CN103840169B - The preparation method of positive pole aluminium foil collector performance is improved with fluoboric acid - Google Patents
The preparation method of positive pole aluminium foil collector performance is improved with fluoboric acid Download PDFInfo
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- CN103840169B CN103840169B CN201410125066.3A CN201410125066A CN103840169B CN 103840169 B CN103840169 B CN 103840169B CN 201410125066 A CN201410125066 A CN 201410125066A CN 103840169 B CN103840169 B CN 103840169B
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- aluminium foil
- positive pole
- pole aluminium
- foil collector
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- 239000005030 aluminium foil Substances 0.000 title claims abstract description 49
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 239000002253 acid Substances 0.000 title claims abstract description 8
- -1 Sodium fluoroborate Chemical compound 0.000 claims abstract description 29
- 238000006243 chemical reaction Methods 0.000 claims abstract description 24
- 239000012530 fluid Substances 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000001035 drying Methods 0.000 claims abstract description 4
- 229910001416 lithium ion Inorganic materials 0.000 claims description 24
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 20
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 9
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 8
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 6
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 6
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 5
- 229960001763 zinc sulfate Drugs 0.000 claims description 5
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 4
- 229910052744 lithium Inorganic materials 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical group [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 3
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 3
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 3
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 3
- 235000011151 potassium sulphates Nutrition 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- 235000011132 calcium sulphate Nutrition 0.000 claims description 2
- 230000008901 benefit Effects 0.000 abstract description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 8
- 229910052782 aluminium Inorganic materials 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000011888 foil Substances 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 229910052493 LiFePO4 Inorganic materials 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 102000004160 Phosphoric Monoester Hydrolases Human genes 0.000 description 2
- 108090000608 Phosphoric Monoester Hydrolases Proteins 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 229910021389 graphene Inorganic materials 0.000 description 2
- 239000005486 organic electrolyte Substances 0.000 description 2
- 230000010287 polarization Effects 0.000 description 2
- 239000005955 Ferric phosphate Substances 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 1
- 230000003321 amplification Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 229940032958 ferric phosphate Drugs 0.000 description 1
- BVBRZOLXXOIMQG-UHFFFAOYSA-N fluoroborane Chemical compound FB BVBRZOLXXOIMQG-UHFFFAOYSA-N 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 1
- 229910000399 iron(III) phosphate Inorganic materials 0.000 description 1
- WFKAJVHLWXSISD-UHFFFAOYSA-N isobutyramide Chemical compound CC(C)C(N)=O WFKAJVHLWXSISD-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/661—Metal or alloys, e.g. alloy coatings
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/665—Composites
- H01M4/667—Composites in the form of layers, e.g. coatings
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Cell Electrode Carriers And Collectors (AREA)
Abstract
The present invention relates to improve the preparation method of positive pole aluminium foil collector performance with fluoboric acid, it is characterized in that: aluminium foil Sodium fluoroborate treatment fluid is processed 1min～30 min at 35 DEG C～78 DEG C of temperature ranges, rinse well with water, last natural drying or the hot-air dry by 70 DEG C～160 DEG C temperature ranges, prepare the positive pole aluminium foil collector containing conversion film.When positive pole aluminium foil collector containing conversion film uses in battery or ultracapacitor, there is the advantages such as good and positive electrode the cohesive force of folding resistance is strong, impedance is little, charge-discharge performance is excellent.
Description
Technical field
The invention belongs to technical field prepared by battery electrode, be specifically related to a kind of positive pole aluminium foil collector that can be used for lithium battery, lithium ion battery, polymer battery and ultracapacitor, improve performance with fluoboric acid.
Technical background
Lithium ion battery have cell voltage height, energy density height, memory-less effect, have extended cycle life, the advantage such as self discharge is low, the performance of positive electrode plays a part decision to the performance of lithium ion battery.At present, lithium ion battery is mainly made up of parts such as organic electrolyte (polymer dielectric), barrier film, positive pole, negative pole, collectors.Owing to the conductive capability of the liquid state organic electrolyte (or polymer dielectric) of lithium ion battery use is more weak, in order to realize the high rate during charging-discharging of lithium ion battery, the positive electrode of lithium ion battery and negative material are the most all processed into powder, again the powder of positive electrode or the powder binding agent etc. of negative material are bondd on a current collector, it is achieved the collection of electric current.Therefore, for lithium ion battery, the performance of battery is had a great impact by contact impedance, collector surface appearance situation of change in charge and discharge process between the surface appearance of collector, collector and positive electrode and negative material.Such as, during charging, the positive pole aluminium foil collector of lithium ion battery is susceptible to passivation and increases polarization of electrode, makes the charge-discharge performance of battery be decreased obviously；The positive pole aluminium foil collector of lithium ion battery is bonding with between positive electrode insecure and the phenomenon of dry linting occurs, affects the charge-discharge performance of battery and the safety of battery.
