CN1038857C - Natural opening process of composite fibre - Google Patents
Natural opening process of composite fibre Download PDFInfo
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- CN1038857C CN1038857C CN 94117189 CN94117189A CN1038857C CN 1038857 C CN1038857 C CN 1038857C CN 94117189 CN94117189 CN 94117189 CN 94117189 A CN94117189 A CN 94117189A CN 1038857 C CN1038857 C CN 1038857C
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- composite fibre
- condensate
- fine method
- fibre according
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Abstract
The present invention relates to a natural opening fiber method of a composite fiber, which can naturally open the composite fiber successfully during dyeing and finishing without using a physical method or a chemical method by controlling the crystallizeation difference of a polymer to generate a good polymer separation state, so that the natural opening fiber method reduces cost and has improved production efficiency, and a protofilament has the advantages of good strength and touch feeling, incapability of generating the environmental protection problems of wastewater in manufacture, etc. and has industrial value.
Description
The present invention relates to a kind of composite fibre and open fine method for making naturally, its mainly be add nucleator in a kind of therein condensate add mould release or add catalyst control its in conjunction with the time viscosity differences or improve the precursor coiling speed, thereby control polymeric crystallization difference, provide the release state of condensate the best, to improve its economic benefit.
Manufacturer must be opened fibre when producing composite fibre now, makes composite fibre have following advantage:
(1) allow the user when wearing, have slightly gas permeability.
(2) have higher water imbibition and reach circulation preferably.
(3) have higher fabric volume and aqueous vapor and air permeability preferably.
(4) has higher covering power.
(5) soft careful feel is arranged, be different from general artificial fibre.
For convenience of description, in this specification tradition or composite fibre of the present invention qualification are made of polyamide-based (Nylon) fiber and two kinds of condensates of polyesters (Polyester) fiber, yet, these explanations just exemplify the present invention and may how to be implemented, so these specific materials should not be understood that restriction of the present invention.
Traditional fiber opening method can be divided into two kinds by summary, a kind ofly opens fibre (claiming machinery to open fibre again) for physics, another kind ofly opens fibre for chemistry, and the examination division is as follows:
(1) physics is opened fibre: see also shown in Figure 3ly, it opens fine flow process for physics, and it just can be finished opening fibre → weave cotton cloth → dyeing and finishing through preparing condensate → spinning → false twisting.
Prepare condensate: as shown in Figure 4, condensate A10 (polyamide) and condensate B20 (polyester) are inserted respectively in each extruder 30, and heating for dissolving extrudes in extruder 30, make the control of polyamide (condensate A) 10 and polyester (condensate B) 20 process measuring pumps 31 and enter spinning zone (SPINPACK) 32, then to spin the quite low speed of fast 500-1500m/min, utilize coiling machine 70 to batch it, wherein can be through cooling zone 40, extension area 50, heat set zone 60, and obtain the composite fibre 80 of structure as shown in Figure 5.
Next composite fibre 80 is twisted earlier with 200T/M, again with 180 ℃, over feed rate(OFR) 0,5% condition are carried out false twisting processing, make composite fibre in two kinds of compound compositions, obtain different contractions and uphold effect and have the fluffy fine state of opening, again through weaving cotton cloth, the process of dyeing and finishing, make it to become cloth with color and luster.
Yet this processing mode has following shortcoming:
1. it adopts and opens fine mode of weaving cotton cloth again earlier and finish, and makes precursor become fluffy state before not weaving cotton cloth, and just weaves cotton cloth then, and this processing mode is quite difficult, and fracture of wire easily, except make produce slowly, more increase the burden of cost.
2. the composite fibre after fibre is opened in false twisting, the distribution of its intensity is also inhomogeneous, destroys the intensity of composite fibre easily.
(2) chemistry is opened fibre: see also shown in Figure 6ly, it opens fine flow process for chemistry, through preparing condensate → spinning → weave cotton cloth → decrement processing → washing → dyeing and finishing, can finish.
The process of preparation condensate and spinning is the same with the mode that physics is opened fibre, but made composite fibre 80 is directly used in and weaves cotton cloth after the process spinning, impose the process of decrement processing after weaving cotton cloth, can adopt the mode of adding caustic soda (NaOH) to finish, make condensate B20 (polyester) the composition dissolving of composite fibre, only remaining cross section is the polyamide monofilament of division shape, as shown in Figure 5, thereby reach out the purpose of very thinization, make composite fibre have fluffy state, through the process of washing caustic soda (NaOH) is removed again, carried out dyeing and finishing then, make it to become cloth with color and luster.
Though this processing mode is opened the easier processing of fibre than physics, still has following shortcoming:
1, because the composite fibre adsorption is strong excessively, will cause the residual problem of caustic soda after the decrement, and the following puzzlement of deriving is grown thickly as the flavescence of embryo cloth, colouring problem, oligomerization zoarium (Oligmer) is removed difficulty, cylinder groove pollution etc.
