CN103865174A - Ultra-thin wall insulating cable material for urban rail - Google Patents

Ultra-thin wall insulating cable material for urban rail Download PDF

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Publication number
CN103865174A
CN103865174A CN201410102479.XA CN201410102479A CN103865174A CN 103865174 A CN103865174 A CN 103865174A CN 201410102479 A CN201410102479 A CN 201410102479A CN 103865174 A CN103865174 A CN 103865174A
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China
Prior art keywords
parts
ultra
add
minute
raw material
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410102479.XA
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Chinese (zh)
Inventor
张万有
周俊
韩俊宝
刘清波
徐晓丽
朱元忠
夏侯东
王斌
唐文群
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Anhui Cable Co Ltd
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Anhui Cable Co Ltd
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Publication date
Application filed by Anhui Cable Co Ltd filed Critical Anhui Cable Co Ltd
Priority to CN201410102479.XA priority Critical patent/CN103865174A/en
Publication of CN103865174A publication Critical patent/CN103865174A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a ultra-thin wall insulating cable material for an urban rail. The cable material is prepared from the following raw materials in parts by weight: 31-40 parts of polydicyclopentadiene, 50-60 parts of polypropylene, 4-6 parts of polyphenyl ether, 0.4-1 part of N-cyclohexyl-N'-phenyl p-phenylenediamine, 12-15 parts of fast extruding furnace black, 1-2 parts of tetramethoxy methyl glycoluril, 3-5 parts of polyethylene glycol monooleate, 4-6 parts of tricresyl phosphate, 1-2 parts of captan, 7-9 parts of marble powder, 1-2 parts of anti-ageing agent BPS, 5-7 parts of silicon carbide, 1-2 parts of ammonium polyphosphate and 10-12 parts of composite filler. The cable material disclosed by the invention is good in mechanical performance, high in insulating resistivity, capable of well protecting a cable from being easily punctured, and realizing ultra-thin performance of an insulating wall, and especially applicable to high-speed railways and urban mass transits.

