CN103833231B - A kind of have glass of graphene oxide nickel-phosphorus composite deposit and preparation method thereof - Google Patents
A kind of have glass of graphene oxide nickel-phosphorus composite deposit and preparation method thereof Download PDFInfo
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- CN103833231B CN103833231B CN201410079393.XA CN201410079393A CN103833231B CN 103833231 B CN103833231 B CN 103833231B CN 201410079393 A CN201410079393 A CN 201410079393A CN 103833231 B CN103833231 B CN 103833231B
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Abstract
The present invention discloses a kind of glass and the preparation method with graphene oxide nickel-phosphorus composite deposit, the described glass with graphene oxide nickel-phosphorus composite deposit comprises glass basis, is also included in one deck graphene oxide nickel-phosphorus composite deposit that described glass basis is coated with on the surface; Described graphene oxide nickel-phosphorus composite deposit to be immersed in by the glass basis after oil removing, scrubbing, alligatoring, activation treatment in graphene oxide nickel-phosphorus electroless plating solution after 20-30min, after distilled water flushing is clean, drying obtains, itself and glass basis bonding force are good, there is very strong wear resistance, erosion resistance and electric property.Described graphene oxide nickel-phosphorus electroless plating solution, calculates by 0.1-1g graphene oxide by often liter, 25-35g single nickel salt, 25-35g inferior sodium phosphate, 15g sodium acetate, 10-15g phytic acid, 8g Trisodium Citrate, 10-15g lactic acid and 0.05g one package stabilizer composition.
Description
Technical field
The present invention relates to a kind of glass with graphene oxide nickel-phosphorus composite deposit
and preparation method thereof.
Background technology
Electroless plating refers to when not having impressed current, utilizes reductive agent by the reducing metal ions in solution out, is deposited on the method that plating piece surface forms coating, especially for baroque workpiece, and the coating surface uniform ground utilizing electroless plating to obtain.Chemical plating coating has surface crystallization densification, and porosity is low, good stability, and hardness is high comparatively, is widely used in space flight, electronics, machinery, precision instrument, five metals and chemical industry.In plating process, add other compound or particle, form composite deposite, improve the performance of single chemical plating, be widely used.
In building, industry, scientific research, life, glass is widely used as a kind of base mateiral.Glass transparent is hard, but matter is crisp frangible, particularly ordinary plate glass, and itself does not possess special performance, cannot play and act on widely, apply very limited in all trades and professions.In order to improve its performance, need to carry out modification and deep processing process to it.Glass surface chemistry plating is common a kind of modified method, and by its surperficial plating, surface attachment layer of metal realizes glass surface functionalization, expands the important method in glass applications field.By plating different metallic membranes, the performances such as the optics of glass, electricity, calorifics, chemistry and mechanics can be changed.Glass surface chemistry coating technology is long-standing, is in 12-13 century the earliest, has occurred the glass scribbling metallic membrane.Occurred again the glass coating of silver, aluminium film afterwards, along with the development of technology, the research of people is more and more deep, has occurred various composite deposite.As glass surface chemistry plating Ni-Fe-Pr-P alloy layer has good conductivity and excellent capability of electromagnetic shielding, can be used as electro-conductive material and the use of electrical loss absorption agent.But the various binding force of cladding material obtained before this are lower, thermal shock method measures bonding force experiment cycle index generally at 8 times; Hardness and wear resistance are general not high, and its friction is weightless usually within the scope of 0.13-0.20mg.
Graphene oxide is the growth of Graphene, the basal plane that the two-dimensional space of the monatomic formation of one deck infinitely extends connects a large amount of oxy radicals, comprise-OH and C-O-C, and containing C=O and COOH in its film source, play very important effect improving in the over-all properties such as calorifics, electricity, mechanics of material.
But, still there is no the report about the glass with graphene oxide nickel-phosphorus composite deposit at present.
Graphene oxide is joined in nickel-phosphorus electroless plating solution, add certain complexing agent, stablizer etc. and make graphene oxide nickel-phosphorus electroless plating solution, for surface treated glass surface, obtain the glass with graphene oxide nickel-phosphorus composite deposit, because coating has good electricity and mechanical property, thus glass can be made to be more widely used.
Summary of the invention
An object of the present invention provides a kind of glass with graphene oxide nickel-phosphorus composite deposit, graphene oxide nickel-phosphorus composite deposit and glass basis have good bonding force, graphene oxide nickel-phosphorus composite deposit has very strong wear resistance, the performances such as erosion resistance.
