capacity at home, how to guarantee or the quality that improves art paper becomes the most important thing of each large papermaking enterprise.
In prior art, the optimization space of the saving of beating energy consumption from equipment and flow process is minimum.How the intensity of paper is improved by chemical intensifier, but effect is limited, and cost is high, also can bring other aspect problems of paper machine operation and paper, as surface printing performance, anionic trash etc.Therefore by biotechnology Integral lifting paper industry technical merits more clean, energy-saving and environmental protection, the existing situation that changes high energy consumption, high pollution is imperative.
Biotechnology receives more concern, because it can reduce destruction to environment, saves the energy, improve the quality of products.Compared with general abiotic catalyst, enzyme has the features such as mildness, selectivity, high efficiency and adjustability.Improve paper pulp fiber by enzyme preliminary treatment, reduce beating energy consumption, improve paper strength, paid close attention to by many personages that are devoted to papermaking biology enzyme.
Summary of the invention
The technical problem that the present invention mainly solves is to provide a kind of making beating enzyme preparation and its preparation method and application, by the synergy of the plurality of enzymes in making beating enzyme preparation, not only greatly reduce Specific energy, and make the wire-dividing broom purification degree of fiber surface higher, avoid strength excessively to cut off, retained longer fibre length, the folding strength of paper and tearability are improved, also can effectively improve fines retention simultaneously, improve the utilization rate of fibrous raw material.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: a kind of making beating enzyme preparation is provided, and percentage meter by weight, described making beating enzyme preparation is composed of the following components:
Surplus is deionized water.
Preferably, the enzyme work of the endo cellulase in described making beating enzyme preparation is 1000 ~ 1500U/mL, and the enzyme work of circumscribed cellulase is 200 ~ 300U/mL, and the enzyme work of zytase is 0 ~ 500U/mL.
Preferably, the polymerized unit number of the polyoxyethylene ether of described fatty alcohol-polyoxyethylene ether is 20.
For solving the problems of the technologies described above, another technical solution used in the present invention is: a kind of method of preparing described making beating enzyme preparation is provided, said method comprising the steps of:
(1) making beating enzyme preparation formula: percentage meter by weight, 10% ~ 15% endo cellulase, 5% ~ 7.5% circumscribed cellulase, 0 ~ 5% zytase, 0.2% ~ 1% fatty alcohol-polyoxyethylene ether, 0.2% ~ 1% Tween-80,0.01% ~ 0.05% potassium sorbate, surplus are deionized water; Take each component by above-mentioned formula;
(2) first use a small amount of deionized water dissolving potassium sorbate, then use enough deionized waters after dissolved dilution Tween-80 and fatty alcohol-polyoxyethylene ether, to pour the potassium sorbate having dissolved in agitator tank;
(3) add again endo cellulase, circumscribed cellulase and zytase, stir 30 minutes with the rotating speeds of 40 revs/min, obtain described making beating enzyme preparation.
Preferably, the enzyme work of the endo cellulase in the making beating enzyme preparation making is 1000 ~ 1500U/mL, and the enzyme work of circumscribed cellulase is 200 ~ 300U/mL, and the enzyme work of zytase is 0 ~ 500U/mL.
Preferably, the polymerized unit number of the polyoxyethylene ether of described fatty alcohol-polyoxyethylene ether is 20.
The present invention has also described described making beating enzyme preparation in the application of processing in sulfate wood pulp.
Preferably, in sulfate wood pulp per ton, add 100 ~ 300 grams of making beating enzyme preparations.
Preferably, described sulfate wood pulp is one or both in needlebush paper pulp and leaf wood paper pulp.
Preferably, described paper pulp is brown stock or bleached pulp.
Fatty alcohol-polyoxyethylene ether in making beating enzyme preparation of the present invention and Tween-80 can improve dispersiveness and the stability of biology enzyme in the aqueous solution, promote diffusion and the infiltration of biology enzyme in paper pulp; Potassium sorbate plays antisepsis, ensures making beating enzyme preparation steady quality.
