CN103834275B - A kind of ultraviolet-curing paint adding nano bamboo carbon powder and preparation method thereof - Google Patents
A kind of ultraviolet-curing paint adding nano bamboo carbon powder and preparation method thereof Download PDFInfo
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- CN103834275B CN103834275B CN201410075415.5A CN201410075415A CN103834275B CN 103834275 B CN103834275 B CN 103834275B CN 201410075415 A CN201410075415 A CN 201410075415A CN 103834275 B CN103834275 B CN 103834275B
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Abstract
The invention discloses a kind of ultraviolet-curing paint adding nano bamboo carbon powder, it is characterized in that, be made up of the raw material of following weight part: polyester acrylate 50-55, tri (propylene glycol) diacrylate 10-12, Viscoat 295 5-8, benzoin dimethylether 4-5, dihydroxy methylpropane diacrylate 10-12, lauryl diglycidyl ether 3-5, hexabromocyclododecane 3-6, cerium oxide 1-2, linking agent TAC2-3, zirconium English powder 3-5, celestite powder 5-7, nano bamboo carbon powder 3-5, auxiliary agent 4-5; The present invention adds nano bamboo carbon powder, good dispersity, adds mobility, and nano bamboo carbon powder has good electromagnetic shielding action, and energy anion releasing and far infrared rays, harmless to human-body safety; Add auxiliary agent, good leveling property, film adhesive is good, and hardness is large, wear-resisting, energy-conserving and environment-protective.
Description
Technical field
The present invention relates to a kind of coating and preparation method thereof, particularly a kind of ultraviolet-curing paint adding nano bamboo carbon powder and preparation method thereof.
Background technology
UV is coating material solidified has become comparatively proven technique, and particularly along with the raising of people's environmental consciousness, production and researchist note the development and application that UV is coating material solidified more.UV is coating material solidified is a kind of environmental type coating, principle that it meets completely " 4E ", it is 1/5 of thermofixation that general UV solidifies energy consumption, and UV is coating material solidified less containing volatiles, pollute little, attract most researchist and developer to be that UV is coating material solidified can reduce raw materials consumption, be conducive to reducing Financial cost.
Current UV solidify material is various, but still in various degree there are some problems, coating material solidified, the generation string stress large through photocuring post-shrinkage ratio of existing UV, cause that film is crisp, sticking power and impact resistance is poor and the snappiness of film difference and the shortcoming such as hardness is low, not corrosion-resistant, easy xanthochromia is aging, this series of problems all needs to continue improvement for different purposes, reduce production cost, expand purposes.
Summary of the invention
The object of this invention is to provide a kind of ultraviolet-curing paint adding nano bamboo carbon powder and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
Add a ultraviolet-curing paint for nano bamboo carbon powder, be made up of the raw material of following weight part: polyester acrylate 50-55, tri (propylene glycol) diacrylate 10-12, Viscoat 295 5-8, benzoin dimethylether 4-5, dihydroxy methylpropane diacrylate 10-12, lauryl diglycidyl ether 3-5, hexabromocyclododecane 3-6, cerium oxide 1-2, linking agent TAC2-3, zirconium English powder 3-5, celestite powder 5-7, nano bamboo carbon powder 3-5, auxiliary agent 4-5;
Described auxiliary agent is made up of the raw material of following weight part: diatomite 10-13, hectorite 5-7, titanium dioxide 5-7, epoxy castor oil 3-4, lemon quintessence oil 0.1-0.2, Viscoat 295 4-6, neopentylglycol diacrylate 3-5, altax 2-3, N-BUTYL ACETATE 20-23; Diatomite is put into calcining furnace to calcine 3-4 hour at 520-540 DEG C by preparation method, takes out, is ground into 50-100 object mixed powder together with hectorite, titanium dioxide; All the other remaining components mixed, be heated to 50-60 DEG C, stir and add mixed powder after 30-45 minute, insulation grinding 1-1.5 hour, to obtain final product.
A kind of ultraviolet-curing paint adding nano bamboo carbon powder of the present invention, be made up of following concrete steps:
(1) polyester acrylate, tri (propylene glycol) diacrylate, Viscoat 295 are put into reactor and stirred, be heated to 75-85 DEG C, stir 15-20 minute;
(2) add all the other remaining components except benzoin dimethylether, continue stirring reaction 30-40 minute, make it to be uniformly dispersed;
(3) be finally cooled to 45-55 DEG C, add benzoin dimethylether, stirring reaction 20-25 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
The invention has the beneficial effects as follows: the present invention adds nano bamboo carbon powder, good dispersity, add mobility, and nano bamboo carbon powder has good electromagnetic shielding action, and energy anion releasing and far infrared rays, harmless to human-body safety; Add auxiliary agent, good leveling property, film adhesive is good, and hardness is large, wear-resisting, energy-conserving and environment-protective.
Specific embodiments
Below by specific examples, the present invention is described in detail.
