CN103880321A - Method for preparing cementing material mix of taking alumina clinker as primary raw material - Google Patents
Method for preparing cementing material mix of taking alumina clinker as primary raw material Download PDFInfo
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- CN103880321A CN103880321A CN201410045670.5A CN201410045670A CN103880321A CN 103880321 A CN103880321 A CN 103880321A CN 201410045670 A CN201410045670 A CN 201410045670A CN 103880321 A CN103880321 A CN 103880321A
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- parts
- aluminum oxide
- raw material
- main raw
- oxide clinker
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- 239000000463 material Substances 0.000 title claims abstract description 103
- 239000002994 raw material Substances 0.000 title claims abstract description 70
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 title abstract 5
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 62
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 49
- 239000000203 mixture Substances 0.000 claims abstract description 41
- 239000000292 calcium oxide Substances 0.000 claims abstract description 31
- 235000012255 calcium oxide Nutrition 0.000 claims abstract description 31
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000010881 fly ash Substances 0.000 claims abstract description 27
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims abstract description 26
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 25
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 25
- 229910021538 borax Inorganic materials 0.000 claims abstract description 25
- 239000001110 calcium chloride Substances 0.000 claims abstract description 25
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 25
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229920000609 methyl cellulose Polymers 0.000 claims abstract description 25
- 239000001923 methylcellulose Substances 0.000 claims abstract description 25
- 239000000843 powder Substances 0.000 claims abstract description 25
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 25
- 239000010457 zeolite Substances 0.000 claims abstract description 25
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims abstract description 25
- 229960001763 zinc sulfate Drugs 0.000 claims abstract description 25
- 229910000368 zinc sulfate Inorganic materials 0.000 claims abstract description 25
- 229910001649 dickite Inorganic materials 0.000 claims abstract description 14
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229960000892 attapulgite Drugs 0.000 claims abstract description 9
- 239000004927 clay Substances 0.000 claims abstract description 9
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 9
- 229910052934 alunite Inorganic materials 0.000 claims abstract description 7
- 239000010424 alunite Substances 0.000 claims abstract description 7
- KPZTWMNLAFDTGF-UHFFFAOYSA-D trialuminum;potassium;hexahydroxide;disulfate Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Al+3].[Al+3].[Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O KPZTWMNLAFDTGF-UHFFFAOYSA-D 0.000 claims abstract description 7
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 72
- 238000002360 preparation method Methods 0.000 claims description 36
- 238000000227 grinding Methods 0.000 claims description 28
- 101710194948 Protein phosphatase PhpP Proteins 0.000 claims description 24
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims description 24
- 239000011734 sodium Substances 0.000 claims description 24
- 229910052708 sodium Inorganic materials 0.000 claims description 24
- 239000004328 sodium tetraborate Substances 0.000 claims description 24
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 24
- CRPOUZQWHJYTMS-UHFFFAOYSA-N dialuminum;magnesium;disilicate Chemical compound [Mg+2].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] CRPOUZQWHJYTMS-UHFFFAOYSA-N 0.000 claims description 18
- -1 0.2 part Substances 0.000 claims description 13
- 238000012856 packing Methods 0.000 claims description 7
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 229910001294 Reinforcing steel Inorganic materials 0.000 abstract 1
- 239000000440 bentonite Substances 0.000 abstract 1
- 229910000278 bentonite Inorganic materials 0.000 abstract 1
- 230000035699 permeability Effects 0.000 abstract 1
- 235000010265 sodium sulphite Nutrition 0.000 abstract 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 abstract 1
- 239000004567 concrete Substances 0.000 description 5
- 239000004568 cement Substances 0.000 description 4
- 238000005336 cracking Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- UPLPHRJJTCUQAY-WIRWPRASSA-N 2,3-thioepoxy madol Chemical compound C([C@@H]1CC2)[C@@H]3S[C@@H]3C[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@](C)(O)[C@@]2(C)CC1 UPLPHRJJTCUQAY-WIRWPRASSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
Landscapes
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
- Treating Waste Gases (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses a method for preparing a cementing material mix of taking an alumina clinker as a primary raw material. The method for preparing the cementing material mix of taking the alumina clinker as the primary raw material is characterized by comprising the following raw materials (in parts by weight): 20-25 parts of alumina clinker, 15-20 parts of calcined alunite, 7-10 parts of zinc sulfate, 5-8 parts of dickite, 5-10 parts of attapulgite clay, 5-10 parts of fly ashes, 1-5 parts of zeolite powder, 2-4 parts of kieselguhr, 2-5 parts of bentonite, 1-2 parts of methylcellulose, 0.5-1 part of sodium sulfite, 0.5-1 part of quick lime, 0.2-0.5 parts of sodium tripolyphosphate, 0.2-0.7 parts of sodium borate and 0.2-0.8 parts of calcium chloride. The cementing material mix of taking the alumina clinker as the primary raw material disclosed by the invention has the functions of efficient water resistance, moisture resistance, expansion, crack resistance, permeability resistance and the like, and is free of corrosive action on a reinforcing steel bar.