The invention has the beneficial effects as follows: distinguish existing beater floor energy consumption high, the poor situation of paper physical intensity making, endo cellulase in making beating enzyme preparation of the present invention can promote fibre cutting and swollen effectively, greatly reduce Specific energy, circumscribed cellulase and zytase can promote the sub-wire of fiber ends effectively, expose abundant hydroxyl and carboxyl, promote adhesion between fiber, the synergy of plurality of enzymes makes the wire-dividing broom purification degree of fiber surface higher simultaneously, thereby avoid strength excessively to cut off, retain longer fibre length, folding strength and the tearability of paper are improved, the lifting of run-inflation effect also can effectively improve fines retention, improves the utilization rate of fibrous raw material.
The specific embodiment
Below in conjunction with embodiment, the present invention is described in detail.
Circumscribed cellulase, endo cellulase and zytase described in embodiment all can be bought from the market, as circumscribed cellulase and endo cellulase can be bought from Novozymes Company, zytase can be bought from Sha Sheng Industrial Group Corporation, and other chemical assistants are general industry product.
In embodiment, measure the enzyme of circumscribed cellulase and endo cellulase by China National Light Industrial Products Department's industry standard " QB2583-2005 cellulase preparation " and live, measure the enzyme of zytase by national standard " GB/T23874-2009 Xylanase activity assay method " and live.
Embodiment 1
(1) making beating enzyme preparation formula: percentage meter by weight, 12% endo cellulase, 7.5% circumscribed cellulase, 0.6% aliphatic alcohol polyethenoxy (20) ether, 0.4% Tween-80,0.01% potassium sorbate, surplus are deionized water; Take each component by above-mentioned formula;
(2) first use a small amount of deionized water dissolving potassium sorbate, then use enough deionized waters after dissolved dilution Tween-80 and aliphatic alcohol polyethenoxy (20) ether, to pour the potassium sorbate having dissolved in agitator tank;
(3) add again endo cellulase and circumscribed cellulase, stir 30 minutes with the rotating speeds of 40 revs/min, obtain described making beating enzyme preparation.
The enzyme of the endo cellulase in the making beating enzyme preparation making is lived and lived for the enzyme of 1200U/mL, circumscribed cellulase is 300U/mL.
Embodiment 2
(1) making beating enzyme preparation formula: percentage meter by weight, 15% endo cellulase, 5% circumscribed cellulase, 1% zytase, 0.2% aliphatic alcohol polyethenoxy (20) ether, 1% Tween-80,0.03% potassium sorbate, surplus are deionized water; Take each component by above-mentioned formula;
(2) first use a small amount of deionized water dissolving potassium sorbate, then use enough deionized waters after dissolved dilution Tween-80 and aliphatic alcohol polyethenoxy (20) ether, to pour the potassium sorbate having dissolved in agitator tank;
(3) add again endo cellulase, circumscribed cellulase and zytase, stir 30 minutes with the rotating speeds of 40 revs/min, obtain described making beating enzyme preparation.
It is that the enzyme 200U/mL of being alive of 1500U/mL, circumscribed cellulase, the enzyme of zytase are lived as 100U/mL that the enzyme of the endo cellulase in the making beating enzyme preparation making is lived.
Embodiment 3
(1) making beating enzyme preparation formula: percentage meter by weight, 10% endo cellulase, 6% circumscribed cellulase, 3% zytase, 0.4% aliphatic alcohol polyethenoxy (20) ether, 0.6% Tween-80,0.05% potassium sorbate, surplus are deionized water; Take each component by above-mentioned formula;
(2) first use a small amount of deionized water dissolving potassium sorbate, then use enough deionized waters after dissolved dilution Tween-80 and aliphatic alcohol polyethenoxy (20) ether, to pour the potassium sorbate having dissolved in agitator tank;
(3) add again endo cellulase, circumscribed cellulase and zytase, stir 30 minutes with the rotating speeds of 40 revs/min, obtain described making beating enzyme preparation.
It is that the enzyme 240U/mL of being alive of 1000U/mL, circumscribed cellulase, the enzyme of zytase are lived as 300U/mL that the enzyme of the endo cellulase in the making beating enzyme preparation making is lived.
