CN103789051B - A kind of composite biomass liquid fuel - Google Patents
A kind of composite biomass liquid fuel Download PDFInfo
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- CN103789051B CN103789051B CN201410066801.8A CN201410066801A CN103789051B CN 103789051 B CN103789051 B CN 103789051B CN 201410066801 A CN201410066801 A CN 201410066801A CN 103789051 B CN103789051 B CN 103789051B
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- 239000002028 Biomass Substances 0.000 title claims abstract description 51
- 239000000446 fuel Substances 0.000 title claims abstract description 43
- 239000007788 liquid Substances 0.000 title claims abstract description 43
- 239000002131 composite material Substances 0.000 title claims abstract description 23
- 239000000463 material Substances 0.000 claims abstract description 24
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 17
- 238000000197 pyrolysis Methods 0.000 claims abstract description 14
- 239000011259 mixed solution Substances 0.000 claims abstract description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 11
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 5
- -1 polyoxyethylene nonylphenol Polymers 0.000 claims description 12
- 239000010902 straw Substances 0.000 claims description 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 9
- 239000002023 wood Substances 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 4
- 238000010298 pulverizing process Methods 0.000 claims description 4
- WDCYWAQPCXBPJA-UHFFFAOYSA-N 1,3-dinitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC([N+]([O-])=O)=C1 WDCYWAQPCXBPJA-UHFFFAOYSA-N 0.000 claims description 3
- JZODKRWQWUWGCD-UHFFFAOYSA-N 2,5-di-tert-butylbenzene-1,4-diol Chemical compound CC(C)(C)C1=CC(O)=C(C(C)(C)C)C=C1O JZODKRWQWUWGCD-UHFFFAOYSA-N 0.000 claims description 3
- CDMGNVWZXRKJNS-UHFFFAOYSA-N 2-benzylphenol Chemical compound OC1=CC=CC=C1CC1=CC=CC=C1 CDMGNVWZXRKJNS-UHFFFAOYSA-N 0.000 claims description 3
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 3
- 229910021591 Copper(I) chloride Inorganic materials 0.000 claims description 3
- 229920000742 Cotton Polymers 0.000 claims description 3
- 244000299507 Gossypium hirsutum Species 0.000 claims description 3
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 claims description 3
- AFBPFSWMIHJQDM-UHFFFAOYSA-N N-methylaniline Chemical compound CNC1=CC=CC=C1 AFBPFSWMIHJQDM-UHFFFAOYSA-N 0.000 claims description 3
- KJUSBZIVYOEDOT-UHFFFAOYSA-N OC([Mn])=O Chemical compound OC([Mn])=O KJUSBZIVYOEDOT-UHFFFAOYSA-N 0.000 claims description 3
- 240000007594 Oryza sativa Species 0.000 claims description 3
- 235000007164 Oryza sativa Nutrition 0.000 claims description 3
- 244000046052 Phaseolus vulgaris Species 0.000 claims description 3
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims description 3
- 240000006394 Sorghum bicolor Species 0.000 claims description 3
- 235000015505 Sorghum bicolor subsp. bicolor Nutrition 0.000 claims description 3
- 235000011684 Sorghum saccharatum Nutrition 0.000 claims description 3
- 235000021307 Triticum Nutrition 0.000 claims description 3
- 240000008042 Zea mays Species 0.000 claims description 3
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 claims description 3
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 3
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 claims description 3
- RZJRJXONCZWCBN-UHFFFAOYSA-N alpha-octadecene Natural products CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 claims description 3
- 238000010504 bond cleavage reaction Methods 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000009833 condensation Methods 0.000 claims description 3
- 230000005494 condensation Effects 0.000 claims description 3
- 239000007859 condensation product Substances 0.000 claims description 3
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical group [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 claims description 3
- 229940045803 cuprous chloride Drugs 0.000 claims description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 3
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 150000002314 glycerols Chemical class 0.000 claims description 3
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 3
- GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 claims description 3
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 claims description 3
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 claims description 3
- 235000009973 maize Nutrition 0.000 claims description 3
