CN103788779B - A kind of anti-formaldehyde sterilization wall finiss - Google Patents
A kind of anti-formaldehyde sterilization wall finiss Download PDFInfo
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- CN103788779B CN103788779B CN201410046414.8A CN201410046414A CN103788779B CN 103788779 B CN103788779 B CN 103788779B CN 201410046414 A CN201410046414 A CN 201410046414A CN 103788779 B CN103788779 B CN 103788779B
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- wall finiss
- formaldehyde
- formaldehyde sterilization
- styrene
- coalescents
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Abstract
The present invention discloses a kind of anti-formaldehyde sterilization wall finiss, based on quality 100%, include: organosilicon modified styrene acrylic acid ester emulsion, styrene acrylate resins liquid, nano titanium oxide, active carbon nanoparticles, siloxane crosslinker, acrylic thickener, ethylene glycol, coalescents, multifunctional assistant, preservative, antifungus agent and antibacterial；The present invention uses organosilicon modified styrene acrylic acid ester emulsion and styrene acrylate resins liquid and activated carbon and titanium dioxide mixture and coordinates siloxane crosslinker, coalescents, multifunctional assistant enables to each component and preferably combines, thus improve the adhesion property of product, simultaneously, use activated carbon adsorption, and under the catalytic action of titanium dioxide, can be by after the pollutant absorption such as the formaldehyde in family, and under the effect of illumination, formaldehyde is degraded removal, it is greatly improved the removal effect of formaldehyde, and by the way of wall finiss, it is coated on whole room, its removal effect is more comprehensive, wider, in hgher efficiency, this wall finiss also has sterilizing function simultaneously, relatively sanitary environment is improved for child.
Description
Technical field
The present invention relates to wall finiss art, refer in particular to a kind of anti-formaldehyde sterilization wall finiss.
Background technology
Owing to environmental protection and the most healthy attention, waterborne wall surface paint the most progressively instead of traditional solvent-borne wall finiss, owing to the technology content of waterborne wall surface paint is higher, it is relatively big that most domestic manufacturers produce difficulty, and solvent borne wall finiss is still propagated its belief on a large scale, and accounts for absolute main flow.It is that charcoal bag is placed on certain position formaldehyde adsorption that activated carbon has people before powerful adsorption function, but is limited in scope after all, saturated after cannot adsorb, become polluter, how the formaldehyde in activated carbon be degraded into important research topic in time.
In addition, along with people's attention to good inhabitation atmosphere, in addition to environmental protection is beneficial to able-bodied requirement, the most also scribble effect, antibiotic and sterilizing effect to wall finiss is required to more and more higher, especially to the family having child, there is again while how ensureing wall finiss environmental-protecting performance good bactericidal property, be urgent problem in this type of wall finiss.
Summary of the invention
In view of this, the present invention is directed to the disappearance of prior art existence, its main purpose is to provide the anti-formaldehyde sterilization wall finiss that a kind of tack is good.
For achieving the above object, the present invention uses such as purgation technical scheme: a kind of anti-formaldehyde sterilization wall finiss, based on quality 100%, includes:
Organosilicone-modified styrene-acrylic emulsion
40~50% ；
Styrene-acrylic resin liquid
20~30%
；
Nano titanium oxide
10-20%；
Active carbon nanoparticles
6~12%
Siloxane crosslinker
0.1-0.4%；
Acrylic thickener
0.2-0.7%
Ethylene glycol
2.0-4.0%；
Coalescents
2.0-5.5%；
Multifunctional assistant
0.05-0.3%；
Preservative
0.1-0.2%,
Antifungus agent
0.2-0.7%
Antibacterial
0.2-0.5%。
Described antibacterial is the mixture of organic antibacterial agent and natural antibacterial agent, and this organic antibacterial agent is quaternary ammonium compound, and this natural antibacterial agent is chitin.
Described coalescents is tripropylene glycol butyl ether.
Described multifunctional assistant is the AMP-95 of LG-DOW.
Described preservative is Kathon LXE.
Described organosilicon modified styrene-acrylic acid ester emulsion for a kind of Tg value be-15 ~-30 DEG C, acid number be 50mgKOH/g, solid content be the filming emulsion of 46 ~ 48%.