Two of the object of the invention is to provide above-mentioned a kind of glass of graphene oxide nickel-phosphorus composite deposit that has
preparation method.
Three of object of the present invention is to provide a kind of above-mentioned for the formation of having graphene oxide nickel-phosphor bath used in the glass of graphene oxide nickel-phosphorus composite deposit.
technical scheme of the present invention
There is a glass for graphene oxide nickel-phosphorus composite deposit, comprise glass basis, be also included in the graphene oxide nickel-phosphorus composite deposit that a layer thickness that the surface of described glass basis is coated with is 4-6 μm;
Described graphene oxide nickel-phosphorus composite deposit is immersed in graphene oxide nickel-phosphorus electroless plating solution after 20-30min by the glass basis after oil removing, scrubbing, alligatoring, activation treatment, and after distilled water flushing is clean, control temperature is 15-20 DEG C and carries out drying and obtain;
Described graphene oxide nickel-phosphorus electroless plating solution, by often liter of calculating, its component and content as follows:
Graphene oxide 0.5-1g
Single nickel salt 25-30g
Inferior sodium phosphate 25-30g
Sodium acetate 15g
Phytic acid 10-15g
Trisodium Citrate 8g
Lactic acid 10-15g
Stablizer 0.05g
All the other are distilled water;
PH is adjusted to be 4.4-4.6 with ammoniacal liquor;
Described one package stabilizer is made up of Allyl thiourea, Potassium Iodate and potassiumiodide, calculates in mass ratio, Allyl thiourea: Potassium Iodate: potassiumiodide is 1:18:18.
Above-mentioned a kind of preparation method with the glass of graphene oxide nickel-phosphorus composite deposit, specifically comprises the steps:
(1), the preparation of graphene oxide nickel-phosphorus electroless plating solution
Graphene oxide, single nickel salt, inferior sodium phosphate, sodium acetate, phytic acid, Trisodium Citrate, lactic acid and one package stabilizer are joined in distilled water successively and dissolves, then adjust pH to be 4.4-4.6 with ammoniacal liquor, namely obtain graphene oxide nickel-phosphor bath;
(2), the pre-treatment on glass basis surface
Clean glass basis with distilled water, then put into acetone, ultrasonic vibration 15min under room temperature, then soaks 10-15min in the ethanol of 75%, and distilled water flushing is clean, reaches the object of oil removing scrubbing;
Then, glass basis is placed in roughening solution and soaks 5min, distilled water flushing; Described roughening solution is by H
2o
2, HF, HNO
3composition, calculates, wherein H by volume
2o
2: HF:HNO
3for 4:8:3;
Then, then glass basis is immersed in 5min in activation solution, simultaneously sonic oscillation, dries under taking out room temperature, put into baking oven, 30min under 165-170 DEG C of condition; Described activation solution, by often liter of calculating, is made up of the distilled water of 250g single nickel salt, 100g inferior sodium phosphate, 50g dehydrated alcohol and surplus, adjusts pH to be 7.0-7.2 with ammoniacal liquor;
(3), the graphene oxide nickel-phosphor bath of step (1) gained is heated to 85-90 DEG C, after glass basis pretreated for step (2) is put into graphene oxide nickel-phosphor bath 20-30min, take out the graphene oxide nickel-phosphor bath with distilled water flushing remained on surface, control temperature be 15-20 DEG C carry out drying after, the glass of graphene oxide nickel-phosphorus composite deposit must be had.
Graphene oxide nickel-phosphorus composite deposit obtained above, it is the method utilizing electroless plating, there is redox reaction in the surface of glass basis, nickel phosphorus is deposited on glass basis, carry graphene oxide particle deposition simultaneously on nickel-phosphorus coating, thus obtain graphene oxide nickel-phosphorus composite deposit.
of the present invention usefuleffect
A kind of glass with graphene oxide nickel-phosphorus composite deposit of the present invention, owing to adding in graphene oxide nickel-phosphor bath used in its preparation process, there is calorifics, electricity, the graphene oxide particle of the over-all propertieies such as mechanics, what obtained has in graphene oxide nickel-phosphorus composite deposit containing a certain proportion of graphene oxide, thus improve the surface tissue of coating, than common coating, there is better bonding force and wear resistance, better electric property, thus for the following applications expanding in fields such as electronic devices and components of the glass with graphene oxide nickel-phosphorus composite deposit prospect.