Description
Technical field
The preparation method who the present invention relates to a kind of gelling material mixed material take aluminum oxide clinker as main raw material, belongs to building material manufacture field.
Background technology
In engineering, many building basements, roofing, highway, bridge all do not reach design service life, some engineerings only come into operation and within several years, are just subject to havoc, have to repair, its major cause be current water-proof material and concrete admixture generally containing Cl-,,, K+ ion is overweight, join in concrete, react with active silica in concrete, generate the silicate gel of alkali and produce concrete swelling cracking, common alkali-aggregate reaction in engineering that Here it is, accelerate steel bar corrosion simultaneously, caused concrete cracking infiltration.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, a kind of preparation method of the gelling material mixed material take aluminum oxide clinker as main raw material with high-effective water-proof, protection against the tide, expansion, cracking resistance, the function such as impervious is provided.
For achieving the above object, the technical solution used in the present invention is as follows:
A kind of preparation method of the gelling material mixed material take aluminum oxide clinker as main raw material, it is characterized in that: the described gelling material mixed material raw material take aluminum oxide clinker as main raw material is (weight): aluminum oxide clinker 20-25 part, calcined alunite 15-20 part, zinc sulfate 7-10 part, dickite 5-8 part, attapulgite clay 5-10 part, flyash 5-10 part, zeolite powder 1-5 part, diatomite 2-4 part, wilkinite 2-5 part, methylcellulose gum 1-2 part, S-WAT 0.5-1 part, unslaked lime 0.5-1 part, tripoly phosphate sodium STPP 0.2-0.5 part, borax 0.2-0.7 part, calcium chloride 0.2-0.8 part,
Described preparation method's step is:
Step (1): according to aluminum oxide clinker 20-25 part, calcined alunite 15-20 part, zinc sulfate 7-10 part, dickite 5-8 part, attapulgite clay 5-10 part, flyash 5-10 part, zeolite powder 1-5 part, diatomite 2-4 part, wilkinite 2-5 part, methylcellulose gum 1-2 part, S-WAT 0.5-1 part, unslaked lime 0.5-1 part, tripoly phosphate sodium STPP 0.2-0.5 part, borax 0.2-0.7 part, calcium chloride 0.2-0.8 part proportioning is prepared raw material
Step (2): aluminum oxide clinker 20-25 part, calcined alunite 15-20 part, zinc sulfate 7-10 part, dickite 5-8 part are carried out to grinding in pulverizer, and rotating speed is 120r/min, grinding 6 hours, obtains mixture A granularity size for 0.5-1mm,
Step (3): attapulgite clay 5-10 part, flyash 5-10 part, zeolite powder 1-5 part, diatomite 2-4 part, wilkinite 2-5 part are carried out to grinding in pulverizer, rotating speed is 100r/min, grinding 2 hours, obtains mixture B granularity size for 0.2-0.3mm
Step (4): step (2) is obtained to mixture A and step (3) is obtained to mixture B packing in mechanical mixer, mechanically mixing 1 hour, pour afterwards methylcellulose gum 1-2 part, S-WAT 0.5-1 part into, unslaked lime 0.5-1 part, tripoly phosphate sodium STPP 0.2-0.5 part, borax 0.2-0.7 part, calcium chloride 0.2-0.8 part, mechanically mixing 2 hours again, obtains the gelling material mixed material take aluminum oxide clinker as main raw material.
