CN103834316B - Adhesive structure, surface conditioning agent and tear off method - Google Patents

Adhesive structure, surface conditioning agent and tear off method Download PDF

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Publication number
CN103834316B
CN103834316B CN201210486352.3A CN201210486352A CN103834316B CN 103834316 B CN103834316 B CN 103834316B CN 201210486352 A CN201210486352 A CN 201210486352A CN 103834316 B CN103834316 B CN 103834316B
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magnetic
particle
invalidation
adhesive
nucleome
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CN103834316A (en
Inventor
葛智逵
林知本
张明仁
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Jiashan Weitang Asset Management Co ltd
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Hongfujin Precision Industry Shenzhen Co Ltd
Hon Hai Precision Industry Co Ltd
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Priority to CN201210486352.3A priority Critical patent/CN103834316B/en
Publication of CN103834316A publication Critical patent/CN103834316A/en
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  • Magnetic Treatment Devices (AREA)

Abstract

Adhesive structure, surface conditioning agent and tear off method.A kind of adhesive structure includes bonding piece and is set in turn in the surface-treated layer and adhesive layer on the bonding piece surface.The surface-treated layer includes magnetic invalidation particle, and the magnetic invalidation particle is coreshell type structure, and the magnetic invalidation particle includes the failure nucleome that can reduce the cohesive force of the adhesive layer for having magnetic magnetic housing and being coated in the magnetic crust body.Because surface-treated layer includes magnetic invalidation particle, when applying externally-applied magnetic field to adhesive structure, the magnetic casing rupture of the magnetic invalidation particle in surface-treated layer, failure nucleome therein is discharged, make the adhesion strength of adhesive layer reduce, so that adhesive layer is easier to tear off from the surface of bonding piece.