When the powder of the positive electrode of lithium ion battery bonds with aluminum foil current collector, adhesive segment is formed by by parts such as viscous aluminium foil, adhesive and graphite agent.Each of which part all affects adhesive property.At present, the research to being processed by bonding aluminium foil surface is less, the main performance being improved aluminium foil by the most graphene coated in the aluminum foil current collector of lithium ion cell positive or carbon dust etc., to realize following effect.As, suppress battery polarization, reduce heat effect, improve high rate performance, reduce the internal resistance of cell, hence it is evident that reduce the dynamic internal resistance amplification of cyclic process；Improve battery with two side terminals, increase the cycle life of battery；Improve the adhesion of active substance and collector, reduce pole piece manufacturing cost；Protection collector is not by electrolytic corrosion；Improve high temperature and the cryogenic property of ferric phosphate lithium cell, improve the processing characteristics of LiFePO4, lithium titanate material.But, the methods such as above-mentioned graphene coated in aluminum foil current collector, carbon dust in advance are for improving the limited use of positive pole aluminium foil collector performance, and complicated process of preparation, cost are high, the method using simple surface to process for this present invention improves the surface property of lithium ion cell positive aluminum foil current collector, reduces the impedance between lithium ion cell positive aluminum foil current collector and positive electrode, reduces the dry linting phenomenon of positive pole.
Summary of the invention
For avoiding the deficiencies in the prior art, the method that the present invention uses simple surface to process improves the surface property of lithium ion cell positive aluminum foil current collector, reduce impedance between positive pole aluminium foil collector and positive electrode, minimizing positive pole dry linting phenomenon, improve battery with two side terminals, make the heavy-current discharge performance of sample significantly improve.Be the technical scheme is that by realizing the purpose of the present invention
Aluminium foil Sodium fluoroborate treatment fluid is processed 1min～30 min at 35 DEG C～78 DEG C of temperature ranges, then rinses well with water, last natural drying or the hot-air dry by 70 DEG C～160 DEG C temperature ranges, prepare the positive pole aluminium foil collector containing conversion film.
The composition of described Sodium fluoroborate treatment fluid is as follows: phosphoric acid 2 g/L～15g/L, sulfate 2 g/L～12g/L, Sodium fluoroborate 3 g/L～12g/L.
Described sulfate is sodium sulfate, potassium sulfate, calcium sulfate, zinc sulfate or magnesium sulfate.
In treatment fluid, phosphoric acid reacts with aluminum surface, and the porous aluminum phosphate of generation can react with Sodium fluoroborate and generate the porous skin covering of the surface containing fluoro boron acid ion, and the surface property of aluminum is played a part improvement.When positive pole aluminium foil collector containing conversion film is as the plus plate current-collecting body of lithium ion battery, there is the advantages such as good and positive electrode the cohesive force of folding resistance is strong, impedance is little, charge-discharge performance is excellent.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further detailed.Embodiment is only supplementing further and illustrating rather than to the restriction invented the present invention.
Embodiment 1
Aluminium foil Sodium fluoroborate treatment fluid is processed 15min at 68 DEG C, then rinses well with water, last natural drying, prepare the positive pole aluminium foil collector containing conversion film.
The composition of described Sodium fluoroborate treatment fluid is as follows: phosphoric acid 5 g/L, zinc sulfate 6 g/L, Sodium fluoroborate 6 g/L.
