CN103788914A - Anti-algae silicone adhesive and preparation method thereof - Google Patents
Anti-algae silicone adhesive and preparation method thereof Download PDFInfo
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- CN103788914A CN103788914A CN201310726905.2A CN201310726905A CN103788914A CN 103788914 A CN103788914 A CN 103788914A CN 201310726905 A CN201310726905 A CN 201310726905A CN 103788914 A CN103788914 A CN 103788914A
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- algae
- silicone adhesive
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- preparation
- filler
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- 239000013464 silicone adhesive Substances 0.000 title claims abstract description 60
- 238000002360 preparation method Methods 0.000 title claims abstract description 28
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- 239000000945 filler Substances 0.000 claims abstract description 19
- 239000007822 coupling agent Substances 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims description 27
- 239000000463 material Substances 0.000 claims description 23
- -1 methyl isopropyl Chemical group 0.000 claims description 22
- 241000195493 Cryptophyta Species 0.000 claims description 19
- 239000003292 glue Substances 0.000 claims description 19
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical group [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 18
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 18
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 18
- XMTQQYYKAHVGBJ-UHFFFAOYSA-N 3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA Chemical compound CN(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XMTQQYYKAHVGBJ-UHFFFAOYSA-N 0.000 claims description 16
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 15
- 229940043810 zinc pyrithione Drugs 0.000 claims description 15
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 claims description 15
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 12
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 12
- 239000004902 Softening Agent Substances 0.000 claims description 10
- PORQOHRXAJJKGK-UHFFFAOYSA-N 4,5-dichloro-2-n-octyl-3(2H)-isothiazolone Chemical compound CCCCCCCCN1SC(Cl)=C(Cl)C1=O PORQOHRXAJJKGK-UHFFFAOYSA-N 0.000 claims description 9
- 239000005510 Diuron Substances 0.000 claims description 9
- 239000010949 copper Substances 0.000 claims description 9
- 238000001125 extrusion Methods 0.000 claims description 9
- 229960004643 cupric oxide Drugs 0.000 claims description 8
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 7
- 229910052802 copper Inorganic materials 0.000 claims description 7
- VCRZAKVGPJFABU-UHFFFAOYSA-N 10-phenoxarsinin-10-yloxyphenoxarsinine Chemical compound C12=CC=CC=C2OC2=CC=CC=C2[As]1O[As]1C2=CC=CC=C2OC2=CC=CC=C21 VCRZAKVGPJFABU-UHFFFAOYSA-N 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 229910021529 ammonia Inorganic materials 0.000 claims description 6
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- 101100188540 Candida albicans (strain SC5314 / ATCC MYA-2876) OBPA gene Proteins 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 5
- LBJNMUFDOHXDFG-UHFFFAOYSA-N copper;hydrate Chemical compound O.[Cu].[Cu] LBJNMUFDOHXDFG-UHFFFAOYSA-N 0.000 claims description 5
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 4
- XUPZWMXQVSOBBU-UHFFFAOYSA-N [As].C1=CC=CC=2OC3=CC=CC=C3NC12 Chemical compound [As].C1=CC=CC=2OC3=CC=CC=C3NC12 XUPZWMXQVSOBBU-UHFFFAOYSA-N 0.000 claims description 4
- TVJPBVNWVPUZBM-UHFFFAOYSA-N [diacetyloxy(methyl)silyl] acetate Chemical compound CC(=O)O[Si](C)(OC(C)=O)OC(C)=O TVJPBVNWVPUZBM-UHFFFAOYSA-N 0.000 claims description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Substances CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 claims description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- 229920002554 vinyl polymer Polymers 0.000 claims description 4
- 241000195649 Chlorella <Chlorellales> Species 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 24
- 239000000853 adhesive Substances 0.000 abstract description 4
- 230000001070 adhesive effect Effects 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 3
- 239000002699 waste material Substances 0.000 abstract description 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 239000003973 paint Substances 0.000 description 6
- 241000894006 Bacteria Species 0.000 description 4
- 230000000844 anti-bacterial effect Effects 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 241000233866 Fungi Species 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 230000002147 killing effect Effects 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000003171 wood protecting agent Substances 0.000 description 3
- RUPBZQFQVRMKDG-UHFFFAOYSA-M Didecyldimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCC[N+](C)(C)CCCCCCCCCC RUPBZQFQVRMKDG-UHFFFAOYSA-M 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 239000003139 biocide Substances 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 150000004756 silanes Chemical class 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- PUAQLLVFLMYYJJ-UHFFFAOYSA-N 2-aminopropiophenone Chemical compound CC(N)C(=O)C1=CC=CC=C1 PUAQLLVFLMYYJJ-UHFFFAOYSA-N 0.000 description 1
- VAJVDSVGBWFCLW-UHFFFAOYSA-N 3-Phenyl-1-propanol Chemical compound OCCCC1=CC=CC=C1 VAJVDSVGBWFCLW-UHFFFAOYSA-N 0.000 description 1
- 201000004384 Alopecia Diseases 0.000 description 1
- 229920002955 Art silk Polymers 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000005749 Copper compound Substances 0.000 description 1