Description

Adhesive structure, surface conditioning agent and tear off method
Technical field
The present invention relates to a kind of adhesive structure, more particularly to a kind of adhesive structure including surface-treated layer;The present invention is also Be related to a kind of surface conditioning agent and a kind of adhesive structure tears off method.
Background technology
Typically two workpiece are bonded together using adhesive layer at present in consumer electronic product.On the one hand, adhesive layer There need to be preferable caking property to bond part with firm;On the other hand, during heavy industry, adhesive layer need to have again preferably easily to be torn off Property;I.e. adhesive layer had not only needed with preferable caking property but also need to be with preferably easy tearing off property.However, current adhesive layer is difficult two Person takes into account.
The content of the invention
In view of the foregoing, it is necessary to the adhesive structure that a kind of adhesive layer is easier to tear off is provided, it is a kind of to there is a need to offer It can make what adhesive layer was easier to the surface conditioning agent that tears off and the adhesive structure to tear off method.
A kind of adhesive structure includes bonding piece and is set in turn in the surface-treated layer and adhesive layer on the bonding piece surface.Should Surface-treated layer includes magnetic invalidation particle, and the magnetic invalidation particle is coreshell type structure, and the magnetic invalidation particle includes having The magnetic housing of magnetic and the failure nucleome being coated in the magnetic crust body.Failure nucleome can drop the cohesive force of the adhesive layer It is low.
A kind of surface conditioning agent, its magnetic invalidation particle for including resin and being scattered in the resin, the magnetic invalidation grain Son is coreshell type structure, and the magnetic invalidation particle includes the failure for having magnetic magnetic housing and being coated in the magnetic crust body Nucleome, the failure nucleome can reduce the cohesive force of adhesive.
A kind of adhesive structure tears off method, and the adhesive structure includes bonding piece and is set in turn in the bonding piece surface Surface-treated layer and adhesive layer, the surface-treated layer include magnetic invalidation particle, and the magnetic invalidation particle is coreshell type structure, should Magnetic invalidation particle includes the cohesive force that can make the adhesive layer for having magnetic magnetic housing and being coated in the magnetic crust body The failure nucleome of reduction, this, which tears off method, includes:Externally-applied magnetic field is applied to the adhesive structure, so that the magnetic in the surface-treated layer Property failure particle magnetic casing rupture, so as to discharge failure nucleome therein;The adhesive layer is torn from the surface of the bonding piece From.
In above-mentioned adhesive structure, because surface-treated layer includes magnetic invalidation particle, when to the additional magnetic of adhesive structure application During field, the magnetic casing rupture of the magnetic invalidation particle in surface-treated layer, failure nucleome therein is discharged, make the viscous of adhesive layer Put forth effort to reduce, so that adhesive layer is easier to tear off from the surface of bonding piece.
Brief description of the drawings
Fig. 1 is the schematic diagram of the adhesive structure of embodiment of the present invention.
Main element symbol description
Adhesive structure 100
First bonding piece 10
Second bonding piece 30
Surface-treated layer 50
Adhesive layer 70
Following embodiment will combine above-mentioned accompanying drawing and further illustrate the present invention.
Embodiment
Referring to Fig. 1, the adhesive structure 100 of embodiment of the present invention includes the first bonding piece 10, the second bonding piece 30, applied The surface-treated layer 50 on the surface of the first bonding piece 10 is overlying on, and the glue being arranged between the bonding piece 30 of surface-treated layer 50 and second Adhesion coating 70.In embodiments of the present invention, the first bonding piece 10, the second bonding piece 30 are metal shell.It is appreciated that the First, the structure of the second bonding piece 10,30 can change with material according to actual use demand, and such as the first bonding piece 10 can be glass base Plate, the second bonding piece 30 can be plastic casing.Adhesive layer 70 to the adhesive coating of surface-treated layer 50 from forming, for by first The bonding piece 30 of bonding piece 10 and second is bonded in together.
Surface-treated layer 50 to the surface coating surface inorganic agent of the first bonding piece 10 from forming, to improve the first bonding piece 10 With the cohesive force between adhesive layer 70.The surface conditioning agent includes:By mass, 5-10% resin, 0.1-1.0% magnetic are lost Imitate particle and the solvent of surplus.Resin is dissolved in solvent, and resin can be acrylic resin, such as polymethyl methacrylate. It is appreciated that resin is not limited to acrylic resin, as long as it can improve the cohesive force of adhesive layer 70 and the first bonding piece 10 i.e. Can.Magnetic invalidation particle is scattered in solvent, and magnetic invalidation particle is coreshell type structure, i.e., with magnetic housing and is coated on this Failure nucleome in magnetic crust body, failure nucleome can reduce the cohesive force of adhesive layer 70.The composition of magnetic housing includes four oxygen Change three-iron(Fe3O4), di-iron trioxide(Fe2O3), Manganese Iron(MnFe2O4), oxidation ferro-cobalt(CoFe2O4)And oxidation ferronickel (NiFe2O4)In one or more.It is appreciated that magnetic housing is not limited to mentioned component, as long as there is magnetic.Failure The composition of nucleome can be silicone oil or cured quasi-molecule.It is appreciated that the composition of failure nucleome is not limited to mentioned component, as long as it can make The cohesive force of adhesive layer 70 reduces.Solvent can be conventional organic solvent, such as ethyl acetate, acetone, butanone.It can manage Solution, the composition of solvent have no it is specifically limited, as long as above-mentioned resin can be dissolved.Even, above-mentioned solvent can be also omitted, in this kind During situation, directly magnetic invalidation particle is scattered in resin, the quality of resin and magnetic invalidation particle is 5- than scope 100。
The method that tears off of the adhesive structure 100 of embodiment of the present invention comprises the following steps:Adhesive structure 100 is applied outer Add magnetic field, so that the magnetic casing rupture of the magnetic invalidation particle in surface-treated layer 50, so as to discharge failure nucleome therein; Adhesive layer 70 is torn off from the surface of first, second bonding piece 10,30.
It is appreciated that adhesive structure 100 also may not include the second bonding piece 30, i.e., only including the first bonding piece 10 and successively It is arranged at the surface-treated layer 50 and adhesive layer 70 on the surface of the first bonding piece 10.
In embodiment of the present invention, because surface-treated layer 50 includes magnetic invalidation particle, apply when to adhesive structure 100 During externally-applied magnetic field, the magnetic casing rupture of the magnetic invalidation particle in surface-treated layer 50, failure nucleome therein is discharged, so as to Make the adhesion strength of the adhesive in adhesive layer 70 reduce, so that adhesive layer 70 is easier to the table from first, second bonding piece 10,30 Face is torn off.When tearing off adhesive layer 70, due to without heating or illumination, so as to not interfere with the property of first, second bonding piece 10,30 Matter.
It is appreciated that those skilled in the art can also do other changes in spirit of the invention, without departing from this hair Bright technique effect.These changes done according to present invention spirit, it should all be included in present invention model claimed Within enclosing.

Claims (10)

