CN103828825A - Pesticide composition containing pyraclostrobin and triazoles - Google Patents
Pesticide composition containing pyraclostrobin and triazoles Download PDFInfo
- Publication number
- CN103828825A CN103828825A CN201310578454.2A CN201310578454A CN103828825A CN 103828825 A CN103828825 A CN 103828825A CN 201310578454 A CN201310578454 A CN 201310578454A CN 103828825 A CN103828825 A CN 103828825A
- Authority
- CN
- China
- Prior art keywords
- pyraclostrobin
- flutriafol
- azoles alcohol
- bitertanol
- triadimenol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000005869 Pyraclostrobin Substances 0.000 title claims abstract description 274
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 title claims abstract description 274
- 239000000203 mixture Substances 0.000 title claims abstract description 86
- 239000000575 pesticide Substances 0.000 title claims abstract description 26
- 150000003852 triazoles Chemical class 0.000 title claims abstract description 7
- JWUCHKBSVLQQCO-UHFFFAOYSA-N 1-(2-fluorophenyl)-1-(4-fluorophenyl)-2-(1H-1,2,4-triazol-1-yl)ethanol Chemical compound C=1C=C(F)C=CC=1C(C=1C(=CC=CC=1)F)(O)CN1C=NC=N1 JWUCHKBSVLQQCO-UHFFFAOYSA-N 0.000 claims abstract description 47
- 239000005787 Flutriafol Substances 0.000 claims abstract description 46
- 239000000839 emulsion Substances 0.000 claims abstract description 31
- 239000000725 suspension Substances 0.000 claims abstract description 31
- 239000000375 suspending agent Substances 0.000 claims abstract description 29
- 239000004562 water dispersible granule Substances 0.000 claims abstract description 28
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 27
- 201000010099 disease Diseases 0.000 claims abstract description 26
- 239000000843 powder Substances 0.000 claims description 50
- 238000009736 wetting Methods 0.000 claims description 41
- 235000013399 edible fruits Nutrition 0.000 claims description 2
- 235000013311 vegetables Nutrition 0.000 claims description 2
- 235000013339 cereals Nutrition 0.000 claims 1
- 238000009472 formulation Methods 0.000 claims 1
- 230000003641 microbiacidal effect Effects 0.000 claims 1
- 229940124561 microbicide Drugs 0.000 claims 1
- 239000002855 microbicide agent Substances 0.000 claims 1
- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 abstract description 44
- VGPIBGGRCVEHQZ-UHFFFAOYSA-N 1-(biphenyl-4-yloxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-ol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC(C=C1)=CC=C1C1=CC=CC=C1 VGPIBGGRCVEHQZ-UHFFFAOYSA-N 0.000 abstract description 44
- UFNOUKDBUJZYDE-UHFFFAOYSA-N 2-(4-chlorophenyl)-3-cyclopropyl-1-(1H-1,2,4-triazol-1-yl)butan-2-ol Chemical compound C1=NC=NN1CC(O)(C=1C=CC(Cl)=CC=1)C(C)C1CC1 UFNOUKDBUJZYDE-UHFFFAOYSA-N 0.000 abstract description 44
- 239000005757 Cyproconazole Substances 0.000 abstract description 44
- 239000005839 Tebuconazole Substances 0.000 abstract description 44
- 239000005846 Triadimenol Substances 0.000 abstract description 44
- BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 abstract description 44
- 230000002195 synergetic effect Effects 0.000 abstract description 25
- 241000221785 Erysiphales Species 0.000 abstract description 16
- FBOUIAKEJMZPQG-BLXFFLACSA-N diniconazole-M Chemical compound C1=NC=NN1/C([C@H](O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1Cl FBOUIAKEJMZPQG-BLXFFLACSA-N 0.000 abstract description 14
- STMIIPIFODONDC-UHFFFAOYSA-N 2-(2,4-dichlorophenyl)-1-(1H-1,2,4-triazol-1-yl)hexan-2-ol Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(O)(CCCC)CN1C=NC=N1 STMIIPIFODONDC-UHFFFAOYSA-N 0.000 abstract description 11
- 240000007594 Oryza sativa Species 0.000 abstract description 11
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 11
- 235000009566 rice Nutrition 0.000 abstract description 11
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 9
- 241000223600 Alternaria Species 0.000 abstract description 8
- 239000004480 active ingredient Substances 0.000 abstract description 8
- 241001530056 Athelia rolfsii Species 0.000 abstract description 2
- 206010039509 Scab Diseases 0.000 abstract description 2
- 239000000546 pharmaceutical excipient Substances 0.000 abstract 1
- 239000004563 wettable powder Substances 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 65
- 150000003851 azoles Chemical class 0.000 description 63
- 239000003814 drug Substances 0.000 description 50
- 239000002131 composite material Substances 0.000 description 41
- 238000012360 testing method Methods 0.000 description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 36
- 150000001336 alkenes Chemical class 0.000 description 34
- -1 aryl phenol Chemical compound 0.000 description 33
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 21
- 230000003449 preventive effect Effects 0.000 description 19
- 210000000481 breast Anatomy 0.000 description 16
- 239000008367 deionised water Substances 0.000 description 16
- 229910021641 deionized water Inorganic materials 0.000 description 16
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 16
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 15
- 241000209140 Triticum Species 0.000 description 15
- 235000021307 Triticum Nutrition 0.000 description 15
- 150000001875 compounds Chemical class 0.000 description 15
- 231100000820 toxicity test Toxicity 0.000 description 15
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 13
- 239000007859 condensation product Substances 0.000 description 13
- 239000000440 bentonite Substances 0.000 description 12
- 229910000278 bentonite Inorganic materials 0.000 description 12
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 12
- 229910052799 carbon Inorganic materials 0.000 description 12
- 239000003795 chemical substances by application Substances 0.000 description 12
- 231100000419 toxicity Toxicity 0.000 description 12
- 230000001988 toxicity Effects 0.000 description 12
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 11
- 230000000149 penetrating effect Effects 0.000 description 11
- 229920002545 silicone oil Polymers 0.000 description 11
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- 240000003377 Shepherdia canadensis Species 0.000 description 10
- 235000018324 Shepherdia canadensis Nutrition 0.000 description 10
- 150000004996 alkyl benzenes Chemical class 0.000 description 10
- 239000011575 calcium Substances 0.000 description 10
- 229910052791 calcium Inorganic materials 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- 229920001296 polysiloxane Polymers 0.000 description 10
- 239000002253 acid Substances 0.000 description 9
- 230000000844 anti-bacterial effect Effects 0.000 description 9
- 229940077388 benzenesulfonate Drugs 0.000 description 9
- 229940079593 drug Drugs 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 229920001732 Lignosulfonate Polymers 0.000 description 8
- 150000007513 acids Chemical class 0.000 description 8
- 235000019197 fats Nutrition 0.000 description 8
- 230000005764 inhibitory process Effects 0.000 description 8
- 206010067482 No adverse event Diseases 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 7
- 125000000217 alkyl group Chemical group 0.000 description 7
- 238000004458 analytical method Methods 0.000 description 7
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- 238000011835 investigation Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- PYODKQIVQIVELM-UHFFFAOYSA-M sodium;2,3-bis(2-methylpropyl)naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CC(C)C)C(CC(C)C)=CC2=C1 PYODKQIVQIVELM-UHFFFAOYSA-M 0.000 description 7
- 239000005995 Aluminium silicate Substances 0.000 description 6
- 240000008067 Cucumis sativus Species 0.000 description 6
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 6
- 229910019142 PO4 Inorganic materials 0.000 description 6
- 239000002202 Polyethylene glycol Substances 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 6
- 235000012211 aluminium silicate Nutrition 0.000 description 6
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 6
- 150000007942 carboxylates Chemical class 0.000 description 6
- 238000009833 condensation Methods 0.000 description 6
- 230000005494 condensation Effects 0.000 description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 6
- 229920000609 methyl cellulose Polymers 0.000 description 6
- 239000001923 methylcellulose Substances 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 6
- 239000010452 phosphate Substances 0.000 description 6
- 229920005646 polycarboxylate Polymers 0.000 description 6
- 229920001223 polyethylene glycol Polymers 0.000 description 6
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 6
- 239000001488 sodium phosphate Substances 0.000 description 6
- 229910000162 sodium phosphate Inorganic materials 0.000 description 6
- 159000000000 sodium salts Chemical class 0.000 description 6
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 6
- 239000013638 trimer Substances 0.000 description 6
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 6
- 229920001285 xanthan gum Polymers 0.000 description 6
- 235000017060 Arachis glabrata Nutrition 0.000 description 5
- 244000105624 Arachis hypogaea Species 0.000 description 5
- 235000010777 Arachis hypogaea Nutrition 0.000 description 5
- 235000018262 Arachis monticola Nutrition 0.000 description 5
- 244000269722 Thea sinensis Species 0.000 description 5
- 229960000892 attapulgite Drugs 0.000 description 5
- 239000003899 bactericide agent Substances 0.000 description 5