- 208000001840 Dandruff Diseases 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- DYUQAZSOFZSPHD-UHFFFAOYSA-N Phenylpropyl alcohol Natural products CCC(O)C1=CC=CC=C1 DYUQAZSOFZSPHD-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003619 algicide Substances 0.000 description 1
- 231100000360 alopecia Toxicity 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical class [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 150000001880 copper compounds Chemical class 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 229940112669 cuprous oxide Drugs 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 235000003599 food sweetener Nutrition 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000000750 industrial fungicide Substances 0.000 description 1
- 239000008235 industrial water Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000010808 liquid waste Substances 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
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- 230000000050 nutritive effect Effects 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000004590 silicone sealant Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000003765 sweetening agent Substances 0.000 description 1
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- 238000010998 test method Methods 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
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- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an anti-algae silicone adhesive and a preparation method thereof. The anti-algae silicone adhesive is prepared by the following step: adding an environment-friendly and efficient anti-algae agent into a base adhesive (107 adhesive), a crosslinking agent, filler, a catalyst, a plasticizer, a coupling agent and the like through a conventional adhesive preparation process by means of existing silicone adhesive production equipment. The anti-algae silicone adhesive provided by the invention is low in cost of raw materials, simple in production process and free from discharge of three wastes, and meets the environment-friendly requirement. The anti-algae silicone adhesive prepared by the invention is excellent in anti-algae performance and satisfies the using technical requirements in the fields such as buildings, electronic and electric appliances, automobiles and ships.
Description
[technical field]
The present invention relates to seal gum field.More specifically, the present invention relates to a kind of silicone adhesive with anti-algae function, also relates to the preparation method of described anti-algae silicone adhesive.
[background technology]
Single-component room-temperature vulcanized (RTV-1) silicone adhesive, with its excellent winter hardiness, thermotolerance, weathering resistance and electrical insulating property etc., has a wide range of applications in fields such as building, communications and transportation, machinery, electronics and chemical industry.In use, some organism that contain in silicone adhesive component are easy to become the nutritive substance that harmful microorganism spreads under optimum conditions.As the silicone adhesive being applied in building curtain wall is easy to grow algae, liver moss etc. in the damp atmosphere that has sunlight, and these materials also can provide nutrition for bacterium, mould, short its Fast Growth, this not only makes to build attractive in appearance being affected, and structure that more seriously can breakseal glue, cause curtain wall to come off, cause security incident; For another example be applied to silicone sealant in boats and ships hull and be easy to be subject to the infringement of algae and stained in the atmospheric marine environment of very severe for a long time, not only affect attractive in appearance, and the more important thing is and make hull surface frictional coefficient become large, cause the speed of a ship or plane to reduce, increase fuel consumption 5% left and right, wasted mass energy, the latter seems particularly important for national defence and war preparedness.In coating and circulating water treatment field, people often suppress the growth and breeding of algae by adding some materials with anti-algae algae removal.The material of having reported has derivative, copper compounds, organic quaternary ammonium salt Huo quaternary alkylphosphonium salt, heterogeneous ring compound of organotin, phenol etc., and wherein most because toxicity is large, application is restricted the derivative of organotin and phenol.Through lot of documents retrieval, there is not yet the report that anti-algae technology is applied in silicone adhesive.
Following field as ocean on various facilities, warship, fishing boat etc.; Some outdoor architecture facility is as the facility such as sculpture, roof in bridge, swimming pool pool wall, purification tank for liquid waste, waterworks pool wall, external wall, city; Dark moist wall or the ground such as bathroom, vault; The pipe-line equipment of industrial water system, often runs into the problem that used common silicone adhesive algal suspension is encroached on.Be badly in need of in the market wanting a kind of safety, environmental protection, efficient anti-algae silicone adhesive to solve problems.Also need the production process of material simple, cost is lower, so that apply on a large scale simultaneously.For this reason, the inventor has completed the present invention finally through lot of experiments.
[summary of the invention]
The object of this invention is to provide a kind of anti-algae silicone adhesive.
Another object of the present invention is to provide the preparation method of described anti-algae silicone adhesive.