- NFWSQSCIDYBUOU-UHFFFAOYSA-N methylcyclopentadiene Chemical compound CC1=CC=CC1 NFWSQSCIDYBUOU-UHFFFAOYSA-N 0.000 claims description 3
- 229940038384 octadecane Drugs 0.000 claims description 3
- 229920001451 polypropylene glycol Polymers 0.000 claims description 3
- 239000000047 product Substances 0.000 claims description 3
- 235000009566 rice Nutrition 0.000 claims description 3
- 230000007017 scission Effects 0.000 claims description 3
- 239000002699 waste material Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 244000098338 Triticum aestivum Species 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 7
- 238000003860 storage Methods 0.000 abstract description 7
- 239000000295 fuel oil Substances 0.000 abstract description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 4
- 239000003350 kerosene Substances 0.000 abstract description 4
- 239000011707 mineral Substances 0.000 abstract description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract description 2
- 239000002283 diesel fuel Substances 0.000 abstract description 2
- 239000003502 gasoline Substances 0.000 abstract description 2
- 238000002485 combustion reaction Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 241000209140 Triticum Species 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005474 detonation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002916 wood waste Substances 0.000 description 1
Landscapes
- Liquid Carbonaceous Fuels (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
The invention discloses a kind of composite biomass liquid fuel, it is obtained by the material of following mass percentage normal temperature mix and blend under 0.5Mpa ~ 1.0Mpa pressure for 6 hours: the biomass pyrolysis liquid of 50% ~ 60%, the alkane mixed solution containing 6 ~ 8 carbon atoms of 20% ~ 30%, 10% ~ 20% containing the monohydroxy-alcohol mixed solution of 2 ~ 4 carbon atoms, stopper, the emulsifying agent of 0.5% ~ 1.5%, the octane promoter of 0.1% ~ 0.3% of 0.5% ~ 1.5%.This case adds the calorific value of this liquid fuel by interpolation alkane and alcohol, the introducing of octane promoter effectively prevent the generation of fuel knock phenomenon, composite biomass liquid fuel calorific value mentioned by the present invention is high, pollution-free, good stability, storage transportation safety is convenient, can be used as clean energy and substitutes the mineral fuel such as existing kerosene, heavy oil, gasoline, diesel oil, for multiple fields such as generating, urban heat supplying, motor-driven vehicle goings.
Description
Technical field
The present invention relates to new energy fuel field, particularly a kind of environment friendly and pollution-free composite biomass liquid fuel.
Background technology
At present, along with the appearance of energy dilemma in world wide and the day by day serious environmental problem owing to using mineral fuel to bring in a large number, the exploitation to biomass energy are more and more paid attention in countries in the world.
Biomass liquid fuel is a kind of Land use systems of biomass energy, and its raw materials for production are forestry " three surplus things " (wood machining residues, forest harvesting residuum, producing material residuum), various wooden tankage, wood wastes, agricultural crop straw and shrub etc.Production process be quality is loosened, can the little biomass material of force density, through the operation such as super-dry, pulverizing, then after high-temperature pressure thermo-cracking, obtain biomass liquid fuel.Biomass liquid fuel energy density is large, and combustion heat value is large, and conveniently, not having sulfur dioxide emissions, is a kind of environment friendly and pollution-free ecological fuel for transport and storage.
No. 201010517711.8th, Chinese patent application discloses a kind of biomass liquid fuel, it obtains a kind of biomass liquid fuel after carrying out thermo-cracking to biomass material, but this fuel combustion value is relatively low, the boiler oil such as kerosene, heavy oil cannot be replaced completely, and due to composition single, transport and use time easily there is fuel knock phenomenon.
Summary of the invention
For the defect existed in prior art, invention has been improvement, a kind of composite biomass liquid fuel provided, combustion heat value is high, pollution-free, good stability, storage transportation safety is convenient, can be used as clean energy and substitutes the mineral fuel such as existing kerosene, heavy oil.
