CN103788572A - Halogen-free and flame-retardant phenolic resin glass steel coating material and preparation method thereof - Google Patents
Halogen-free and flame-retardant phenolic resin glass steel coating material and preparation method thereof Download PDFInfo
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- CN103788572A CN103788572A CN201410016846.4A CN201410016846A CN103788572A CN 103788572 A CN103788572 A CN 103788572A CN 201410016846 A CN201410016846 A CN 201410016846A CN 103788572 A CN103788572 A CN 103788572A
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Abstract
The invention discloses a halogen-free and flame-retardant phenolic resin glass steel coating material. The halogen-free and flame-retardant phenolic resin glass steel coating material is characterized by being prepared from the following raw materials in parts by weight: 30-35 parts of phenolic resin, 8-10 parts of vinyl ester resin, 2-3 parts of silicon carbide, 20-24 parts of chopped glass fiber, 2-3 parts of aluminum triphosphate, 1-2 parts of tree ash, 1-2 parts of cobalt naphthenate, 1-2 parts of white cement, 4-6 parts of butanone peroxide, 3-5 parts of smoke sheet rubber, 7-9 parts of coumarone, 7-9 parts of allyl glycidyl ether, 3-5 parts of dioctyl phthalate, 2-3 parts of tetraisooctyl titanate, 1-2 parts of sodium benzoate and 1-2 parts of aid. The material, added with the aid, is good in physical performance and mechanical performance, has a reinforcement function, is acid-resistant, alkali-resistant, high-temperature-resistant, long in service life, good in heat resistance, ideal in strength and environment-friendly, and cannot release ammonia gas during molding.
Description
Technical field
The present invention relates to a kind of matrix material and preparation method thereof, particularly phenolic resin frp coated material of a kind of halogen-free flameproof and preparation method thereof.
Background technology
Glass-reinforced plastic material is to embed by glass fibre reinforcement the material that is wrapped to form composite structure in curing thermosetting resin or by it, has light weight, good toughness, the advantage such as corrosion-resistant, is therefore widely used in the field such as automobile, building.The field such as automobile, building is comparatively paid close attention to the flame-retarding characteristic of glass fiber reinforced plastics composite material.The fire retardant using in glass fiber reinforced plastics composite material is at present generally antimonous oxide, and its flame retardant effect is poor.And in antimonous oxide product, conventionally also have arsenic oxide arsenoxide, but arsenic oxide arsenoxide is poisonous, so can be to environment, not environmental protection in glass reinforced plastic use procedure.
Summary of the invention
The object of this invention is to provide phenolic resin frp coated material of a kind of halogen-free flameproof and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A phenolic resin frp coated material for halogen-free flameproof, is made up of the raw material of following weight part: resol 30-35, vinyl ester resin 8-10, silicon carbide 2-3, short glass fiber 20-24, aluminium triphosphate 2-3, trees ashes 1-2, cobalt naphthenate 1-2, white cement 1-2, methylethyl ketone peroxide 4-6, smoke sheet rubber 3-5, coumarone 7-9, propenyl glycidyl ether 7-9, dioctyl phthalate (DOP) 3-5, the different monooctyl ester 2-3 of metatitanic acid four, Sodium Benzoate 1-2, auxiliary agent 1-2;
Described auxiliary agent is made up of the raw material of following weight part: nano aluminium oxide 12-14, zircon 4-6, mica powder 3-4, aluminum nitride powder 2-3, feldspar 3-5, zinc borate 2-4, zinc oxide 5-7, bicarbonate of ammonia 3-4, dibutyltin oxide 2-3, vinylbenzene 3-5, the just own ester 3-4 of methacrylic acid, Syzygium aromaticum stem oil 2-3; Nano aluminium oxide, zircon, aluminum nitride powder, feldspar are put into calcining furnace by preparation method, at 550-570 ℃, calcine 4-5 hour, take out, mix with mica powder, zinc borate, zinc oxide, bicarbonate of ammonia, grinding obtains 300-400 order powder, then, add again the just own ester of vinylbenzene, methacrylic acid, Syzygium aromaticum stem oil to mix, continue to grind 40-50 minute, to fully disperseing, then add other remaining component, continue to grind after 30-45 minute, under 1400-1600 rev/min, stir 15-30 minute, obtain auxiliary agent.