As preferably, the preparation method of the described gelling material mixed material take aluminum oxide clinker as main raw material, gelling material mixed material raw material take aluminum oxide clinker as main raw material is 20 parts of aluminum oxide clinkers, 15 parts of calcined alunites, 7 parts, zinc sulfate, 5 parts of dickites, 5 parts of attapulgite clays, 5 parts, flyash, 1 part of zeolite powder, 2 parts, diatomite, 2 parts of wilkinites, 1 part of methylcellulose gum, 0.5 part of S-WAT, 0.5 part of unslaked lime, 0.2 part of tripoly phosphate sodium STPP, 0.2 part of borax, 0.2 part, calcium chloride.
As preferably, the preparation method of the described gelling material mixed material take aluminum oxide clinker as main raw material, gelling material mixed material raw material take aluminum oxide clinker as main raw material is 25 parts of aluminum oxide clinkers, 20 parts of calcined alunites, 10 parts, zinc sulfate, 8 parts of dickites, 10 parts of attapulgite clays, 10 parts, flyash, 5 parts of zeolite powders, 4 parts, diatomite, 5 parts of wilkinites, 2 parts of methylcellulose gum, 1 part of S-WAT, 1 part of unslaked lime, 0.5 part of tripoly phosphate sodium STPP, 0.7 part of borax, 0.8 part, calcium chloride.
As preferably, the preparation method of the described gelling material mixed material take aluminum oxide clinker as main raw material, gelling material mixed material raw material take aluminum oxide clinker as main raw material is 23 parts of aluminum oxide clinkers, 17 parts of calcined alunites, 8 parts, zinc sulfate, 7 parts of dickites, 7 parts of attapulgite clays, 7 parts, flyash, 3 parts of zeolite powders, 3 parts, diatomite, 3 parts of wilkinites, 1.5 parts of methylcellulose gum, 0.8 part of S-WAT, 0.8 part of unslaked lime, 0.4 part of tripoly phosphate sodium STPP, 0.5 part of borax, 0.5 part, calcium chloride.
As preferably, the preparation method of the described gelling material mixed material take aluminum oxide clinker as main raw material, gelling material mixed material raw material take aluminum oxide clinker as main raw material is 22 parts of aluminum oxide clinkers, 18 parts of calcined alunites, 9 parts, zinc sulfate, 6 parts of dickites, 6 parts of attapulgite clays, 6 parts, flyash, 4 parts of zeolite powders, 3 parts, diatomite, 4 parts of wilkinites, 1.5 parts of methylcellulose gum, 0.8 part of S-WAT, 0.8 part of unslaked lime, 0.3 part of tripoly phosphate sodium STPP, 0.5 part of borax, 0.6 part, calcium chloride.
As preferably, the preparation method of the described gelling material mixed material take aluminum oxide clinker as main raw material, it is 0.7mm that step (2) obtains mixture A granularity size.
As preferably, the preparation method of the described gelling material mixed material take aluminum oxide clinker as main raw material, it is 0.25mm that step (3) obtains mixture B granularity size.
As preferably, the preparation method of the described gelling material mixed material take aluminum oxide clinker as main raw material, attapulgite clay composition is (weight): 56.7%SiO
2, 16.8%MgO, 3.4%FeO, 5.5%Fe
2o
3, 9.1%Al
2o
3, 2.7%CaO, 5.8% loss on ignition.
As preferably, the preparation method of the described gelling material mixed material take aluminum oxide clinker as main raw material, dickite composition is (weight): 61.1%SiO
2, 31.3%Al
2o
3, 1.2%Fe
2o
3, 1.1%CaO, 0.5%MgO, 4.8% loss on ignition.
As preferably, the preparation method of the described gelling material mixed material take aluminum oxide clinker as main raw material, flyash composition is (weight): 53.3%SiO
2, 29.7%Al
2o
3, 5.3%Fe
2o
3, 2.1%CaO, 4.8%MgO, 4.8% loss on ignition.
Compared with prior art, the present invention has following beneficial effect:
The preparation of test sample: adopt cement 282g, the gelling material mixed material 18g take aluminum oxide clinker as main raw material preparing, sand 750g, water consumption 120ml, and moulding 40 × 40 × 160mm test specimen, 20 ± 2 ℃ of temperature, humidity is maintenance under more than 90% condition.
