CN103804728B - A kind of half steel car snow tyre tread rubber combination - Google Patents

A kind of half steel car snow tyre tread rubber combination Download PDF

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CN103804728B
CN103804728B CN201310596814.1A CN201310596814A CN103804728B CN 103804728 B CN103804728 B CN 103804728B CN 201310596814 A CN201310596814 A CN 201310596814A CN 103804728 B CN103804728 B CN 103804728B
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parts
carbon black
half steel
tyre tread
tread rubber
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CN103804728A (en
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唐跃
韩树民
王世永
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Zhengdao Tire Co ltd
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SHANDONG LONGYUE RUBBER Co Ltd
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Abstract

The present invention relates to a kind of half steel car snow tyre tread rubber combination, be made up of the raw material of following weight part: Natural rubber 30-50 part, low along BR5-20 part, solution polymerized butadiene styrene rubber SSBR12-30 part, zinc oxide 2-6 part, stearic acid 0.6-1.6 part, protective agent 4010NA? 0.5-1.5 part, anti-aging agent 124? 0.5-1.5 part, carbon black N234? 40-55 part, carbon black N339? 20-30 part, white carbon black 30-40 part, aromatic hydrocarbon oil 1-6 part, oleic acid monooctyl ester 2-8 part, silane coupling agent Si-69? 4-9 part, altax 0.4-1.2 part, vulkacit D 0.2-0.8 part, accelerator NS 0.4-1.6 part, accelerant CZ 1-2.6 part, sulphur 0.8-2.4 part, carbamate crosslinker 2.4-8.4 part, anti-scorching agent CTP 0.05-0.15 part, Microcrystalline Wax 0.5-1.5 part, the present invention is by adding a certain amount of low carbon black along BR and two kind of different model, and not only have superior physicals, and show superior cold tolerance, meanwhile, while not reducing tire handling, ice face earth-catching property is effectively improved.