Embodiment
Below in conjunction with specific embodiment, technical scheme of the present invention is further described, but the present invention is not limited in following embodiment.
Various raw materials used in various embodiments of the present invention, if no special instructions, are commercially available.
embodiment 1
There is a glass for graphene oxide nickel-phosphorus composite deposit, comprise glass basis, be also included in the graphene oxide nickel-phosphorus composite deposit that a layer thickness that the surface of described glass basis is coated with is 4-6 μm;
Described graphene oxide nickel-phosphorus composite deposit is immersed in graphene oxide nickel-phosphorus electroless plating solution after 20-30min by the glass basis after oil removing, scrubbing, alligatoring, activation treatment, and after distilled water flushing is clean, control temperature is 15-20 DEG C and carries out drying and obtain;
Described graphene oxide nickel-phosphorus electroless plating solution, by often liter of calculating, its component and content as follows:
Graphene oxide 0.5g
Single nickel salt 25g
Inferior sodium phosphate 25g
Sodium acetate 15g
Phytic acid 15g
Trisodium Citrate 8g
Lactic acid 10g
Stablizer 0.05g
All the other are distilled water;
PH is adjusted to be 4.4-4.6 with ammoniacal liquor;
Described one package stabilizer is made up of Allyl thiourea, Potassium Iodate and potassiumiodide, calculates in mass ratio, Allyl thiourea: Potassium Iodate: potassiumiodide is 1:18:18.
Above-mentioned a kind of preparation method with the glass of graphene oxide nickel-phosphorus composite deposit, specifically comprises the steps:
(1), the preparation of graphene oxide nickel-phosphorus electroless plating solution
Graphene oxide, single nickel salt, inferior sodium phosphate, sodium acetate, phytic acid, Trisodium Citrate, lactic acid and one package stabilizer are joined in distilled water successively according to above-mentioned specification of quality and dissolves, then adjust pH to be 4.4-4.6 with ammoniacal liquor, namely obtain graphene oxide nickel-phosphor bath;
(2), the pre-treatment on glass basis surface
Clean glass basis with distilled water, then put into acetone, ultrasonic vibration 15min under room temperature, then soaks 10-15min, distilled water flushing in the ethanol of 75%, reaches the object of oil removing scrubbing;
Then, glass basis is placed in roughening solution and soaks 5min, distilled water flushing; Described roughening solution is by H
2o
2, HF, HNO
3composition, calculates, wherein H by volume
2o
2: HF:HNO
3for 4:8:3;
Then, then glass basis is immersed in 5min in activation solution, simultaneously sonic oscillation, dries under taking out room temperature, put into baking oven, 30min under 165-170 DEG C of condition; Described activation solution, by often liter of calculating, is made up of the distilled water of 250g single nickel salt, 100g inferior sodium phosphate, 50g dehydrated alcohol and surplus, adjusts pH to be 7.0-7.2 with ammoniacal liquor;
(3), the graphene oxide nickel-phosphor bath of step (1) gained is heated to 85-90 DEG C, after glass basis pretreated for step (2) is put into graphene oxide nickel-phosphor bath 20-30min, take out the graphene oxide nickel-phosphor bath with distilled water flushing remained on surface, control temperature be 15-20 DEG C carry out drying after, the glass of graphene oxide nickel-phosphorus composite deposit must be had.
The glass with graphene oxide nickel-phosphorus composite deposit of above-mentioned gained, detects through scanning electronic microscope, and the composite deposite formed combines closely, and in cellular growth, surface tissue is smooth, and is amorphous structure.
The glass with graphene oxide nickel-phosphorus composite deposit of above-mentioned gained, utilize thermal shock method measuring bonding force, baking oven for heating plating piece is to 200 DEG C, room temperature water chilling, through 10 circulations, there is the coating non-scale of the glass surface of graphene oxide nickel-phosphorus composite deposit, not bubbling, illustrate that graphene oxide nickel-phosphorus composite deposit and glass basis have good bonding force.