Technical scheme of the present invention is summarized as follows:
A kind of composite biomass liquid fuel, it is obtained by material normal temperature mix and blend under 0.5Mpa ~ 1.0Mpa pressure of following mass percentage for 6 hours:
Wherein, described biomass pyrolysis liquid is obtained by following methods: after biomass material drying, pulverizing, in rapid pyrolysis reactor, carry out heat scission reaction, collect the liquid of condensation, obtain biomass pyrolysis liquid;
The wood chip that described biomass material is selected from wooden tankage, wooden waste products, wood working produce, wheat stalk, maize straw, broomcorn straw, cotton stem, rice straw, beans stalk, Pericarppium arachidis hypogaeae or its combination;
Described stopper is selected from cuprous chloride, iron trichloride, Resorcinol, Meta-dinitrobenzene, 2,5 di tert butyl hydroquinone or its combination;
Described emulsifying agent is selected from polyoxyethylene nonylphenol ether, Ben-zylphenol Polyoxyethyl Ether, octadecane alcohol radical Soxylat A 25-7, polyoxylethylene abietate, Glycerol dimer polypropylene glycol ether, di-isopropyl sodium naphthalene sulfonate, xenol Soxylat A 25-7 formaldehyde condensation products, Dodecyl trimethyl ammonium chloride or its combination;
Described octane promoter is made up of following material: the methyl cyclopentadiene three carboxyl manganese of 5wt%, the mono methyl aniline 99.5004323A8urity of 25wt%, the isobutyl acetate of 30wt%, the methyl tertiary butyl ether of 40wt%.
Preferably, described composite biomass liquid fuel, the described alkane mixed solution containing 6 ~ 8 carbon atoms is the normal alkane mixed solution containing 6 ~ 8 carbon atoms.
Preferably, described composite biomass liquid fuel, biomass material being dried to water ratio is 10wt% ~ 16wt%.
The invention has the beneficial effects as follows: the calorific value being added this liquid fuel by interpolation alkane and alcohol, the introducing of octane promoter effectively prevent the generation of fuel knock phenomenon, composite biomass liquid fuel calorific value mentioned by the present invention is high, pollution-free, good stability, storage transportation safety is convenient, can be used as clean energy and substitutes the mineral fuel such as existing kerosene, heavy oil, gasoline, diesel oil, for multiple fields such as generating, urban heat supplying, motor-driven vehicle goings.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail, can implement according to this with reference to specification sheets word to make those skilled in the art.
A kind of composite biomass liquid fuel, it is obtained by material normal temperature mix and blend under 0.5Mpa ~ 1.0Mpa pressure of following mass percentage for 6 hours:
Wherein, the alkane mixed solution containing 6 ~ 8 carbon atoms is preferably the normal alkane mixed solution containing 6 ~ 8 carbon atoms.Alkane mixed solution containing 6 ~ 8 carbon atoms can select oneself alkane, heptane, octane or its combination, the combustionproperty of three is close, so can with arbitrarily than mixing, whether also do not limit alkane used in this case must be normal alkane, the structure of this type of alkane is limited on combustionproperty impact, therefore only need containing the alkane containing 6 ~ 8 carbon atoms in this case.Same, the monohydroxy-alcohol mixed solution containing 2 ~ 4 carbon atoms is not also particularly limited the structure of alcohol, and it can be selected from ethanol, propyl alcohol, butanols or its combination, and can any combination.
The object inserting alkane mixed solution and alcohol mixed solution in biomass pyrolysis liquid is the energy density in order to improve this liquid fuel, increases its combustion heat value, to expanding the Application Areas of this fuel further.