Description

A kind of half steel car snow tyre tread rubber combination
Technical field
The present invention relates to a kind of Tire tread rubber composition, specifically, relate to a kind of half steel car snow tyre tread rubber combination, belong to field of rubber technology.
Background technology
Along with the fast development of automotive industry; the performance requriements of people to tire is more and more higher; single all season tyre can not meet the segmentation demand of existing market; especially in the winter time; our northern most area often can run into the weather that ice and snow accompanies each other, and under this weather condition, conventional tyre cannot meet the demand of normal vehicle operation, braking.And Tire used in winter is design for this weather just, the walking of tire on ice-snow road, braking and steering capability can be improved, the safety of powerful guarantee driver and pedestrian.In some countries of European Union, use in winter snow tire has become a kind of laws and regulations requirement.
The design of low temperature resistant snowfield tread glue formula plays crucial effect to capacity semisteel car cold tolerance, and half steel car snow tyre tread glue formula not only requires resistance to low temperature, requires that ice face earth-catching property is also given prominence to than conventional tyre simultaneously.
Summary of the invention
The object of the invention is for the deficiencies in the prior art, the half steel car snow tyre tread rubber combination that a kind of resistance to low temperature is good, earth-catching property is good is provided.
For solving the problem, the present invention is by the following technical solutions: a kind of half steel car snow tyre tread rubber combination, be made up of the raw material of following weight part: Natural rubber 30-50 part, low along BR5-20 part, solution polymerized butadiene styrene rubber SSBR12-30 part, zinc oxide 2-6 part, stearic acid 0.6-1.6 part, protective agent 4010NA0.5-1.5 part, anti-aging agent 1240.5-1.5 part, carbon black N23440-55 part, carbon black N33920-30 part, white carbon black 30-40 part, aromatic hydrocarbon oil 1-6 part, oleic acid monooctyl ester 2-8 part, silane coupling agent Si-694-9 part, altax 0.4-1.2 part, vulkacit D 0.2-0.8 part, accelerator NS 0.4-1.6 part, accelerant CZ 1-2.6 part, sulphur 0.8-2.4 part, carbamate crosslinker 2.4-8.4 part, anti-scorching agent CTP 0.05-0.15 part, Microcrystalline Wax 0.5-1.5 part.
Preferably, a kind of half steel car snow tyre tread rubber combination, be made up of the raw material of following weight part: Natural rubber 40 parts, low along BR12.5 part, solution polymerized butadiene styrene rubber SSBR21 part, 4 parts, zinc oxide, stearic acid 1.1 parts, protective agent 4010NA1 part, 1241 parts, anti-aging agent, carbon black N23447.5 part, carbon black N33925 part, white carbon black 35 parts, aromatic hydrocarbon oil 3.5 parts, oleic acid monooctyl ester 5 parts, silane coupling agent Si-696.5 part, altax 0.8 part, vulkacit D 0.5 part, accelerator NS 1 part, accelerant CZ 1.8 parts, 1.6 parts, sulphur, carbamate crosslinker 5.4 parts, anti-scorching agent CTP 0.1 part, Microcrystalline Wax 1 part.
DIN wear loss≤the 0.30cm of described half steel car snow tyre tread rubber combination 3/ 1.61km.
The second-order transition temperature of described half steel car snow tyre tread rubber combination is-67 DEG C ~-57 DEG C.
The second-order transition temperature of described half steel car snow tyre tread rubber combination is-67 DEG C.
The present invention compared with prior art, have the following advantages: the present invention is by adding a certain amount of low carbon black along BR and two kind of different model, not only have superior physicals, and show superior cold tolerance, meanwhile, while not reducing tire handling, ice face earth-catching property is effectively improved.In addition, the finished tire test made from the present invention shows, the endurance quality of test recipe tire is good, and high speed and strength property improve, and the stopping distance on ice and snow road shortens 14% ~ 35%.
Below in conjunction with embodiment, technical scheme of the present invention is described further.
Embodiment
Embodiment 1, a kind of half steel car snow tyre tread rubber combination, be made up of the raw material of following weight part: Natural rubber 30 parts, low along BR5 part, solution polymerized butadiene styrene rubber SSBR12 part, 2 parts, zinc oxide, stearic acid 0.6 part, protective agent 4010NA0.5 part, 1240.5 parts, anti-aging agent, carbon black N23440 part, carbon black N33920 part, white carbon black 30 parts, aromatic hydrocarbon oil 1 part, oleic acid monooctyl ester 2 parts, silane coupling agent Si-694 part, altax 0.4 part, vulkacit D 0.2 part, accelerator NS 0.4 part, accelerant CZ 1 part, 0.8 part, sulphur, carbamate crosslinker 2.4 parts, anti-scorching agent CTP 0.05 part, Microcrystalline Wax 0.5 part.
Embodiment 2, a kind of half steel car snow tyre tread rubber combination, be made up of the raw material of following weight part: Natural rubber 40 parts, low along BR12.5 part, solution polymerized butadiene styrene rubber SSBR21 part, 4 parts, zinc oxide, stearic acid 1.1 parts, protective agent 4010NA1 part, 1241 parts, anti-aging agent, carbon black N23447.5 part, carbon black N33925 part, white carbon black 35 parts, aromatic hydrocarbon oil 3.5 parts, oleic acid monooctyl ester 5 parts, silane coupling agent Si-696.5 part, altax 0.8 part, vulkacit D 0.5 part, accelerator NS 1 part, accelerant CZ 1.8 parts, 1.6 parts, sulphur, carbamate crosslinker 5.4 parts, anti-scorching agent CTP 0.1 part, Microcrystalline Wax 1 part.
Embodiment 3, a kind of half steel car snow tyre tread rubber combination, be made up of the raw material of following weight part: Natural rubber 50 parts, low along BR20 part, solution polymerized butadiene styrene rubber SSBR30 part, 6 parts, zinc oxide, stearic acid 1.6 parts, protective agent 4010NA1.5 part, 1241.5 parts, anti-aging agent, carbon black N23455 part, carbon black N33930 part, white carbon black 40 parts, aromatic hydrocarbon oil 6 parts, oleic acid monooctyl ester 8 parts, silane coupling agent Si-699 part, altax 1.2 parts, vulkacit D 0.8 part, accelerator NS 1.6 parts, accelerant CZ 2.6 parts, 2.4 parts, sulphur, carbamate crosslinker 8.4 parts, anti-scorching agent CTP 0.15 part, Microcrystalline Wax 1.5 parts.