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- 229910052625 palygorskite Inorganic materials 0.000 description 5
- 235000020232 peanut Nutrition 0.000 description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 5
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- 230000009471 action Effects 0.000 description 4
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 239000004530 micro-emulsion Substances 0.000 description 4
- 125000006353 oxyethylene group Chemical group 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 229920000136 polysorbate Polymers 0.000 description 4
- 235000010413 sodium alginate Nutrition 0.000 description 4
- 239000000661 sodium alginate Substances 0.000 description 4
- 229940005550 sodium alginate Drugs 0.000 description 4
- 239000004546 suspension concentrate Substances 0.000 description 4
- 244000215068 Acacia senegal Species 0.000 description 3
- 241000255789 Bombyx mori Species 0.000 description 3
- 239000004375 Dextrin Substances 0.000 description 3
- 229920001353 Dextrin Polymers 0.000 description 3
- 108010010803 Gelatin Proteins 0.000 description 3
- 229920000084 Gum arabic Polymers 0.000 description 3
- 239000005800 Kresoxim-methyl Substances 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 3
- 235000010489 acacia gum Nutrition 0.000 description 3
- 239000000205 acacia gum Substances 0.000 description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 3
- 235000011130 ammonium sulphate Nutrition 0.000 description 3
- 230000008485 antagonism Effects 0.000 description 3
- 235000019425 dextrin Nutrition 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229920000159 gelatin Polymers 0.000 description 3
- 239000008273 gelatin Substances 0.000 description 3
- 235000019322 gelatine Nutrition 0.000 description 3
- 235000011852 gelatine desserts Nutrition 0.000 description 3
- ZOTBXTZVPHCKPN-HTXNQAPBSA-N kresoxim-methyl Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC=C1C ZOTBXTZVPHCKPN-HTXNQAPBSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 229910021653 sulphate ion Inorganic materials 0.000 description 3
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 2
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920005682 EO-PO block copolymer Polymers 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- 239000007884 disintegrant Substances 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 230000002070 germicidal effect Effects 0.000 description 2
- 230000009036 growth inhibition Effects 0.000 description 2
- 230000036039 immunity Effects 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 230000010534 mechanism of action Effects 0.000 description 2
- 230000002438 mitochondrial effect Effects 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000000241 respiratory effect Effects 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- 230000001018 virulence Effects 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- LFJPHHQZBOYLOW-UHFFFAOYSA-N 1-(1,2,4-triazol-1-yl)hexan-2-ol Chemical compound CCCCC(O)CN1C=NC=N1 LFJPHHQZBOYLOW-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- JCUDAMKYTWVICI-UHFFFAOYSA-N 4-benzyl-2,3-dimethylphenol Chemical compound C1=C(O)C(C)=C(C)C(CC=2C=CC=CC=2)=C1 JCUDAMKYTWVICI-UHFFFAOYSA-N 0.000 description 1
- 241000235349 Ascomycota Species 0.000 description 1
- 241000221198 Basidiomycota Species 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 235000009024 Ceanothus sanguineus Nutrition 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 240000007154 Coffea arabica Species 0.000 description 1
- 241000219112 Cucumis Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 240000007049 Juglans regia Species 0.000 description 1
- 235000009496 Juglans regia Nutrition 0.000 description 1
- 240000003553 Leptospermum scoparium Species 0.000 description 1
- 235000015459 Lycium barbarum Nutrition 0.000 description 1
- 240000008790 Musa x paradisiaca Species 0.000 description 1
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 241000233654 Oomycetes Species 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- ZCILODAAHLISPY-UHFFFAOYSA-N biphenyl ether Natural products C1=C(CC=C)C(O)=CC(OC=2C(=CC(CC=C)=CC=2)O)=C1 ZCILODAAHLISPY-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 230000030833 cell death Effects 0.000 description 1
- 235000016213 coffee Nutrition 0.000 description 1
- 235000013353 coffee beverage Nutrition 0.000 description 1
- 229940125898 compound 5 Drugs 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000035613 defoliation Effects 0.000 description 1
- 230000007850 degeneration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229940043237 diethanolamine Drugs 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 244000037666 field crops Species 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 210000003470 mitochondria Anatomy 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- KFSLWBXXFJQRDL-UHFFFAOYSA-N peroxyacetic acid Substances CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 235000021003 saturated fats Nutrition 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 230000004763 spore germination Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 230000003612 virological effect Effects 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a pesticide composition containing pyraclostrobin and triazoles. The composition comprises an active ingredient A and an active ingredient B, wherein the active ingredient A is selected from pyraclostrobin; the active ingredient B is selected from one of tebuconazole, diniconazole, flutriafol, hexaconazole, cyproconazole, triadimenol and bitertanol; the weight ratio of the active ingredient A to the active ingredient B is (1%-60%): (1%-60%). The active ingredients are added with aids and excipients to be prepared into wettable powder, water dispersible granules, a suspension agent or a suspension emulsion. The composition is used for preventing and controlling powdery mildew, alternaria leaf spot, scab, leaf spot disease, anthracnose, rust disease, epidemic disease, banded sclerotial blight and rice blast of crops, is resistant to rainwash, and has a remarkable synergistic effect.
Description
The application is divisional application, the patent application " a kind of composition pesticide that contains pyraclostrobin and triazole type " that original application is Shanxi Thompson Biological Technology Co., Ltd., and the application number of original application is ︰ 201110066540.6, and original application day is 2011.03.19.
Technical field
The invention belongs to technical field of pesticide, relate to the application of a kind of composition pesticide that contains pyraclostrobin and triazole type in crop pest.
Technical background
Pyraclostrobin (pyraclostrobin), molecular formula: C
20h
23n
3o
2, chemical name: methyl (N)-[[[1-(4-chlorobenzene) pyrazoles-3 base)-oxygen]-0-methoxyl group]-N-methoxymethyl carbamate.
Pyraclostrobin is the bactericide of BASF AG's latest model methoxy acrylic.Sterling is that white is to the tasteless crystalline solid of oldlace.The mechanism of action is mitochondrial respiratory inhibitor.Make mitochondria can not produce and provide cell eubolism institute energy requirement, finally cause cell death.It can control most of diseases such as Ascomycetes, Basidiomycetes, deuteromycetes, Oomycete.Growth to spore germination and leaf intramatrical mycelium has very strong inhibitory action, has protection and therapeutic activity.Have permeability and local systemic activity, the lasting period is long, resistance of rainwater washing against.Be widely used in preventing and treating the disease on wheat, paddy rice, peanut, grape, vegetables, potato, banana, lemon, coffee, fruit tree, walnut, tea tree, tobacco and ornamental plants, lawn and other field crops.This compound not only toxicity is low, to non-target organism safety, and to user and all safety close friends of environment, is classified as " the candidate's medicament that reduces risk " by U.S. EPA.In addition, pyraclostrobin can be to making the positive physiological regulatory action of deposits yields, and the generation of its energy ethene suppressing can help crop to have longer time deposit bio-energy to guarantee maturity like this; The activity that can significantly improve the restore nitrification enzyme of crop, means the use that can reduce Nitrogen In Soils fertilizer, thereby further reduces the impact on underground water; In the time that crop is subject to viral attack, the formation that it can accelerate to resist albumen--identical to the synthesis of degeneration-resistant albumen with crop self salicylic acid synthetic.Pyraclostrobin is the efficient mitochondrial respiratory inhibitor after improving on kresoxim-methyl basis, is to have replaced the o-methyl-phenyl-in kresoxim-methyl molecular structure with N-rubigan pyrazolyl, and the another methoxy acrylic wide-spectrum bactericide of exploitation.Its activity is higher, is current 3 times with series bactericidal agent.And kresoxim-methyl just has the report occurring about wheat powdery mildew resistance for 1 year afterwards in practical application, to 2000 resistance spore (2%-99%) in German the north, the existing a large amount of report in the north and Britain of France.At present the existing institute of the preventive effect of powdery mildew is declined at home.