The phenolic resin frp coated material of halogen-free flameproof of the present invention, made by following concrete steps:
(1) resol, vinyl ester resin, cobalt naphthenate, smoke sheet rubber, coumarone, propenyl glycidyl ether, dioctyl phthalate (DOP) are put into reactor and be heated to while stirring molten state, obtain A material;
(2) short glass fiber is put into ball mill and grind, mix with silicon carbide, aluminium triphosphate, trees ashes, white cement, the different monooctyl ester of metatitanic acid four, Sodium Benzoate, stir 15-20 minute, obtain B material;
(3) A material is mixed with B material, add auxiliary agent and all the other remaining components, under the speed of 450-550 rev/min, stir 20-25 minute, cast, curing.
Advantage of the present invention is: the present invention adds auxiliary agent, makes material have good physicals and mechanical property, plays the effect of reinforcement; Material of the present invention is acidproof, alkaline-resisting, high temperature resistant, long service life, has that resistance toheat is good, intensity is desirable, can not discharge the strong point of ammonia when moulding, environmentally friendly.
Embodiment
Below by specific examples, the present invention is described in detail.
A phenolic resin frp coated material for halogen-free flameproof, by following weight part (kilogram) raw material make: resol 30, vinyl ester resin 8, silicon carbide 2, short glass fiber 20, aluminium triphosphate 2, trees ashes 1, cobalt naphthenate 1, white cement 1, methylethyl ketone peroxide 4, smoke sheet rubber 3, coumarone 7, propenyl glycidyl ether 7, dioctyl phthalate (DOP) 3, the different monooctyl ester 2 of metatitanic acid four, Sodium Benzoate 1, auxiliary agent 1;
Described auxiliary agent by following weight part (kilogram) raw material make: nano aluminium oxide 12, zircon 4, mica powder 3, aluminum nitride powder 2, feldspar 3, zinc borate 2, zinc oxide 5, bicarbonate of ammonia 3, dibutyltin oxide 2, vinylbenzene 3, the just own ester 3 of methacrylic acid, Syzygium aromaticum stem oil 2; Nano aluminium oxide, zircon, aluminum nitride powder, feldspar are put into calcining furnace by preparation method, at 550-570 ℃, calcine 4-5 hour, take out, mix with mica powder, zinc borate, zinc oxide, bicarbonate of ammonia, grinding obtains 300-400 order powder, then, add again the just own ester of vinylbenzene, methacrylic acid, Syzygium aromaticum stem oil to mix, continue to grind 40-50 minute, to fully disperseing, then add other remaining component, continue to grind after 30-45 minute, under 1400-1600 rev/min, stir 15-30 minute, obtain auxiliary agent.
The phenolic resin frp coated material of halogen-free flameproof of the present invention, made by following concrete steps:
(1) resol, vinyl ester resin, cobalt naphthenate, smoke sheet rubber, coumarone, propenyl glycidyl ether, dioctyl phthalate (DOP) are put into reactor and be heated to while stirring molten state, obtain A material;
(2) short glass fiber is put into ball mill and grind, mix with silicon carbide, aluminium triphosphate, trees ashes, white cement, the different monooctyl ester of metatitanic acid four, Sodium Benzoate, stir 15-20 minute, obtain B material;
(3) A material is mixed with B material, add auxiliary agent and all the other remaining components, under the speed of 450-550 rev/min, stir 20-25 minute, cast, curing.
The tensile strength of the glass-reinforced plastic material of the embodiment of the present invention is 251 Mpa.