Returning back to original state after positive pole aluminium foil collector doubling 180 ° containing conversion film and be designated as 180 °, then roll over 180 °, be designated as 360 °, the rest may be inferred.Test shows, the positive pole aluminium foil collector containing conversion film of preparation rolls over 7306 ° continuously, will not fracture.3g polyvinylidene fluoride resin is dissolved in 29ml dimethyl acetylamide and prepares viscose glue.Being coated on the aluminium foil containing conversion film by this viscose glue, the peel strength after 180 DEG C of heating 10min reaches 0.0773 N/mm2Above.Coating LiFePO4 sample on the aluminium foil containing conversion film, under 2C multiplying power electric current during discharge and recharge, the discharge capacity circulated first is higher than 131mAh/g.And on the aluminium foil processed without Modified Membrane, coat LiFePO4 sample, under same current, the discharge capacity circulated first can only achieve 106mAh/g.
When the positive pole aluminium foil collector containing conversion film of preparation is as the plus plate current-collecting body of lithium ion battery, there is the advantages such as good and positive electrode the cohesive force of folding resistance is strong, impedance is little, charge-discharge performance is excellent.
Embodiment 2
Aluminium foil Sodium fluoroborate treatment fluid is processed 30 min at 78 DEG C, then rinses well with water, finally with the hot-air dry of 160 DEG C, prepare the positive pole aluminium foil collector containing conversion film.
The composition of described Sodium fluoroborate treatment fluid is as follows: phosphatase 11 5g/L, magnesium sulfate 12g/L, Sodium fluoroborate 12g/L.
The positive pole aluminium foil collector containing conversion film of preparation, as the plus plate current-collecting body of lithium ion battery, has the advantages such as folding resistance is good and positive electrode cohesive force is strong, impedance is little, charge-discharge performance is excellent.
Embodiment 3
Aluminium foil Sodium fluoroborate treatment fluid is processed 1min at 35 DEG C, then rinses well with water, finally with the hot-air dry of 70 DEG C, prepare the positive pole aluminium foil collector containing conversion film.
The composition of described Sodium fluoroborate treatment fluid is as follows: phosphoric acid 2 g/L, sodium sulfate 2 g/L, Sodium fluoroborate 3 g/L.
When the positive pole aluminium foil collector containing conversion film of preparation is as the plus plate current-collecting body of lithium ion battery, there is the advantages such as good and positive electrode the cohesive force of folding resistance is strong, impedance is little, charge-discharge performance is excellent.
Embodiment 4
Aluminium foil Sodium fluoroborate treatment fluid is processed 1min at 78 DEG C, then rinses well with water, finally with the hot-air dry of 100 DEG C, prepare the positive pole aluminium foil collector containing conversion film.
The composition of described Sodium fluoroborate treatment fluid is as follows: phosphoric acid 2 g/L, zinc sulfate 12g/L, Sodium fluoroborate 12g/L.
When the positive pole aluminium foil collector containing conversion film of preparation is as the plus plate current-collecting body of lithium ion battery, there is the advantages such as good and positive electrode the cohesive force of folding resistance is strong, impedance is little, charge-discharge performance is excellent.
Embodiment 5
Aluminium foil Sodium fluoroborate treatment fluid is processed 30 min at 35 DEG C, then rinses well with water, finally with the hot-air dry of 138 DEG C, prepare the positive pole aluminium foil collector containing conversion film.
The composition of described Sodium fluoroborate treatment fluid is as follows: phosphatase 11 5g/L, zinc sulfate 2 g/L, Sodium fluoroborate 3 g/L.
When the positive pole aluminium foil collector containing conversion film of preparation is as the plus plate current-collecting body of lithium ion battery, there is the advantages such as good and positive electrode the cohesive force of folding resistance is strong, impedance is little, charge-discharge performance is excellent.
Embodiment 6
Aluminium foil Sodium fluoroborate treatment fluid is processed 7min at 66 DEG C, then rinses well with water, finally with 80 DEG C of hot-air dries, prepare the positive pole aluminium foil collector containing conversion film.
The composition of described Sodium fluoroborate treatment fluid is as follows: phosphoric acid 5 g/L, potassium sulfate 7 g/L, Sodium fluoroborate 5 g/L.
When the positive pole aluminium foil collector containing conversion film of preparation is as the plus plate current-collecting body of lithium ion battery, there is the advantages such as good and positive electrode the cohesive force of folding resistance is strong, impedance is little, charge-discharge performance is excellent.
Embodiment 7
Aluminium foil Sodium fluoroborate treatment fluid is processed 2min at 35 DEG C, then rinses well with water, finally with the hot-air dry of 77 DEG C, prepare the positive pole aluminium foil collector containing conversion film.
