CN102453556A - Biomass liquid fuel - Google Patents

Biomass liquid fuel Download PDF

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Publication number
CN102453556A
CN102453556A CN2010105177118A CN201010517711A CN102453556A CN 102453556 A CN102453556 A CN 102453556A CN 2010105177118 A CN2010105177118 A CN 2010105177118A CN 201010517711 A CN201010517711 A CN 201010517711A CN 102453556 A CN102453556 A CN 102453556A
Authority
CN
China
Prior art keywords
biomass
liquid fuel
pyrolysis oil
biomass pyrolysis
stalk
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2010105177118A
Other languages
Chinese (zh)
Inventor
肖进彬
王郑建
马新荣
崔志琦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henan Provincial High-New Tech Commercial And Industrial General Co
Original Assignee
Henan Provincial High-New Tech Commercial And Industrial General Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henan Provincial High-New Tech Commercial And Industrial General Co filed Critical Henan Provincial High-New Tech Commercial And Industrial General Co
Priority to CN2010105177118A priority Critical patent/CN102453556A/en
Publication of CN102453556A publication Critical patent/CN102453556A/en
Pending legal-status Critical Current

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Abstract

The present invention relates to a biomass liquid fuel. The biomass liquid fuel comprises, by weight, 80-98% of biomass pyrolysis oil, 0.5-5% of a polymerization inhibitor, and 0.5-5% of an emulsifying agent. The liquid fuel of the present invention can replace coal, diesel fuel, heavy oil, and other boiler fuels, and can be used for power generation, urban heating, and the like.

Description

A kind of biomass liquid fuel
Technical field
The invention belongs to the resource and environment field, particularly relate to a kind of biomass liquid fuel.
Background technology
The biomass as resources, the energy technology that with the stalk are raw material can be converted into stalk products such as solid, liquid, geseous fuel and fertilizer; Wherein stalk liquefaction is converted into the energy density that liquid fuel can improve fuel, is beneficial to processing, transportation and use more.
The biomass pyrolysis oil that obtains after utilizing pyrolysis technology with the stalk cracking is the biomass recyclable fuel of a kind of cleaning, environmental protection, non-carbon-emitting, can replace boiler oils such as coal, diesel oil, heavy oil, is used for generating, urban heat supplying etc.Owing to contain a large amount of unsaturated materialss in the biomass pyrolysis oil, polymerization and losing flowability gradually in heating or storage process, influence is normally used.
Summary of the invention
The present invention relates to a kind of biomass liquid fuel, this liquid fuel can replace boiler oils such as coal, diesel oil, heavy oil, is used for generating, urban heat supplying etc.A kind of biomass liquid fuel that the present invention relates to, its weight percent comprises:
Biomass pyrolysis oil: 80%~98%
Stopper: 0.5%~5%
Emulsifying agent: 0.5%~5%
Described biomass pyrolysis oil is to be raw material with stalk (agricultural wastes such as straw, cornstalk, rice straw, cotton stalk, beans stalk, Pericarppium arachidis hypogaeae), through the biomass pyrolysis oil that obtains after the thermo-cracking, water cut 20%~30%.
Described stopper is quinhydrones, para benzoquinone, toluhydroquinone, 2-Tert. Butyl Hydroquinone, 2,5 di tert butyl hydroquinone, is their one or more mixture.
Described emulsifying agent is TX10 (OP series, TX series), AEO (AEO series), is their one or more mixture.
Beneficial effect of the present invention
After in biomass pyrolysis oil, adding stopper and emulsifying agent among the present invention, can improve the stability in storage and the flowability of biomass pyrolysis oil, the stable storing time is long, and pour point is low.
Embodiment
Further set forth the present invention below in conjunction with specific embodiment, these embodiment only are used to explain the present invention rather than restriction the present invention, and those skilled in the art can make various changes and modification in the scope of the application's appended claims.
Embodiment 1
A kind of biomass fuel material formula of the present invention is (by weight percentage) as follows:
Biomass pyrolysis oil 85%
Para benzoquinone 10%
OP-10 3%
TX-7 2%
The preparation process:
With biomass pyrolysis oil, para benzoquinone, OP-10, TX-7 mixes, and stirs.
This liquid fuel stable storing phase is greater than 6 months, pour point-15 ℃.
Embodiment 2
A kind of biomass fuel material formula of the present invention is (by weight percentage) as follows:
Biomass pyrolysis oil 95%
2-Tert. Butyl Hydroquinone 3%
OP-100 2%
The preparation process:
With biomass pyrolysis oil, the 2-Tert. Butyl Hydroquinone, OP-100 mixes, and stirs.
This liquid fuel stable storing phase is greater than 6 months, pour point-15 ℃.
Embodiment 3
A kind of biomass fuel material formula of the present invention is (by weight percentage) as follows:
Biomass pyrolysis oil 90%
2,5 di tert butyl hydroquinone 3%
TX-4 2%
The preparation process:
With biomass pyrolysis oil, 2,5 di tert butyl hydroquinone, TX-4 mixes, and stirs.
This liquid fuel stable storing phase is greater than 6 months, pour point-15 ℃.
Embodiment 4
A kind of biomass fuel material formula of the present invention is (by weight percentage) as follows:
Biomass pyrolysis oil 90%
Toluhydroquinone 7%
AEO9 3%
The preparation process:
With biomass pyrolysis oil, toluhydroquinone, AEO9 mixes, and stirs.
This liquid fuel stable storing phase is greater than 6 months, pour point-15 ℃.
Test shows, the decontamination value of this washing liquid is above standard washing powder more than 30%.