6 quality % of cement amount in the gelling material mixed material place of cement sill take aluminum oxide clinker as main raw material making are mixed in cement-based material, make 20 test blocks, the average index that detects the properties of 20 test blocks is: fineness (specific surface area): 410m2/kg, time of coagulation: initial set 115min final set 300min, limited expansion rate: 7d-0.024%; 28d-0.015%, ultimate compression strength: 7d:32.3Mpa; 28d:50.3MPa, permeated height ratio: 32%, water demand ratio: 66%, to steel bar corrosion effect: non-corroding.Gelling material mixed material take aluminum oxide clinker as main raw material for building of the present invention has high-effective water-proof, protection against the tide, expansion, cracking resistance, the function such as impervious, to the effect of reinforcing bar non-corroding, is the large technological breakthrough of current architectural waterproof material one.
Embodiment
Embodiment 1
A preparation method for gelling material mixed material take aluminum oxide clinker as main raw material, is characterized in that:
Described preparation method's step is:
Step (1): according to 20 parts of aluminum oxide clinkers, 15 parts of calcined alunites, 7 parts, zinc sulfate, 5 parts of dickites, 5 parts of attapulgite clays, 5 parts, flyash, 1 part of zeolite powder, 2 parts, diatomite, 2 parts of wilkinites, 1 part of methylcellulose gum, 0.5 part of S-WAT, 0.5 part of unslaked lime, 0.2 part of tripoly phosphate sodium STPP, 0.2 part of borax, 0.2 part of proportioning of calcium chloride is prepared raw material
Step (2): 5 parts of 20 parts of aluminum oxide clinkers, 15 parts of calcined alunites, 7 parts, zinc sulfate, dickite are carried out to grinding in pulverizer, and rotating speed is 120r/min, grinding 6 hours, obtaining mixture A granularity size is 0.5-1mm,
Step (3): 2 parts of 5 parts of attapulgite clays, 5 parts, flyash, 1 part of zeolite powder, 2 parts, diatomite, wilkinite are carried out to grinding in pulverizer, and rotating speed is 100r/min, grinding 2 hours, obtaining mixture B granularity size is 0.2-0.3mm,
Step (4): step (2) is obtained to mixture A and step (3) is obtained to mixture B packing in mechanical mixer, mechanically mixing 1 hour, pour afterwards 1 part of methylcellulose gum, 0.5 part of S-WAT into, 0.5 part of unslaked lime, 0.2 part of tripoly phosphate sodium STPP, 0.2 part of borax, 0.2 part, calcium chloride, mechanically mixing 2 hours again, obtains the gelling material mixed material take aluminum oxide clinker as main raw material.
Embodiment 2
A preparation method for gelling material mixed material take aluminum oxide clinker as main raw material, is characterized in that:
Described preparation method's step is:
Step (1): according to 25 parts of aluminum oxide clinkers, 20 parts of calcined alunites, 10 parts, zinc sulfate, 8 parts of dickites, 10 parts of attapulgite clays, 10 parts, flyash, 5 parts of zeolite powders, 4 parts, diatomite, 5 parts of wilkinites, 2 parts of methylcellulose gum, 1 part of S-WAT, 1 part of unslaked lime, 0.5 part of tripoly phosphate sodium STPP, 0.7 part of borax, 0.8 part of proportioning of calcium chloride is prepared raw material
Step (2): 8 parts of 25 parts of aluminum oxide clinkers, 20 parts of calcined alunites, 10 parts, zinc sulfate, dickite are carried out to grinding in pulverizer, and rotating speed is 120r/min, grinding 6 hours, obtaining mixture A granularity size is 0.5-1mm,
Step (3): 5 parts of 10 parts of attapulgite clays, 10 parts, flyash, 5 parts of zeolite powders, 4 parts, diatomite, wilkinite are carried out to grinding in pulverizer, and rotating speed is 100r/min, grinding 2 hours, obtaining mixture B granularity size is 0.2-0.3mm,
Step (4): step (2) is obtained to mixture A and step (3) is obtained to mixture B packing in mechanical mixer, mechanically mixing 1 hour, pour afterwards 2 parts of methylcellulose gum, 1 part of S-WAT into, 1 part of unslaked lime, 0.5 part of tripoly phosphate sodium STPP, 0.7 part of borax, 0.8 part, calcium chloride, mechanically mixing 2 hours again, obtains the gelling material mixed material take aluminum oxide clinker as main raw material.