Biomass pyrolysis liquid is obtained by following methods: be after 10wt% ~ 16wt%, pulverizing by biomass material drying to water ratio, carry out heat scission reaction, collect the liquid of condensation, obtain biomass pyrolysis liquid in rapid pyrolysis reactor;
The wood chip that biomass material is selected from wooden tankage, wooden waste products, wood working produce, wheat stalk, maize straw, broomcorn straw, cotton stem, rice straw, beans stalk, Pericarppium arachidis hypogaeae or its combination;
Stopper is selected from cuprous chloride, iron trichloride, Resorcinol, Meta-dinitrobenzene, 2,5 di tert butyl hydroquinone or its combination;
Emulsifying agent is selected from polyoxyethylene nonylphenol ether, Ben-zylphenol Polyoxyethyl Ether, octadecane alcohol radical Soxylat A 25-7, polyoxylethylene abietate, Glycerol dimer polypropylene glycol ether, di-isopropyl sodium naphthalene sulfonate, xenol Soxylat A 25-7 formaldehyde condensation products, Dodecyl trimethyl ammonium chloride or its combination;
Octane promoter is made up of following material: the methyl cyclopentadiene three carboxyl manganese of 5wt%, the mono methyl aniline 99.5004323A8urity of 25wt%, the isobutyl acetate of 30wt%, the methyl tertiary butyl ether of 40wt%.
Owing to containing a large amount of unsaturated materials in biomass pyrolysis oil, can be polymerized gradually in heating or storage process and lose flowability, impact is normal to be used, this case with the addition of stopper and emulsifying agent in technical recipe for this reason, they effectively can improve stability in storage and the mobility of biomass pyrolysis oil, the stable storing time is long, and pour point is low.
After biomass pyrolysis liquid mixes with alkane, alcohol, after long-term transport or storage, can produce more active superoxide, easily there is phenomenon of detonation in fuel, effectively can avoid problems by adding a small amount of octane promoter.
The calorific value of obtained composite biomass liquid fuel is at 8000 ~ 9600Kcal/kg.
Embodiment 1
A kind of composite biomass liquid fuel, it is obtained by material normal temperature mix and blend under 1.0Mpa pressure of following mass percentage for 6 hours:
The calorific value of this composite biomass liquid fuel is 9600Kcal/kg.
Embodiment 2
A kind of composite biomass liquid fuel, it is obtained by material normal temperature mix and blend under 0.9Mpa pressure of following mass percentage for 6 hours:
The calorific value of this composite biomass liquid fuel is 8000Kcal/kg.
Embodiment 3
A kind of composite biomass liquid fuel, it is obtained by material normal temperature mix and blend under 0.75Mpa pressure of following mass percentage for 6 hours:
The calorific value of this composite biomass liquid fuel is 8800Kcal/kg.
Embodiment 4
A kind of composite biomass liquid fuel, it is obtained by material normal temperature mix and blend under 0.6Mpa pressure of following mass percentage for 6 hours:
The calorific value of this composite biomass liquid fuel is 9010Kcal/kg.
Embodiment 5
A kind of composite biomass liquid fuel, it is obtained by material normal temperature mix and blend under 0.5Mpa pressure of following mass percentage for 6 hours:
The calorific value of this composite biomass liquid fuel is 8690Kcal/kg.
Although embodiment of the present invention are open as above, but it is not restricted to listed in specification sheets and embodiment utilization, it can be applied to various applicable the field of the invention completely, for those skilled in the art, can easily realize other amendment, therefore do not deviating under the universal that claim and equivalency range limit, the present invention is not limited to specific details.
