CN103881135A - Reinforced modified nano-silica masterbatch - Google Patents
Reinforced modified nano-silica masterbatch Download PDFInfo
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- CN103881135A CN103881135A CN201410105535.5A CN201410105535A CN103881135A CN 103881135 A CN103881135 A CN 103881135A CN 201410105535 A CN201410105535 A CN 201410105535A CN 103881135 A CN103881135 A CN 103881135A
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Abstract
The invention discloses a reinforced modified nano-silica masterbatch. The reinforced modified nano-silica masterbatch comprises the following raw materials in parts by weight: 50-60 parts of nano-silica, 20-30 parts of ultrafine aluminium silicate, 10-15 parts of absolute ethyl alcohol, 2-3 parts of pure acrylic emulsion, 1-2 parts of trimethylolpropane, 3-5 parts of polyamide wax micropowder, 1-2 parts of polydimethylsiloxane, 1-2 parts of dodecyl trimethyl ammonium chloride and 0.1-0.2 part of 8-hydroxyquinoline. The masterbatch can be widely applied to various industries, such as coatings, rubber, plastics and the like, and not only can enhance the compatibility among various materials and improve the mechanical strength such as wear resistance, tear resistance and the like of the finished product but also can enhance the weather resistance and improve the total mass of a finished product.
Description
Technical field
The present invention relates generally to Material Field, relates in particular to a kind of reinforced type modified manometer silicon dioxide master batch.
Background technology
Nano silicon is one of ultra tiny New Inorganic Materials of extremely important high-tech, because of its particle diameter very little, specific surface area is large, surface adsorption power is strong, surface can be large, and the aspects such as chemical purity is high, dispersing property good, thermal resistance, resistance have special performance, with its superior stability, reinforcement, thickening property and thixotropy, in numerous subjects and field, show unique characteristics, have the effect of not replacing.Nano silicon is commonly called as " ultra-fine white carbon black ", be widely used in every profession and trade as additive, support of the catalyst, petrochemical complex, discoloring agent, matting agent, rubber reinforcing filler, plastics filling agent, ink thickening material, the soft polishing agent of metal, insulation and thermal insulation weighting agent, the various fields such as high-grade daily-use makeup filler and spray material, medicine, environmental protection.
Superfine alumina silicate is a kind of new type functional silicate, is called " synthetic kaolin " by people.It is widely used in the industrial sectors such as coating, ink, plastics, rubber, leather, printing and dyeing, papermaking.It belongs to a kind of layered silicate, and there is very high gloss on its sheet surface, has very strong light scattering property; Its iron level is little, and purity is high, has again fabulous suspension stability, is titanium dioxide in coating and the ideal substitute of high-quality kaolin, and market outlook are boundless.
Above-mentioned nano silicon and superfine alumina silicate all tool can be used as material reinforcement use, will directly be mixed to join in material, consistency is poor.
Summary of the invention
The object of the invention is just to provide a kind of reinforced type modified manometer silicon dioxide master batch.
The present invention is achieved by the following technical solutions:
A kind of reinforced type modified manometer silicon dioxide master batch, it is made up of the raw material of following weight parts:
Nano silicon 50-60, superfine alumina silicate 20-30, dehydrated alcohol 10-15, pure-acrylic emulsion 2-3, TriMethylolPropane(TMP) 1-2, polyamide wax micropowder 3-5, polydimethylsiloxane 1-2, Dodecyl trimethyl ammonium chloride 1-2, copper 8-quinolinolate 0.1-0.2.
A preparation method for reinforced type modified manometer silicon dioxide master batch, comprises the following steps:
(1) be scattered in 4-6 water doubly ultrasonic above-mentioned nano silicon, add TriMethylolPropane(TMP), ultrasonic dispersion 10-13 minute, obtains dispersion liquid a;
(2) above-mentioned superfine alumina silicate is mixed with polyamide wax micropowder, after stirring, add pure-acrylic emulsion, at 60-80 DEG C, be uniformly mixed 3-5 minute, add dehydrated alcohol, be stirred to normal temperature, add Dodecyl trimethyl ammonium chloride, 300-400 rev/min of dispersed with stirring 4-6 minute, obtains compound b;
(3) above-mentioned dispersion liquid a and compound b are mixed, add the each raw material of residue, 1600-2000 rev/min of dispersed with stirring 10-15 minute, filters, and dries, and granulation after ball milling, crosses 80-100 mesh sieve, obtains described reinforced type modified manometer silicon dioxide master batch.
Advantage of the present invention is:
Nano silicon and superfine alumina silicate mixing are made master batch by the present invention, can be widely applied to various industries, such as coating, rubber, plastics etc., not only can strengthen the consistency of each storeroom, improve the mechanical strength such as wear-resistant, anti tear of finished product, can also strengthen weathering resistance, improve the total quality of finished product.
Embodiment
Embodiment 1
A kind of reinforced type modified manometer silicon dioxide master batch, it is made up of the raw material of following weight parts:
Nano silicon 60, superfine alumina silicate 30, dehydrated alcohol 15, pure-acrylic emulsion 3, TriMethylolPropane(TMP) 2, polyamide wax micropowder 5, polydimethylsiloxane 1, Dodecyl trimethyl ammonium chloride 2, copper 8-quinolinolate 0.2.