The glass with graphene oxide nickel-phosphorus composite deposit of above-mentioned gained, MMW-1A friction wear testing machine is adopted to measure its wear resisting property, at load 196N, rotating speed is 150r/min, when fraction time 30min, wear weight loss, at 0.09-0.12mg, illustrates that graphene oxide nickel-phosphorus composite deposit has good wear resisting property.
embodiment 2
There is a glass for graphene oxide nickel-phosphorus composite deposit, comprise glass basis, be also included in the graphene oxide nickel-phosphorus composite deposit that a layer thickness that the surface of described glass basis is coated with is 4-6 μm;
Described graphene oxide nickel-phosphorus composite deposit is immersed in graphene oxide nickel-phosphorus electroless plating solution after 20-30min by the glass basis after oil removing, scrubbing, alligatoring, activation treatment, and after distilled water flushing is clean, control temperature is 15-20 DEG C and carries out drying and obtain;
Described graphene oxide nickel-phosphorus electroless plating solution, by often liter of calculating, its component and content as follows:
Graphene oxide 1g
Single nickel salt 25g
Inferior sodium phosphate 25g
Sodium acetate 15g
Phytic acid 15g
Trisodium Citrate 8g
Lactic acid 10g
Stablizer 0.05g
All the other are distilled water;
PH is adjusted to be 4.4-4.6 with ammoniacal liquor;
Described one package stabilizer is made up of Allyl thiourea, Potassium Iodate and potassiumiodide, calculates in mass ratio, Allyl thiourea: Potassium Iodate: potassiumiodide is 1:18:18.
Above-mentioned a kind of preparation method with the glass of graphene oxide nickel-phosphorus composite deposit, specifically comprises the steps:
(1), the preparation of graphene oxide nickel-phosphorus electroless plating solution
Graphene oxide, single nickel salt, inferior sodium phosphate, sodium acetate, phytic acid, Trisodium Citrate, lactic acid and one package stabilizer are joined in distilled water successively according to above-mentioned specification of quality and dissolves, then adjust pH to be 4.4-4.6 with ammoniacal liquor, namely obtain graphene oxide nickel-phosphor bath;
(2), the pre-treatment on glass basis surface
Clean glass basis with distilled water, then put into acetone, ultrasonic vibration 15min under room temperature, then soaks 10-15min, distilled water flushing in the ethanol of 75%, reaches the object of oil removing scrubbing;
Then, glass basis is placed in roughening solution and soaks 5min, distilled water flushing; Described roughening solution is by H
2o
2, HF, HNO
3composition, calculates, wherein H by volume
2o
2: HF:HNO
3for 4:8:3;
Then, then glass basis is immersed in 5min in activation solution, simultaneously sonic oscillation, dries under taking out room temperature, put into baking oven, 30min under 165-170 DEG C of condition; Described activation solution, by often liter of calculating, is made up of the distilled water of 250g single nickel salt, 100g inferior sodium phosphate, 50g dehydrated alcohol and surplus, adjusts pH to be 7.0-7.2 with ammoniacal liquor;
(3), the graphene oxide nickel-phosphor bath of step (1) gained is heated to 85-90 DEG C, after glass basis pretreated for step (2) is put into graphene oxide nickel-phosphor bath 20-30min, take out the graphene oxide nickel-phosphor bath with distilled water flushing remained on surface, control temperature be 15-20 DEG C carry out drying after, the glass of graphene oxide nickel-phosphorus composite deposit must be had.
The glass with graphene oxide nickel-phosphorus composite deposit of above-mentioned gained, detects through scanning electronic microscope, and the composite deposite formed combines closely, and in cellular growth, surface tissue is smooth, and is amorphous structure.
The glass with graphene oxide nickel-phosphorus composite deposit of above-mentioned gained, utilize thermal shock method measuring bonding force, baking oven for heating plating piece is to 200 DEG C, room temperature water chilling, through 10 circulations, there is the coating non-scale of the glass surface of graphene oxide nickel-phosphorus composite deposit, not bubbling, illustrate that graphene oxide nickel-phosphorus composite deposit and glass basis have good bonding force.
The glass with graphene oxide nickel-phosphorus composite deposit of above-mentioned gained, MMW-1A friction wear testing machine is adopted to measure its wear resisting property, at load 196N, rotating speed is 150r/min, when fraction time 30min, wear weight loss, at 0.09-0.12mg, illustrates that graphene oxide nickel-phosphorus composite deposit has good wear resisting property.