2, for the state of dissimilar (different fiber, section, configuration of surface etc.) combination, the difference of decrement speed produces, and will cause side decrement extremely, and makes the strength reduction of fiber.
3, composite fibre is very responsive for the unusual fluctuation of reduction rate, 1% decrement rate variance, and the difference of feel is just very big, generally speaking, must not surpass 13%.
4, chemistry is opened fibre except needing be considered carefully for the wastewater treatment environmental issue after storage-stable, operational security, processing stable homogeneous, cooling property, draining and the washing of medicament, and has increased cost relatively.
The inventor is because conventional physical is opened fibre or chemistry is opened fine shortcoming, invent out a kind ofly reduce cost, enhance productivity, precursor has intensity, sense of touch is good, do not have environmental issue when making open fine method for making naturally.
Main purpose of the present invention is: provide a kind of composite fibre to open fine method for making naturally, its mainly be add nucleator, mould release or catalyst in a kind of therein condensate or control its in conjunction with the time viscosity differences or improve the coiling speed of composite fibre, thereby control polymeric crystallization difference in advance, the release state of condensate the best is provided, make the present invention open fibre without physics or chemical mode, just can be when dyeing and finishing, naturally open fibre smoothly, reach and meet economy, free of contamination problem.
Composite fibre of the present invention is opened fine method for making naturally, and it is characterized in that: each condensate is inserted respectively in each extruder, and controls polymeric crystallization difference in advance, makes each condensate become best release state,
Wherein controlling the mode of polymeric crystallization difference can finish with the interpolation nucleator.
Secondly technical scheme of the present invention is: provide a kind of composite fibre to open fine method for making naturally, it is characterized in that: each condensate is inserted respectively in each extruder, and controls polymeric crystallization difference in advance, makes each condensate become best release state,
Wherein controlling the mode of polymeric crystallization difference can finish with the interpolation mould release.
It three is technical scheme of the present invention: provide a kind of composite fibre to open fine method for making naturally, it is characterized in that: each condensate is inserted respectively in each extruder, and controls polymeric crystallization difference in advance, makes each condensate become best release state,
Wherein controlling the mode of polymeric crystallization difference can finish with the interpolation catalyst.
It four is technical scheme of the present invention: provide a kind of composite fibre to open fine method for making naturally, it is characterized in that: each condensate is inserted respectively in each extruder, and controls polymeric crystallization difference in advance, makes each condensate become best release state,
Wherein controlling the mode of polymeric crystallization difference can finish with the control viscosity differences.
Naturally open fine method for making according to composite fibre of the present invention, it is characterized in that: improve coiling speed approximately to 3000-8000m/min, utilize the different crystallinity that improve between coiling speed generation condensate, and be easy to release.
Aforesaid composite fibre is opened fine method for making naturally, it is characterized in that, it adds nucleator when preparing condensate, and its nucleator addition is 1000-5000ppm, as calcium silicates (CaSiO
3), silica (SiO
2), molybdenum bisuphide (MoS
2) etc.
Aforesaid composite fibre is opened fine method for making naturally, it is characterized in that: the mould release of interpolation can be not dragon of ultra tiny iron.
Aforesaid composite fibre is opened fine method for making naturally, it is characterized in that: the amorphism condensate that its interpolation catalyst is interpolation 20 to 80 percent is to the crystallinity condensate, make its boiling water shrinkage be increased to 25 percent by 10, cause and another polymeric difference, and be easy to release.
Aforesaid composite fibre is opened fine method for making naturally, it is characterized in that: its control viscosity differences is that the control hetero-polymer produces different viscosity differences in different melt temperatures, and is easy to release.
The present invention mainly comprises two aspects, the first, when preparing condensate, cooperate add nucleator or add mould release or add catalyst or control its in conjunction with the time viscosity differences, thereby control polymeric crystallization difference, the release state of condensate the best is provided.
The second, cooperate the coiling speed that improves composite fibre again, control polymeric crystallization difference, utilize the different different crystallinity that produce between condensate of coiling speed, thereby be easy to release.
This shows that method for making of the present invention breaks through conventional physical fully and opens fibre or the chemical shortcoming of opening fibre, at first, the present invention weaves cotton cloth and weaves with precursor, so efficient improves, cost reduces; Moreover, open fibre without physical or chemical treatment, can keep the intensity of precursor, and make the present invention have splendid sense of touch; Secondly, the environmental issue that does not have wastewater treatment; In addition, be easy to dyeing and finishing and need be with preferable dyeing and finishing technique; In sum, the present invention improves industrial utilization effectively, is a splendid new invention.
Further specify specific structural features of the present utility model and purpose below in conjunction with accompanying drawing.
Brief Description Of Drawings:
Fig. 1 is a flow chart of the present invention.
Fig. 2 is a flow chart of the present invention.
Fig. 3 is that conventional physical is opened fine flow chart.
Fig. 4 is a conventional composite fiber manufacturing process schematic diagram.
Fig. 5 is the structure cross-sectional schematic of composite fibre.
