CN103840021B - Thin-film solar cell of tandem type - Google Patents

Thin-film solar cell of tandem type Download PDF

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Publication number
CN103840021B
CN103840021B CN201210483379.7A CN201210483379A CN103840021B CN 103840021 B CN103840021 B CN 103840021B CN 201210483379 A CN201210483379 A CN 201210483379A CN 103840021 B CN103840021 B CN 103840021B
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thin
solar battery
tandem type
conducting layer
battery cell
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CN103840021A (en
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徐剑平
于大洋
丁建
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Zishi Energy Co.,Ltd.
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Beijing Chong Yu Technology Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
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Abstract

The present invention relates to a kind of Thinfilm solar cell assembly, specifically related to a kind of thin-film solar cell of tandem type, the thin-film solar cell of tandem type includes at least two solar battery cells and corresponding viscous conducting layer, also include a supporting substrate, the solar battery cell and corresponding viscous conducting layer interval dispersed arrangement are arranged on supporting substrate, the viscous conducting layer is arranged between supporting substrate and solar battery cell, and the viscous conducting layer has the width wider than the solar battery cell;The solar battery cell both sides are set in insulating barrier, two neighboring solar battery cell, and the positive electrode of the unit viscous conducting layer corresponding with another unit is connected by conductive connection layer, and the conductive connection layer is arranged at the outside of insulating barrier.The present invention simplifies production handling process, reduction production cost, the series connection of large-scale solar battery cell is easily realized, so as to realize large-scale batch production.