Claims (2)
1. the phenolic resin frp coated material of a halogen-free flameproof, it is characterized in that, made by the raw material of following weight part: resol 30-35, vinyl ester resin 8-10, silicon carbide 2-3, short glass fiber 20-24, aluminium triphosphate 2-3, trees ashes 1-2, cobalt naphthenate 1-2, white cement 1-2, methylethyl ketone peroxide 4-6, smoke sheet rubber 3-5, coumarone 7-9, propenyl glycidyl ether 7-9, dioctyl phthalate (DOP) 3-5, the different monooctyl ester 2-3 of metatitanic acid four, Sodium Benzoate 1-2, auxiliary agent 1-2;
Described auxiliary agent is made up of the raw material of following weight part: nano aluminium oxide 12-14, zircon 4-6, mica powder 3-4, aluminum nitride powder 2-3, feldspar 3-5, zinc borate 2-4, zinc oxide 5-7, bicarbonate of ammonia 3-4, dibutyltin oxide 2-3, vinylbenzene 3-5, the just own ester 3-4 of methacrylic acid, Syzygium aromaticum stem oil 2-3; Nano aluminium oxide, zircon, aluminum nitride powder, feldspar are put into calcining furnace by preparation method, at 550-570 ℃, calcine 4-5 hour, take out, mix with mica powder, zinc borate, zinc oxide, bicarbonate of ammonia, grinding obtains 300-400 order powder, then, add again the just own ester of vinylbenzene, methacrylic acid, Syzygium aromaticum stem oil to mix, continue to grind 40-50 minute, to fully disperseing, then add other remaining component, continue to grind after 30-45 minute, under 1400-1600 rev/min, stir 15-30 minute, obtain auxiliary agent.
2. the phenolic resin frp coated material of halogen-free flameproof according to claim 1, is characterized in that, is made up of following concrete steps:
(1) resol, vinyl ester resin, cobalt naphthenate, smoke sheet rubber, coumarone, propenyl glycidyl ether, dioctyl phthalate (DOP) are put into reactor and be heated to while stirring molten state, obtain A material;
(2) short glass fiber is put into ball mill and grind, mix with silicon carbide, aluminium triphosphate, trees ashes, white cement, the different monooctyl ester of metatitanic acid four, Sodium Benzoate, stir 15-20 minute, obtain B material;
(3) A material is mixed with B material, add auxiliary agent and all the other remaining components, under the speed of 450-550 rev/min, stir 20-25 minute, cast, curing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410016846.4A CN103788572A (en) | 2014-01-15 | 2014-01-15 | Halogen-free and flame-retardant phenolic resin glass steel coating material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410016846.4A CN103788572A (en) | 2014-01-15 | 2014-01-15 | Halogen-free and flame-retardant phenolic resin glass steel coating material and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103788572A true CN103788572A (en) | 2014-05-14 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410016846.4A Pending CN103788572A (en) | 2014-01-15 | 2014-01-15 | Halogen-free and flame-retardant phenolic resin glass steel coating material and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107815881A (en) * | 2017-10-30 | 2018-03-20 | 浙江彩蝶实业有限公司 | A kind of high density waterproof shell fabric and its processing method |
| CN114249962A (en) * | 2022-03-02 | 2022-03-29 | 山东墨匠新材料科技有限公司 | Glass fiber resin composite material and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1256296A (en) * | 1998-12-10 | 2000-06-14 | 任春和 | Water soluble paint |
| CN102127349A (en) * | 2011-01-28 | 2011-07-20 | 张发 | Aqueous environment-friendly paint with high anticorrosive performance |
-
2014
- 2014-01-15 CN CN201410016846.4A patent/CN103788572A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1256296A (en) * | 1998-12-10 | 2000-06-14 | 任春和 | Water soluble paint |
| CN102127349A (en) * | 2011-01-28 | 2011-07-20 | 张发 | Aqueous environment-friendly paint with high anticorrosive performance |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107815881A (en) * | 2017-10-30 | 2018-03-20 | 浙江彩蝶实业有限公司 | A kind of high density waterproof shell fabric and its processing method |
| CN114249962A (en) * | 2022-03-02 | 2022-03-29 | 山东墨匠新材料科技有限公司 | Glass fiber resin composite material and preparation method thereof |
| CN114249962B (en) * | 2022-03-02 | 2022-05-03 | 山东墨匠新材料科技有限公司 | Glass fiber resin composite material and preparation method thereof |
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Application publication date: 20140514 |
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| RJ01 | Rejection of invention patent application after publication |