No matter be pyraclostrobin, effective active composition B or other efficient germicides, long-term use separately, easily makes disease develop immunity to drugs, and causes the problems such as dosage increasing, preventive effect reduction, lasting period shortening, is unfavorable for environment sustainable development.The active ingredient of the different mechanisms of action is carried out composite, is to delay the disease conventional method that develops immunity to drugs, and according to the effect in production application, judge this composite be synergistic effect or antagonism.Complex role is significantly filled a prescription, and can obviously improve preventive effect, greatly reduces the dosage of agricultural chemicals, also can expand fungicidal spectrum, improves germicidal efficiency, alleviates the pollution to environment.Pyraclostrobin is different from the effective active composition B mechanism of action, mutually composite have good synergistic effect within the specific limits, and relevant composite about Tebuconazole, alkene azoles alcohol, Flutriafol, own azoles alcohol, cyproconazole, Triadimenol, bitertanol, there is not yet relevant report at present at home and abroad.
Summary of the invention
The object of the invention is to propose a kind of have synergistic effect, use cost is low, preventive effect the is good bactericidal composition that contains pyraclostrobin and effective active composition B.
The present invention is achieved through the following technical solutions:
A kind of composition pesticide that contains pyraclostrobin and triazole type, it is characterized in that: the percentage by weight of A, two kinds of active components of B is 1～80% ︰ 1～80%, described active component A is pyraclostrobin, and active component B is selected from the one in Tebuconazole, alkene azoles alcohol, Flutriafol, own azoles alcohol, cyproconazole, Triadimenol, bitertanol.
Described own azoles alcohol (hexaconazole), molecular formula is C
14h
17cl
2x
3o, chemical name: (RS)-2-(2,4-dichlorophenyl)-1-(1H-1,2,4-triazol-1-yl)-oneself-2-alcohol.
Described Tebuconazole (tebuconazole), molecular formula is C
16h
22oN
3cl, chemical name: p-chlorphenyl-4 of (RS)-1-, 4-dimethyl-3 (1H-1,2,4-triazol-1-yl methyl) amylalcohol.
Described Flutriafol (flutriafol), molecular formula is C16H13F2N30, chemical name: α-(2-fluorophenyl)-α-(4-fluorophenyl)-1H-1,2,4-triazole-1-ethanol.
Described alkene azoles alcohol (diniconazole), molecular formula is C
15h
17cl
2n
3o, chemical name: (E)-(RS)-1-(2,4-dichlorophenyl)-4,4-dimethyl-2-(1,2,4-triazol-1-yl)-1-POL.
Described Triadimenol (triadimenol), molecular formula is C
14h
18clN
3o
2, chemical name: 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1H-1,2,4 triazole-1 bases) butyl-2-alcohol.
Described cyproconazole (Cyproconazole), molecular formula: C
15h
18clN
3o, chemical name: 2-(4-chlorphenyl)-3-cyclopropyl-1-(1H-1,2,4-triazol-1-yl) fourth-2-alcohol.
Described bitertanol (bitertanol), molecular formula: C
20h
23n
3o
2, chemical name: 1-(biphenyl-4-base oxygen)-1-(1H-1,2,4-triazol-1-yl) 3,3-dimethyl butyrate-2-alcohol.
The described pyraclostrobin bactericidal composition that contains, is characterized in that: wherein the percentage by weight of pyraclostrobin and effective active composition B is 5～60% ︰ 5～60%.
The described bactericidal composition that contains pyraclostrobin, is characterized in that: the percentage by weight of pyraclostrobin and Tebuconazole is 10～40% ︰ 10～40%;
The percentage by weight of pyraclostrobin and alkene azoles alcohol is 10～40% ︰ 10～40%;
The percentage by weight of pyraclostrobin and Flutriafol is 10～40% ︰ 10～40%;
The percentage by weight of pyraclostrobin and own azoles alcohol is 10～40% ︰ 10～40%;
The percentage by weight of pyraclostrobin and cyproconazole is 10～40% ︰ 10～40%;
The percentage by weight of pyraclostrobin and Triadimenol is 10～40% ︰ 10～40%;
The percentage by weight of pyraclostrobin and bitertanol is 10～40% ︰ 10～40%.
The described bactericidal composition that contains pyraclostrobin, wherein effective active component content accounts for 1～95% of gross weight, is preferably 20～80%.
The described bactericidal composition that contains pyraclostrobin is made wetting powder, water dispersible granules, suspending agent or suspension emulsion.
Described dispersant is selected from alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, polyoxyethylene carboxylate, one or more during ester polyoxyethylene is phonetic.
Described wetting agent is selected from: lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, tea are withered, one or more in silkworm excrement, soapberry powder.
Described disintegrant is selected from: one or more in sodium bicarbonate, sodium carbonate, bentonite, urea, ammonium sulfate, aluminium chloride.
Described binding agent is selected from: one or more in gelatin, melon glue, gum Arabic, xanthans, sodium phosphate trimer, phenolic resins, sodium alginate, white dextrin, methylcellulose, PAA, polyvinylpyrrolidone, crospolyvinylpyrrolidone, polyethylene glycol, polyvinyl alcohol.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, diethylene glycol (DEG), triethylene glycol, polyethylene glycol.
Described defoamer is selected from: silicone, C
8～10aliphatic alcohols, C
10～20one or more in saturated fat acids (as capric acid) and acid amides, silicone oil, silicone compound.
Described emulsifier is selected from: agriculture breast 500#(alkyl benzene calcium sulfonate), OP series phosphate (polyoxyethylene nonylphenol ether phosphate), 600# phosphate (phenyl phenol polyoxy ethyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, agriculture breast 400#(benzyl dimethyl phenol polyoxy ethyl ether), agriculture breast 600#(phenyl phenol polyoxy ethyl ether), Nongru-700 #(alkylphenol-formaldehyde resin polyoxy ethyl ether), agriculture breast 36#(phenethyl fluosite polyoxy ethyl ether), agriculture breast 1600#(phenethyl phenol polyoxy ethyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, OP series (polyoxyethylene nonylphenol ether), By series (castor oil polyoxyethylene ether), agriculture breast 33#(alkylaryl polyoxyethylene polyoxypropylene ether), agriculture breast 34#(alkylaryl polyoxyethylene poly-oxygen propylene aether), sapn series (sorbitan monostearate), tween series (sorbitan fatty acid ester APEO), one or more in AEO series (fat alcohol alcohol APEO).
Described stabilizing agent is selected from: one or more in BHT, triphenyl phosphite, epoxychloropropane, tributyl phosphate, triethanolamine, diethanol amine, monoethanolamine.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
Composition of the present invention can be by user before use through dilution or directly use.Its preparation can be prepared by common processing method, after mixing, then adds surfactant as one or more in dispersant, wetting agent, disintegrant, emulsifier, adhesive, defoamer, stabilizing agent etc. by active substance with liquid flux or solid carrier.
Beneficial effect of the present invention: (1) present composition effective active composition pyraclostrobin and effective active composition B belong to the bactericide of two kinds of different mechanisms of action, and both mutual mixtures can not produce conflict; (2) present composition has good synergistic effect within the specific limits, and preventive effect is higher than single dose, and dosage is little; (3) the present invention not with an organic solvent, is difficult for producing poisoning, is convenient to transport and storage; (4) present composition has expanded fungicidal spectrum, and the diseases such as crop powdery mildew, spot defoliation, scab, leaf spot, anthracnose, rust, epidemic disease, banded sclerotial blight, rice blast are all had to special efficacy.
Embodiment
Below in conjunction with embodiment, to further instruction of the present invention, the percentage in embodiment is all weight percentage, but the present invention is not limited thereto.
The embodiment of the present invention is the method that adopts Toxicity Determination and field trial to combine.
