CN103897496A - Preparation method of light resistant waterproof coating - Google Patents
Preparation method of light resistant waterproof coating Download PDFInfo
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- CN103897496A CN103897496A CN201410183507.5A CN201410183507A CN103897496A CN 103897496 A CN103897496 A CN 103897496A CN 201410183507 A CN201410183507 A CN 201410183507A CN 103897496 A CN103897496 A CN 103897496A
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- 238000000576 coating method Methods 0.000 title claims abstract description 32
- 239000011248 coating agent Substances 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 54
- 238000006243 chemical reaction Methods 0.000 claims abstract description 53
- 238000003756 stirring Methods 0.000 claims abstract description 27
- 229920002678 cellulose Polymers 0.000 claims abstract description 21
- 235000010980 cellulose Nutrition 0.000 claims abstract description 21
- 239000000843 powder Substances 0.000 claims abstract description 21
- 239000000047 product Substances 0.000 claims abstract description 20
- 239000007788 liquid Substances 0.000 claims abstract description 16
- 239000000243 solution Substances 0.000 claims abstract description 15
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims abstract description 12
- 229930182490 saponin Natural products 0.000 claims abstract description 12
- 150000007949 saponins Chemical class 0.000 claims abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 11
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910017604 nitric acid Inorganic materials 0.000 claims abstract description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 9
- GRWVQDDAKZFPFI-UHFFFAOYSA-H chromium(III) sulfate Chemical compound [Cr+3].[Cr+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRWVQDDAKZFPFI-UHFFFAOYSA-H 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- 239000008139 complexing agent Substances 0.000 claims abstract description 8
- 238000010790 dilution Methods 0.000 claims abstract description 8
- 239000012895 dilution Substances 0.000 claims abstract description 8
- 239000006228 supernatant Substances 0.000 claims abstract description 8
- 238000005406 washing Methods 0.000 claims abstract description 8
- 239000001913 cellulose Substances 0.000 claims description 20
- 230000000176 photostabilization Effects 0.000 claims description 12
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 claims description 10
- 239000001117 sulphuric acid Substances 0.000 claims description 7
- 235000011149 sulphuric acid Nutrition 0.000 claims description 7
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical group OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- RPEPGIOVXBBUMJ-UHFFFAOYSA-N 2,3-difluorophenol Chemical group OC1=CC=CC(F)=C1F RPEPGIOVXBBUMJ-UHFFFAOYSA-N 0.000 claims description 5
- 229940074391 gallic acid Drugs 0.000 claims description 5
- 235000004515 gallic acid Nutrition 0.000 claims description 5
- 239000001488 sodium phosphate Substances 0.000 claims description 5
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 5
- -1 methylsiloxane Chemical class 0.000 claims description 4
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 claims description 3
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 3
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 3
- 239000011790 ferrous sulphate Substances 0.000 claims description 3
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 3
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 3
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 claims description 3
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims description 3
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 3
- 235000011008 sodium phosphates Nutrition 0.000 claims description 3
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 2
- 229940122361 Bisphosphonate Drugs 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- 150000002386 heptoses Chemical class 0.000 claims description 2
- 239000000661 sodium alginate Substances 0.000 claims description 2
- 235000010413 sodium alginate Nutrition 0.000 claims description 2
- 229940005550 sodium alginate Drugs 0.000 claims description 2
- 229940095064 tartrate Drugs 0.000 claims description 2
- 229910000406 trisodium phosphate Inorganic materials 0.000 claims description 2
- 235000019801 trisodium phosphate Nutrition 0.000 claims description 2
- 229960004418 trolamine Drugs 0.000 claims description 2
- 239000003973 paint Substances 0.000 abstract description 4
- 239000012295 chemical reaction liquid Substances 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000001291 vacuum drying Methods 0.000 abstract 1
- 229920001220 nitrocellulos Polymers 0.000 description 5
- 230000001105 regulatory effect Effects 0.000 description 5
- CKKOVFGIBXCEIJ-UHFFFAOYSA-N 2,6-difluorophenol Chemical compound OC1=C(F)C=CC=C1F CKKOVFGIBXCEIJ-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 239000005357 flat glass Substances 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009435 building construction Methods 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 238000001782 photodegradation Methods 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Abstract