Described styrene-acrylate liquid be a kind of Tg value be 100 ~ 105 DEG C, acid number be 220mgKOH/g, solid content be the water-soluble resin of 35 ~ 37%.
nullThe present invention compared with prior art has clear advantage and beneficial effect，The present invention shows to use organosilicone-modified styrene-acrylic emulsion and styrene-acrylic resin liquid and activated carbon and titanium dioxide mixture by lot of experiments and coordinates siloxane crosslinker、Coalescents、Multifunctional assistant enables to each component and preferably combines，Thus improve the adhesion property of product，Simultaneously，Use activated carbon adsorption，And under the catalytic action of titanium dioxide，Can be by after the pollutant absorption such as the formaldehyde in family，And under the effect of illumination，Formaldehyde is degraded removal，It is greatly improved the removal effect of formaldehyde，And by the way of wall finiss, it is coated on whole room，Its removal effect is more comprehensive，Wider，In hgher efficiency，This wall finiss also has sterilizing function simultaneously，Relatively sanitary environment is improved for child.
Detailed description of the invention
Embodiment 1
A kind of anti-formaldehyde sterilization wall finiss, based on quality 100%, includes:
Organosilicone-modified styrene-acrylic emulsion
40% ；
Styrene-acrylic resin liquid
30%
；
Nano titanium oxide
13%；
Active carbon nanoparticles
10%
Siloxane crosslinker
0.1%；
Acrylic thickener
0.2%
Ethylene glycol
2.0%；
Coalescents
2.5%；
Multifunctional assistant
0.05%；
Preservative
0.15%,
Antifungus agent
0.5%
Antibacterial
0.5%。
Described antibacterial is the mixture of organic antibacterial agent and natural antibacterial agent, and this organic antibacterial agent is quaternary ammonium compound, and this natural antibacterial agent is chitin.
Described coalescents is tripropylene glycol butyl ether.
Described multifunctional assistant is the AMP-95 of LG-DOW.
Described preservative is Kathon LXE.
Described organosilicon modified styrene-acrylic acid ester emulsion be a kind of Tg value be-15 DEG C, acid number be 50mgKOH/g, solid content be the filming emulsion of 46%.
Described styrene-acrylate liquid be a kind of Tg value be 100 ~ 105 DEG C, acid number be 220mgKOH/g, solid content be the water-soluble resin of 37%.
Embodiment 2
A kind of anti-formaldehyde sterilization wall finiss, based on quality 100%, includes:
Organosilicone-modified styrene-acrylic emulsion
48.2% ；
Styrene-acrylic resin liquid
20%
；
Nano titanium oxide
15%；
Active carbon nanoparticles
8%
Siloxane crosslinker
0.3%；
Acrylic thickener
0.5%
Ethylene glycol
3.0%；
Coalescents
4%；
Multifunctional assistant
0.1%；
Preservative
0.1%,
Antifungus agent
0.5%
Antibacterial
0.3%。
Described antifungus agent is the chloro-benzimidazolyl-2 radicals-methyl acid of amidocarbonic acid-1-and N-(3,4 Dichlorobenzene base) mixture of-N.N-dimethyl urea.
Described antibacterial is the mixture of organic antibacterial agent and natural antibacterial agent, and this organic antibacterial agent is quaternary ammonium compound, and this natural antibacterial agent is chitin.
Described coalescents is tripropylene glycol butyl ether.
Described multifunctional assistant is the AMP-95 of LG-DOW.
Described preservative is Kathon LXE.
Described organosilicon modified styrene-acrylic acid ester emulsion be a kind of Tg value be-30 DEG C, acid number be 50mgKOH/g, solid content be the filming emulsion of 47%.
Described styrene-acrylate liquid be a kind of Tg value be 100 ~ 105 DEG C, acid number be 220mgKOH/g, solid content be the water-soluble resin of 36%.
Embodiment 3
A kind of anti-formaldehyde sterilization wall finiss, based on quality 100%, includes:
Organosilicone-modified styrene-acrylic emulsion
42% ；
Styrene-acrylic resin liquid
20%
；
Nano titanium oxide
18%；
Active carbon nanoparticles
12%
Siloxane crosslinker
0.4%；
Acrylic thickener
0.7%
Ethylene glycol
3%；
Coalescents
3%；
Multifunctional assistant
0.25%；
Preservative
0.15%,
Antifungus agent
0.2%
Antibacterial
0.3%。
Described antifungus agent is the chloro-benzimidazolyl-2 radicals-methyl acid of amidocarbonic acid-1-and N-(3,4 Dichlorobenzene base) mixture of-N.N-dimethyl urea.