Application Example one
Example 1 60% pyraclostrobin Tebuconazole wetting powder
Pyraclostrobin 10%, Tebuconazole 50%, alkylphenol-polyethenoxy are phonetic 6%, lauryl sodium sulfate 7%, kaolin add to 100%, and mixture carries out air-flow crushing, makes 60% pyraclostrobin Tebuconazole wetting powder.
Example 2 65% pyraclostrobin Tebuconazole wetting powders
Pyraclostrobin 40%, Tebuconazole 25%, wetting and penetrating agent F 5%, aliphatic amine polyoxyethylene are phonetic 8%, diatomite adds to 100%, and mixture carries out air-flow crushing, makes 65% pyraclostrobin Tebuconazole wetting powder.
Example 3 50% pyraclostrobin tebuconazole water dispersible granules
Pyraclostrobin 25%, Tebuconazole 25%, lignosulfonates 7%, Nekal BX 5%, ammonium sulfate 2%, bentonite add to 100%, mix and make 50% pyraclostrobin tebuconazole water dispersible granule.
Example 4 60% pyraclostrobin tebuconazole water dispersible granules
Pyraclostrobin 12%, Tebuconazole 48%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8%, spaonin powder 6%, precipitated calcium carbonate add to 100%, mix and make 60% pyraclostrobin tebuconazole water dispersible granule.
Example 5 20% pyraclostrobin tebuconazole suspension concentrates
Pyraclostrobin 10%, Tebuconazole 10%, octylphenol polyethylene oxyethylene group ether sulfate 6%, soapberry powder 5%, silicone compound 0.2%, polyvinyl alcohol 1.3%, ethylene glycol 1.8%, deionized water add to 100%, mix and make 20% pyraclostrobin tebuconazole suspension concentrates.
Example 6 45% pyraclostrobin tebuconazole suspension concentrates
Pyraclostrobin 5%, Tebuconazole 40%, aryl phenol polyoxyethylene succinate sulfonate 7%, tea are withered 5%, C
10～20saturated fat acids 0.3%, methylcellulose 1.4%, triethylene glycol 1.1%, deionized water add to 100%, mix and make 45% pyraclostrobin tebuconazole suspension concentrates.
Example 7 30% pyraclostrobin Tebuconazole suspension emulsions
Pyraclostrobin 10%, Tebuconazole 20%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 8%, lauryl sodium sulfate 6%, silicone oil 0.4%, sodium phosphate trimer 1.5%, tween series 6%, diethylene glycol (DEG) 1.2%, water add to 100%, aforementioned formula material is mixed, make 30% pyraclostrobin Tebuconazole suspension emulsion.
Example 8 36% pyraclostrobin Tebuconazole suspension emulsions
Pyraclostrobin 26%, Tebuconazole 10%, the phonetic formaldehyde condensation products sulphate 6% of alkylphenol-polyethenoxy, spaonin powder 5%, silicone compound 0.3%, xanthans 1.2%, agriculture breast 600#7%, glycerine 1.8%, water add to 100%, aforementioned formula material is mixed, make 36% pyraclostrobin Tebuconazole suspension emulsion.
Example 9 65% pyraclostrobin alkene azoles alcohol wetting powders
Pyraclostrobin 25%, alkene azoles alcohol 40%, polyoxyethylene carboxylate 8%, soapberry powder 6%, bentonite add to 100%, and mixture carries out air-flow crushing, make 65% pyraclostrobin alkene azoles alcohol wetting powder.
Example 10 70% pyraclostrobin alkene azoles alcohol wetting powders
Pyraclostrobin 20%, alkene azoles alcohol 50%, alkyl benzene sulfonate calcium salt 7%, lauryl sodium sulfate 7%, white carbon add to 100%, and mixture carries out air-flow crushing, make 70% pyraclostrobin alkene azoles alcohol wetting powder.
Example 11 62% pyraclostrobin diniconazole water dispersible granules
Pyraclostrobin 12%, alkene azoles alcohol 50%, naphthalene sulfonic acid-formaldehyde condensation product 6%, wetting and penetrating agent F 5%, sodium carbonate 1.5%, bentonite add to 100%, mix and make 62% pyraclostrobin diniconazole water dispersible granule.
Example 12 55% pyraclostrobin diniconazole water dispersible granules
Pyraclostrobin 40%, alkene azoles alcohol 15%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 5%, Nekal BX 6%, bentonite add to 100%, mix and make 55% pyraclostrobin diniconazole water dispersible granule.
Example 13 10% pyraclostrobin diniconazole suspending agents
Pyraclostrobin 5%, alkene azoles alcohol 5%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, spaonin powder 5%, C
8～10aliphatic alcohols 0.2%, PAA 1.5%, glycerine 2%, deionized water add to 100%, mix and make 10% pyraclostrobin diniconazole suspending agent.
Example 14 42% pyraclostrobin diniconazole suspending agents
Pyraclostrobin 12%, alkene azoles alcohol 30%, polycarboxylate 8%, neopelex 6%, silicone compound 0.5%, xanthans 1%, triethylene glycol 1.5%, deionized water add to 100%, mix and make 42% pyraclostrobin diniconazole suspending agent.
Example 15 25% pyraclostrobin alkene azoles alcohol suspension emulsions
Pyraclostrobin 20%, alkene azoles alcohol 5%, ester polyoxyethylene are phonetic 6%, lauryl sodium sulfate 5%, C
10～20saturated fat acids 0.4%, methylcellulose 1%, agriculture breast 1600#8%, polyethylene glycol 2%, water add to 100%, and aforementioned formula material is mixed, and make 25% pyraclostrobin alkene azoles alcohol suspension emulsion.
Example 16 35% pyraclostrobin alkene azoles alcohol suspension emulsions
Pyraclostrobin 5%, alkene azoles alcohol 30%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%, wetting and penetrating agent F 6%, silicone oil 0.2%, sodium phosphate trimer 1.5%, agriculture breast 600# 5%, diethylene glycol (DEG) 1.5%, water add to 100%, aforementioned formula material is mixed, make 35% pyraclostrobin alkene azoles alcohol suspension emulsion.
Example 17 62% pyraclostrobin Flutriafol wetting powders
Pyraclostrobin 12%, Flutriafol 50%, naphthalene sulfonic acid-formaldehyde condensation product 8%, spaonin powder 6%, attapulgite add to 100%, and mixture carries out air-flow crushing, make 62% pyraclostrobin Flutriafol wetting powder.
Example 18 58% pyraclostrobin Flutriafol wetting powders
Pyraclostrobin 40%, Flutriafol 18%, lignosulfonates 6%, Nekal BX 4%, diatomite add to 100%, and mixture carries out air-flow crushing, make 58% pyraclostrobin Flutriafol wetting powder.
Example 19 70% pyraclostrobin Flutriafol water dispersible granules
Pyraclostrobin 10%, Flutriafol 60%, aliphatic amine polyoxyethylene are phonetic 7%, neopelex 6%, bentonite add to 100%, mix and make 70% pyraclostrobin Flutriafol water dispersible granules.
Example 20 60% pyraclostrobin Flutriafol water dispersible granules
Pyraclostrobin 20%, Flutriafol 40%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 8%, silkworm excrement 7%, aluminium chloride 1.2%, kaolin add to 100%, mix and make 60% pyraclostrobin Flutriafol water dispersible granules.
Example 21 30% pyraclostrobin Flutriafol suspending agents
Pyraclostrobin 15%, Flutriafol 15%, alkyl benzene sulfonate calcium salt 6%, wetting and penetrating agent F 5%, silicone oil 0.4%, sodium alginate 1.2%, propane diols 1.8%, deionized water add to 100%, mix and make 30% pyraclostrobin Flutriafol suspending agent.
Example 22 36% pyraclostrobin Flutriafol suspending agents
Pyraclostrobin 6%, Flutriafol 30%, alkylphenol-polyethenoxy are phonetic 7%, soapberry powder 5%, C
10～20saturated fat acids 0.2%, gum Arabic 1%, triethylene glycol 1.5%, deionized water add to 100%, mix and make 36% pyraclostrobin Flutriafol suspending agent.
Example 23 20% pyraclostrobin Flutriafol suspension emulsions
Pyraclostrobin 10%, Flutriafol 10%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 6%, spaonin powder 6%, sodium phosphate trimer 1.2%, agriculture breast 34# 6%, ethylene glycol 1.4%, C
8～10aliphatic alcohols 0.2%, water add to 100%, make 20% pyraclostrobin Flutriafol suspension emulsion through mixing.