Description

Thin-film solar cell of tandem type
Technical field
The present invention relates to a kind of Thinfilm solar cell assembly, and in particular to a kind of thin-film solar cell of tandem type.
Background technology
At present, the development of solar battery technology mainly has two kinds of different routes, and one kind is by being adulterated to monocrystalline silicon The materials such as boron, phosphorus, antimony formation P-N junction, forms hole-electron pair, and then formed in one in electric field, this kind under direct sunlight Although solar cell prepared by technology possesses good transformation efficiency and long-term reliability, due to monocrystalline silicon battery raw material Expensive and battery series connection complex process, cost is higher when installing large area photovoltaic module.Another technology is by heavy Product multi-lager semiconductor thin-film material forms solar cell on substrate, and solar cell prepared by the technology is to materials demand Few, cost is relatively low, can meet large-scale production.
Develop with the continuous innovation of technology, have significant enhancement on the cell transformation efficiency of above two technology, But, photovoltaic energy application be but still limited by the relatively low conversion efficiency of photovoltaic cell, and set up Large Copacity energy resource system must One of key factor that must be considered is exactly its process costs.Solar cell can be described as high current low-voltage equipment, lead to Normal single battery voltage is less than 1 volt, and high efficient energy sources collection must minimize its impedance loss and make full use of its high current Characteristic;One of method for minimizing impedance loss is exactly to reduce the size of single battery and they are together in series, voltage It is stepped up with the series connection of battery, so that required voltage is reached, while electric current and impedance loss reach minimum.But, realize Efficient between solar cell, durable link cost is higher and technique is complex;In order to reduce cost, it is necessary to consider The use of substrate, many factors such as default of processing procedure.And due to thin-film solar cells can with extensive deposition, therefore, In terms of large-scale production and serial array, the monocrystalline silicon battery technology of thin film solar cell technologies relative discrete is with more excellent Gesture.
In view of the technology and cost advantage of thin-film solar cells, to realize large-scale production, a variety of thin film solars Battery serial connection technology is suggested.In the prior art, it is that semiconductive thin film sinks to have a kind of series connection method of thin-film solar cells After accumulating onto glass substrate, line segmentation forms the single battery of small area, and single battery is cascaded afterwards.Although should The series connection method of kind thin-film solar cells relative monocrystalline silicon battery in terms of large-scale production is easy, but a precondition is Glass substrate allows for being resistant to the processing of each processing procedure, and setting is improper to have a negative impact.United States Patent (USP) US4965655 and US4697041 individually disclose a kind of thin-film solar cell of tandem type, and it, which is prepared, needs laser scribing and swash Light is heated, and it also requires depositing metal conductive layer causes cost of a relatively high, while low on film under the conditions of low vacuum Vacuum metal layer resistance significantly limit the zone of action of independent battery.
It is well known that the efficiency of film solar battery structure can be greatly improved under hot conditions, so selection high temperature resistant Metal is used as substrate, it is allowed to which what is continuously rotated is treated as one of scheme of raising thin-film solar cells efficiency.But, although Metal substrate can bear high temperature process, but the series connection of battery is still extremely difficult, because metal substrate is conductive, phase The contact of the metal substrate of adjacent battery unit can cause short circuit.For this problem, many solutions are also suggested, and the U.S. is special Sharp US4746618 discloses a kind of series connection method of solar cell, using stainless steel as substrate, realizes the film of volume to volume Deposition and battery series connection;But the preparation process of this method includes multiple cuttings, deposition and manufacturing procedure, cost is very high;The U.S. is special Sharp US5385848 also discloses that a kind of series connection method of solar cell, by mechanically and chemically handling the portion removed on substrate Divide semi-conducting material and top electrode, expose a part of metal substrate, exposed metal substrate is just as the contact with adjacent cell Region, realizes the series connection of battery, and this kind of method allows high-temperature process, can also realize large-scale production, but be due to go Except the semi-conducting material on metal substrate causes cost to raise, the wasting of resources, process complications and performance accuracy is difficult to control to.
In view of problem above, need badly it is a kind of it is inexpensive, effective, allow high-temperature process and can realize a wide range of series connection and The thin-film solar cell of tandem type of large-scale production.
The content of the invention
Present invention aims at a kind of thin-film solar cell of tandem type is provided, by setting viscous conducting layer and conductive connection Tie layer, realize the series connection between solar battery cell, overcome in the prior art battery be connected into it is high, be difficult to realize a wide range of string Connection and the shortcoming of large-scale production.
The purpose of the present invention is achieved through the following technical solutions:Including at least two solar battery cells and corresponding Viscous conducting layer, the solar battery cell includes the positive electrode, semiconductor material layer and the negative electrode that stack gradually, the string Connection type thin-film solar cells also includes a supporting substrate, the solar battery cell and corresponding viscous conductive interlayer It is arranged on every dispersed arrangement on supporting substrate, the viscous conducting layer is arranged between supporting substrate and solar battery cell, Supporting substrate is bonded together with solar battery cell by viscous conducting layer, and the viscous conducting layer has than the sun Can the wide width of battery unit;The solar battery cell both sides are set in insulating barrier, two neighboring solar battery cell, The positive electrode of the one unit viscous conducting layer corresponding with another unit is connected by conductive connection layer, the conductive connection Knot layer is arranged at the outside of insulating barrier.
The spacing of the two neighboring solar battery cell is 5-10 millimeters.
One side portion of the viscous conducting layer is alignd with a side portion of the solar battery cell, described viscous Property conductive layer is wider than the solar battery cell 2-5 millimeters.
Respectively than two sides of the solar battery cell on two side portion widths of the viscous conducting layer Edge is big 2-5 millimeters.
The thickness of the viscous conducting layer is 40-60 microns.
The thickness of the conductive connection layer is 40-60 microns.
The thickness of the insulating barrier is 50-100 microns.
The material of the supporting substrate is polymeric material, and the polymeric material is polyethylene terephthalate(PET)、 Polyethylene (PE), polyvinyl chloride(PVC), polyimides(PI)Or polymethacrylates(PMMA)In one kind.