The present invention is achieved through the following technical solutions.
The present invention relates to a kind of anti-algae silicone adhesive, it is characterized in that what described anti-algae silicone adhesive was made up of following component by weight:
Basis glue 50-80 part;
Linking agent 2-10 part;
Filler 2-40 part;
Catalyzer 0.05-1 part;
Softening agent 0-20 part;
Coupling agent 0.5-5 part;
Anti-algae agent 0.5-2 part;
Described basic glue is α, alpha, omega-dihydroxy polydimethyl siloxane (107 glue); Described linking agent is the one in methyl triacetoxysilane, methyl tributanoximo silane, vinyl tributyl ketoximyl silane, methyltrimethoxy silane, tetraethyl silicate or methyl isopropyl alkene TMOS; Described filler is the one in gas-phase silica or nano-calcium carbonate; Described catalyzer is the one in dibutyl tin laurate or tetra-n-butyl titanic acid ester; Described softening agent is polydimethylsiloxane; Described coupling agent is (KH-560) one in propyl trimethoxy silicane or γ-(methacryloxypropyl) propyl trimethoxy silicane (KH-570) of γ-(2,3-epoxy the third oxygen).
Described anti-algae agent is cupric oxide, Red copper oxide, the molten quaternary ammonium copper of ammonia (ACQ-B), 3-(3,4-dichlorophenyl)-1,1-dimethyl urea (Diuron Tech), Zinc Pyrithione (ZPT), N-octyl group-isothiazolinone (OIT), 4,5-bis-chloro-N-octyl group-4-isothiazoline-3-ketone (DCOIT), 1,2-benzisothiazole-3-ketone (BIT), n-butyl-1,2-isothiazoline-3-ketone (BBIT) or 10, one or more in the two phenoxazine arsenic (OBPA) of 10 '-oxo.
The invention still further relates to the preparation method of anti-algae silicone adhesive, the step that it is characterized in that the method is as follows: first basic glue, softening agent, linking agent are dropped in planetary kneader by proportioning, at 80-120 ℃ after vacuum stirring 15-30min, divide and drop into filler by proportioning 2-4 time, every minor tick 10-15 min, adds filler and continues to stir 30-60min; And then add catalyzer, anti-algae agent and coupling agent by proportioning, vacuum stirring 30-60min at 80-120 ℃; Finally be cooled to 30-40 ℃ of extrusion material and pack, complete the preparation of anti-algae silicone adhesive.
Anti-algae silicone adhesive type of the present invention is the de-acetic acid type of single-component, single-component ketoxime removing type, single-component dealcoholization-type or single-component deacetone, can meet the different technical requirements in silicone adhesive different application field.
Product stock stable performance of the present invention, raw materials safety and environmental protection, in use can effectively suppress the growth and breeding of harmful algae, 4 kinds of anti-algae grades of mixing algae such as chlorella, silk algae, four tail grid algaes, the algae that quivers are reached to 1～0 grade, and endurance quality excellence.
The present invention will be described below in more detail.
The present invention relates to a kind of anti-algae silicone adhesive, it is characterized in that what described anti-algae silicone adhesive was made up of following component by weight:
Basis glue 50-80 part;
Linking agent 2-10 part;
Filler 2-40 part;
Catalyzer 0.05-1 part;
Softening agent 0-20 part;
Coupling agent 0.5-5 part;
Anti-algae agent 0.5-2 part.
According to the bright a kind of preferred implementation of this law, described basic glue is α, alpha, omega-dihydroxy polydimethyl siloxane (107 glue); Described linking agent is the one in methyl triacetoxysilane, methyl tributanoximo silane, vinyl tributyl ketoximyl silane, methyltrimethoxy silane, tetraethyl silicate or methyl isopropyl alkene TMOS; Described filler is the one in gas-phase silica or nano-calcium carbonate; Described catalyzer is the one in dibutyl tin laurate or tetra-n-butyl titanic acid ester; Described softening agent is polydimethylsiloxane; Described coupling agent is (KH-560) one in propyl trimethoxy silicane or γ-(methacryloxypropyl) propyl trimethoxy silicane (KH-570) of γ-(2,3-epoxy the third oxygen).The above raw material of the present invention is the commercially available conventional products of preparing silicone adhesive.
According to the bright another kind of preferred implementation of this law, described anti-algae agent is cupric oxide, Red copper oxide, the molten quaternary ammonium copper of ammonia (ACQ-B), 3-(3,4-dichlorophenyl)-1,1-dimethyl urea (Diuron Tech), Zinc Pyrithione (ZPT), N-octyl group-isothiazolinone (OIT), 4,5-bis-chloro-N-octyl group-4-isothiazoline-3-ketone (DCOIT), 1,2-benzisothiazole-3-ketone (BIT), n-butyl-1,2-isothiazoline-3-ketone (BBIT) or 10, one or more in the two phenoxazine arsenic (OBPA) of 10 '-oxo.