Example 24 32% pyraclostrobin Flutriafol suspension emulsions
Pyraclostrobin 24%, Flutriafol 8%, the phonetic formaldehyde condensation products sulphate 8% of alkylphenol-polyethenoxy, Nekal BX 6%, polyvinylpyrrolidone 2%, OP series phosphate 8%, polyethylene glycol 2%, silicone compound 0.2%, water add to 100%, make 32% pyraclostrobin Flutriafol suspension emulsion through mixing.
Embodiment 25 40% pyraclostrobin hexaconazole microemulsions
By pyraclostrobin 35%, own azoles alcohol 5%, ethylene glycol 4%, polyvinyl alcohol 2%, nonionic EO-PO block copolymer 8%, alkylbenzenesulfonate 3%, silicone oil 0.4%, deionized water supplies 100%, makes 40% pyraclostrobin hexaconazole microemulsion.
Embodiment 26 30% pyraclostrobin hexaconazole microemulsions
By pyraclostrobin 20%, own azoles alcohol 10%, tween 4%, alkylbenzenesulfonate 3%, phenethyl phenol polyethenoxy ether phosphate 5%, xanthans 2%, propane diols 3%, silicone oil 0.4%, deionized water is supplied 100%, 30% pyraclostrobin hexaconazole microemulsion.
Example 27 55% pyraclostrobin diniconazole water dispersible granules
Pyraclostrobin 40%, own azoles alcohol 15%, octylphenol polyethylene oxyethylene group ether sulfate 6%, lauryl sodium sulfate 5%, bentonite add to 100%, mix and make 55% pyraclostrobin diniconazole water dispersible granule.
Example 28 58% pyraclostrobin diniconazole water dispersible granules
Pyraclostrobin 8%, own azoles alcohol 50%, polycarboxylate 8%, Nekal BX 6%, sodium bicarbonate 2%, starch add to 100%, mix and make 58% pyraclostrobin diniconazole water dispersible granule.
Example 29 24% pyraclostrobin hexaconazole suspending agents
Pyraclostrobin 12%, own azoles alcohol 12%, polyoxyethylene carboxylate 7%, wetting and penetrating agent F 6%, C
8～10aliphatic alcohols 0.5%, xanthans 1.3%, polyethylene glycol 1.6%, deionized water add to 100%, mix and make 24% pyraclostrobin hexaconazole suspending agent.
Example 30 40% pyraclostrobin hexaconazole suspending agents
Pyraclostrobin 8%, own azoles alcohol 32%, naphthalene sulfonic acid-formaldehyde condensation product 8%, soapberry powder 6%, silicone oil 0.2%, sodium alginate 1.4%, diethylene glycol (DEG) 1.9%, deionized water add to 100%, mix and make 40% pyraclostrobin hexaconazole suspending agent.
The own azoles alcohol of example 31 18% pyraclostrobin suspension emulsion
Pyraclostrobin 2%, own azoles alcohol 16%, alkyl benzene sulfonate calcium salt 6%, lauryl sodium sulfate 5%, silicone compound 0.5%, methylcellulose 1.5%, agriculture breast 1600# 7%, triethylene glycol 2%, water add to 100%, aforementioned formula material is mixed, make the own azoles alcohol of 18% pyraclostrobin suspension emulsion.
The own azoles alcohol of example 32 35% pyraclostrobin suspension emulsion
Pyraclostrobin 20%, own azoles alcohol 15%, lignosulfonates 7%, spaonin powder 6%, C
10～20saturated fat acids 0.1%, gelatin 1.6%, agriculture breast 500# 9%, propane diols 1.5%, water add to 100%, and aforementioned formula material is mixed, and make the own azoles alcohol of 35% pyraclostrobin suspension emulsion.
Example 33 50% pyraclostrobin cyproconazole wetting powders
Pyraclostrobin 10%, cyproconazole 40%, polyoxyethylene carboxylate 6%, wetting and penetrating agent F 5%, bentonite add to 100%, and mixture carries out air-flow crushing, make 50% pyraclostrobin cyproconazole wetting powder.
Example 34 60% pyraclostrobin cyproconazole wetting powders
Pyraclostrobin 45%, cyproconazole 15%, alkylphenol-polyethenoxy are phonetic 8%, lauryl sodium sulfate 7%, attapulgite add to 100%, and mixture carries out air-flow crushing, makes 60% pyraclostrobin cyproconazole wetting powder.
Example 35 52% pyraclostrobin cyproconazole water dispersible granules
Pyraclostrobin 40%, cyproconazole 12%, alkyl benzene sulfonate calcium salt 7%, spaonin powder 5%, bentonite add to 100%, mix and make 52% pyraclostrobin cyproconazole water dispersible granules.
Example 36 64% pyraclostrobin cyproconazole water dispersible granules
Pyraclostrobin 50%, cyproconazole 14%, lignosulfonates 6%, soapberry powder 4%, ammonium sulfate 3%, kaolin add to 100%, mix and make 64% pyraclostrobin cyproconazole water dispersible granules.
Example 37 20% pyraclostrobin cyproconazole suspending agents
Pyraclostrobin 15%, cyproconazole 5%, octylphenol polyethylene oxyethylene group ether sulfate 8%, lauryl sodium sulfate 6%, C
10～20saturated fat acids 0.4%, phenolic resins 1.3%, triethylene glycol 2.1%, deionized water add to 100%, mix and make 20% pyraclostrobin cyproconazole suspending agent.
Example 38 34% pyraclostrobin cyproconazole suspending agents
Pyraclostrobin 17%, cyproconazole 17%, polycarboxylate 7%, wetting and penetrating agent F 6%, silicone oil 0.3%, sodium phosphate trimer 1.1%, ethylene glycol 1.6%, deionized water add to 100%, mix and make 34% pyraclostrobin cyproconazole suspending agent.
Example 39 30% pyraclostrobin cyproconazole suspension emulsions
Pyraclostrobin 5%, cyproconazole 25%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 7%, wetting and penetrating agent F 6%, silicone compound 0.3%, methylcellulose 1.8%, tween series 8%, propane diols 2%, water add to 100%, aforementioned formula material is mixed, make 30% pyraclostrobin cyproconazole suspension emulsion.
Example 40 40% pyraclostrobin cyproconazole suspension emulsions
Pyraclostrobin 10%, cyproconazole 30%, alkylphenol-polyethenoxy are phonetic 8%, tea is withered 6%, C
8～10aliphatic alcohols 0.2%, xanthans 1.9%, agriculture breast 400#8%, diethylene glycol (DEG) 1.2%, water add to 100%, and aforementioned formula material is mixed, and make 40% pyraclostrobin cyproconazole suspension emulsion.
Example 41 63% pyraclostrobin Triadimenol wetting powders
Pyraclostrobin 9%, Triadimenol 54%, alkyl benzene sulfonate calcium salt 8%, spaonin powder 7%, diatomite add to 100%, and mixture carries out air-flow crushing, make 63% pyraclostrobin Triadimenol wetting powder.
Example 42 65% pyraclostrobin Triadimenol wetting powders
Pyraclostrobin 15%, Triadimenol 50%, polycarboxylate 7%, lauryl sodium sulfate 6%, attapulgite add to 100%, and mixture carries out air-flow crushing, make 65% pyraclostrobin Triadimenol wetting powder.
Example 43 50% pyraclostrobin triadimenol water dispersion granules
Pyraclostrobin 40%, Triadimenol 10%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%, soapberry powder 6%, sodium carbonate 1.8%, kaolin add to 100%, mix and make 50% pyraclostrobin triadimenol water dispersion granules.
Example 44 60% pyraclostrobin triadimenol water dispersion granules
Pyraclostrobin 20%, Triadimenol 40%, alkyl benzene sulfonate calcium salt 6%, tea are withered 4%, bentonite adds to 100%, mix and make 60% pyraclostrobin triadimenol water dispersion granules.