embodiment 3
There is a glass for graphene oxide nickel-phosphorus composite deposit, comprise glass basis, be also included in the graphene oxide nickel-phosphorus composite deposit that a layer thickness that the surface of described glass basis is coated with is 4-6 μm;
Described graphene oxide nickel-phosphorus composite deposit is immersed in graphene oxide nickel-phosphorus electroless plating solution after 20-30min by the glass basis after oil removing, scrubbing, alligatoring, activation treatment, and after distilled water flushing is clean, control temperature is 15-20 DEG C and carries out drying and obtain;
Described graphene oxide nickel-phosphorus electroless plating solution, by often liter of calculating, its component and content as follows:
Graphene oxide 0.75g
Single nickel salt 30g
Inferior sodium phosphate 25g
Sodium acetate 15g
Phytic acid 10g
Trisodium Citrate 8g
Lactic acid 15g
Stablizer 0.05g
All the other are distilled water;
PH is adjusted to be 4.4-4.6 with ammoniacal liquor;
Described one package stabilizer is made up of Allyl thiourea, Potassium Iodate and potassiumiodide, calculates in mass ratio, Allyl thiourea: Potassium Iodate: potassiumiodide is 1:18:18.
Above-mentioned a kind of preparation method with the glass of graphene oxide nickel-phosphorus composite deposit, specifically comprises the steps:
(1), the preparation of graphene oxide nickel-phosphorus electroless plating solution
Graphene oxide, single nickel salt, inferior sodium phosphate, sodium acetate, phytic acid, Trisodium Citrate, lactic acid and one package stabilizer are joined in distilled water successively according to above-mentioned specification of quality and dissolves, then adjust pH to be 4.4-4.6 with ammoniacal liquor, namely obtain graphene oxide nickel-phosphor bath;
(2), the pre-treatment on glass basis surface
Clean glass basis with distilled water, then put into acetone, ultrasonic vibration 15min under room temperature, then soaks 10-15min, distilled water flushing in the ethanol of 75%, reaches the object of oil removing scrubbing;
Then, glass basis is placed in roughening solution and soaks 5min, distilled water flushing; Described roughening solution is by H
2o
2, HF, HNO
3composition, calculates, wherein H by volume
2o
2: HF:HNO
3for 4:8:3;
Then, then glass basis is immersed in 5min in activation solution, simultaneously sonic oscillation, dries under taking out room temperature, put into baking oven, 30min under 165-170 DEG C of condition; Described activation solution, by often liter of calculating, is made up of the distilled water of 250g single nickel salt, 100g inferior sodium phosphate, 50g dehydrated alcohol and surplus, adjusts pH to be 7.0-7.2 with ammoniacal liquor;
(3), the graphene oxide nickel-phosphor bath of step (1) gained is heated to 85-90 DEG C, after glass basis pretreated for step (2) is put into graphene oxide nickel-phosphor bath 20-30min, take out the graphene oxide nickel-phosphor bath with distilled water flushing remained on surface, control temperature be 15-20 DEG C carry out drying after, the glass of graphene oxide nickel-phosphorus composite deposit must be had.
The glass with graphene oxide nickel-phosphorus composite deposit of above-mentioned gained, detects through scanning electronic microscope, and the composite deposite formed combines closely, and in cellular growth, surface tissue is smooth, and is amorphous structure.
The glass with graphene oxide nickel-phosphorus composite deposit of above-mentioned gained, utilize thermal shock method measuring bonding force, baking oven for heating plating piece is to 200 DEG C, room temperature water chilling, through 10 circulations, there is the coating non-scale of the glass surface of graphene oxide nickel-phosphorus composite deposit, not bubbling, illustrate that graphene oxide nickel-phosphorus composite deposit and glass basis have good bonding force.
The glass with graphene oxide nickel-phosphorus composite deposit of above-mentioned gained, MMW-1A friction wear testing machine is adopted to measure its wear resisting property, at load 196N, rotating speed is 150r/min, when fraction time 30min, wear weight loss, at 0.09-0.12mg, illustrates that graphene oxide nickel-phosphorus composite deposit has good wear resisting property.
embodiment 4
There is a glass for graphene oxide nickel-phosphorus composite deposit, comprise glass basis, be also included in the graphene oxide nickel-phosphorus composite deposit that a layer thickness that the surface of described glass basis is coated with is 4-6 μm;
Described graphene oxide nickel-phosphorus composite deposit is immersed in graphene oxide nickel-phosphorus electroless plating solution after 20-30min by the glass basis after oil removing, scrubbing, alligatoring, activation treatment, and after distilled water flushing is clean, control temperature is 15-20 DEG C and carries out drying and obtain;
Described graphene oxide nickel-phosphorus electroless plating solution, by often liter of calculating, its component and content as follows:
Graphene oxide 0.75g
Single nickel salt 30g
Inferior sodium phosphate 30g
Sodium acetate 15g
Phytic acid 10g
Trisodium Citrate 8g
Lactic acid 10g
Stablizer 0.05g
All the other are distilled water;
PH is adjusted to be 4.4-4.6 with ammoniacal liquor;
Described one package stabilizer is made up of Allyl thiourea, Potassium Iodate and potassiumiodide, calculates in mass ratio, Allyl thiourea: Potassium Iodate: potassiumiodide is 1:18:18.