The viscous conducting layer is one kind in copper-foil conducting electricity adhesive tape, conductive aluminium foil rubber tape or conductive silver paste.
The material of the insulating barrier is epoxy resin.
The conductive tie layers are one kind in copper-foil conducting electricity adhesive tape, conductive aluminium foil rubber tape or conductive silver paste.
The positive electrode includes the metal oxide of flexible substrate and deposition on flexible substrates, and the negative electrode is transparent Conductive oxide, the semiconductor material layer is plural layers;The material of the flexible substrate is in stainless steel, copper, titanium or aluminium One kind;The metal oxide is one kind in zinc oxide, Al-Doped ZnO or boron-doping zinc oxide;The transparent conductive oxide Thing is one kind in indium oxide, tin oxide, zinc oxide, chromium oxide, tin indium oxide or zinc oxide aluminum;The semi-conducting material is copper One or more in indium gallium selenium, cadmium telluride, cadmium sulfide, non-crystalline silicon or microcrystal silicon.
Compared with prior art, a kind of thin-film solar cell of tandem type of the invention has the following advantages that:
1)The present invention uses polymeric material as supporting substrate, easily realizes the string of large-scale solar battery cell Connection.
2)The present invention simplifies handling process by setting viscous conducting layer, reduces production cost, and easily realizes large-scale Batch production.
Brief description of the drawings
Fig. 1 is the front view schematic diagram of the thin-film solar cell of tandem type of the present invention.
Embodiment
Below by embodiment, and with reference to accompanying drawing, technical scheme is described in further detail, but do not limited In the content of the present embodiment.
Embodiment 1
Referring to Fig. 1, a kind of thin-film solar cell of tandem type, including two solar battery cells 10 and corresponding Viscous conducting layer 20, the solar battery cell includes positive electrode 11, semiconductor material layer 12 and negative electrode 13;The tandem type Thin-film solar cells also includes a supporting substrate 30, the solar battery cell 10 and corresponding viscous conducting layer 20 By being arranged on each other away from 5 millimeters of dispersed arrangements on supporting substrate 30, the viscous conducting layer 20 be arranged on supporting substrate 30 with Between solar battery cell 10, supporting substrate 30 is bonded together with solar battery cell 10 by viscous conducting layer 20, The viscous conducting layer 20 has the width wider than solar battery cell 10;The both sides of solar battery cell 10 set exhausted In edge layer 40, two neighboring solar battery cell 10, the positive electrode 11 of the unit viscosity corresponding with another unit Conductive layer 20 is connected by conductive connection layer 50, and the conductive connection layer 50 is arranged at the outside of insulating barrier 40.
In the present embodiment, a side portion of the viscous conducting layer 20 and a side of the solar battery cell 10 Edge is alignd, and the viscous conducting layer 20 is wider than the solar battery cell 3 millimeters;The thickness of the viscous conducting layer 20 is 40 microns;The positive electrode 11, semiconductor material layer 12 and negative electrode of solar battery cell 10 is completely covered in the insulating barrier 40 13 two side portions and a side portion of viscous conducting layer 20, the thickness of the insulating barrier 40 is 50 microns;The conductive connection The thickness for tying layer 50 is 40 microns.
In the present embodiment, the material of the supporting substrate 30 is polymeric material polyethylene terephthalate(PET);It is described Viscous conducting layer 20 is copper-foil conducting electricity adhesive tape;The material of the insulating barrier 40 is epoxy resin;Described conductive connection layer 50 is Copper-foil conducting electricity adhesive tape.
In the present embodiment, the solar battery cell 10 can be prepared using prior art, and the positive electrode 11 is wrapped The metal oxide of flexible substrate and deposition on flexible substrates is included, the negative electrode 13 is transparent conductive oxide;This implementation In example, the material of the flexible substrate is stainless steel, and the metal oxide is Al-Doped ZnO, the transparent conductive oxide It is tin indium oxide, the semiconductor material layer is CIGS and the plural layers with cadmium sulfide.
Embodiment 2
The present embodiment technology contents in the same manner as in Example 1 or similar are no longer described one by one in the present embodiment.
In the present embodiment, the solar battery cell 10 and corresponding viscous conducting layer 20 are by each other away from 10 millis Rice dispersed arrangement is arranged on supporting substrate 30, a side portion and the solar battery cell of the viscous conducting layer 20 10 side portion alignment, the viscous conducting layer 20 is wider than the solar battery cell 5 millimeters;The viscous conducting layer 20 thickness is 60 microns;The positive electrode 11 of solar battery cell 10, semiconductor material layer is completely covered in the insulating barrier 40 12 and two side portions and a side portion of viscous conducting layer 20 of negative electrode 13, the thickness of the insulating barrier 40 is 100 microns; The thickness of the conductive connection layer 50 is 50 microns.
In the present embodiment, the material of the supporting substrate 30 is polyimides(PI);The viscous conducting layer 20 is conductive Aluminum foil and adhesive tape;The material of the insulating barrier 40 is epoxy resin;Described conductive connection layer 50 is conductive aluminium foil rubber tape.
Embodiment 3
The present embodiment technology contents in the same manner as in Example 1 or similar are no longer described one by one in the present embodiment.
In the present embodiment, the solar battery cell 10 and corresponding viscous conducting layer 20 are by each other away from 7 millis Rice dispersed arrangement is arranged on supporting substrate 30, a side portion and the solar battery cell of the viscous conducting layer 20 10 side portion alignment, the viscous conducting layer 20 is wider than the solar battery cell 2 millimeters;The viscous conducting layer 20 thickness is 50 microns;The positive electrode 11 of solar battery cell 10, semiconductor material layer is completely covered in the insulating barrier 40 12 and two side portions and a side portion of viscous conducting layer 20 of negative electrode 13, the thickness of the insulating barrier 40 is 75 microns; The thickness of the conductive connection layer 50 is 45 microns.
In the present embodiment, the material of the supporting substrate 30 is polymethacrylates(PMMA);The viscous conducting layer 20 be conductive silver paste;The material of the insulating barrier 40 is epoxy resin;Described conductive connection layer 50 is copper-foil conducting electricity adhesive tape.
Embodiment 4
The present embodiment technology contents in the same manner as in Example 1 or similar are no longer described one by one in the present embodiment.
In the present embodiment, the solar battery cell 10 and corresponding viscous conducting layer 20 are by each other away from 10 millis Rice dispersed arrangement is arranged on supporting substrate 30, respectively than described on two side portion widths of the viscous conducting layer 20 Two side portions of solar battery cell 10 are big 3 millimeters;The corresponding viscous conducting layer 20 of two adjacent units can not connect Touch.
In the present embodiment, the material of the supporting substrate 30 is polyethylene terephthalate(PET);The viscous conducting layer 20 be copper-foil conducting electricity adhesive tape;The material of the insulating barrier 40 is epoxy resin;Described conductive connection layer 50 is conductive aluminum foil glue Band.