The composition of described Sodium fluoroborate treatment fluid is as follows: phosphoric acid 2 g/L, calcium sulfate 10 g/L, Sodium fluoroborate 7 g/L.
When the positive pole aluminium foil collector containing conversion film of preparation is as the plus plate current-collecting body of lithium ion battery, there is the advantages such as good and positive electrode the cohesive force of folding resistance is strong, impedance is little, charge-discharge performance is excellent.
Claims (3)
1. the preparation method of positive pole aluminium foil collector performance is improved with fluoboric acid, it is characterised in that: aluminium foil Sodium fluoroborate treatment fluid is processed 1min～30 at 35 DEG C～78 DEG C of temperature ranges
Min, rinses well with water, last natural drying or the hot-air dry by 70 DEG C～160 DEG C temperature ranges, prepares the positive pole aluminium foil collector containing conversion film;
The composition of described Sodium fluoroborate treatment fluid is as follows: phosphoric acid 2 g/L～15g/L, sulfate 2
G/L～12g/L, Sodium fluoroborate 3 g/L～12g/L.
Fluoboric acid the most according to claim 1 improves the preparation method of positive pole aluminium foil collector performance, it is characterised in that described sulfate is sodium sulfate, potassium sulfate, calcium sulfate, zinc sulfate or magnesium sulfate.
Fluoboric acid the most according to claim 1 improves the preparation method of positive pole aluminium foil collector performance, it is characterised in that the described positive pole aluminium foil collector containing conversion film is for lithium battery, lithium ion battery, polymer battery or ultracapacitor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410125066.3A CN103840169B (en) | 2014-03-31 | 2014-03-31 | The preparation method of positive pole aluminium foil collector performance is improved with fluoboric acid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410125066.3A CN103840169B (en) | 2014-03-31 | 2014-03-31 | The preparation method of positive pole aluminium foil collector performance is improved with fluoboric acid |
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| Publication Number | Publication Date |
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| CN103840169A CN103840169A (en) | 2014-06-04 |
| CN103840169B true CN103840169B (en) | 2016-10-05 |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107634227B (en) * | 2017-08-21 | 2020-07-03 | 清华大学 | Aluminum current collector and method for manufacturing the same, and lithium secondary battery and method for manufacturing the same |
| CN109346724A (en) * | 2018-10-24 | 2019-02-15 | 遵义源创生产力促进中心有限公司 | A kind of fluoboric acid improvement positive pole aluminium foil collector performance methodology |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1434150A (en) * | 2002-01-25 | 2003-08-06 | 肖银华 | Method for preparing green environment protection type normal temp. liquid phosphide |
| CN101525746A (en) * | 2009-04-22 | 2009-09-09 | 湖南大学 | Preparation method of tungstate conversion film on surface of aluminum alloy |
| CN102242364A (en) * | 2011-06-23 | 2011-11-16 | 沈阳理工大学 | Preparation method of ceramic film through chemical conversion and micro-arc oxidation of aluminum and aluminum alloy |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1310262C (en) * | 2003-07-08 | 2007-04-11 | 深圳市东阳光化成箔股份有限公司 | Methof for manufacturing foil of cathode of electrolytic capacitor |
| CN101812682A (en) * | 2009-02-24 | 2010-08-25 | 中化化工科学技术研究总院 | Zinc phosphating solution of aluminium and aluminium alloy |
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|---|---|---|---|---|
| CN1434150A (en) * | 2002-01-25 | 2003-08-06 | 肖银华 | Method for preparing green environment protection type normal temp. liquid phosphide |
| CN101525746A (en) * | 2009-04-22 | 2009-09-09 | 湖南大学 | Preparation method of tungstate conversion film on surface of aluminum alloy |
| CN102242364A (en) * | 2011-06-23 | 2011-11-16 | 沈阳理工大学 | Preparation method of ceramic film through chemical conversion and micro-arc oxidation of aluminum and aluminum alloy |
Non-Patent Citations (1)
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| 锂离子电池正极铝集流体耐蚀性能研究;陈海;《中国优秀硕士学位论文全文数据库工程科技Ⅱ辑》;20111215(第S2期);标题；摘要第1、4段；第6页第1段 * |
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