Embodiment 3
A preparation method for gelling material mixed material take aluminum oxide clinker as main raw material, is characterized in that:
Described preparation method's step is:
Step (1): according to 23 parts of aluminum oxide clinkers, 17 parts of calcined alunites, 8 parts, zinc sulfate, 7 parts of dickites, 7 parts of attapulgite clays, 7 parts, flyash, 3 parts of zeolite powders, 3 parts, diatomite, 3 parts of wilkinites, 1.5 parts of methylcellulose gum, 0.8 part of S-WAT, 0.8 part of unslaked lime, 0.4 part of tripoly phosphate sodium STPP, 0.5 part of borax, 0.5 part of proportioning of calcium chloride is prepared raw material
Step (2): 7 parts of 23 parts of aluminum oxide clinkers, 17 parts of calcined alunites, 8 parts, zinc sulfate, dickite are carried out to grinding in pulverizer, and rotating speed is 120r/min, grinding 6 hours, obtaining mixture A granularity size is 0.5-1mm,
Step (3): 3 parts of 7 parts of attapulgite clays, 7 parts, flyash, 3 parts of zeolite powders, 3 parts, diatomite, wilkinite are carried out to grinding in pulverizer, and rotating speed is 100r/min, grinding 2 hours, obtaining mixture B granularity size is 0.2-0.3mm,
Step (4): step (2) is obtained to mixture A and step (3) is obtained to mixture B packing in mechanical mixer, mechanically mixing 1 hour, pour afterwards 1.5 parts of methylcellulose gum, 0.8 part of S-WAT into, 0.8 part of unslaked lime, 0.4 part of tripoly phosphate sodium STPP, 0.5 part of borax, 0.5 part, calcium chloride, mechanically mixing 2 hours again, obtains the gelling material mixed material take aluminum oxide clinker as main raw material.
Embodiment 4
A preparation method for gelling material mixed material take aluminum oxide clinker as main raw material, is characterized in that:
Described preparation method's step is:
Step (1): according to 22 parts of aluminum oxide clinkers, 18 parts of calcined alunites, 9 parts, zinc sulfate, 6 parts of dickites, 6 parts of attapulgite clays, 6 parts, flyash, 4 parts of zeolite powders, 3 parts, diatomite, 4 parts of wilkinites, 1.5 parts of methylcellulose gum, 0.8 part of S-WAT, 0.8 part of unslaked lime, 0.3 part of tripoly phosphate sodium STPP, 0.5 part of borax, 0.6 part of proportioning of calcium chloride is prepared raw material
Step (2): 6 parts of 22 parts of aluminum oxide clinkers, 18 parts of calcined alunites, 9 parts, zinc sulfate, dickite are carried out to grinding in pulverizer, and rotating speed is 120r/min, grinding 6 hours, obtaining mixture A granularity size is 0.5-1mm,
Step (3): 4 parts of 6 parts of attapulgite clays, 6 parts, flyash, 4 parts of zeolite powders, 3 parts, diatomite, wilkinite are carried out to grinding in pulverizer, and rotating speed is 100r/min, grinding 2 hours, obtaining mixture B granularity size is 0.2-0.3mm,
Step (4): step (2) is obtained to mixture A and step (3) is obtained to mixture B packing in mechanical mixer, mechanically mixing 1 hour, pour afterwards 1.5 parts of methylcellulose gum, 0.8 part of S-WAT into, 0.8 part of unslaked lime, 0.3 part of tripoly phosphate sodium STPP, 0.5 part of borax, 0.6 part, calcium chloride, mechanically mixing 2 hours again, obtains the gelling material mixed material take aluminum oxide clinker as main raw material.