Cupric oxide (CuO), CAS is numbered 1317-38-0, and median size is 0.05-10 μ m, is mainly used in artificial silk processed, pottery, glaze and enamel, battery, petroleum sweetening agent, sterilant, also for hydrogen manufacturing, catalyzer, green glass etc.The present invention's ultrafine copper oxide powder used is commercially available.
Red copper oxide (Cu O), CAS is numbered 1317-39-1, median size is 0.05-10 μ m, can be used for ship bottom anti-fouling paint processed (killing rudimentary marine animal), also for the manufacture of various mantoquitas, analytical reagent and for the rectification of electrical equipment industry electroplate, the sterilant of farm crop and rectifier material etc.The present invention's ultrafine cuprous oxide powder used is commercially available.
The molten quaternary ammonium copper of ammonia (Ammonical Copper Quat), be called for short ACQ, it is the novel wood preservative that small-sized wood preservation company of the 70's of 20th century, one, Sweden develops and applies for a patent, the 80's were bought this patent by american chemical industrial (CSI), and carried out great many of experiments and improvement, form business-like ACQ wood preservative.In this sanitas, do not contain chromium class heavy metal and arsenic class highly toxic substance, little to person poultry toxicity, also have remarkable anticorrosion, insect protected function simultaneously, in timber, fixation performance is good, little to environmental influence.This sanitas development is in recent years very fast, becomes the representative of water ballast wood preservative of new generation.The main component of ACQ-B is cupric oxide (CuO) and Timbercote 2000 (DDAC).The present invention ACQ-B used is Dalian Ming Huimu industry company limited product sold.
3-(3,4-dichlorophenyl)-1,1-dimethyl urea (Diuron Tech), CAS is numbered 330-54-1, and molecular formula is C
9h
10c
l2n
2o, sterling is white odorless crystal, belongs to phenyl ureagroup herbicides, inhale conduction and certain action of contace poison, but it has the very strong effect of killing to algae in tool.The present invention's Diuron Tech used is the product of Wuhan Jin Nuo Chemical Co., Ltd. production and sales.
ZPT, English name is Pyrithionc Zinc, writes a Chinese character in simplified form ZPT, calls as Pyrithionc Zinc, and CAS is numbered 13463-41-7, and molecular formula is C
10h
8n
2o
2s
2zn, molecular weight is 317.7.For shampoo anti-dandruff, can suppress the growth of Gram-positive, negative bacteria and mould.Hair conditioning effectively, delays the aging of hair, controls the generation of white hair and alopecia.Also be used as in addition makeup preservatives or finish, coating biocide; As the Biocidal algae-killing agent of the product such as coating and plastics, use also very extensive.The present invention's ZPT used (ZPT) is the set a prairie fire product of Chemical Co., Ltd.'s production and sales of Hebei KeYu biochemical industry company limited or Jiangsu.
N-octyl group-isothiazolinone, CAS is numbered 26530-20-1, is called for short OIT, is dissolved in organic solvent, is slightly soluble in water, is a kind of low toxicity, efficient, broad spectrum type mould inhibitor algaecide, and mould, algae are had to very strong killing action, can reach desirable anti-mold effect.Can be widely used in all multi-products such as coating, paint, lubricating oil, shoe polish, leather chemistry, timber-work and historical relic's protection.VOC free, high light and high temperatures, sterilization broad-spectrum high efficacy, can effectively prevent bacterium and fungi in plastics.The present invention OIT used is the product of Dalian Bai Ao chemical company or Beijing Tianqing Chemical Co., Ltd.'s production and sales.
The chloro-N-octyl group-4-of 4,5-bis-isothiazoline-3-ketone, CAS is numbered 64359-81-5, is called for short DCOIT, is a kind of wide-spectrum bactericide.Can be widely used in the plastic industries such as paint, coating, polyethylene, polyurethane, leather, paint, coating, sewage, papermaking, timber, tackiness agent, the fields such as ink, can replace the compound such as organoarsenic of huge poison.The present invention DCOIT used is the product of Dalian Bai Ao chemical company or Beijing Tianqing Chemical Co., Ltd.'s production and sales.