A preparation method for reinforced type modified manometer silicon dioxide master batch, comprises the following steps:
(1) by the ultrasonic above-mentioned nano silicon water that is scattered in 4 times, add TriMethylolPropane(TMP), ultrasonic dispersion 13 minutes, obtains dispersion liquid a;
(2) above-mentioned superfine alumina silicate is mixed with polyamide wax micropowder, after stirring, add pure-acrylic emulsion, at 80 DEG C, be uniformly mixed 5 minutes, add dehydrated alcohol, be stirred to normal temperature, add Dodecyl trimethyl ammonium chloride, 300 revs/min of dispersed with stirring 6 minutes, obtain compound b;
(3) above-mentioned dispersion liquid a and compound b are mixed, add the each raw material of residue, 2000 revs/min of dispersed with stirring 15 minutes, filter, and dry, and granulation after ball milling, crosses 100 mesh sieves, obtains described reinforced type modified manometer silicon dioxide master batch.
Claims (2)
1. a reinforced type modified manometer silicon dioxide master batch, is characterized in that what it was made up of the raw material of following weight parts:
Nano silicon 50-60, superfine alumina silicate 20-30, dehydrated alcohol 10-15, pure-acrylic emulsion 2-3, TriMethylolPropane(TMP) 1-2, polyamide wax micropowder 3-5, polydimethylsiloxane 1-2, Dodecyl trimethyl ammonium chloride 1-2, copper 8-quinolinolate 0.1-0.2.
2. a preparation method for reinforced type modified manometer silicon dioxide master batch as claimed in claim 1, is characterized in that comprising the following steps:
(1) be scattered in 4-6 water doubly ultrasonic above-mentioned nano silicon, add TriMethylolPropane(TMP), ultrasonic dispersion 10-13 minute, obtains dispersion liquid a;
(2) above-mentioned superfine alumina silicate is mixed with polyamide wax micropowder, after stirring, add pure-acrylic emulsion, at 60-80 DEG C, be uniformly mixed 3-5 minute, add dehydrated alcohol, be stirred to normal temperature, add Dodecyl trimethyl ammonium chloride, 300-400 rev/min of dispersed with stirring 4-6 minute, obtains compound b;
(3) above-mentioned dispersion liquid a and compound b are mixed, add the each raw material of residue, 1600-2000 rev/min of dispersed with stirring 10-15 minute, filters, and dries, and granulation after ball milling, crosses 80-100 mesh sieve, obtains described reinforced type modified manometer silicon dioxide master batch.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410105535.5A CN103881135B (en) | 2014-03-15 | 2014-03-15 | A kind of reinforced type modified manometer silicon dioxide master batch |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201410105535.5A CN103881135B (en) | 2014-03-15 | 2014-03-15 | A kind of reinforced type modified manometer silicon dioxide master batch |
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| Publication Number | Publication Date |
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| CN103881135A true CN103881135A (en) | 2014-06-25 |
| CN103881135B CN103881135B (en) | 2016-02-03 |
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| CN201410105535.5A Expired - Fee Related CN103881135B (en) | 2014-03-15 | 2014-03-15 | A kind of reinforced type modified manometer silicon dioxide master batch |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104119622A (en) * | 2014-07-02 | 2014-10-29 | 合肥和安机械制造有限公司 | Modified silicon dioxide for automobile wiring harness PVC sheath material and preparation method thereof |
| CN114477839A (en) * | 2022-03-10 | 2022-05-13 | 日照海工研新材料有限公司 | Marine concrete corrosion inhibitor and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101987927A (en) * | 2009-08-05 | 2011-03-23 | 任绍志 | Method for preparing modified nano-silica from polysilane |
| CN102083892A (en) * | 2008-07-24 | 2011-06-01 | 内格罗梅克斯工业可变动资本额公司 | Processes for making silane, hydrophobated silica, silica masterbatch and rubber products |
| CN103374194A (en) * | 2012-04-16 | 2013-10-30 | 苏州萃智新技术开发有限公司 | Gas phase nano silicon dioxide master batches for plastic modification and preparation method thereof |
-
2014
- 2014-03-15 CN CN201410105535.5A patent/CN103881135B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102083892A (en) * | 2008-07-24 | 2011-06-01 | 内格罗梅克斯工业可变动资本额公司 | Processes for making silane, hydrophobated silica, silica masterbatch and rubber products |
| CN101987927A (en) * | 2009-08-05 | 2011-03-23 | 任绍志 | Method for preparing modified nano-silica from polysilane |
| CN103374194A (en) * | 2012-04-16 | 2013-10-30 | 苏州萃智新技术开发有限公司 | Gas phase nano silicon dioxide master batches for plastic modification and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104119622A (en) * | 2014-07-02 | 2014-10-29 | 合肥和安机械制造有限公司 | Modified silicon dioxide for automobile wiring harness PVC sheath material and preparation method thereof |
| CN114477839A (en) * | 2022-03-10 | 2022-05-13 | 日照海工研新材料有限公司 | Marine concrete corrosion inhibitor and preparation method thereof |
| CN114477839B (en) * | 2022-03-10 | 2022-09-27 | 日照海工研新材料有限公司 | Marine concrete corrosion inhibitor and preparation method thereof |
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| CN103881135B (en) | 2016-02-03 |
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Inventor after: Guo Huanyin Inventor after: Wang Guiying Inventor after: Yue Mingdao Inventor after: Cao Baoyin Inventor after: Hao Baoming Inventor before: Xu Haifeng Inventor before: Wang Guiying Inventor before: Yue Mingdao Inventor before: Cao Baoyin Inventor before: Hao Baoming |
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Granted publication date: 20160203 Termination date: 20180315 |