Described antibacterial is the mixture of organic antibacterial agent and natural antibacterial agent, and this organic antibacterial agent is quaternary ammonium compound, and this natural antibacterial agent is chitin.
Described coalescents is tripropylene glycol butyl ether.
Described multifunctional assistant is the AMP-95 of LG-DOW.
Described preservative is Kathon LXE.
Described organosilicon modified styrene-acrylic acid ester emulsion be a kind of Tg value be-20 DEG C, acid number be 50mgKOH/g, solid content be the filming emulsion of 48%.
Described styrene-acrylate liquid be a kind of Tg value be 100 ~ 105 DEG C, acid number be 220mgKOH/g, solid content be the water-soluble resin of 35%.
The present invention shows to use organosilicone-modified styrene-acrylic emulsion and styrene-acrylic resin liquid and activated carbon and titanium dioxide mixture by lot of experiments and coordinates siloxane crosslinker, coalescents, multifunctional assistant enables to each component and preferably combines, thus improve the adhesion property of product, simultaneously, use activated carbon adsorption, and under the catalytic action of titanium dioxide, can be by after the pollutant absorption such as the formaldehyde in family, and under the effect of illumination, formaldehyde is degraded removal, it is greatly improved the removal effect of formaldehyde, and by the way of wall finiss, it is coated on whole room, its removal effect is more comprehensive, wider, in hgher efficiency, this wall finiss also has sterilizing function simultaneously, relatively sanitary environment is improved for child.
Anti-formaldehyde sterilization wall finiss prepared by embodiment 1 to 3, proves through a large amount of engineering tests, its formaldehyde treated efficiency is high, effective, and after coating ten days, formaldehyde clearance is more than 96.27%, and antibacterial ability is strong, and its bacteriostasis rate is more than 99.99%.
The above, it it is only presently preferred embodiments of the present invention, not the technical scope of the present invention is imposed any restrictions, therefore every technical spirit according to the present invention is to any trickle amendment made for any of the above embodiments, equivalent variations and modification, all still falls within the range of technical solution of the present invention.
Claims (7)
1. an anti-formaldehyde sterilization wall finiss, it is characterised in that: based on quality 100%, include:
Organosilicone-modified styrene-acrylic emulsion 40 ~ 50%；
Styrene-acrylic resin liquid 20 ~ 30%；
Nano titanium oxide 10-20%；
Active carbon nanoparticles 6 ~ 12%；
Siloxane crosslinker 0.1-0.4%；
Acrylic thickener 0.2-0.7%；
Ethylene glycol 2.0-4.0%；
Coalescents 2.0-5.5%；
Multifunctional assistant 0.05-0.3%；
Preservative 0.1-0.2%；
Antifungus agent 0.2-0.7%；
Antibacterial 0.2-0.5%.
A kind of anti-formaldehyde sterilization wall finiss, it is characterised in that: described antibacterial is organic antibacterial agent
With the mixture of natural antibacterial agent, this organic antibacterial agent is quaternary ammonium compound, and this natural antibacterial agent is chitin.
A kind of anti-formaldehyde sterilization wall finiss, it is characterised in that: described coalescents is tripropylene glycol
Butyl ether.
A kind of anti-formaldehyde sterilization wall finiss, it is characterised in that: described multifunctional assistant is U.S.'s pottery
The AMP-95 of family name.
A kind of anti-formaldehyde sterilization wall finiss, it is characterised in that: described preservative is Kathon
LXE。
A kind of anti-formaldehyde sterilization wall finiss, it is characterised in that: described organosilicon modified styrene-
Acrylic acid ester emulsion for a kind of Tg value be-15 ~-30 DEG C, acid number be 50mgKOH/g, solid content be the filming emulsion of 46 ~ 48%.