BIT, CAS is numbered 2634-33-5, is called for short BIT, is main industrial sterilization, anticorrosion, anti-enzyme agent.There is the grow effects of microorganism in organic medium such as outstanding mould fungus inhibition (fungi, bacterium), algae, solved that the organic products that microbial growth causes is mouldy, fermentation, rotten, breakdown of emulsion, smelly, etc. series of problems.The present invention DCOIT used is the product of Dalian Bai Ao chemical company production and sales.
N-butyl-1,2-isothiazoline-3-ketone, CAS is numbered CAS 4299-07-4, be called for short BBIT, be exclusively used in to kill and corrode the microorganism being attached on the macromolecular materials such as urethane (PU), polyvinyl chloride (PVC), polysiloxane (silicone), polyethylene (PE), polypropylene (PP), can be miscible with softening agent, organic carrier and thinner, easy to use.The present invention BBIT used is the product of Shandong Ai Pu chemical company production and sales.
10, the two phenoxazine arsenic (OBPA) of 10 '-oxo, CAS is numbered 58-36-6, and molecular formula is C
24h
16as
2o
3, be a kind of novel industrial fungicide, simultaneously mildew-resistant, antibacterial, anti-algae, be one of the most effective antiseptic-germicide of industrial circle.Can add PVC goods, plastics, PVC flooring material, wallcovering, paint, ink, paper etc. to, than other inorganic or organic system only can be antibacterial or effect that only can mildew-resistant more excellent.
Preferably, anti-algae agent of the present invention is the molten quaternary ammonium copper of Red copper oxide, ammonia (ACQ-B), 3-(3,4-dichlorophenyl)-1,1-dimethyl urea (Diuron Tech), Zinc Pyrithione (ZPT), 4,5-bis-chloro-N-octyl group-4-isothiazoline-3-ketone (DCOIT), 1,2-benzisothiazole-3-ketone (BIT) or n-butyl-1, one or more in 2-isothiazoline-3-ketone (BBIT).
More preferably, anti-algae agent of the present invention is the molten quaternary ammonium copper of ammonia (ACQ-B), 3-(3,4-dichlorophenyl)-1,1-dimethyl urea (Diuron Tech), Zinc Pyrithione (ZPT) or n-butyl-1, one or more in 2-isothiazoline-3-ketone (BBIT).
The invention still further relates to the preparation method of anti-algae silicone adhesive, the step that it is characterized in that the method is as follows: first basic glue, softening agent, linking agent are dropped in planetary kneader by proportioning, at 80-120 ℃ after vacuum stirring 15-30min, divide and drop into filler by proportioning 2-4 time, every minor tick 10-15 min, adds filler and continues to stir 30-60min; And then add catalyzer, anti-algae agent and coupling agent by proportioning, vacuum stirring 30-60min at 80-120 ℃; Finally be cooled to 30-40 ℃ of extrusion material and pack, complete the preparation of anti-algae silicone adhesive.
According to the bright a kind of preferred implementation of this law, described planetary kneader is multilayer paddle formula double-planet stirrer, is a kind of reaction, mixing, mixing, efficient, multipurpose plant of being separated into one of collecting.Be applicable to the liquid-liquid, solid-liquid, lotion-lotion, powder-cream material density ratio great disparity of every profession and trade, from low-viscosity to high viscosity in the production technique of (1,500,000 CPS).The present invention's multi-layer oar blade formula used double-planet stirrer is the equipment of Shanghai Suowei Electromechanical Equipment Co., Ltd.'s production and sales.
According to the bright another kind of preferred implementation of this law, in described preparation technology, the vacuum tightness of planetary kneader is-0.08～0.1MPa, and rotating speed is 300-600rpm.In product of the present invention preparation, material system must remain in high vacuum state, contained humidity in material is departed from away, otherwise can affect the storage effect of moulding product; It is moderate that material spoils speed, both guaranteed material kneading fully, do not waste energy again, thinks that equipment mixing speed is controlled at 300-600rpm most suitable through great many of experiments.
Describe the detection test of the anti-algae performance of anti-algae silicone adhesive prepared by the present invention below in detail.
Detection method and detected result are as follows: the anti-mold effect of the anti-algae companion's of 0.5% antibacterial and mouldproof phenylpropyl alcohol construction coating for internal wall has been added in the anti-algae effect assessment test of the anti-algae silicone adhesive of the present invention by the measurement of test method of GB/T 21353-2008 " the anti-algae property assay method of paint film " standard regulation.Its test-results is listed in table 1.
Table 1: the anti-algae test-results of the anti-algae silicone adhesive of the present invention
The anti-algae silicone adhesive that the present invention makes is as can be seen from Table 1 to four kinds of anti-algae performance excellences of mixing algae such as chlorella, silk algaes, and anti-algae grade reaches 1-0 level.