Above-mentioned a kind of preparation method with the glass of graphene oxide nickel-phosphorus composite deposit, specifically comprises the steps:
(1), the preparation of graphene oxide nickel-phosphorus electroless plating solution
Graphene oxide, single nickel salt, inferior sodium phosphate, sodium acetate, phytic acid, Trisodium Citrate, lactic acid and one package stabilizer are joined in distilled water successively according to above-mentioned specification of quality and dissolves, then adjust pH to be 4.4-4.6 with ammoniacal liquor, namely obtain graphene oxide nickel-phosphor bath;
(2), the pre-treatment on glass basis surface
Clean glass basis with distilled water, then put into acetone, ultrasonic vibration 15min under room temperature, then soaks 10-15min, distilled water flushing in the ethanol of 75%, reaches the object of oil removing scrubbing;
Then, glass basis is placed in roughening solution and soaks 5min, distilled water flushing; Described roughening solution is by H
2o
2, HF, HNO
3composition, calculates, wherein H by volume
2o
2: HF:HNO
3for 4:8:3;
Then, then glass basis is immersed in 5min in activation solution, simultaneously sonic oscillation, dries under taking out room temperature, put into baking oven, 30min under 165-170 DEG C of condition; Described activation solution, by often liter of calculating, is made up of the distilled water of 250g single nickel salt, 100g inferior sodium phosphate, 50g dehydrated alcohol and surplus, adjusts pH to be 7.0-7.2 with ammoniacal liquor;
(3), the graphene oxide nickel-phosphor bath of step (1) gained is heated to 85-90 DEG C, after glass basis pretreated for step (2) is put into graphene oxide nickel-phosphor bath 20-30min, take out the graphene oxide nickel-phosphor bath with distilled water flushing remained on surface, control temperature be 15-20 DEG C carry out drying after, the glass of graphene oxide nickel-phosphorus composite deposit must be had.
The glass with graphene oxide nickel-phosphorus composite deposit of above-mentioned gained, detects through scanning electronic microscope, and the graphene oxide nickel-phosphorus composite deposit formed combines closely, and in cellular growth, surface tissue is smooth, and is amorphous structure.
The glass with graphene oxide nickel-phosphorus composite deposit of above-mentioned gained, utilize thermal shock method measuring bonding force, baking oven for heating plating piece is to 200 DEG C, room temperature water chilling, through 10 circulations, there is the coating non-scale of the glass surface of graphene oxide nickel-phosphorus composite deposit, not bubbling, illustrate that graphene oxide nickel-phosphorus composite deposit and glass basis have good bonding force.
The glass with graphene oxide nickel-phosphorus composite deposit of above-mentioned gained, MMW-1A friction wear testing machine is adopted to measure its wear resisting property, at load 196N, rotating speed is 150r/min, when fraction time 30min, wear weight loss, at 0.09-0.12mg, illustrates that graphene oxide nickel-phosphorus composite deposit has good wear resisting property.
Above said content be only the present invention conceive under basic explanation, and according to any equivalent transformation that technical scheme of the present invention is done, all should protection scope of the present invention be belonged to.
Claims (6)
1. there is a glass for graphene oxide nickel-phosphorus composite deposit, comprise glass basis, characterized by further comprising the graphene oxide nickel-phosphorus composite deposit that a layer thickness be coated with on the surface of described glass basis is 4-6 μm;
Described graphene oxide nickel-phosphorus composite deposit is immersed in graphene oxide nickel-phosphorus electroless plating solution after 20-30min by the glass basis after oil removing, scrubbing, alligatoring, activation treatment, and after distilled water flushing is clean, drying obtains;
Described graphene oxide nickel-phosphorus electroless plating solution, by often liter of calculating, its component and content as follows:
Graphene oxide 0.5-1g
Single nickel salt 25-30g
Inferior sodium phosphate 25-30g
Sodium acetate 15g
Phytic acid 10-15g
Trisodium Citrate 8g
Lactic acid 10-15g
Stablizer 0.05g
All the other are distilled water;
PH is adjusted to be 4.4-4.6 with ammoniacal liquor;
Described stablizer is made up of Allyl thiourea, Potassium Iodate and potassiumiodide, calculates in mass ratio, Allyl thiourea: Potassium Iodate: potassiumiodide is 1:18:18.