Claims (1)
1. a composite biomass liquid fuel, is characterized in that, it is obtained by material normal temperature mix and blend under 0.5Mpa ~ 1.0Mpa pressure of following mass percentage for 6 hours:
Wherein, described biomass pyrolysis liquid is obtained by following methods: after biomass material drying, pulverizing, in rapid pyrolysis reactor, carry out heat scission reaction, collect the liquid of condensation, obtain biomass pyrolysis liquid;
The wood chip that described biomass material is selected from wooden tankage, wooden waste products, wood working produce, wheat stalk, maize straw, broomcorn straw, cotton stem, rice straw, beans stalk, Pericarppium arachidis hypogaeae or its combination;
Described stopper is selected from cuprous chloride, iron trichloride, Resorcinol, Meta-dinitrobenzene, 2,5 di tert butyl hydroquinone or its combination;
Described emulsifying agent is selected from polyoxyethylene nonylphenol ether, Ben-zylphenol Polyoxyethyl Ether, octadecane alcohol radical Soxylat A 25-7, polyoxylethylene abietate, Glycerol dimer polypropylene glycol ether, di-isopropyl sodium naphthalene sulfonate, xenol Soxylat A 25-7 formaldehyde condensation products, Dodecyl trimethyl ammonium chloride or its combination;
Described octane promoter is made up of following material: the methyl cyclopentadiene three carboxyl manganese of 5wt%, the mono methyl aniline 99.5004323A8urity of 25wt%, the isobutyl acetate of 30wt%, the methyl tertiary butyl ether of 40wt%;
The described alkane mixed solution containing 6 ~ 8 carbon atoms is the normal alkane mixed solution containing 6 ~ 8 carbon atoms;
Biomass material being dried to water ratio is 10wt% ~ 16wt%.
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| CN201410066801.8A CN103789051B (en) | 2014-02-26 | 2014-02-26 | A kind of composite biomass liquid fuel |
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| CN201410066801.8A CN103789051B (en) | 2014-02-26 | 2014-02-26 | A kind of composite biomass liquid fuel |
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| CN103789051A CN103789051A (en) | 2014-05-14 |
| CN103789051B true CN103789051B (en) | 2015-12-09 |
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| CN105331397B (en) * | 2015-10-27 | 2017-04-12 | 河南隆正生物能源有限公司 | Preparation method of high-cleanness and high-calorific-value fuel oil |
| CN107699268B (en) * | 2017-09-17 | 2020-01-17 | 长沙仲善新能源科技有限公司 | Low-carbon high-efficiency biological liquid fuel and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102453556A (en) * | 2010-10-25 | 2012-05-16 | 河南省高新技术实业总公司 | Biomass liquid fuel |
| CN102660310A (en) * | 2012-04-28 | 2012-09-12 | 上海交通大学 | Method for improving stability of biological oil by utilizing ethanol serving as additive |
| CN103254947A (en) * | 2013-05-10 | 2013-08-21 | 辽宁鼎瀚能源开发有限公司 | Hydrocarbon oil for spark-ignition engine and preparation method thereof |
| CN103254948A (en) * | 2013-04-26 | 2013-08-21 | 中国科学技术大学 | Method for improving stability of bio-oil, and bio-oil with improved stability |
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| CA2705431A1 (en) * | 2006-11-08 | 2008-05-15 | Innovations Solutions Now Inc. | Fuel or fuel additive composition and method for its manufacture and use |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102453556A (en) * | 2010-10-25 | 2012-05-16 | 河南省高新技术实业总公司 | Biomass liquid fuel |
| CN102660310A (en) * | 2012-04-28 | 2012-09-12 | 上海交通大学 | Method for improving stability of biological oil by utilizing ethanol serving as additive |
| CN103254948A (en) * | 2013-04-26 | 2013-08-21 | 中国科学技术大学 | Method for improving stability of bio-oil, and bio-oil with improved stability |
| CN103254947A (en) * | 2013-05-10 | 2013-08-21 | 辽宁鼎瀚能源开发有限公司 | Hydrocarbon oil for spark-ignition engine and preparation method thereof |
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Effective date of registration: 20180920 Address after: 473300 Mao Village, Zhouzhuang village, lower wa Township, Nanyang County, Henan Province Patentee after: Li Hui Address before: 223907 southern side of Xiangjiang Road, Sihong Economic Development Zone, Jiangsu Patentee before: SIHONG INOVO WOOD INDUSTRY Co.,Ltd. |
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