The present invention has following beneficial effect:
The present invention utilizes existing silicone adhesive production unit, and the frequent regulation adhesive process of environmental protection, the agent of Effective Anti algae of meticulously selecting is added in silicone adhesive material and gone, and completes anti-algae silicone adhesive and produces.Production technique is simple, and facility investment is few, is easy to suitability for industrialized production, and production cost is low, environmentally friendly, has the very strong market competitiveness.The present invention, by adjusting basic material kind, easily realizes multiple types as the production of de-acetic acid type, ketoxime removing type, dealcoholizing-type and the anti-algae silicone adhesive of deacetone, meets different field without technical requirements.Anti-algae silicone adhesive storge quality prepared by the present invention is stable, anti-algae performance excellence.
[embodiment]
To understand better the present invention by following these embodiment.
embodiment 1:the preparation of the anti-algae silicone adhesive of the present invention
First by 68.4 parts of α, alpha, omega-dihydroxy polydimethyl siloxane (107 glue), 5 parts of polydimethylsiloxanes, 2 parts of methyl triacetoxysilanes drop in the multi-layer oar blade formula double-planet stirrer of Shanghai Suowei Electromechanical Equipment Co., Ltd.'s production, at 100 ℃ after vacuum stirring 20min, divide and drop into 20 parts of thermal silicas 4 times, every minor tick 10min, adds filler and continues to stir 40min; Then add 0.1 part of dibutyl tin laurate, 0.5 part of Cu
2o, 1 part of Diuron Tech and 3 parts of KH560, vacuum stirring 60min at 100 ℃; Finally be cooled to 30-40 ℃ of extrusion material and pack, complete the preparation of the de-acetic acid type silicone adhesive of anti-algae.The vacuum tightness of stirrer is-0.08～0.1MPa, and rotating speed is 600rpm.
embodiment 2:the preparation of the anti-algae silicone adhesive of the present invention
First by 58.5 parts of α, alpha, omega-dihydroxy polydimethyl siloxane (107 glue), 3 parts of polydimethylsiloxanes, 5 parts of methyl tributanoximo silanes drop in the multi-layer oar blade formula double-planet stirrer of Shanghai Suowei Electromechanical Equipment Co., Ltd.'s production, at 110 ℃ after vacuum stirring 20min, divide and drop into 20 parts of nano-calcium carbonates 4 times, every minor tick 15min, adds filler and continues to stir 50min; Then add 0.5 part of tetra-n-butyl titanic acid ester, 1 part of ZPT and 5 parts of KH570, vacuum stirring 60min at 110 ℃; Finally be cooled to 30-40 ℃ of extrusion material and pack, complete the preparation of anti-algae ketoxime removing type silicone adhesive.The vacuum tightness of stirrer is-0.08～0.1MPa, and rotating speed is 400rpm.
embodiment 3:the preparation of the anti-algae silicone adhesive of the present invention
First by 73.8 parts of α, alpha, omega-dihydroxy polydimethyl siloxane (107 glue), 5 parts of polydimethylsiloxanes, 8 parts of methyltrimethoxy silanes drop in the multi-layer oar blade formula double-planet stirrer of Shanghai Suowei Electromechanical Equipment Co., Ltd.'s production, at 100 ℃ after vacuum stirring 20min, divide and drop into 10 parts of thermal silicas 2 times, every minor tick 15min, adds filler and continues to stir 40min; Then add 0.1 part of dibutyl tin laurate, 0.1 part of DCOIT, 1 part of Diuron Tech and 2 parts of KH560, vacuum stirring 60min at 100 ℃; Finally be cooled to 30-40 ℃ of extrusion material and pack, complete the preparation of anti-algae dealcoholizing-type silicone adhesive.The vacuum tightness of stirrer is-0.08～0.1MPa, and rotating speed is 500rpm.
embodiment 4:the preparation of the anti-algae silicone adhesive of the present invention
First by 75.4 parts of α, alpha, omega-dihydroxy polydimethyl siloxane (107 glue), 8 parts of polydimethylsiloxanes, 5 parts of methyl isopropyl alkene TMOSs drop in the multi-layer oar blade formula double-planet stirrer of Shanghai Suowei Electromechanical Equipment Co., Ltd.'s production, at 100 ℃ after vacuum stirring 10min, divide and drop into 10 parts of thermal silicas 2 times, every minor tick 10min, adds filler and continues to stir 60min; Then add 0.6 part of dibutyl tin laurate, 0.2 part of ACQ-B, 0.2 part of OIT and 0.1 part of BBIT and 0.5 part of KH560, vacuum stirring 60min at 100 ℃; Finally be cooled to 30-40 ℃ of extrusion material and pack, complete the preparation of anti-algae deacetone silicone adhesive.The vacuum tightness of stirrer is-0.08～0.1MPa, and rotating speed is 300rpm.