2. a kind of glass with graphene oxide nickel-phosphorus composite deposit as claimed in claim 1, is characterized in that described graphene oxide nickel-phosphorus electroless plating solution, by often liter of calculating, its component and content as follows:
Graphene oxide 0.5g
Single nickel salt 25g
Inferior sodium phosphate 25g
Sodium acetate 15g
Phytic acid 15g
Trisodium Citrate 8g
Lactic acid 10g
Stablizer 0.05g
All the other are distilled water.
3. a kind of glass with graphene oxide nickel-phosphorus composite deposit as claimed in claim 1, is characterized in that described graphene oxide nickel-phosphorus electroless plating solution, by often liter of calculating, its component and content as follows:
Graphene oxide 1g
Single nickel salt 25g
Inferior sodium phosphate 25g
Sodium acetate 15g
Phytic acid 15g
Trisodium Citrate 8g
Lactic acid 10g
Stablizer 0.05g
All the other are distilled water.
4. a kind of glass with graphene oxide nickel-phosphorus composite deposit as claimed in claim 1, is characterized in that described graphene oxide nickel-phosphorus electroless plating solution, by often liter of calculating, its component and content as follows:
Graphene oxide 0.75g
Single nickel salt 30g
Inferior sodium phosphate 25g
Sodium acetate 15g
Phytic acid 10g
Trisodium Citrate 8g
Lactic acid 15g
Stablizer 0.05g
All the other are distilled water.
5. a kind of glass with graphene oxide nickel-phosphorus composite deposit as claimed in claim 1, is characterized in that described graphene oxide nickel-phosphorus electroless plating solution, by often liter of calculating, its component and content as follows:
Graphene oxide 0.75g
Single nickel salt 30g
Inferior sodium phosphate 30g
Sodium acetate 15g
Phytic acid 10g
Trisodium Citrate 8g
Lactic acid 10g
Stablizer 0.05g
All the other are distilled water.
6. a kind of preparation method with the glass of graphene oxide nickel-phosphorus composite deposit as described in claim as arbitrary in claim 1-5, is characterized in that specifically comprising the steps:
(1), the preparation of graphene oxide nickel-phosphorus electroless plating solution
Graphene oxide, single nickel salt, inferior sodium phosphate, sodium acetate, phytic acid, Trisodium Citrate, lactic acid and one package stabilizer are joined in distilled water successively and dissolves, then adjust pH to be 4.4-4.6 with ammoniacal liquor, namely obtain graphene oxide nickel-phosphor bath;
(2), the pre-treatment on glass basis surface
Clean glass basis with distilled water, then put into acetone, ultrasonic vibration 15min under room temperature, then in the ethanol of 75%, soak 10-15min, distilled water flushing is clean;
Then, glass basis is placed in roughening solution and soaks 5min, distilled water flushing; Described roughening solution is made up of H2O2, HF, HNO3, calculates by volume, and wherein H2O2:HF:HNO3 is 4:8:3;
Then, then glass basis is immersed in 5min in activation solution, simultaneously sonic oscillation, dries under taking out room temperature, put into baking oven, 30min under 165-170 DEG C of condition; Described activation solution, by often liter of calculating, is made up of the distilled water of 250g single nickel salt, 100g inferior sodium phosphate, 50g dehydrated alcohol and surplus, adjusts pH to be 7.0-7.2 with ammoniacal liquor;
(3), the graphene oxide nickel-phosphor bath of step (1) gained is heated to 85-90 DEG C, after glass basis pretreated for step (2) is put into graphene oxide nickel-phosphor bath 20-30min, take out the graphene oxide nickel-phosphor bath with distilled water flushing remained on surface, control temperature be 15-20 DEG C carry out drying after, the glass of graphene oxide nickel-phosphorus composite deposit must be had.
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| CN113981424B (en) * | 2021-09-24 | 2023-09-12 | 宁波博威合金材料股份有限公司 | Chemical plating Ni-P-graphene composite coating and preparation method thereof |
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