Claims (6)

1. a biomass liquid fuel is characterized in that, has following composition:
Biomass pyrolysis oil: 80%~98%
Stopper: 0.5%~5%
Emulsifying agent: 0.5%~5%
2. biomass pyrolysis oil according to claim 1 is to be raw material with stalk (agricultural wastes such as straw, cornstalk, rice straw, cotton stalk, beans stalk, Pericarppium arachidis hypogaeae), through the biomass pyrolysis oil that obtains after the thermo-cracking, water cut 20%~30%.
3. stopper according to claim 1 is quinhydrones, para benzoquinone, toluhydroquinone, 2-Tert. Butyl Hydroquinone, 2,5 di tert butyl hydroquinone, is their one or more mixture.
4. emulsifying agent according to claim 1 is TX10 (OP series, TX series), AEO (AEO series), is their one or more mixture.
5. the carbon chain lengths of TX10 according to claim 4 is between 8~12.
6. the carbon chain lengths of AEO according to claim 4 is between 12~18.
CN2010105177118A 2010-10-25 2010-10-25 Biomass liquid fuel Pending CN102453556A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2010105177118A CN102453556A (en) 2010-10-25 2010-10-25 Biomass liquid fuel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2010105177118A CN102453556A (en) 2010-10-25 2010-10-25 Biomass liquid fuel

Publications (1)

Publication Number Publication Date
CN102453556A true CN102453556A (en) 2012-05-16

Family

ID=46037259

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2010105177118A Pending CN102453556A (en) 2010-10-25 2010-10-25 Biomass liquid fuel

Country Status (1)

Country Link
CN (1) CN102453556A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103789051A (en) * 2014-02-26 2014-05-14 泗洪新创源木业有限公司 Composite biomass liquid fuel
GB2618210A (en) * 2022-03-23 2023-11-01 Innospec Ltd Compositions, methods and uses

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101348738A (en) * 2008-01-14 2009-01-21 郑州亚星能源科技有限公司 Emulsified biomass oil additive, emulsified biomass oil using the emulsified biomass oil additive and preparation thereof
CN101538490A (en) * 2009-04-30 2009-09-23 合肥工业大学 Micro-emulsified biomass fuel and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101348738A (en) * 2008-01-14 2009-01-21 郑州亚星能源科技有限公司 Emulsified biomass oil additive, emulsified biomass oil using the emulsified biomass oil additive and preparation thereof
CN101538490A (en) * 2009-04-30 2009-09-23 合肥工业大学 Micro-emulsified biomass fuel and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103789051A (en) * 2014-02-26 2014-05-14 泗洪新创源木业有限公司 Composite biomass liquid fuel
CN103789051B (en) * 2014-02-26 2015-12-09 泗洪新创源木业有限公司 A kind of composite biomass liquid fuel
GB2618210A (en) * 2022-03-23 2023-11-01 Innospec Ltd Compositions, methods and uses

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Application publication date: 20120516