embodiment 5:the preparation of the anti-algae silicone adhesive of the present invention
First by 56.2 parts of α, alpha, omega-dihydroxy polydimethyl siloxane (107 glue), 5 parts of polydimethylsiloxanes, 2 parts of vinyl tributyl ketoximyl silanes drop in the multi-layer oar blade formula double-planet stirrer of Shanghai Suowei Electromechanical Equipment Co., Ltd.'s production, at 120 ℃ after vacuum stirring 20min, divide and drop into 30 parts of nano-calcium carbonates 4 times, every minor tick 15min, adds filler and continues to stir 60min; Then add 1 part of tetra-n-butyl titanic acid ester, 0.5 part of Cu
2o, 0.3 part of OIT and 5 parts of KH570, vacuum stirring 60min at 100 ℃; Finally be cooled to 30-40 ℃ of extrusion material and pack, complete the preparation of anti-algae ketoxime removing type silicone adhesive.The vacuum tightness of stirrer is-0.08～0.1MPa, and rotating speed is 600rpm.
embodiment 6:the preparation of the anti-algae silicone adhesive of the present invention
First by 79.3 parts of α, alpha, omega-dihydroxy polydimethyl siloxane (107 glue), 8 parts of polydimethylsiloxanes, 5 parts of tetraethyl silicate drop in the multi-layer oar blade formula double-planet stirrer of Shanghai Suowei Electromechanical Equipment Co., Ltd.'s production, at 80 ℃ after vacuum stirring 10min, divide and drop into 6 parts of thermal silicas 2 times, every minor tick 10min, adds filler and continues to stir 60min; Then add 0.6 part of dibutyl tin laurate, 0.1 part of OBPA, 0.5 part of CuO and 0.5 part of KH560, vacuum stirring 60min at 100 ℃; Finally be cooled to 30-40 ℃ of extrusion material and pack, complete the preparation of anti-algae dealcoholizing-type silicone adhesive.The vacuum tightness of stirrer is-0.08～0.1MPa, and rotating speed is 400rpm.
Adopt the testing method of describing in this specification sheets, tested the anti-algae performance of anti-algae silicone adhesive prepared by the present embodiment 1-6, its test result lists in table 2.
Table 2: the anti-algae performance test-results of anti-algae silicone adhesive prepared by embodiment 1-6
Claims (7)
1. an anti-algae silicone adhesive, is characterized in that what described anti-algae silicone adhesive was made up of following component by weight:
Basis glue 50-80 part;
Linking agent 2-10 part;
Filler 2-40 part;
Catalyzer 0.05-1 part;
Softening agent 0-20 part;
Coupling agent 0.5-5 part;
Anti-algae agent 0.5-2 part;
Described basic glue is α, alpha, omega-dihydroxy polydimethyl siloxane (107 glue); Described linking agent is the one in methyl triacetoxysilane, methyl tributanoximo silane, vinyl tributyl ketoximyl silane, methyltrimethoxy silane, tetraethyl silicate or methyl isopropyl alkene TMOS; Described filler is the one in gas-phase silica or nano-calcium carbonate; Described catalyzer is the one in dibutyl tin laurate or tetra-n-butyl titanic acid ester; Described softening agent is polydimethylsiloxane; Described coupling agent is (KH-560) one in propyl trimethoxy silicane or γ-(methacryloxypropyl) propyl trimethoxy silicane (KH-570) of γ-(2,3-epoxy the third oxygen).
2. anti-algae silicone adhesive according to claim 1, it is characterized in that described anti-algae agent is cupric oxide, Red copper oxide, the molten quaternary ammonium copper of ammonia (ACQ-B), 3-(3,4-dichlorophenyl)-1,1-dimethyl urea (Diuron Tech), Zinc Pyrithione (ZPT), N-octyl group-isothiazolinone (OIT), 4,5-bis-chloro-N-octyl group-4-isothiazoline-3-ketone (DCOIT), 1,2-benzisothiazole-3-ketone (BIT), n-butyl-1,2-isothiazoline-3-ketone (BBIT) or 10, one or more in the two phenoxazine arsenic (OBPA) of 10 '-oxo.