Embodiment 4, a kind of half steel car snow tyre tread rubber combination, be made up of the raw material of following weight part: Natural rubber 40 parts, low along BR5 part, solution polymerized butadiene styrene rubber SSBR21 part, 4 parts, zinc oxide, stearic acid 1.1 parts, protective agent 4010NA1 part, 1241 parts, anti-aging agent, carbon black N23447.5 part, carbon black N33925 part, white carbon black 35 parts, aromatic hydrocarbon oil 3.5 parts, oleic acid monooctyl ester 5 parts, silane coupling agent Si-696.5 part, altax 0.8 part, vulkacit D 0.5 part, accelerator NS 1 part, accelerant CZ 1.8 parts, 1.6 parts, sulphur, carbamate crosslinker 5.4 parts, anti-scorching agent CTP 0.1 part, Microcrystalline Wax 1 part.
Embodiment 5, a kind of half steel car snow tyre tread rubber combination, be made up of the raw material of following weight part: Natural rubber 40 parts, low along BR20 part, solution polymerized butadiene styrene rubber SSBR21 part, 4 parts, zinc oxide, stearic acid 1.1 parts, protective agent 4010NA1 part, 1241 parts, anti-aging agent, carbon black N23447.5 part, carbon black N33925 part, white carbon black 35 parts, aromatic hydrocarbon oil 3.5 parts, oleic acid monooctyl ester 5 parts, silane coupling agent Si-696.5 part, altax 0.8 part, vulkacit D 0.5 part, accelerator NS 1 part, accelerant CZ 1.8 parts, 1.6 parts, sulphur, carbamate crosslinker 5.4 parts, anti-scorching agent CTP 0.1 part, Microcrystalline Wax 1 part.
Embodiment 6, a kind of half steel car snow tyre tread rubber combination, be made up of the raw material of following weight part: Natural rubber 40 parts, low along BR12.5 part, solution polymerized butadiene styrene rubber SSBR21 part, 4 parts, zinc oxide, stearic acid 1.1 parts, protective agent 4010NA1 part, 1241 parts, anti-aging agent, carbon black N23440 part, carbon black N33920 part, white carbon black 35 parts, aromatic hydrocarbon oil 3.5 parts, oleic acid monooctyl ester 5 parts, silane coupling agent Si-696.5 part, altax 0.8 part, vulkacit D 0.5 part, accelerator NS 1 part, accelerant CZ 1.8 parts, 1.6 parts, sulphur, carbamate crosslinker 5.4 parts, anti-scorching agent CTP 0.1 part, Microcrystalline Wax 1 part.
Embodiment 7, a kind of half steel car snow tyre tread rubber combination, be made up of the raw material of following weight part: Natural rubber 40 parts, low along BR12.5 part, solution polymerized butadiene styrene rubber SSBR21 part, 4 parts, zinc oxide, stearic acid 1.1 parts, protective agent 4010NA1 part, 1241 parts, anti-aging agent, carbon black N23455 part, carbon black N33930 part, white carbon black 35 parts, aromatic hydrocarbon oil 3.5 parts, oleic acid monooctyl ester 5 parts, silane coupling agent Si-696.5 part, altax 0.8 part, vulkacit D 0.5 part, accelerator NS 1 part, accelerant CZ 1.8 parts, 1.6 parts, sulphur, carbamate crosslinker 5.4 parts, anti-scorching agent CTP 0.1 part, Microcrystalline Wax 1 part.
Description of test
According to national standard, carry out quantitative measurement respectively to embodiment 1 to embodiment 7, physical performance index sees the following form 1.
Table 1
150 DEG C of sulfuration * 30min Standard Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6 Embodiment 7
Tensile strength/Mpa 18 19.25 21.39 19.45 20.77 20.9 20.15 20.55
Tensile yield/% 400 486 572 499 459 554 483 467
Shao Er A type hardness tester 55 62 58 63 60 61 59 57
DIN wear loss cm3/1.61km 0.4 0.243 0.266 0.251 0.251 0.253 0.246 0.268
100% stress at definite elongation/Mpa 2 3.74 3.77 3.86 4.09 3.95 3.84 3.59
300% stress at definite elongation/Mpa 8 8.58 10.04 9.54 10.42 10 10.17 8.95
Rebound value/% 30 37 34 38 38 35 36 33
Tension set/% 20 22 26 24 25 27 26 25
Second-order transition temperature/DEG C -50 -57 -67 -57 -62 -63 -62 -64
Aging resistance 100 DEG C of * 24h
Tensile strength/Mpa 18 18.51 20.56 18.64 19.53 19.7 19.25 19.16
Tensile yield/% 400 444 514 442 458 461 455 457
Shao Er A type hardness tester 55 60 65 62 64 64 64 65
DIN wear loss cm 3/1.61km 0.4 0.256 0.277 0.259 0.263 0.271 0.258 0.261
100% stress at definite elongation/Mpa 3 3.54 4.22 3.65 3.83 3.85 3.67 3.77
300% stress at definite elongation/Mpa 8 8.34 9.95 8.49 9.11 9.64 9.13 9.15
Rebound value/% 30 33 36 33 35 34 36 35
Aging coefficient 0.9 0.91 0.97 0.93 0.96 0.95 0.94 0.94
As can be seen from Table 1, the present invention not only has superior physicals, and shows superior cold tolerance, wherein, embodiment 2 is most preferably scheme, and second-order transition temperature reaches-67 DEG C, meanwhile, while not reducing tire handling, ice face earth-catching property is effectively improved.
In addition, embodiment 2 is compared with embodiment 4, embodiment 5, different places is the low difference along BR add-on, shown by the data of table 1, the performance index of the half steel car snow tyre tread rubber combination of embodiment 2 are best, namely, time the low add-on along BR is 12.5 parts, the performance index of half steel car snow tyre tread rubber combination are best; Embodiment 2 is compared with enforcement 6, embodiment 7, different places is the difference of carbon black N234 and carbon black N339 add-on, shown by the data of table 1, the performance index of the half steel car snow tyre tread rubber combination of embodiment 2 are best, namely the add-on of carbon black N234 is 47.5 parts, time the add-on of carbon black N339 is 25 parts, the performance index of half steel car snow tyre tread rubber combination are best.
More than show and describe ultimate principle of the present invention and principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; what describe in above-described embodiment and specification sheets just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.Application claims protection domain is defined by appending claims and equivalent thereof.