The invention discloses a preparation method of light resistant waterproof coating. The preparation method comprises the following steps: immersing celluloses in water, adding chromium sulfate and a light resistant material, adjusting a reaction temperature to 30-50 DEG C, adjusting pH to 3.2-4.5, stirring and reacting for 2-4 hours, and carrying out vacuum drying on the obtained liquid so as to obtain solid powder A; immersing the solid powder A in a sulfuric acid solution with the concentration of 60%, stirring and reacting for 3-5 hours at the temperature of 50-85 DEG C, and adding water for dilution so as to stop reaction, thus obtaining reaction liquid B; centrifuging the reaction liquid B, removing supernatant liquid, adding water for washing, and centrifuging so as to obtain a product C; and adding nitric acid to a product C, stirring and reacting for 3-5 hours at a normal temperature, adding water and saponin, heating to 30-60 DEG C, then adding a waterproof agent and a complexing agent, adjusting pH to 8, stirring and reacting for 1-2 hours, thus obtaining the light resistant waterproof coating. The obtained light resistant waterproof coating is used as coating and oil paint on surfaces of interior and exterior walls, furniture and hardware.
Description
Technical field
The present invention relates to a kind of preparation method of coating, particularly a kind of preparation method of fast light and preventing water coating.
Background technology
Be sprayed at coating and the paint on external and internal wall, furniture, hardware surface, all the time all directly or indirectly contacting with the mankind, the health that poisonous, harmful coating moment is wherein threatening people.On the other hand, because the place using often contacts sunlight, and in solar ray, contain a large amount of UV-light harmful to coloured object, approximately 290～460nm of its wavelength, these harmful UV-light, by redoxomorphism chemically, make the variation of coating generation color.
Water-proof material main application fields comprises the roofing of building construction, underground, exterior wall and indoor; The public works such as urban road bridges and the underground space; The bridge of motorway and high-speed railway, tunnel; The traffic engineering such as sub.; The hydro projects such as flume, reservoir, dam body, natural flow station and water treatment, be applicable to roofing and lavatory bathe between, the waterproof of vault, water reservoir, metope, antiseepage, protection against the tide.Divide and can be used for the fields such as papermaking, weaving, leather according to application material.
Common nitrocotton is white in color filamentary fibers shape like cotton, and variable color is decomposed in exposure.Therefore in the time using at coating and finish paint, need to improve its photostabilization and water-repellancy, domestic research aspect nitrocotton is at present almost blank.
Summary of the invention
Technical problem to be solved by this invention is, a kind of preparation method of fast light and preventing water coating is provided, select chromium sulphate under suitable pH with photostabilization material, Mierocrystalline cellulose, there is complexing combination, select the good Saponin/TSM of photostabilization and water-resisting agent to be grafted in nitrocotton under the effect of complexing agent, obtain fast light and preventing water coating.
The present invention has adopted following technical scheme.
A preparation method for fast light and preventing water coating, is characterized in that carrying out according to following steps:
(1), Mierocrystalline cellulose is immersed in the water of cellulose 100 ~ 200%, add the chromium sulphate of cellulose 20 ~ 40% and the photostabilization material of cellulose 5 ~ 10%, regulate temperature of reaction to 30 ~ 50 DEG C, regulate pH to 3.2 ~ 4.5, stirring reaction 2 ~ 4h, gained liquid vacuum is dry, obtain pressed powder A;
(2), pressed powder A is immersed in the sulphuric acid soln that the concentration of cellulose 100 ~ 200% is 60%, at 50～85 DEG C of stirring reaction 3 ~ 5h, add cellulose 400% water dilution reaction is stopped, obtaining reaction solution B;
(3), by centrifugal reaction solution B, remove supernatant liquid, then add cellulose 400% water washing, the more centrifugal product C that obtains;
(4), in product C, add nitric acid, stirring reaction 3 ~ 5h under normal temperature, adds water and Saponin/TSM, is warmed up to 30 ~ 60 DEG C, then adds water-resisting agent and complexing agent, regulate pH be 8, stirring reaction 1 ~ 2h, obtains fire-retardant and lightfast coating material;
Wherein, the weight ratio of product C, nitric acid, Saponin/TSM, water-resisting agent, complexing agent is 1:2:0.5:0.5:0.2, and water is 20% of product C weight.