Embodiment 4
(1) making beating enzyme preparation formula: percentage meter by weight, 13% endo cellulase, 7% circumscribed cellulase, 5% zytase, 1% aliphatic alcohol polyethenoxy (20) ether, 0.2% Tween-80,0.02% potassium sorbate, surplus are deionized water; Take each component by above-mentioned formula;
(2) first use a small amount of deionized water dissolving potassium sorbate, then use enough deionized waters after dissolved dilution Tween-80 and aliphatic alcohol polyethenoxy (20) ether, to pour the potassium sorbate having dissolved in agitator tank;
(3) add again endo cellulase, circumscribed cellulase and zytase, stir 30 minutes with the rotating speeds of 40 revs/min, obtain described making beating enzyme preparation.
It is that the enzyme 280U/mL of being alive of 1300U/mL, circumscribed cellulase, the enzyme of zytase are lived as 500U/mL that the enzyme of the endo cellulase in the making beating enzyme preparation making is lived.
Embodiment 5
By bleached sulphate softwood pulp production of copper millboard.
First in pulping pot, drop into the reuse plain boiled water of approximately 40 cubic metres, water temperature is 40 ~ 50 ℃, and pH value is 7.2 ~ 7.3, then drops into approximately 1.8 tons of over dry pulpboards, the making beating enzyme preparation that simultaneously adds embodiment 1 to make, and slurry per ton uses 133g; After pulping finishes, slurry is delivered to slurry tower before the mill of 270 cubic metres, and liquid level remains on 200 cubes of left and right, per hourly measures approximately 8 tons of oven dry stocks with slurry, and slurry stops and after approximately 90 minutes, starts defibrination to beating degree and reach 30 ~ 33 ° of SR.
Slurry by above-mentioned processing more routinely technique carry out subsequent operation.
Compared with the making beating enzyme preparation that does not add the present embodiment 1 to make, while reaching identical beating degree, add making beating enzyme preparation that the present embodiment 1 makes can save bleached sulphate softwood pulp Specific energy and reach 70kWh/ ton slurry, greatly save energy consumption; In addition, the long-time making beating enzyme preparation that uses the present embodiment 1 to make on art paper production line, has to a certain degree improved the problem such as folding strength deficiency, chip of this type of high-grade culture paper, makes into paper folding strength and improves 3 left and right.
Embodiment 6
With 18% bleaching needle-point leaf pulp and 82% bleached hardwood pulp production neutral sizing.
First in pulping pot, add approximately 20 cubic metres of reuse plain boiled waters and part hot water, water temperature is 65 ~ 70 ℃, and pH value is 8.5 ~ 8.8, drops in proportion 1 ton of over dry pulpboard when adding water, making beating enzyme preparation simultaneously that add embodiment 2 to make in pulping pot, slurry per ton uses 150g; Pulping is transported to slurry tower before the mill of approximately 100 cubic metres after approximately 15 minutes, liquid level approximately 80% is per hourly measured approximately 8 tons of oven dry stocks with slurry, and slurry stops after 30 ~ 40 minutes and starts defibrination to 56 ~ 60 ° of SR of beating degree.
Slurry by above-mentioned processing more routinely technique carry out subsequent operation.
Compared with the making beating enzyme preparation that does not add embodiment 2 to make, add the making beating enzyme preparation that embodiment 2 makes guaranteeing under weight in wet base index stable case, beating degree reduces slightly, produce dehydration and drying property good, become paper index steadily increasing, greatly shorten the defibrination time, ton slurry Specific energy reduces by 80 ~ 100 degree, approximately 60 yuan of costs simultaneously.
Embodiment 7
With the high shiny beating production of true qualities kp softwood pulp kraft capacitor paper.
In trough-style pulp beater, drop into approximately 1.5 tons of pulp boards, add water to concentration to be about 5%, temperature is 25 ℃, pH value is 6.8 ~ 7.0, then start after stone Kun trough-style pulp beater makes slurry concentration evenly and drop into the making beating enzyme preparation that embodiment 3 makes, slurry per ton uses 300g, continues to pull an oar to beating degree to reach 96 ° of SR.
Slurry by above-mentioned processing more routinely technique carry out subsequent operation.
Compared with the making beating enzyme preparation that does not add embodiment 3 to make, while reaching identical beating degree, add the making beating enzyme preparation that embodiment 3 makes that the time of former slot type making beating is shortened greatly, within 11 hours, foreshorten to 9 hours from original making beating, ton slurry is saved power consumption and is reached 200kWh.
Embodiment 8
By bleached sulphate softwood pulp and hardwood pulp productive life paper using.