1. a kind of adhesive structure, its adhesive layer for including bonding piece and being arranged in the bonding piece, it is characterised in that:The bonding knot Structure also includes the surface-treated layer for being formed at the bonding piece surface, and the surface-treated layer is located at the bonding piece surface and the adhesive layer Between, the surface-treated layer includes magnetic invalidation particle, and the magnetic invalidation particle is coreshell type structure, the magnetic invalidation particle bag The failure nucleome for having magnetic magnetic housing and being coated in the magnetic crust body is included, the failure nucleome can make the viscous of the adhesive layer Tying power reduces.
2. adhesive structure as claimed in claim 1, it is characterised in that:The composition of the magnetic housing includes ferroso-ferric oxide, three Aoxidize the one or more in two iron, Manganese Iron, oxidation ferro-cobalt and oxidation ferronickel.
3. adhesive structure as claimed in claim 1, it is characterised in that:The composition of failure nucleome is silicone oil or wax class molecule.
4. adhesive structure as claimed in claim 1, it is characterised in that:The surface-treated layer also includes resin, the magnetic invalidation Particle is scattered in the resin.
5. adhesive structure as claimed in claim 4, it is characterised in that:The quality of the resin and the magnetic invalidation particle compares scope For 5 to 100.
6. a kind of surface conditioning agent, it includes resin, it is characterised in that:The surface conditioning agent also includes being scattered in the resin Magnetic invalidation particle, the magnetic invalidation particle are coreshell type structure, and the magnetic invalidation particle includes having magnetic magnetic housing And the failure nucleome in the magnetic crust body is coated on, the failure nucleome can reduce the cohesive force of adhesive.
7. surface conditioning agent as claimed in claim 6, it is characterised in that:The quality of the resin and the magnetic invalidation particle compares model Enclose for 5 to 100.
8. surface conditioning agent as claimed in claim 6, it is characterised in that:The composition of the magnetic housing include ferroso-ferric oxide, One or more in di-iron trioxide, Manganese Iron, oxidation ferro-cobalt and oxidation ferronickel.
9. surface conditioning agent as claimed in claim 6, it is characterised in that:The composition of failure nucleome is silicone oil or wax class molecule.
10. a kind of adhesive structure tears off method, the adhesive structure includes bonding piece and is set in turn in the bonding piece surface Surface-treated layer and adhesive layer, the surface-treated layer include magnetic invalidation particle, and the magnetic invalidation particle is coreshell type structure, should Magnetic invalidation particle includes the failure nucleome for having magnetic magnetic housing and being coated in the magnetic crust body, the failure nucleome energy Make the cohesive force of the adhesive layer reduce, this, which tears off method, includes:Externally-applied magnetic field is applied to the adhesive structure, so that the surface treatment The magnetic casing rupture of the magnetic invalidation particle of layer, so as to discharge failure nucleome therein;And by the adhesive layer from the bonding piece Surface tear off.
CN201210486352.3A 2012-11-26 2012-11-26 Adhesive structure, surface conditioning agent and tear off method Active CN103834316B (en)

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Application Number Priority Date Filing Date Title
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CN103834316B true CN103834316B (en) 2017-11-21

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Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3450143A4 (en) * 2016-04-26 2019-12-25 Nitto Denko Corporation Shaping-stage adhesive sheet and lamination shaping device

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2157891A1 (en) * 1993-03-09 1994-09-15 Joseph P. Callahan, Jr. A method for magnetically and/or electrostatically positioning pressure-sensitive adhesive beads and magnetically positionable pressure-sensitive adhesive beads
CN1445797A (en) * 2003-04-01 2003-10-01 吉林大学 Magnetic hud fine particles possessing strong magnetic field response capability and its preparing method
CN1718619A (en) * 2005-08-08 2006-01-11 北京师范大学 Magnetic composite microglobule possessing inorganic/organic core shell structure and its preparation method
CN1753963A (en) * 2001-11-13 2006-03-29 德古萨股份公司 Curable bonded assemblies capable of being dissociated
CN101817960A (en) * 2010-03-17 2010-09-01 中国石油大学(华东) Method for preparing magnetic composite nanoparticles with core-shell structure
DE102009028942A1 (en) * 2009-08-27 2011-03-03 Evonik Degussa Gmbh Inductively curable adhesive composition

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090246437A1 (en) * 2008-04-01 2009-10-01 Do Kyun Lim Laminate Sheet and Manufacturing Method Thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2157891A1 (en) * 1993-03-09 1994-09-15 Joseph P. Callahan, Jr. A method for magnetically and/or electrostatically positioning pressure-sensitive adhesive beads and magnetically positionable pressure-sensitive adhesive beads
CN1753963A (en) * 2001-11-13 2006-03-29 德古萨股份公司 Curable bonded assemblies capable of being dissociated
CN1445797A (en) * 2003-04-01 2003-10-01 吉林大学 Magnetic hud fine particles possessing strong magnetic field response capability and its preparing method
CN1718619A (en) * 2005-08-08 2006-01-11 北京师范大学 Magnetic composite microglobule possessing inorganic/organic core shell structure and its preparation method
DE102009028942A1 (en) * 2009-08-27 2011-03-03 Evonik Degussa Gmbh Inductively curable adhesive composition
CN101817960A (en) * 2010-03-17 2010-09-01 中国石油大学(华东) Method for preparing magnetic composite nanoparticles with core-shell structure

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Effective date of registration: 20191106

Address after: Room 2, west of the second floor, No. 355, Huanbei West Road, Weitang street, Jiashan County, Jiaxing City, Zhejiang Province

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Address before: 518109, No. two, No. tenth, East Ring Road, Pinus tabulaeformis Industrial Zone, Longhua Town, Baoan District, Guangdong, Shenzhen, 2

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Patentee before: HONG FU JIN PRECISION INDUSTRY (SHENZHEN) Co.,Ltd.

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Denomination of invention: Bonding structure, surface treatment agent and tearing off method

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Denomination of invention: Adhesive structure, surface treatment agent, and tear off method

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