Description

A kind of ultra-thin-wall insulation city rail CABLE MATERIALS
Technical field
The present invention relates generally to field of cables, relates in particular to a kind of ultra-thin-wall insulation city rail CABLE MATERIALS.
Background technology
Along with the fast development of cable cause, high-quality CABLE MATERIALS is subject to increasing favor, not only good weatherability of high-quality CABLE MATERIALS, long service life, and safety and environmental protection, therefore pursue the competition that higher-quality CABLE MATERIALS not only can be won the market, also modernization construction has been played to great support and help.
Summary of the invention
The object of the invention is just to provide a kind of ultra-thin-wall insulation city rail CABLE MATERIALS.
The present invention is achieved by the following technical solutions:
A kind of ultra-thin-wall insulation city rail CABLE MATERIALS, it is made up of the raw material of following weight parts:
Polydicyclopentadiene 31-40, polypropylene 50-60, polyphenylene oxide 4-6, N cyclohexyl N' phenyl P phenylene diamine 0.4-1, extrude carbon black 12-15, tetramethoxymethylglycoluril 1-2, polyoxyethylene oleic acid ester 3-5, Tritolyl Phosphate 4-6, Vancide 89 1-2, marble flour 7-9, anti-aging agent BPS1-2, silicon carbide 5-7, ammonium polyphosphate 1-2, compounded mix 10-12 soon;
Described compounded mix is made up of the raw material of following weight parts:
Linear low density polyethylene 25-30, sepiolite powder 10-16, pentaerythritol triacrylate 2-3, light calcium carbonate 5-10, aluminium dihydrogen phosphate 2-3, tetrafluoroethylene 3-5, polydimethylsiloxane 1-2;
Above-mentioned linear low density polyethylene, sepiolite powder are mixed, and at 500-600 DEG C, stirring heating 4-10 minute, is cooled to normal temperature, add tetrafluoroethylene, ball grinding stirring mixing 6-8 minute, obtains Preblend, above-mentioned light calcium carbonate, aluminium dihydrogen phosphate are mixed, at 60-70 DEG C, be uniformly mixed 3-5 minute, add pentaerythritol triacrylate, be stirred to normal temperature, mix with above-mentioned Preblend, add the each raw material of residue, post-drying stirs, grind, obtain described compounded mix.
A preparation method for CABLE MATERIALS for ultra-thin-wall insulation city rail, comprises the following steps:
Above-mentioned fast extrusion carbon black, polydicyclopentadiene, polyoxyethylene oleic acid ester are mixed, at 70-100 DEG C, be uniformly mixed 4-6 minute, be reduced to 40-60 DEG C, add ammonium polyphosphate, tetramethoxymethylglycoluril, continue to be uniformly mixed 10-12 minute, be cooled to normal temperature, add the each raw material of residue, melt extrude, cooling, granulation, obtains described CABLE MATERIALS.
Advantage of the present invention is:
CABLE MATERIALS good mechanical property of the present invention, insulation resistivity is high, can be good at protecting cable to be not easy breakdown, realizes the ultra-thin property of insulating wall, is specially adapted to high-speed railway and urban track traffic.
Embodiment
Embodiment 1
A kind of ultra-thin-wall insulation city rail CABLE MATERIALS, it by following weight parts (kilogram) raw material form:
Polydicyclopentadiene 40, polypropylene 60, polyphenylene oxide 6, N cyclohexyl N' phenyl P phenylene diamine 0.4, extrude carbon black 15, tetramethoxymethylglycoluril 1, polyoxyethylene oleic acid ester 3, Tritolyl Phosphate 4, Vancide 89 2, marble flour 7-9, anti-aging agent BPS2, silicon carbide 5, ammonium polyphosphate 2, compounded mix 12 soon;
Described compounded mix is made up of the raw material of following weight parts:
Linear low density polyethylene 30, sepiolite powder 16, pentaerythritol triacrylate 3, light calcium carbonate 10, aluminium dihydrogen phosphate 2, tetrafluoroethylene 3, polydimethylsiloxane 1;
Above-mentioned linear low density polyethylene, sepiolite powder are mixed, and at 600 DEG C, stirring heating 10 minutes, is cooled to normal temperature, add tetrafluoroethylene, ball grinding stirring mixes 8 minutes, obtains Preblend, above-mentioned light calcium carbonate, aluminium dihydrogen phosphate are mixed, at 70 DEG C, be uniformly mixed 5 minutes, add pentaerythritol triacrylate, be stirred to normal temperature, mix with above-mentioned Preblend, add the each raw material of residue, post-drying stirs, grind, obtain described compounded mix.
A preparation method for CABLE MATERIALS for ultra-thin-wall insulation city rail, comprises the following steps:
Above-mentioned fast extrusion carbon black, polydicyclopentadiene, polyoxyethylene oleic acid ester are mixed, at 100 DEG C, be uniformly mixed 6 minutes, be reduced to 60 DEG C, add ammonium polyphosphate, tetramethoxymethylglycoluril, continue to be uniformly mixed 12 minutes, be cooled to normal temperature, add the each raw material of residue, melt extrude, cooling, granulation, obtains described CABLE MATERIALS.
Performance test:
Tensile strength: 16.8MPa;
Elongation at break: 443%;
Hardness Shao Shi (A): 89.

Claims (2)

1. a ultra-thin-wall insulation city rail CABLE MATERIALS, is characterized in that what it was made up of the raw material of following weight parts:
Polydicyclopentadiene 31-40, polypropylene 50-60, polyphenylene oxide 4-6, N cyclohexyl N' phenyl P phenylene diamine 0.4-1, extrude carbon black 12-15, tetramethoxymethylglycoluril 1-2, polyoxyethylene oleic acid ester 3-5, Tritolyl Phosphate 4-6, Vancide 89 1-2, marble flour 7-9, anti-aging agent BPS1-2, silicon carbide 5-7, ammonium polyphosphate 1-2, compounded mix 10-12 soon;
Described compounded mix is made up of the raw material of following weight parts:
Linear low density polyethylene 25-30, sepiolite powder 10-16, pentaerythritol triacrylate 2-3, light calcium carbonate 5-10, aluminium dihydrogen phosphate 2-3, tetrafluoroethylene 3-5, polydimethylsiloxane 1-2;
Above-mentioned linear low density polyethylene, sepiolite powder are mixed, and at 500-600 DEG C, stirring heating 4-10 minute, is cooled to normal temperature, add tetrafluoroethylene, ball grinding stirring mixing 6-8 minute, obtains Preblend, above-mentioned light calcium carbonate, aluminium dihydrogen phosphate are mixed, at 60-70 DEG C, be uniformly mixed 3-5 minute, add pentaerythritol triacrylate, be stirred to normal temperature, mix with above-mentioned Preblend, add the each raw material of residue, post-drying stirs, grind, obtain described compounded mix.
2. a preparation method for CABLE MATERIALS for ultra-thin-wall insulation city rail as claimed in claim 1, is characterized in that comprising the following steps:
Above-mentioned fast extrusion carbon black, polydicyclopentadiene, polyoxyethylene oleic acid ester are mixed, at 70-100 DEG C, be uniformly mixed 4-6 minute, be reduced to 40-60 DEG C, add ammonium polyphosphate, tetramethoxymethylglycoluril, continue to be uniformly mixed 10-12 minute, be cooled to normal temperature, add the each raw material of residue, melt extrude, cooling, granulation, obtains described CABLE MATERIALS.
CN201410102479.XA 2014-03-19 2014-03-19 Ultra-thin wall insulating cable material for urban rail Pending CN103865174A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410102479.XA CN103865174A (en) 2014-03-19 2014-03-19 Ultra-thin wall insulating cable material for urban rail