Adopt making beating respectively, needle slurry pulping is the continuous pulping of hydrabrusher, production is 20 ~ 30 ℃ by plain boiled water temperature, due to pulpboard slant acidity, slurry pH value is 4.3 ~ 4.5, pulping amount per hour is about 4.8 tons of oven dry stocks, when pulping feeds intake, adds the making beating enzyme preparation that embodiment 4 makes with measuring pump with the flow of 8mL/min, and slurry per ton uses 100g; Broken good slurry is transported to and unloads slurry tower before slurry slurry tower and mill, starts defibrination and make beating degree reach 28 ~ 30 ° of SR after approximately 2 hours, and the behaviour that then slurry carries out paper makes.
Slurry by above-mentioned processing more routinely technique carry out subsequent operation.
Compared with the making beating enzyme preparation that does not add embodiment 4 to make, while reaching identical beating degree, add the making beating enzyme preparation that embodiment 4 makes to make former Specific energy be reduced to 180kWh/t oven dry stock from 240kWh/t oven dry stock, and become paper tension intensity to improve, produce health body paper per ton simultaneously and reduced 2 kilograms of dry strength agent use amounts.
Although the specific embodiment of the present invention has obtained detailed description, it will be understood to those of skill in the art that according to disclosed all instructions, can carry out various modifications and replacement to those details, these change all within protection scope of the present invention.Four corner of the present invention is provided by claims and any equivalent thereof.
Claims (10)
2. making beating enzyme preparation according to claim 1, is characterized in that, the enzyme work of the endo cellulase in described making beating enzyme preparation is 1000 ~ 1500U/mL, and the enzyme work of circumscribed cellulase is 200 ~ 300U/mL, and the enzyme work of zytase is 0 ~ 500U/mL.
3. making beating enzyme preparation according to claim 2, is characterized in that, the polymerized unit number of the polyoxyethylene ether of described fatty alcohol-polyoxyethylene ether is 20.
4. the preparation method of making beating enzyme preparation according to claim 1, is characterized in that, said method comprising the steps of:
(1) making beating enzyme preparation formula: percentage meter by weight, 10% ~ 15% endo cellulase, 5% ~ 7.5% circumscribed cellulase, 0 ~ 5% zytase, 0.2% ~ 1% fatty alcohol-polyoxyethylene ether, 0.2% ~ 1% Tween-80,0.01% ~ 0.05% potassium sorbate, surplus are deionized water; Take each component by above-mentioned formula;
(2) first use a small amount of deionized water dissolving potassium sorbate, then use enough deionized waters after dissolved dilution Tween-80 and fatty alcohol-polyoxyethylene ether, to pour the potassium sorbate having dissolved in agitator tank;
(3) add again endo cellulase, circumscribed cellulase and zytase, stir 30 minutes with the rotating speeds of 40 revs/min, obtain described making beating enzyme preparation.
5. method according to claim 4, is characterized in that, the enzyme work of the endo cellulase in described making beating enzyme preparation is 1000 ~ 1500U/mL, and the enzyme work of circumscribed cellulase is 200 ~ 300U/mL, and the enzyme work of zytase is 0 ~ 500U/mL.
6. method according to claim 5, is characterized in that, the polymerized unit number of the polyoxyethylene ether of described fatty alcohol-polyoxyethylene ether is 20.
7. the application in processing sulfate wood pulp according to the making beating enzyme preparation described in claim 1 ~ 3 any one.
8. application according to claim 7, is characterized in that, adds 100 ~ 300 grams of making beating enzyme preparations in sulfate wood pulp per ton.
9. application according to claim 8, is characterized in that, described sulfate wood pulp is one or both in needlebush paper pulp and leaf wood paper pulp.
10. application according to claim 9, is characterized in that, described paper pulp is brown stock or bleached pulp.
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CN104711887A (en) * | 2015-02-16 | 2015-06-17 | 广西大学 | Method for preparing 3D printing materials from recovered waste raw materials containing plant fiber |
CN105839471A (en) * | 2016-05-26 | 2016-08-10 | 福建希源纸业有限公司 | Production technology of low basis weight and high transparency semitransparent paper |
CN105908562A (en) * | 2016-06-21 | 2016-08-31 | 福建省晋江优兰发纸业有限公司 | Method for producing translucent paper through beating enzymes |
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