Photostabilization material is the one of Gallic Acid, pentahydroxyflavone-3-rhamnoside, methylphenol; Water-resisting agent is 2,3-difluorophenol, 2, the one of 6-difluorophenol, poly-carborane methylsiloxane; Complexing agent is ethylenediamine tetraacetic acid (EDTA), diethylenetriamine pentacarboxylic acid salt, ethylenediamine tetraacetic methene sodium phosphate, diethylene triamine pentamethylene phosphonic salt, tetraethyl-propylene-1, in 3-bisphosphonates, trisodium phosphate, trolamine, tartrate, heptose hydrochlorate, Sunmorl N 60S, sodium alginate, the one of ferrous sulfate.
Positively effect of the present invention is:
(1), the present invention selects Gallic Acid, pentahydroxyflavone-3-rhamnoside, Saponin/TSM to do fast light material, gained nitrocotton photostabilization is good;
(2), select 2,3-difluorophenol, 2,6-difluorophenol, poly-carborane methylsiloxane can increase substantially the water-repellancy of nitrocotton;
embodiment
Further illustrate the present invention below in conjunction with example.
Example one
(1), Mierocrystalline cellulose 25g powder is immersed in water 25g, add chromium sulphate 5g and Gallic Acid 1.25g, be warmed up to 30 DEG C, regulate pH to 3.2, stirring reaction 2h, gained liquid vacuum is dry, and obtaining pressed powder A is 30g;
(2), by pressed powder A to immerse concentration be 60% sulphuric acid soln 25g, at 50 DEG C of stirring reaction 3h, the 100g that adds water dilution stops reaction, obtains reaction solution B; By centrifugal reaction solution B, remove supernatant liquid, then the 100g washing that adds water, the more centrifugal product C that obtains is 39g;
(3), in 39g product C, add nitric acid 78g, stirring at normal temperature reaction 3h, add water 7.8g and Saponin/TSM 19.5g, be warmed up to 30 DEG C and add 2,3-difluorophenol 19.5g and ethylenediamine tetraacetic acid (EDTA) 7.8g again, regulating pH is 8, reaction 1h, obtains fast light and preventing water coating.
Example two
(1), Mierocrystalline cellulose 25g powder is immersed in water 50g, add chromium sulphate 10g and pentahydroxyflavone-3-rhamnoside 2.5g, be warmed up to 50 DEG C, regulate pH to 4.5, stirring reaction 4h, gained liquid vacuum is dry, and obtaining pressed powder A is 36g;
(2), by pressed powder A to immerse concentration be 60% sulphuric acid soln 50g, at 85 DEG C of stirring reaction 5h, the 100g that adds water dilution stops reaction, obtains reaction solution B; By centrifugal reaction solution B, remove supernatant liquid, then the 100g washing that adds water, the more centrifugal product C that obtains is 44g;
(3), in 44g product C, add nitric acid 88g, stirring at normal temperature reaction 5h, 88g and Saponin/TSM 22g add water, be warmed up to 60 DEG C and add 2,6-difluorophenol 22g and diethylenetriamine pentacarboxylic acid salt 8.8g again, regulating pH is 8, reaction 2h, obtains fast light and preventing water coating.
Example three
(1), Mierocrystalline cellulose 25g powder is immersed in water 38g, add chromium sulphate 7.5g and methylphenol 1.9g, be warmed up to 40 DEG C, regulate pH to 4.0, stirring reaction 3h, gained liquid vacuum is dry, and obtaining pressed powder A is 33g;
(2), by pressed powder A to immerse concentration be 60% sulphuric acid soln 37.5g, at 70 DEG C of stirring reaction 4h, the 100g that adds water dilution stops reaction, obtains reaction solution B; By centrifugal reaction solution B, remove supernatant liquid, then the 100g washing that adds water, the more centrifugal product C that obtains is 45g;
(3), in 45g product C, add nitric acid 90g, stirring at normal temperature reaction 4h, 9g and Saponin/TSM 22.5g add water, be warmed up to 45 DEG C and add again poly-carborane methylsiloxane 22.5g and ethylenediamine tetraacetic methene sodium phosphate 9g, regulating pH is 8, and reaction 1h, obtains fast light and preventing water coating.