3. according to the preparation method of the anti-algae silicone adhesive described in claim 1-2, the step that it is characterized in that the method is as follows: first basic glue, softening agent, linking agent are dropped in planetary kneader by proportioning, at 80-120 ℃ after vacuum stirring 15-30min, divide and drop into filler by proportioning 2-4 time, every minor tick 10-15 min, adds filler and continues to stir 30-60min; And then add catalyzer, anti-algae agent and coupling agent by proportioning, vacuum stirring 30-60min at 80-120 ℃; Finally be cooled to 30-40 ℃ of extrusion material and pack, complete the preparation of anti-algae silicone adhesive.
4. preparation method according to claim 3, is characterized in that described planetary kneader is multilayer paddle formula double-planet stirrer.
5. preparation method according to claim 3, is characterized in that the vacuum tightness of described planetary kneader is-0.08～0.1MPa, and rotating speed is 300-600rpm.
6. according to the anti-algae silicone adhesive described in claim 1-5, it is characterized in that described silicone adhesive type is the de-acetic acid type of single-component, single-component ketoxime removing type, single-component dealcoholization-type or single-component deacetone.
7. according to the anti-algae silicone adhesive described in claim 1-6, it is characterized in that described anti-algae silicone adhesive reaches 1～0 grade to 4 kinds of anti-algae grades of mixing algae such as chlorella, silk algae, four tail grid algaes, the algaes that quivers.
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104388040A (en) * | 2014-10-23 | 2015-03-04 | 中国航空工业集团公司北京航空材料研究院 | Single-component flame-retardant ketoxime-removed/dealcoholized room temperature vulcanized organosilicon sealant and preparation method thereof |
| CN105885768A (en) * | 2016-06-06 | 2016-08-24 | 湖北新海鸿化工有限公司 | Antibacterial and anti-oxidation silicone adhesive and preparing method thereof |
| CN106084234A (en) * | 2016-06-06 | 2016-11-09 | 湖北新海鸿化工有限公司 | The preparation method of a kind of organosilicon quaternary amine antibacterial and silicone adhesive |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6103804A (en) * | 1998-10-07 | 2000-08-15 | Wacker Silicones Corporation | Process for the sealing components exposed to aggressive functional fluids and RTV silicone compositions suitable for use therein |
| CN102277127A (en) * | 2011-08-05 | 2011-12-14 | 曾庆铭 | Acidic silicone sealant |
-
2013
- 2013-12-26 CN CN201310726905.2A patent/CN103788914B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6103804A (en) * | 1998-10-07 | 2000-08-15 | Wacker Silicones Corporation | Process for the sealing components exposed to aggressive functional fluids and RTV silicone compositions suitable for use therein |
| CN102277127A (en) * | 2011-08-05 | 2011-12-14 | 曾庆铭 | Acidic silicone sealant |
Non-Patent Citations (1)
| Title |
|---|
| 李子东等: "《胶黏剂助剂》", 28 February 2005, article "《胶黏剂助剂》", pages: 458 * |
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| CN104388040B (en) * | 2014-10-23 | 2016-02-24 | 中国航空工业集团公司北京航空材料研究院 | Single component flame retardant takes off ketoxime/alcohol room temperature vulcanized organosilicon sealant and preparation method |
| CN105885768A (en) * | 2016-06-06 | 2016-08-24 | 湖北新海鸿化工有限公司 | Antibacterial and anti-oxidation silicone adhesive and preparing method thereof |
| CN106084234A (en) * | 2016-06-06 | 2016-11-09 | 湖北新海鸿化工有限公司 | The preparation method of a kind of organosilicon quaternary amine antibacterial and silicone adhesive |
| WO2018076337A1 (en) * | 2016-10-31 | 2018-05-03 | Wacker Chemie Ag | One-part room-temperature curable compositions on basis of organosilicon compounds and titanium curing catalysts |
| US11814522B2 (en) | 2016-10-31 | 2023-11-14 | Wacker Chemie Ag | One-part room-temperature curable compositions on the basis of organosilicon compounds and titanium curing catalysts |
| CN106753201A (en) * | 2016-12-14 | 2017-05-31 | 中蓝晨光化工研究设计院有限公司 | A kind of automotive electronics label silicon rubber bonder and preparation method thereof |
| CN107325397A (en) * | 2017-06-12 | 2017-11-07 | 广东省微生物研究所（广东省微生物分析检测中心） | A kind of mildew-resistant algae-resistant feature wood plastic composite and preparation method thereof |
| WO2021027032A1 (en) * | 2019-08-14 | 2021-02-18 | 中国船舶重工集团公司第七二五研究所 | Coated anti-fouling agent nanocapsule having temperature control dcoit release rate and method for fabrication thereof |
| CN112175550A (en) * | 2020-10-19 | 2021-01-05 | 佛山吉麟环保新材料有限公司 | Special sealant for polycarbonate products |
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