A kind of anti-formaldehyde sterilization wall finiss, it is characterised in that: described styrene-acrylate
Resin liquid for a kind of Tg value be 100 ~ 105 DEG C, acid number be 220mgKOH/g, solid content be the water-soluble resin of 35 ~ 37%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410046414.8A CN103788779B (en) | 2014-02-10 | 2014-02-10 | A kind of anti-formaldehyde sterilization wall finiss |
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| CN201410046414.8A CN103788779B (en) | 2014-02-10 | 2014-02-10 | A kind of anti-formaldehyde sterilization wall finiss |
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| Publication Number | Publication Date |
|---|---|
| CN103788779A CN103788779A (en) | 2014-05-14 |
| CN103788779B true CN103788779B (en) | 2016-08-17 |
Family
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| CN (1) | CN103788779B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111635683A (en) * | 2020-06-05 | 2020-09-08 | 嘉应学院 | Antibacterial ceramic-like coating on stainless steel surface and preparation method thereof |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104479545A (en) * | 2014-12-21 | 2015-04-01 | 劳启绪 | Antibacterial coating |
| CN107083120A (en) * | 2017-05-15 | 2017-08-22 | 吉林省吉泥环保科技有限公司 | A kind of coating with damping and long-acting decomposing formaldehyde |
| CN107353740B (en) * | 2017-08-23 | 2020-02-21 | 重庆索利特装饰有限公司 | Energy-saving self-cleaning exterior wall latex paint, preparation method thereof and building exterior wall |
| CN107434930A (en) * | 2017-09-22 | 2017-12-05 | 苏州振振好新型建材科技有限公司 | A kind of interior wall washability high adhesion force mildew-proof latex paint and preparation method thereof |
| CN108441034A (en) * | 2018-04-23 | 2018-08-24 | 合肥浦尔菲电线科技有限公司 | One kind having antibacterial taste removal effect environment protection type wall covering paint |
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| CN1392210A (en) * | 2002-07-18 | 2003-01-22 | 中山大学 | High weather resistant water-thinned wall paint and its preparing method |
| CN1517373A (en) * | 2003-01-13 | 2004-08-04 | 广州宏昌胶粘带厂 | Composition of elastic organic silicon phenylpropyl resin emulsion for paint and its preparation method |
| CN101104766A (en) * | 2006-07-12 | 2008-01-16 | 上海雅达特种涂料有限公司 | Colorful coating for purifying indoor air and producing method thereof |
| CN103555110A (en) * | 2013-11-11 | 2014-02-05 | 苏州市姑苏新型建材有限公司 | Interior wall paint capable of absorbing and decomposing formaldehyde |
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2014
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1392210A (en) * | 2002-07-18 | 2003-01-22 | 中山大学 | High weather resistant water-thinned wall paint and its preparing method |
| CN1517373A (en) * | 2003-01-13 | 2004-08-04 | 广州宏昌胶粘带厂 | Composition of elastic organic silicon phenylpropyl resin emulsion for paint and its preparation method |
| CN101104766A (en) * | 2006-07-12 | 2008-01-16 | 上海雅达特种涂料有限公司 | Colorful coating for purifying indoor air and producing method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111635683A (en) * | 2020-06-05 | 2020-09-08 | 嘉应学院 | Antibacterial ceramic-like coating on stainless steel surface and preparation method thereof |
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| CN103788779A (en) | 2014-05-14 |
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Address after: 528400 Zhongshan Torch Development Zone, Guangdong, West Road, No. 12 Patentee after: Guangdong Huazibuxin Mstar Technology Ltd Address before: 528400 Zhongshan Torch Development Zone, Guangdong, West Road, No. 12 Patentee before: Guangdong Valspar Chemical Industry Co., Ltd. |
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| TR01 | Transfer of patent right |
Effective date of registration: 20190125 Address after: 528437 First Floor of the Second Factory Building of Yixian Industrial Park (beside Weida Printing Co., Ltd.) in Zhongshan Torch Development Zone, Guangdong Province Patentee after: Zhongshan Motu New Material Technology Co., Ltd. Address before: 528400 No. 12 Deneng West Road, Torch Development Zone, Zhongshan City, Guangdong Province Patentee before: Guangdong Huazibuxin Mstar Technology Ltd |
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Effective date of registration: 20190531 Address after: 528437 Room 202, 2nd floor, No. 12 Deneng West Road Office Building, Zhongshan Torch Development Zone, Guangdong Province (Residence Declaration) Patentee after: Zhongshan Magic Painting New Material Technology Co., Ltd. Address before: 528437 First Floor of the Second Factory Building of Yixian Industrial Park (beside Weida Printing Co., Ltd.) in Zhongshan Torch Development Zone, Guangdong Province Patentee before: Zhongshan Motu New Material Technology Co., Ltd. |
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