Embodiment 5
A preparation method for gelling material mixed material take aluminum oxide clinker as main raw material, is characterized in that:
Described preparation method's step is:
Step (1): according to 24 parts of aluminum oxide clinkers, 19 parts of calcined alunites, 9 parts, zinc sulfate, 7 parts of dickites, 9 parts of attapulgite clays, 9 parts, flyash, 4 parts of zeolite powders, 3 parts, diatomite, 3 parts of wilkinites, 1.5 parts of methylcellulose gum, 0.9 part of S-WAT, 0.9 part of unslaked lime, 0.4 part of tripoly phosphate sodium STPP, 0.6 part of borax, 0.7 part of proportioning of calcium chloride is prepared raw material
Step (2): 7 parts of 24 parts of aluminum oxide clinkers, 19 parts of calcined alunites, 9 parts, zinc sulfate, dickite are carried out to grinding in pulverizer, and rotating speed is 120r/min, grinding 6 hours, obtaining mixture A granularity size is 0.5-1mm,
Step (3): 3 parts of 9 parts of attapulgite clays, 9 parts, flyash, 4 parts of zeolite powders, 3 parts, diatomite, wilkinite are carried out to grinding in pulverizer, and rotating speed is 100r/min, grinding 2 hours, obtaining mixture B granularity size is 0.2-0.3mm,
Step (4): step (2) is obtained to mixture A and step (3) is obtained to mixture B packing in mechanical mixer, mechanically mixing 1 hour, pour afterwards 1.5 parts of methylcellulose gum, 0.9 part of S-WAT into, 0.9 part of unslaked lime, 0.4 part of tripoly phosphate sodium STPP, 0.6 part of borax, 0.7 part, calcium chloride, mechanically mixing 2 hours again, obtains the gelling material mixed material take aluminum oxide clinker as main raw material.
Claims (10)
1. the preparation method of the gelling material mixed material take aluminum oxide clinker as main raw material, it is characterized in that: the described gelling material mixed material raw material take aluminum oxide clinker as main raw material is (weight): aluminum oxide clinker 20-25 part, calcined alunite 15-20 part, zinc sulfate 7-10 part, dickite 5-8 part, attapulgite clay 5-10 part, flyash 5-10 part, zeolite powder 1-5 part, diatomite 2-4 part, wilkinite 2-5 part, methylcellulose gum 1-2 part, S-WAT 0.5-1 part, unslaked lime 0.5-1 part, tripoly phosphate sodium STPP 0.2-0.5 part, borax 0.2-0.7 part, calcium chloride 0.2-0.8 part,
Described preparation method's step is:
Step (1): according to aluminum oxide clinker 20-25 part, calcined alunite 15-20 part, zinc sulfate 7-10 part, dickite 5-8 part, attapulgite clay 5-10 part, flyash 5-10 part, zeolite powder 1-5 part, diatomite 2-4 part, wilkinite 2-5 part, methylcellulose gum 1-2 part, S-WAT 0.5-1 part, unslaked lime 0.5-1 part, tripoly phosphate sodium STPP 0.2-0.5 part, borax 0.2-0.7 part, calcium chloride 0.2-0.8 part proportioning is prepared raw material
Step (2): aluminum oxide clinker 20-25 part, calcined alunite 15-20 part, zinc sulfate 7-10 part, dickite 5-8 part are carried out to grinding in pulverizer, and rotating speed is 120r/min, grinding 6 hours, obtains mixture A granularity size for 0.5-1mm,
Step (3): attapulgite clay 5-10 part, flyash 5-10 part, zeolite powder 1-5 part, diatomite 2-4 part, wilkinite 2-5 part are carried out to grinding in pulverizer, rotating speed is 100r/min, grinding 2 hours, obtains mixture B granularity size for 0.2-0.3mm
Step (4): step (2) is obtained to mixture A and step (3) is obtained to mixture B packing in mechanical mixer, mechanically mixing 1 hour, pour afterwards methylcellulose gum 1-2 part, S-WAT 0.5-1 part into, unslaked lime 0.5-1 part, tripoly phosphate sodium STPP 0.2-0.5 part, borax 0.2-0.7 part, calcium chloride 0.2-0.8 part, mechanically mixing 2 hours again, obtains the gelling material mixed material take aluminum oxide clinker as main raw material.
2. the preparation method of the gelling material mixed material take aluminum oxide clinker as main raw material as claimed in claim 1, gelling material mixed material raw material take aluminum oxide clinker as main raw material is 20 parts of aluminum oxide clinkers, 15 parts of calcined alunites, 7 parts, zinc sulfate, 5 parts of dickites, 5 parts of attapulgite clays, 5 parts, flyash, 1 part of zeolite powder, 2 parts, diatomite, 2 parts of wilkinites, 1 part of methylcellulose gum, 0.5 part of S-WAT, 0.5 part of unslaked lime, 0.2 part of tripoly phosphate sodium STPP, 0.2 part of borax, 0.2 part, calcium chloride.