Example four
(1), Mierocrystalline cellulose 25g powder is immersed in water 50g, add chromium sulphate 10g and pentahydroxyflavone-3-rhamnoside 2.5g, be warmed up to 50 DEG C, regulate pH to 4.5, stirring reaction 4h, gained liquid vacuum is dry, and obtaining pressed powder A is 36g;
(2), by pressed powder A to immerse concentration be 60% sulphuric acid soln 50g, at 85 DEG C of stirring reaction 5h, the 100g that adds water dilution stops reaction, obtains reaction solution B; By centrifugal reaction solution B, remove supernatant liquid, then the 100g washing that adds water, the more centrifugal product C that obtains is 44g;
(3), in 44g product C, add nitric acid 88g, stirring at normal temperature reaction 5h, 88g and Saponin/TSM 22g add water, be warmed up to 60 DEG C and add 2,6-difluorophenol 22g and diethylene triamine pentamethylene phosphonic salt 8.8g again, regulating pH is 8, reaction 2h, obtains fast light and preventing water coating.
Example five
(1), Mierocrystalline cellulose 25g powder is immersed in water 25g, add chromium sulphate 5g and Gallic Acid 1.25g, be warmed up to 30 DEG C, regulate pH to 3.2, stirring reaction 2h, gained liquid vacuum is dry, and obtaining pressed powder A is 30g;
(2), by pressed powder A to immerse concentration be 60% sulphuric acid soln 25g, at 50 DEG C of stirring reaction 3h, the 100g that adds water dilution stops reaction, obtains reaction solution B; By centrifugal reaction solution B, remove supernatant liquid, then the 100g washing that adds water, the more centrifugal product C that obtains is 39g;
(3), in 39g product C, add nitric acid 78g, stirring at normal temperature reaction 3h, add water 7.8g and Saponin/TSM 19.5g, be warmed up to 30 DEG C and add 2,3-difluorophenol 19.5g and ferrous sulfate 7.8g again, regulating pH is 8, reaction 1h, obtains fast light and preventing water coating.
Further illustrate beneficial effect of the present invention below by related experiment data.
Water tolerance employing is got appropriate emulsion and is evenly coated on sheet glass, after drying and forming-film, sheet glass is put into deionized water and soak under certain temperature, observes film and becomes blue, turns white, bubbles, sends out the situation of wrinkling, coming off.
For quantitative description resistance to light of coating energy, adopt spectrophotometer to detect, to obtain inverse difference △ E, the photostabilization of coating and finish paint is described.△ E has represented colour-change degree, and △ E is larger, and color change is more obvious.In general, △ E value is the slight variation of 0～1.5 genus; △ E value is that 1.5～3.0 genus can be felt variation; △ E value be 3.0～6.0 belong to considerable changes (referring to Wang Fang, party's climax, Wang Liqin, the photodegradation [J] of several organic historical relic's protection polymer coatings. Northwest University's journal, 2005,35 (5): 56 ~ 58).
Fire-retardant and the lightfast coating material institute film forming photostabilization of table one
Can find from table one, example one all in slight variation range, shows good photostabilization to the prepared coating photostabilization of example five.
One kind, table two is fast light and the film properties of preventing water coating
Can find from table two, from film outward appearance, hardness, sticking power, flexibility better performances.