Example 45 24% pyraclostrobin Triadimenol suspending agents
Pyraclostrobin 6%, Triadimenol 18%, aliphatic amine polyoxyethylene are phonetic 8%, neopelex 7%, gum Arabic 1.5%, silicone compound 0.4%, glycerine 1.2%, deionized water adds to 100%, mixes and makes 24% pyraclostrobin Triadimenol suspending agent.
Example 46 40% pyraclostrobin Triadimenol suspending agents
Pyraclostrobin 20%, Triadimenol 20%, lignosulfonates 6%, tea are withered 4%, C
8～10aliphatic alcohols 0.1%, methylcellulose 1.3%, diethylene glycol (DEG) 1.5%, deionized water adds to 100%, mixes and makes 40% pyraclostrobin Triadimenol suspending agent.
Example 47 20% pyraclostrobin Triadimenol suspension emulsions
Pyraclostrobin 10%, Triadimenol 10%, aryl phenol polyoxyethylene succinate sulfonate 7%, wetting and penetrating agent F 6%, sodium phosphate trimer 1.2%, polyethylene glycol 1.6%, C
10～20saturated fat acids 0.4%, 600# phosphate 6%, water add to 100%, mix and make 20% pyraclostrobin Triadimenol suspension emulsion.
Example 48 28% pyraclostrobin Triadimenol suspension emulsions
Pyraclostrobin 21%, Triadimenol 7%, polyoxyethylene carboxylate 6%, soapberry powder 6%, sodium alginate 1.3%, ethylene glycol 1.4%, silicone oil 0.6%, Nongru-700 # 9%, water add to 100%, mix and make 28% pyraclostrobin Triadimenol suspension emulsion.
Example 49 55% pyraclostrobin bitertanol wetting powders
Pyraclostrobin 15%, bitertanol 40%, lignosulfonates 7%, Nekal BX 6%, kaolin add to 100%, and mixture carries out air-flow crushing, make 55% pyraclostrobin bitertanol wetting powder.
Example 50 62% pyraclostrobin bitertanol wetting powders
Pyraclostrobin 45%, bitertanol 17%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8%, silkworm excrement 7%, diatomite add to 100%, and mixture carries out air-flow crushing, make 62% pyraclostrobin bitertanol wetting powder.
Example 51 60% pyraclostrobin bitertanol water dispersible granules
Pyraclostrobin 10%, bitertanol 50%, alkylphenol-polyethenoxy are phonetic 8%, neopelex 6%, aluminium chloride 1.6%, attapulgite add to 100%, mix and make 60% pyraclostrobin bitertanol water dispersible granules.
Example 52 56% pyraclostrobin bitertanol water dispersible granules
Pyraclostrobin 48%, bitertanol 8%, alkyl benzene sulfonate calcium salt 7%, spaonin powder 6%, bentonite add to 100%, mix and make 56% pyraclostrobin bitertanol water dispersible granules.
Example 53 30% pyraclostrobin bitertanol suspending agents
Pyraclostrobin 15%, bitertanol 15%, polyoxyethylene carboxylate 6%, soapberry powder 5%, silicone oil 0.5%, white dextrin 1.3%, propane diols 1.7%, deionized water add to 100%, mix and make 30% pyraclostrobin bitertanol suspending agent.
Example 54 32% pyraclostrobin bitertanol suspending agents
Pyraclostrobin 10%, bitertanol 22%, lignosulfonates 7%, wetting and penetrating agent F 6%, C
10～20saturated fat acids 0.4%, PAA 1.2%, ethylene glycol 1.5%, deionized water add to 100%, mix and make 32% pyraclostrobin bitertanol suspending agent.
Example 55 16% pyraclostrobin bitertanol suspension emulsions
Pyraclostrobin 4%, bitertanol 12%, alkyl benzene sulfonate calcium salt 6%, lauryl sodium sulfate 5%, silicone oil 0.3%, gelatin 1.3%, agriculture breast 500# 8%, glycerine 1.4%, water add to 100%, aforementioned formula material is mixed, make 16% pyraclostrobin bitertanol suspension emulsion.
Example 56 40% pyraclostrobin bitertanol suspension emulsions
Pyraclostrobin 30%, bitertanol 10%, polycarboxylate 8%, soapberry powder 6%, silicone compound 0.2%, white dextrin 1.5%, agriculture breast 500# 6%, diethylene glycol (DEG) 1.1%, water add to 100%, aforementioned formula material is mixed, make 40% pyraclostrobin bitertanol suspension emulsion.
The embodiment of the present invention is the method that adopts Toxicity Determination and field trial to combine.The embodiment of the present invention is the method that adopts Toxicity Determination and field trial to combine.First by Toxicity Determination, the synergy ratio (SR) after clear and definite two kinds of medicaments are composite by a certain percentage, SR < 0.5 is antagonism, 0.5≤SR≤1.5 are summation action, SR > 1.5 is synergistic effect, on this basis, then carries out field trial.
Pyraclostrobin and active component B(B are selected from the one in Tebuconazole, alkene azoles alcohol, Flutriafol, own azoles alcohol, cyproconazole, Triadimenol, bitertanol) composite to crop pest Toxicity Determination.
After the effective inhibition concentration scope of each medicament is determined in prerun, each medicament is established respectively 5 dosage processing by active constituent content, establishes clear water contrast.Carry out with reference to " farm-chemical indoor determination test rule bactericide ", adopt mycelial growth rate method to measure the virulence of medicament to crop germ.After 72h, measure colony diameter by right-angled intersection method, calculate each processing net growth, mycelial growth inhibition rate.
Net growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), and liquor strength (μ g/mL) converts logarithm value to (x), tries to achieve virulence regression equation (y=a+bx) with method of least squares, and calculates thus the EC of every kind of medicament
50value.Calculate the different proportioning synergy ratios of two medicaments (SR) according to Wadley method, SR < 0.5 is antagonism simultaneously, and 0.5≤SR≤1.5 are summation action, and SR > 1.5 is synergistic effect.Computing formula is as follows:
Wherein: a, b are respectively active component pyraclostrobin and active component B(Tebuconazole, alkene azoles alcohol, Flutriafol, own azoles alcohol, cyproconazole, Triadimenol, bitertanol) shared ratio in combination;
A is pyraclostrobin;
B is the one in Tebuconazole, alkene azoles alcohol, Flutriafol, own azoles alcohol, cyproconazole, Triadimenol, bitertanol.
Implementation of an application example two:
Pyraclostrobin and Tebuconazole are composite to alternaria leaf spot of apple Toxicity Determination.
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective inhibition concentration scope of determining pyraclostrobin, Original Tebuconazole and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 1 pyraclostrobin, Tebuconazole and the composite toxicity test analysis of results table to alternaria leaf spot of apple thereof
As shown in Table 1, pyraclostrobin, the EC of Tebuconazole to alternaria leaf spot of apple
50be respectively 0.86mg/L and 0.95mg/L.Pyraclostrobin and Tebuconazole proportioning are in the time of 80:1 to 1:80, synergy ratio SR is all greater than 1.5, illustrate that pyraclostrobin and Tebuconazole mixture in 80:1 to 1:80 scope all shows synergistic effect, especially when the two proportioning is during at 8:1 to 1:8, synergistic effect is more obviously outstanding, wherein synergy ratio SR maximum in the time that pyraclostrobin and Tebuconazole percentage by weight are 1:1, synergistic effect is the most obvious.
Implementation of an application example three
Pyraclostrobin and alkene azoles alcohol are composite to wheat rust Toxicity Determination.
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective inhibition concentration scope of determining pyraclostrobin, the former medicine of alkene azoles alcohol and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 2 pyraclostrobin, alkene azoles alcohol and the composite toxicity test analysis of results table to wheat rust thereof
As shown in Table 2, pyraclostrobin, the EC of alkene azoles alcohol to wheat rust
50be respectively 0.82mg/L and 0.53mg/L.Pyraclostrobin and alkene azoles alcohol proportioning are in the time of 80:1 to 1:80, synergy ratio SR is all greater than 1.5, illustrate that pyraclostrobin and alkene azoles alcohol mixture in 80:1 to 1:80 scope all show synergistic effect, especially when the two proportioning is during at 8:1 to 1:8, synergistic effect is more obviously outstanding, wherein synergy ratio SR maximum in the time that pyraclostrobin and alkene azoles alcohol percentage by weight are 1:1, synergistic effect is the most obvious.