Claims (12)

1. a kind of thin-film solar cell of tandem type, including at least two solar battery cells and corresponding viscous conductive Layer, the solar battery cell includes positive electrode, semiconductor material layer and the negative electrode stacked gradually, it is characterised in that institute Stating thin-film solar cell of tandem type also includes a supporting substrate, and the material of the supporting substrate is polymeric material, it is described too Positive energy battery unit and corresponding viscous conducting layer interval dispersed arrangement are arranged on supporting substrate, the viscous conducting layer It is arranged between supporting substrate and solar battery cell, supporting substrate is bonded with solar battery cell by viscous conducting layer Together, the viscous conducting layer has the width wider than the solar battery cell;The solar battery cell both sides Set in insulating barrier, two neighboring solar battery cell, the positive electrode of the unit viscosity corresponding with another unit Conductive layer is connected by conductive connection layer, and the conductive connection layer is arranged at the outside of insulating barrier;The positive electrode includes soft Property substrate and deposition metal oxide on flexible substrates.
2. thin-film solar cell of tandem type according to claim 1, it is characterised in that the two neighboring solar-electricity The spacing of pool unit is 5-10 millimeters.
3. thin-film solar cell of tandem type according to claim 2, it is characterised in that one of the viscous conducting layer Side portion is alignd with a side portion of the solar battery cell, and the viscous conducting layer is than the solar battery cell It is wide 2-5 millimeters.
4. thin-film solar cell of tandem type according to claim 2, it is characterised in that two of the viscous conducting layer Two side portions on side portion width respectively than the solar battery cell are big 2-5 millimeters.
5. thin-film solar cell of tandem type according to claim 1, it is characterised in that the thickness of the viscous conducting layer It is 40-60 microns.
6. thin-film solar cell of tandem type according to claim 1, it is characterised in that the thickness of the conductive connection layer It is 40-60 microns.
7. thin-film solar cell of tandem type according to claim 1, it is characterised in that the thickness of the insulating barrier is 50-100 microns.
8. the thin-film solar cell of tandem type according to claim 1-7 any one, it is characterised in that the polymer Material is polyethylene terephthalate (PET), polyethylene (PE), polyvinyl chloride (PVC), polyimides (PI) or polymethyl One kind in acid esters (PMMA).
9. thin-film solar cell of tandem type according to claim 8, it is characterised in that the viscous conducting layer is conductive One kind in copper foil tape, conductive aluminium foil rubber tape or conductive silver paste.
10. thin-film solar cell of tandem type according to claim 8, it is characterised in that the material of the insulating barrier is Epoxy resin.
11. thin-film solar cell of tandem type according to claim 8, it is characterised in that the conductive connection layer is to lead One kind in electrolytic copper foil belt, conductive aluminium foil rubber tape or conductive silver paste.
12. thin-film solar cell of tandem type according to claim 8, it is characterised in that the negative electrode is transparent leads Electroxidation thing, the semiconductor material layer is plural layers;The material of the flexible substrate is in stainless steel, copper, titanium or aluminium It is a kind of;The metal oxide is one kind in zinc oxide, Al-Doped ZnO or boron-doping zinc oxide;The transparent conductive oxide It is one kind in indium oxide, tin oxide, zinc oxide, chromium oxide, tin indium oxide or zinc oxide aluminum;The semi-conducting material is copper and indium One or more in gallium selenium, cadmium telluride, cadmium sulfide, non-crystalline silicon or microcrystal silicon.
CN201210483379.7A 2012-11-23 2012-11-23 Thin-film solar cell of tandem type Active CN103840021B (en)

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KR101594841B1 (en) * 2014-10-07 2016-02-18 한국에너지기술연구원 Solar cell module and method for manufactoring the same
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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102790099A (en) * 2011-05-20 2012-11-21 绿阳光电股份有限公司 Solar cell module and method for manufacturing same
CN202948927U (en) * 2012-11-23 2013-05-22 汉能科技有限公司 Series connection type thin-film solar cell

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102790099A (en) * 2011-05-20 2012-11-21 绿阳光电股份有限公司 Solar cell module and method for manufacturing same
CN202948927U (en) * 2012-11-23 2013-05-22 汉能科技有限公司 Series connection type thin-film solar cell

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