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410102479.XA CN103865174A (en) 2014-03-19 2014-03-19 Ultra-thin wall insulating cable material for urban rail

Publications (1)

Publication Number Publication Date
CN103865174A true CN103865174A (en) 2014-06-18

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105175882A (en) * 2015-07-14 2015-12-23 安徽春辉仪表线缆集团有限公司 Flame resistant polypropylene cable material for urban rail transport and preparation method thereof
CN108170201A (en) * 2018-01-26 2018-06-15 夏勇 A kind of Intelligent control handle
CN108239308A (en) * 2017-11-28 2018-07-03 安徽华源电缆集团有限公司 A kind of fire resistant winding cladding cable material

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0278547A (en) * 1988-09-16 1990-03-19 Tonen Sekiyukagaku Kk Polyolefin-based multi-layer films
US5171628A (en) * 1989-05-25 1992-12-15 Exxon Chemical Patents Inc. Low creep polypropylene textiles
JP2003105102A (en) * 2001-09-28 2003-04-09 Toray Ind Inc Biaxially oriented polypropylene film
CN102690485A (en) * 2011-11-30 2012-09-26 河南科技大学 Polydicyclopentadiene/polyacrylate composite material and preparation method thereof
CN102746573A (en) * 2012-06-07 2012-10-24 安徽胜华电缆集团有限公司 Methyl vinyl silicone rubber insulating heat-resistant control cable material and preparation method thereof
CN103467866A (en) * 2013-08-26 2013-12-25 晶锋集团股份有限公司 125 DEG C high-voltage-resistant insulated cable material and preparation method thereof
CN103709487A (en) * 2014-01-10 2014-04-09 安徽瑞升电气科技有限公司 Polypropylene cable material

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0278547A (en) * 1988-09-16 1990-03-19 Tonen Sekiyukagaku Kk Polyolefin-based multi-layer films
US5171628A (en) * 1989-05-25 1992-12-15 Exxon Chemical Patents Inc. Low creep polypropylene textiles
JP2003105102A (en) * 2001-09-28 2003-04-09 Toray Ind Inc Biaxially oriented polypropylene film
CN102690485A (en) * 2011-11-30 2012-09-26 河南科技大学 Polydicyclopentadiene/polyacrylate composite material and preparation method thereof
CN102746573A (en) * 2012-06-07 2012-10-24 安徽胜华电缆集团有限公司 Methyl vinyl silicone rubber insulating heat-resistant control cable material and preparation method thereof
CN103467866A (en) * 2013-08-26 2013-12-25 晶锋集团股份有限公司 125 DEG C high-voltage-resistant insulated cable material and preparation method thereof
CN103709487A (en) * 2014-01-10 2014-04-09 安徽瑞升电气科技有限公司 Polypropylene cable material

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
洪仲苓主编: "《化工有机原料深加工》", 30 June 1997 *
罗河胜: "《塑料材料手册(第三版)》", 31 March 2010, 广东科技出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105175882A (en) * 2015-07-14 2015-12-23 安徽春辉仪表线缆集团有限公司 Flame resistant polypropylene cable material for urban rail transport and preparation method thereof
CN108239308A (en) * 2017-11-28 2018-07-03 安徽华源电缆集团有限公司 A kind of fire resistant winding cladding cable material
CN108170201A (en) * 2018-01-26 2018-06-15 夏勇 A kind of Intelligent control handle

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Application publication date: 20140618

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