Implementation of an application example four
Pyraclostrobin and Flutriafol are composite to powdery mildew of cucumber Toxicity Determination.
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective inhibition concentration scope of determining pyraclostrobin, the former medicine of Flutriafol and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 3 pyraclostrobin, Flutriafol and the composite toxicity test analysis of results table to powdery mildew of cucumber thereof
As shown in Table 3, pyraclostrobin, the EC of Flutriafol to powdery mildew of cucumber
50be respectively 0.85mg/L and 0.52mg/L.Pyraclostrobin and Flutriafol proportioning are in the time of 80:1 to 1:80, synergy ratio SR is all greater than 1.5, illustrate that pyraclostrobin and Flutriafol mixture in 80:1 to 1:80 scope all shows synergistic effect, especially when the two proportioning is during at 8:1 to 1:8, synergistic effect is more obviously outstanding, wherein synergy ratio SR maximum in the time that pyraclostrobin and Flutriafol percentage by weight are 1:1, synergistic effect is the most obvious.
Implementation of an application example five:
Pyraclostrobin and own azoles alcohol are composite to rice sheath blight disease Toxicity Determination.
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective inhibition concentration scope of determining pyraclostrobin, the former medicine of own azoles alcohol and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 4 pyraclostrobin, own azoles alcohol and the composite toxicity test analysis of results table to rice sheath blight disease thereof
As shown in Table 4, pyraclostrobin, the EC of own azoles alcohol to rice sheath blight disease
50be respectively 0.84mg/L and 0.62mg/L.Pyraclostrobin and own azoles alcohol proportioning are in the time of 80:1 to 1:80, synergy ratio SR is all greater than 1.5, illustrate that pyraclostrobin and own azoles alcohol mixture in 80:1 to 1:80 scope all show synergistic effect, wherein synergy ratio SR maximum in the time that pyraclostrobin and own azoles alcohol percentage by weight are 1:1, synergistic effect is the most obvious.
Implementation of an application example six
Pyraclostrobin and cyproconazole are composite to apple mildew Toxicity Determination.
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective inhibition concentration scope of determining pyraclostrobin, the former medicine of cyproconazole and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 5 pyraclostrobin, cyproconazole and the composite toxicity test analysis of results table to apple mildew thereof
As shown in Table 5, pyraclostrobin, the EC of cyproconazole to apple mildew
50be respectively 0.96mg/L and 0.87mg/L.Pyraclostrobin and cyproconazole proportioning are in the time of 80:1 to 1:80, synergy ratio SR is all greater than 1.5, illustrate that pyraclostrobin and cyproconazole mixture in 80:1 to 1:80 scope all shows synergistic effect, wherein synergy ratio SR maximum in the time that pyraclostrobin and cyproconazole percentage by weight are 1:1, synergistic effect is the most obvious.
Implementation of an application example seven
Pyraclostrobin and Triadimenol are composite to rice blast Toxicity Determination.
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective inhibition concentration scope of determining pyraclostrobin, the former medicine of Triadimenol and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 6 pyraclostrobin, Triadimenol and the composite toxicity test analysis of results table to wheat powdery mildew thereof
As shown in Table 6, pyraclostrobin, the EC of Triadimenol to wheat powdery mildew
50be respectively 1.02mg/L and 1.03mg/L.Pyraclostrobin and Triadimenol proportioning are in the time of 80:1 to 1:80, synergy ratio SR is all greater than 1.5, illustrate that pyraclostrobin and Triadimenol mixture in 80:1 to 1:80 scope all shows synergistic effect, wherein synergy ratio SR maximum in the time that pyraclostrobin and Triadimenol percentage by weight are 1:1, synergistic effect is the most obvious.
Implementation of an application example eight:
Pyraclostrobin and bitertanol are composite to toxicity test in powdery mildew of cucumber.
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective inhibition concentration scope of determining pyraclostrobin, the former medicine of bitertanol and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 7 pyraclostrobin, bitertanol and the composite toxicity test analysis of results table to powdery mildew of cucumber thereof
As shown in Table 7, pyraclostrobin, the EC of bitertanol to powdery mildew of cucumber
50be respectively 0.86mg/L and 0.92mg/L.Pyraclostrobin and bitertanol proportioning are in the time of 80:1 to 1:80, synergy ratio SR is all greater than 1.5, illustrate that pyraclostrobin and bitertanol mixture in 80:1 to 1:80 scope all shows synergistic effect, especially when the two proportioning is during at 8:1 to 1:8, synergistic effect is more obviously outstanding, wherein synergy ratio SR maximum in the time that pyraclostrobin and bitertanol percentage by weight are 1:1, synergistic effect is the most obvious.
Application Example nine pyraclostrobins and Tebuconazole and composite control alternaria leaf spot of apple thereof
The test of pesticide effectiveness
This experimental establishment is in Liquan County, Xianyang, Shanxi province city, and test medicine is provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 25% pyraclostrobin missible oil (commercial), 25% Tebuconazole wetting powder (commercial).
The investigation alternaria leaf spot of apple state of an illness before medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in every 10 days once, is total to dispenser 2 times.Within after dispenser 7 days, 14 days for the second time, investigate respectively disease index and calculate preventive effect.Experimental result is as follows:
Table 8 pyraclostrobin, Tebuconazole and the composite control alternaria leaf spot of apple test of pesticide effectiveness thereof
As can be seen from Table 8, after pyraclostrobin and Tebuconazole are composite, can effectively prevent and treat alternaria leaf spot of apple, control efficiency is all better than the preventive effect of single dose.In test scope of medication, target crop is had no adverse effects.
Application Example ten pyraclostrobins and alkene azoles alcohol and the composite control wheat powdery mildew test of pesticide effectiveness thereof
This experimental establishment is in Changan District, Xi'an City, Shanxi Province, and test medicine is researched and developed, provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 25% pyraclostrobin missible oil (commercial), 12.5% alkene azoles alcohol wetting powder (commercial).
Investigation wheat powdery mildew disease index before medicine, in their early stage dispenser, dispenser for the second time after 7 days, dispenser 2 times altogether, investigates disease indexs and calculates preventive effect for after dispenser 7 days, 14 days for the second time.Experimental result is as follows:
Table 9 pyraclostrobin, alkene azoles alcohol and the composite control wheat powdery mildew test of pesticide effectiveness thereof
As can be seen from Table 9, after pyraclostrobin and alkene azoles alcohol are composite, can effectively prevent and treat wheat powdery mildew, control efficiency is all better than the preventive effect of single dose.In test scope of medication, target crop is had no adverse effects.
Application Example 11 pyraclostrobins and Flutriafol and the composite wheat rust test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in Changan District, Xi'an City, Shanxi Province, and test medicine is researched and developed, provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 25% pyraclostrobin missible oil (commercial), 50% Flutriafol wetting powder (commercial).
The investigation wheat rust state of an illness before medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in every 10 days once, is total to dispenser 2 times.Within after dispenser 7 days, 14 days for the second time, investigate respectively disease index and calculate preventive effect.Experimental result is as follows:
Table 10 pyraclostrobin, Flutriafol and the composite wheat rust test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 10, after pyraclostrobin and Flutriafol are composite, can effectively prevent and treat wheat rust, control efficiency is all better than the preventive effect of single dose.In test scope of medication, target crop is had no adverse effects.
Application Example 12 pyraclostrobins and own azoles alcohol and the composite rice sheath blight disease test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in the suburb of Liuzhou City, Guangxi province, and test medicine is researched and developed, provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 25% pyraclostrobin missible oil (commercial), 10% hexaconazole suspending agent (commercial).
Investigation rice sheath blight disease disease index before medicine, in their early stage dispenser, dispenser for the second time after 7 days, dispenser 2 times altogether, investigates disease indexs and calculates preventive effect for after dispenser 7 days, 14 days for the second time.Experimental result is as follows:
Table 11 pyraclostrobin, own azoles alcohol and the composite rice sheath blight disease test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 11, after pyraclostrobin and own azoles alcohol are composite, can effectively prevent and treat rice sheath blight disease, control efficiency is all better than the preventive effect of single dose.In test scope of medication, target crop is had no adverse effects.