Add a ultraviolet-curing paint for nano bamboo carbon powder, be made up of the raw material of following weight part (kilogram): polyester acrylate 50, tri (propylene glycol) diacrylate 10, Viscoat 295 5, benzoin dimethylether 4, dihydroxy methylpropane diacrylate 10, lauryl diglycidyl ether 3, hexabromocyclododecane 3, cerium oxide 1, linking agent TAC2, zirconium English powder 3, celestite powder 5, nano bamboo carbon powder 3, auxiliary agent 4;
Described auxiliary agent is made up of the raw material of following weight part (kilogram): diatomite 10, hectorite 5, titanium dioxide 5, epoxy castor oil 3, lemon quintessence oil 0.1, Viscoat 295 4, neopentylglycol diacrylate 3, altax 2, N-BUTYL ACETATE 20; Diatomite is put into calcining furnace to calcine 3-4 hour at 520-540 DEG C by preparation method, takes out, is ground into 50-100 object mixed powder together with hectorite, titanium dioxide; All the other remaining components mixed, be heated to 50-60 DEG C, stir and add mixed powder after 30-45 minute, insulation grinding 1-1.5 hour, to obtain final product.
A kind of ultraviolet-curing paint adding nano bamboo carbon powder of the present invention, be made up of following concrete steps:
(1) polyester acrylate, tri (propylene glycol) diacrylate, Viscoat 295 are put into reactor and stirred, be heated to 75-85 DEG C, stir 15-20 minute;
(2) add all the other remaining components except benzoin dimethylether, continue stirring reaction 30-40 minute, make it to be uniformly dispersed;
(3) be finally cooled to 45-55 DEG C, add benzoin dimethylether, stirring reaction 20-25 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
This coating can adopt roller coating, showering, spraying form of construction work construct.Paint spraying on plank the sticking power obtained by above scheme is all better than secondary, resistance to 75% ethanol more than 24 hours, alkaline-resisting more than 24 hours, acidproof more than 48 hours, tolerance 40 degrees below zero and the cold cycling of 40 degree do not ftracture for 10 times, resistance to 15% salt solution more than 60 hours, hardness can regulate between 2H to 3H, and abrasion resistance index is more than 4000 turns.
Claims (2)
1. one kind is added the ultraviolet-curing paint of nano bamboo carbon powder, it is characterized in that, be made up of the raw material of following weight part: polyester acrylate 50-55, tri (propylene glycol) diacrylate 10-12, Viscoat 295 5-8, benzoin dimethylether 4-5, dihydroxy methylpropane diacrylate 10-12, lauryl diglycidyl ether 3-5, hexabromocyclododecane 3-6, cerium oxide 1-2, linking agent TAC2-3, zirconium English powder 3-5, celestite powder 5-7, nano bamboo carbon powder 3-5, auxiliary agent 4-5;
Described auxiliary agent is made up of the raw material of following weight part: diatomite 10-13, hectorite 5-7, titanium dioxide 5-7, epoxy castor oil 3-4, lemon quintessence oil 0.1-0.2, Viscoat 295 4-6, neopentylglycol diacrylate 3-5, altax 2-3, N-BUTYL ACETATE 20-23; Diatomite is put into calcining furnace to calcine 3-4 hour at 520-540 DEG C by preparation method, takes out, is ground into 50-100 object mixed powder together with hectorite, titanium dioxide; All the other remaining components mixed, be heated to 50-60 DEG C, stir and add mixed powder after 30-45 minute, insulation grinding 1-1.5 hour, to obtain final product.
2. a kind of ultraviolet-curing paint adding nano bamboo carbon powder according to claim 1, is characterized in that, be made up of following concrete steps:
(1) polyester acrylate, tri (propylene glycol) diacrylate, Viscoat 295 are put into reactor and stirred, be heated to 75-85 DEG C, stir 15-20 minute;
(2) add all the other remaining components except benzoin dimethylether, continue stirring reaction 30-40 minute, make it to be uniformly dispersed;
(3) be finally cooled to 45-55 DEG C, add benzoin dimethylether, stirring reaction 20-25 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410075415.5A CN103834275B (en) | 2014-03-04 | 2014-03-04 | A kind of ultraviolet-curing paint adding nano bamboo carbon powder and preparation method thereof |
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| CN201410075415.5A CN103834275B (en) | 2014-03-04 | 2014-03-04 | A kind of ultraviolet-curing paint adding nano bamboo carbon powder and preparation method thereof |
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| CN103834275A CN103834275A (en) | 2014-06-04 |
| CN103834275B true CN103834275B (en) | 2016-03-30 |
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Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9017772B2 (en) * | 2010-07-08 | 2015-04-28 | Xerox Corporation | Process for fabrication of seamless UV cured intermediate transfer belts (ITB) |
| CN102093809B (en) * | 2010-12-09 | 2013-11-13 | 浙江荣泰科技企业有限公司 | Photosensitive dipping resin |
| CN102633915B (en) * | 2012-04-12 | 2013-11-06 | 广州市博兴化工科技有限公司 | Method for preparing photocurable resin from animal and vegetable triglyceride and photocurable resin prepared by method |
| JP5960088B2 (en) * | 2012-04-24 | 2016-08-02 | オリジン電気株式会社 | UV curable resin composition and coating film |
| CN103525272A (en) * | 2013-09-30 | 2014-01-22 | 安徽蓝柯复合材料有限公司 | Flame-retardant UV curing coating and preparation method thereof |
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Inventor after: Shu Huaying Inventor after: Deng Zhenhua Inventor before: Tang Guangshun |
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Effective date of registration: 20170330 Address after: 519075 Guangdong province Zhuhai City Huayu Road No. 639 building, 3 floor third A zone Patentee after: Zhuhai Ze printing supplies Co., Ltd. Address before: 241200 Anhui city of Wuhu province Fanchang Sunshine City Garden Building 406 room 3 Patentee before: Wuhu Edison Automation Equipment Co., Ltd. |