Claims (2)

1. a half steel car snow tyre tread rubber combination, it is characterized in that: be made up of the raw material of following weight part: Natural rubber 40 parts, low along BR12.5 part, solution polymerized butadiene styrene rubber SSBR21 part, 4 parts, zinc oxide, stearic acid 1.1 parts, protective agent 4010NA1 part, 1241 parts, anti-aging agent, carbon black N23447.5 part, carbon black N33925 part, white carbon black 35 parts, aromatic hydrocarbon oil 3.5 parts, oleic acid monooctyl ester 5 parts, silane coupling agent Si-696.5 part, altax 0.8 part, vulkacit D 0.5 part, accelerator NS 1 part, accelerant CZ 1.8 parts, 1.6 parts, sulphur, carbamate crosslinker 5.4 parts, anti-scorching agent CTP 0.1 part, Microcrystalline Wax 1 part,
Akron abrasion loss≤the 0.30cm of described half steel car snow tyre tread rubber combination 3/ 1.61km.
2. a kind of half steel car snow tyre tread rubber combination as claimed in claim 1, is characterized in that: the second-order transition temperature of described half steel car snow tyre tread rubber combination is-67 DEG C.
CN201310596814.1A 2013-11-25 2013-11-25 A kind of half steel car snow tyre tread rubber combination Active CN103804728B (en)

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CN104292516A (en) * 2014-09-19 2015-01-21 明光瑞泰工业有限公司 Bicycle tire crown compound
CN104277252A (en) * 2014-09-22 2015-01-14 安徽喜洋洋儿童用品有限公司 High-performance tread rubber for stroller
CN104448417A (en) * 2014-12-01 2015-03-25 四川凯力威科技股份有限公司 Special rubber material for tread of all-steel radial tire for ice-snow covered road and preparation method of rubber material
US10179479B2 (en) 2015-05-19 2019-01-15 Bridgestone Americas Tire Operations, Llc Plant oil-containing rubber compositions, tread thereof and race tires containing the tread
CN104893039B (en) * 2015-06-10 2017-07-18 青岛科技大学 A kind of application process of the natural gutta percha of epoxidation
CN105037824B (en) * 2015-07-23 2017-05-31 杭州朝阳橡胶有限公司 A kind of all steel load automobile snow tyre tread rubber composition
CN105622996A (en) * 2016-03-17 2016-06-01 青岛振华轮胎有限公司 Formula of motorcycle tire tube rubber
CN106279818A (en) * 2016-08-30 2017-01-04 瑞安市智造科技有限公司 Radial that a kind of ageing-resistant performance is good and preparation method thereof
CN106589481A (en) * 2016-12-16 2017-04-26 山东龙跃橡胶有限公司 Special semi-steel radial tire for snow field and preparation method thereof
CN106674637B (en) * 2016-12-30 2018-11-30 太仓冠联高分子材料有限公司 A kind of snow tire special (purpose) rubber
CN107383457A (en) * 2017-09-11 2017-11-24 三角轮胎股份有限公司 For standard testing tire tread rubber composition
CN111592695A (en) * 2020-06-30 2020-08-28 山东金宇轮胎有限公司 All-steel radial tire tread formula and preparation method thereof
CN112662009B (en) * 2020-12-16 2021-11-05 兰溪市双牛助剂化工有限公司 Rubber vulcanization accelerator and preparation method thereof
CN113321856B (en) * 2021-06-10 2023-04-07 正新橡胶(中国)有限公司 Rubber composition for improving performance of tire in ice and snow fields and tire

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CN102432922A (en) * 2010-12-20 2012-05-02 双钱集团(如皋)轮胎有限公司 Tire bead adhesive for radial tire and preparation method thereof
CN102850602B (en) * 2011-06-27 2013-12-11 太仓冠联高分子材料有限公司 Tire rubber and its preparation method
CN103012873A (en) * 2011-09-26 2013-04-03 北京橡胶工业研究设计院 Rubber composition for tire sidewall part of run-flat tire

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