Application Example 13 pyraclostrobins and cyproconazole and the composite apple mildew test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in Liquan County, Xianyang, Shanxi province city, and test medicine is researched and developed, provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 25% pyraclostrobin missible oil (commercial), 40% cyproconazole suspending agent (commercial).
The investigation apple mildew state of an illness before medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in every 10 days once, is total to dispenser 2 times.Within after dispenser 7 days, 14 days for the second time, investigate respectively disease index and calculate preventive effect.Experimental result is as follows:
Table 12 pyraclostrobin, cyproconazole and the composite apple mildew test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 12, after pyraclostrobin and cyproconazole are composite, can effectively prevent and treat apple mildew, control efficiency is all better than the preventive effect of single dose.In test scope of medication, target crop is had no adverse effects.
Application Example 14 pyraclostrobins and Triadimenol and the composite sigatoka test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in San Jiang county of Liuzhou City of Guangdong Province, and test medicine is researched and developed, provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 25% pyraclostrobin missible oil (commercial), 10% Triadimenol wetting powder (commercial).
Investigation sigatoka disease index before medicine, in their early stage dispenser, dispenser for the second time after 10 days, dispenser 2 times altogether, investigates disease indexs and calculates preventive effect for after dispenser 7 days, 14 days for the second time.Experimental result is as follows:
Table 13 pyraclostrobin, the composite sigatoka test of pesticide effectiveness of preventing and treating of Triadimenol
As can be seen from Table 13, after pyraclostrobin and Triadimenol are composite, can effectively prevent and treat sigatoka, control efficiency is all better than the preventive effect of single dose.In test scope of medication, target crop is had no adverse effects.
Application Example 15 pyraclostrobins and bitertanol and the composite leaf spot of peanut test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in Weinan City Dali County, Shaanxi Province, and test medicine is provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 25% pyraclostrobin missible oil (commercial), 10% bitertanol water dispersible granules (commercial).
The investigation leaf spot of peanut state of an illness before medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in every 7 days once, is total to dispenser 2 times.Within after dispenser 7 days, 14 days for the second time, investigate respectively disease index and calculate preventive effect.Experimental result is as follows:
Table 14 pyraclostrobin, bitertanol and the composite leaf spot of peanut test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 14, after pyraclostrobin and bitertanol are composite, can effectively prevent and treat leaf spot of peanut, control efficiency is all better than the preventive effect of single dose.In test scope of medication, target crop is had no adverse effects.
Claims (5)
1. a composition pesticide that contains pyraclostrobin and triazole type, is characterized in that: the percentage by weight of A, two kinds of active components of B is 1～80% ︰ 1～80%, and described active component A is pyraclostrobin, and active component B is selected from Flutriafol.
2. composition pesticide according to claim 1, is characterized in that: wherein the percentage by weight of pyraclostrobin and effective active composition B is 5～60% ︰ 5～60%.
3. composition pesticide according to claim 2, is characterized in that: the percentage by weight of pyraclostrobin and Flutriafol is 10～40% ︰ 10～40%.
4. composition pesticide according to claim 1, is characterized in that: the formulation of microbicide compositions is selected from: wetting powder, water dispersible granules, suspending agent, suspension emulsion.
5. composition pesticide according to claim 1 is for preventing and treating disease common on fruit tree, vegetables and cereal crop.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310578454.2A CN103828825B (en) | 2011-03-19 | 2011-03-19 | Pesticide composition containing pyraclostrobin and triazoles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310578454.2A CN103828825B (en) | 2011-03-19 | 2011-03-19 | Pesticide composition containing pyraclostrobin and triazoles |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110066540.6A Division CN102172241B (en) | 2011-03-19 | 2011-03-19 | Pesticide composition containing pyraclostrobin and triazoles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103828825A true CN103828825A (en) | 2014-06-04 |
| CN103828825B CN103828825B (en) | 2015-02-18 |
Family
ID=50792977
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310578454.2A Active CN103828825B (en) | 2011-03-19 | 2011-03-19 | Pesticide composition containing pyraclostrobin and triazoles |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103828825B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106508950A (en) * | 2016-11-04 | 2017-03-22 | 淄博市农业科学研究院 | Compound seed coating agent containing pyraclostrobin, tebuconazole and dinotefuran, and application thereof |
| CN111109266A (en) * | 2018-10-30 | 2020-05-08 | 江苏剑牌农化股份有限公司 | Triadimenol suspension bactericide with plant growth regulating effect and preparation method thereof |
| CN111484367A (en) * | 2020-04-10 | 2020-08-04 | 郑州博翔科技有限公司 | Accurate rice regulation and control method |
| CN113729074A (en) * | 2021-10-11 | 2021-12-03 | 安徽农业大学 | Preservative for preventing and treating anthracnose of pears and application of preservative |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006105888A2 (en) * | 2005-04-06 | 2006-10-12 | Bayer Cropscience Ag | Synergistic fungicidal active substance combinations |
| CN101683076A (en) * | 2009-08-05 | 2010-03-31 | 陕西标正作物科学有限公司 | Pyraclostrobin-containing water emulsion pesticide and preparation method thereof |
-
2011
- 2011-03-19 CN CN201310578454.2A patent/CN103828825B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006105888A2 (en) * | 2005-04-06 | 2006-10-12 | Bayer Cropscience Ag | Synergistic fungicidal active substance combinations |
| CN101683076A (en) * | 2009-08-05 | 2010-03-31 | 陕西标正作物科学有限公司 | Pyraclostrobin-containing water emulsion pesticide and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106508950A (en) * | 2016-11-04 | 2017-03-22 | 淄博市农业科学研究院 | Compound seed coating agent containing pyraclostrobin, tebuconazole and dinotefuran, and application thereof |
| CN111109266A (en) * | 2018-10-30 | 2020-05-08 | 江苏剑牌农化股份有限公司 | Triadimenol suspension bactericide with plant growth regulating effect and preparation method thereof |
| CN111484367A (en) * | 2020-04-10 | 2020-08-04 | 郑州博翔科技有限公司 | Accurate rice regulation and control method |
| CN113729074A (en) * | 2021-10-11 | 2021-12-03 | 安徽农业大学 | Preservative for preventing and treating anthracnose of pears and application of preservative |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103828825B (en) | 2015-02-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102172241B (en) | Pesticide composition containing pyraclostrobin and triazoles | |
| CN102224822B (en) | Microbicidal composition containing chloroisobromine cyanuric acid and antibiotics | |
| CN102204541B (en) | Synergetic antibacterial composition containing trifloxystrobin | |
| CN102177912A (en) | Pesticide composite containing pyraclostrobin | |
| CN101971812B (en) | Eugenol-containing germicidal composition | |
| CN102258043A (en) | Germicide composition containing protioconazole | |
| CN102017961B (en) | Bactericidal composition containing tridemorph | |
| CN103766350A (en) | Bactericidal composition containing trifloxystrobin and tebuconazole | |
| CN102258039A (en) | Bactericidal composition containing prothioconazole and thiocarbamates | |
| CN102258033A (en) | Novel pesticidal composition containing prothioconazole and triazole | |
| CN102100234B (en) | Sterilization composition containing pyraclostrobin and carbamates | |
| CN103828825B (en) | Pesticide composition containing pyraclostrobin and triazoles | |
| CN103250717A (en) | Bactericidal composition containing procymidone | |
| CN102308823B (en) | Bactericide composition containing pyraclostrobin | |
| CN102239855A (en) | Bactericidal composition containing trifloxystrobin and triazole | |
| CN102273461A (en) | Synergistic pesticide composition containing prothioconazole and triazoles | |
| CN102204542A (en) | Bactericidal composition containing enostroburin and triazole compound | |
| CN102047890B (en) | Sterilization composition containing Azoxystrobin and Epoxiconazole | |
| CN101999368B (en) | Propiconazole-containing bactericidal composition | |
| CN102037983A (en) | Synergistic sterilization composition containing triticonazole | |
| CN102067866A (en) | Bitertanol-containing antibacterial composition | |
| CN102239879B (en) | Bactericidal composition containing trifloxystrobin | |
| CN102165957B (en) | Synergic sterilizing composite containing fenbuconazole and triazole compound | |
| CN103719103A (en) | Flutriafol-containing sterilization composite | |
| CN101999367B (en) | Flutriafol-containing sterilizing composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| OL01 | Intention to license declared |