Claims (4)
1. a preparation method for fast light and preventing water coating, is characterized in that carrying out according to following steps:
(1), Mierocrystalline cellulose is immersed in the water of cellulose 100 ~ 200%, add the chromium sulphate of cellulose 20 ~ 40% and the photostabilization material of cellulose 5 ~ 10%, regulate temperature of reaction to 30 ~ 50 DEG C, regulate pH to 3.2 ~ 4.5, stirring reaction 2 ~ 4h, gained liquid vacuum is dry, obtain pressed powder A;
(2), pressed powder A is immersed in the sulphuric acid soln that the concentration of cellulose 100 ~ 200% is 60%, at 50～85 DEG C of stirring reaction 3 ~ 5h, add cellulose 400% water dilution reaction is stopped, obtaining reaction solution B;
(3), by centrifugal reaction solution B, remove supernatant liquid, then add cellulose 400% water washing, the more centrifugal product C that obtains;
(4), in product C, add nitric acid, stirring reaction 3 ~ 5h under normal temperature, adds water and Saponin/TSM, is warmed up to 30 ~ 60 DEG C, then adds water-resisting agent and complexing agent, regulate pH be 8, stirring reaction 1 ~ 2h, obtains fast light and preventing water coating;
Wherein, the weight ratio of product C, nitric acid, Saponin/TSM, water-resisting agent, complexing agent is 1:2:0.5:0.5:0.2, and water is 20% of product C weight.
2. the preparation method of a kind of fast light and preventing water coating according to claim 1, is characterized in that: photostabilization material is the one of Gallic Acid, pentahydroxyflavone-3-rhamnoside, methylphenol.
3. the preparation method of a kind of fast light and preventing water coating according to claim 1, is characterized in that: water-resisting agent is 2,3-difluorophenol, 2, the one of 6-difluorophenol, poly-carborane methylsiloxane.
4. the preparation method of a kind of fast light and preventing water coating according to claim 1, it is characterized in that: complexing agent is ethylenediamine tetraacetic acid (EDTA), diethylenetriamine pentacarboxylic acid salt, ethylenediamine tetraacetic methene sodium phosphate, diethylene triamine pentamethylene phosphonic salt, tetraethyl-propylene-1, the one of 3-bisphosphonates, trisodium phosphate, trolamine, tartrate, heptose hydrochlorate, Sunmorl N 60S, sodium alginate, ferrous sulfate.
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| CN201410183507.5A CN103897496B (en) | 2014-05-04 | 2014-05-04 | A kind of fast light preparation method with preventing water coating |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108912776A (en) * | 2018-07-03 | 2018-11-30 | 西安随心呼汽车服务有限公司 | A kind of vehicle paint maintenance film coating agent |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4022724A (en) * | 1974-07-24 | 1977-05-10 | Bayer Aktiengesellschaft | Nitrocellulose alkyd resin lacquers containing bis-(hydroxyphenyl)-alkanes |
| CN101638541A (en) * | 2008-07-31 | 2010-02-03 | 上海奇想青晨化工科技股份有限公司 | Waterborne rusted paint and preparation method thereof |
| CN103436093A (en) * | 2013-08-26 | 2013-12-11 | 孙宝林 | Anti-counterfeiting stamp-pad ink and preparation method thereof |
| CN103555114A (en) * | 2013-10-25 | 2014-02-05 | 广州慧谷化学有限公司 | Coating composition for hydrophilic treatment of air-conditioning parallel flow heat exchanger |
-
2014
- 2014-05-04 CN CN201410183507.5A patent/CN103897496B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4022724A (en) * | 1974-07-24 | 1977-05-10 | Bayer Aktiengesellschaft | Nitrocellulose alkyd resin lacquers containing bis-(hydroxyphenyl)-alkanes |
| CN101638541A (en) * | 2008-07-31 | 2010-02-03 | 上海奇想青晨化工科技股份有限公司 | Waterborne rusted paint and preparation method thereof |
| CN103436093A (en) * | 2013-08-26 | 2013-12-11 | 孙宝林 | Anti-counterfeiting stamp-pad ink and preparation method thereof |
| CN103555114A (en) * | 2013-10-25 | 2014-02-05 | 广州慧谷化学有限公司 | Coating composition for hydrophilic treatment of air-conditioning parallel flow heat exchanger |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108912776A (en) * | 2018-07-03 | 2018-11-30 | 西安随心呼汽车服务有限公司 | A kind of vehicle paint maintenance film coating agent |
| CN108912776B (en) * | 2018-07-03 | 2020-11-10 | 西安随心呼汽车服务有限公司 | Vehicle paint maintenance coating agent |
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| CN103897496B (en) | 2015-11-18 |
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