3. the preparation method of the gelling material mixed material take aluminum oxide clinker as main raw material as claimed in claim 1, gelling material mixed material raw material take aluminum oxide clinker as main raw material is 25 parts of aluminum oxide clinkers, 20 parts of calcined alunites, 10 parts, zinc sulfate, 8 parts of dickites, 10 parts of attapulgite clays, 10 parts, flyash, 5 parts of zeolite powders, 4 parts, diatomite, 5 parts of wilkinites, 2 parts of methylcellulose gum, 1 part of S-WAT, 1 part of unslaked lime, 0.5 part of tripoly phosphate sodium STPP, 0.7 part of borax, 0.8 part, calcium chloride.
4. the preparation method of the gelling material mixed material take aluminum oxide clinker as main raw material as claimed in claim 1, gelling material mixed material raw material take aluminum oxide clinker as main raw material is 23 parts of aluminum oxide clinkers, 17 parts of calcined alunites, 8 parts, zinc sulfate, 7 parts of dickites, 7 parts of attapulgite clays, 7 parts, flyash, 3 parts of zeolite powders, 3 parts, diatomite, 3 parts of wilkinites, 1.5 parts of methylcellulose gum, 0.8 part of S-WAT, 0.8 part of unslaked lime, 0.4 part of tripoly phosphate sodium STPP, 0.5 part of borax, 0.5 part, calcium chloride.
5. the preparation method of the gelling material mixed material take aluminum oxide clinker as main raw material as claimed in claim 1, gelling material mixed material raw material take aluminum oxide clinker as main raw material is 22 parts of aluminum oxide clinkers, 18 parts of calcined alunites, 9 parts, zinc sulfate, 6 parts of dickites, 6 parts of attapulgite clays, 6 parts, flyash, 4 parts of zeolite powders, 3 parts, diatomite, 4 parts of wilkinites, 1.5 parts of methylcellulose gum, 0.8 part of S-WAT, 0.8 part of unslaked lime, 0.3 part of tripoly phosphate sodium STPP, 0.5 part of borax, 0.6 part, calcium chloride.
6. the preparation method of the gelling material mixed material take aluminum oxide clinker as main raw material as claimed in claim 1, step (2) obtains mixture A granularity size for 0.7mm.
7. the preparation method of the gelling material mixed material take aluminum oxide clinker as main raw material as claimed in claim 1, step (3) obtains mixture B granularity size for 0.25mm.
8. the preparation method of the gelling material mixed material take aluminum oxide clinker as main raw material as claimed in claim 1, attapulgite clay composition is (weight): 56.7%SiO
2, 16.8%MgO, 3.4%FeO, 5.5%Fe
2o
3, 9.1%Al
2o
3, 2.7%CaO, 5.8% loss on ignition.
9. the preparation method of the gelling material mixed material take aluminum oxide clinker as main raw material as claimed in claim 1, dickite composition is (weight): 61.1%SiO
2, 31.3%Al
2o
3, 1.2%Fe
2o
3, 1.1%CaO, 0.5%MgO, 4.8% loss on ignition.
10. the preparation method of the gelling material mixed material take aluminum oxide clinker as main raw material as claimed in claim 10, flyash composition is (weight): 53.3%SiO
2, 29.7%Al
2o
3, 5.3%Fe
2o
3, 2.1%CaO, 4.8%MgO, 4.8% loss on ignition.
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| CN107601987A (en) * | 2017-10-09 | 2018-01-19 | 安徽新瑞重工股份有限公司 | A kind of precast floor slab special cracking resistant concrete |
| CN108793790A (en) * | 2018-09-03 | 2018-11-13 | 浙江新都水泥有限公司 | A method of cement being prepared in rotary kiln using quick lime |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106746874A (en) * | 2015-11-20 | 2017-05-31 | 甘肃曼特睿尔公路材料研发有限责任公司 | A kind of cement additire and preparation method thereof |
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| CN108793790A (en) * | 2018-09-03 | 2018-11-13 | 浙江新都水泥有限公司 | A method of cement being prepared in rotary kiln using quick lime |
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| Publication number | Publication date |
|---|---|
| CN104773966B (en) | 2017-02-22 |
| CN103880321B (en) | 2016-01-20 |
| CN104773966A (en) | 2015-07-15 |
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