Fig. 6 is that traditional chemical is opened fine flow chart.
The present invention relates to a kind of composite fibre and open fine method for making naturally, as Fig. 1
Prepare condensate: as shown in Figure 4, condensate A10 and condensate B20 are inserted respectively in each extruder 30, and control the crystallization difference of condensate A10, B20 in advance, make condensate A10 and condensate B20 fiber become best release state, its mode of controlling polymeric crystallization difference can be finished by following arbitrary mode:
(1) adds nucleator: add nucleator 1000-5000ppm in a kind of therein condensate, as calcium silicates (CaSiO
3), silica (SiO
2), molybdenum bisuphide (MoS
2) etc., help wherein a kind of condensate to be easy to crystallization, reduce surperficial coefficient of friction, have lubrication and be easy to release.
(2) add mould release: add mould release in a kind of therein condensate, for example ultra tiny iron is dragon not, the release degree between condensate is increased, and produce difference with another condensate, and be easy to release.
(3) add catalyst: add 20 to 80 percent amorphism condensate to the crystallinity condensate, make its boiling water shrinkage be increased to 25 percent, cause and another polymeric difference, and be easy to release by 10.
(4) control viscosity differences: the control condensate produces different viscosity differences in different melt temperatures, and is easy to release.
Certainly, the different crystalline four kinds of modes between above-mentioned control condensate can be arranged in pairs or groups arbitrarily mutually.
Spinning: enter the condensate A10 and the condensate B20 of spinning zone 32, be combined into composite fibre shown in Figure 5 80 structures through mould.
Through the process of weaving cotton cloth, fibre is opened in dyeing and finishing, just open fibre smoothly naturally then.
Please referring to shown in Figure 2, it is the flow chart of another embodiment of the present invention; The present invention also can be when spinning, improves coiling speed approximately to 3000-8000m/min, utilize to improve coiling speed and produce different crystallinity between condensate, thereby and be easy to the release fibre of opening naturally; Certainly, this control different crystallinity modes between condensate, also can with above-mentioned interpolation nucleator or add mould release or add catalyst or control its in conjunction with the time the viscosity differences use of arranging in pairs or groups arbitrarily.
Claims (10)
1, a kind of composite fibre is opened fine method naturally, it is characterized in that: each condensate is inserted respectively in each extruder, and control polymeric crystallization difference, make each condensate become best release state.
2, composite fibre according to claim 1 is opened fine method naturally, and it is characterized in that: the mode of controlling polymeric crystallization difference is to finish with the interpolation nucleator.
3, composite fibre according to claim 1 is opened fine method naturally, and it is characterized in that: the mode of controlling polymeric crystallization difference is to finish with the interpolation mould release.
4, composite fibre according to claim 1 is opened fine method naturally, and it is characterized in that: the mode of controlling polymeric crystallization difference is to finish with the interpolation catalyst.
5, composite fibre according to claim 1 is opened fine method naturally, it is characterized in that: the mode of controlling polymeric crystallization difference is to be finished by the control viscosity differences.
6, composite fibre according to claim 1 is opened fine method naturally, it is characterized in that: improve coiling speed approximately to 3000-8000 rice/minute, utilize and improve coiling speed and generate different crystallinity between condensate, and be easy to release.
7, composite fibre according to claim 2 is opened fine method naturally, it is characterized in that: add nucleator when preparing condensate; The addition of nucleator is 1000-5000ppm, and described nucleator comprises calcium silicates, silica, molybdenum bisuphide.
8, composite fibre according to claim 3 is opened fine method naturally, and it is characterized in that: the mould release of its interpolation is ultra-fine fe fluon.
9, composite fibre according to claim 4 is opened fine method naturally, it is characterized in that: it adds catalyst is to add amorphism condensate 20 to 80 percent to the crystallinity condensate, make its boiling water shrinkage be increased to 25 percent by 10, cause and another polymeric difference, and be easy to release.
10, composite fibre according to claim 5 is opened fine method naturally, it is characterized in that: the control viscosity differences is that the control hetero-polymer generates different viscosity differences in different melt temperatures, and is easy to release.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 94117189 CN1038857C (en) | 1994-10-21 | 1994-10-21 | Natural opening process of composite fibre |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 94117189 CN1038857C (en) | 1994-10-21 | 1994-10-21 | Natural opening process of composite fibre |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1121121A CN1121121A (en) | 1996-04-24 |
| CN1038857C true CN1038857C (en) | 1998-06-24 |
Family
ID=5038233
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 94117189 Expired - Fee Related CN1038857C (en) | 1994-10-21 | 1994-10-21 | Natural opening process of composite fibre |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1038857C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104251858A (en) * | 2013-06-28 | 2014-12-31 | 王辰 | In-vitro detection method used for detecting oxidative stress marker d-ROMs |
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1994
- 1994-10-21 CN CN 94117189 patent/CN1038857C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1121121A (en) | 1996-04-24 |
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| C14 | Grant of patent or utility model | ||
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