CN103774416B - Finishing agent that a kind of resisted shrinkage is antibacterial and preparation method thereof - Google Patents
Finishing agent that a kind of resisted shrinkage is antibacterial and preparation method thereof Download PDFInfo
- Publication number
- CN103774416B CN103774416B CN201310749263.8A CN201310749263A CN103774416B CN 103774416 B CN103774416 B CN 103774416B CN 201310749263 A CN201310749263 A CN 201310749263A CN 103774416 B CN103774416 B CN 103774416B
- Authority
- CN
- China
- Prior art keywords
- parts
- finishing agent
- antibacterial
- resisted shrinkage
- reaction still
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 27
- 238000003756 stirring Methods 0.000 claims abstract description 16
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 10
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 10
- 150000008442 polyphenolic compounds Chemical class 0.000 claims abstract description 10
- 235000013824 polyphenols Nutrition 0.000 claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 10
- 239000010457 zeolite Substances 0.000 claims abstract description 10
- UWFRVQVNYNPBEF-UHFFFAOYSA-N 1-(2,4-dimethylphenyl)propan-1-one Chemical compound CCC(=O)C1=CC=C(C)C=C1C UWFRVQVNYNPBEF-UHFFFAOYSA-N 0.000 claims abstract description 8
- IEQAICDLOKRSRL-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-dodecoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO IEQAICDLOKRSRL-UHFFFAOYSA-N 0.000 claims abstract description 8
- 108010010803 Gelatin Proteins 0.000 claims abstract description 8
- 229920000159 gelatin Polymers 0.000 claims abstract description 8
- 239000008273 gelatin Substances 0.000 claims abstract description 8
- 235000019322 gelatine Nutrition 0.000 claims abstract description 8
- 235000011852 gelatine desserts Nutrition 0.000 claims abstract description 8
- OQZCJRJRGMMSGK-UHFFFAOYSA-M potassium metaphosphate Chemical compound [K+].[O-]P(=O)=O OQZCJRJRGMMSGK-UHFFFAOYSA-M 0.000 claims abstract description 8
- 229940099402 potassium metaphosphate Drugs 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000007789 sealing Methods 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 3
- 238000000265 homogenisation Methods 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 5
- 238000004321 preservation Methods 0.000 claims description 5
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 abstract 1
- 241000191967 Staphylococcus aureus Species 0.000 description 4
- 230000002401 inhibitory effect Effects 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- 241000588724 Escherichia coli Species 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 239000004753 textile Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004166 bioassay Methods 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Finishing agent that a kind of resisted shrinkage is antibacterial and preparation method thereof, the antibacterial finishing agent of resisted shrinkage is made up of according to weight ratio following composition: Brij-35 is 8 ~ 12 parts, zeolite powder is 3 ~ 5 parts, gelatin is 3 ~ 4 parts, Tea Polyphenols is 2 ~ 3 parts, ethylene glycol diglycidylether is 3 ~ 6 parts, potassium metaphosphate is 2 ~ 6 parts, 1,3-PD is 40 ~ 60 parts, water is 180 ~ 200 parts.The preparation process of the finishing agent that resisted shrinkage is antibacterial comprises: heating, stirring, homogeneous, sealing etc.The finishing agent prepared has and prevents clothing from shrinking and antibacterial performance.
Description
Technical field
The present invention relates to a kind of clothing finishing agent and preparation method thereof, particularly relate to a kind ofly can effectively prevent clothing from shrinking, the finishing agent improving clothing antibacterial functions and preparation method thereof.
Background technology
Clothes, after repeatedly cleaning with washing machine, there will be the situation of contraction.After clothing shrinks, size diminishes, and affects the dress of people.Meanwhile, if clothing is common cotton clothes, not there is antibacterial function, after the intrusion being subject to bacterium, can breed on clothes, add the risk wearing clothing people.Conventional finishing agent only has the function preventing clothing from shrinking usually, and do not possess antibacterial function, if therefore finishing agent is not only provided with the function preventing clothing from shrinking, also possesses the function effectively suppressing Escherichia coli and staphylococcus aureus breeding simultaneously, expand the scope of application of finishing agent greatly, also can increase the market value of this type of finishing agent.
Summary of the invention
The technical problem solved: common cotton clothes shrinks at clothes after repeatedly cleaning, and normal laundry does not possess the problem of anti-microbial property.
Technical scheme: the invention discloses antibacterial finishing agent of a kind of resisted shrinkage and preparation method thereof, the antibacterial finishing agent of resisted shrinkage is made up of according to weight ratio following composition: Brij-35 is 8 ~ 12 parts, zeolite powder is 3 ~ 5 parts, gelatin is 3 ~ 4 parts, Tea Polyphenols is 2 ~ 3 parts, ethylene glycol diglycidylether is 3 ~ 6 parts, potassium metaphosphate is 2 ~ 6 parts, 1,3-PD is 40 ~ 60 parts, water is 180 ~ 200 parts.
A preparation method for the finishing agent that resisted shrinkage is antibacterial, comprises the following steps: vacuum reaction still temperature is adjusted to 70 DEG C ~ 75 DEG C by (1), and maintaining in reactor is vacuum state; (2) in vacuum reaction still, 1 is dropped into by the window that feeds intake, ammediol is 40 ~ 60 parts, water is 180 ~ 200 parts, Brij-35 is 8 ~ 12 parts, ethylene glycol diglycidylether is 3 ~ 6 parts, stirs with the paddle that vacuum reaction still carries; (3) add that zeolite powder is 3 ~ 5 parts, gelatin is 3 ~ 4 parts, Tea Polyphenols is 2 ~ 3 parts, potassium metaphosphate is 2 ~ 6 parts by the vacuum reaction still window that feeds intake again, under vacuum state, stir 30min; (4) after stirring, reactor is recovered normal pressure, dressing liquid Homogenizing pump is carried out homogeneous, homogenization pressure is 20 ~ 25Mpa, and homogenizing time is 5min ~ 10min; (5), after homogeneous terminates, finishing agent is carried out sealing rear low-temperature preservation.
The Tea Polyphenols added is preferably 3 parts.During homogeneous, homogenization pressure is preferably 25Mpa.The zeolite powder added is preferably 300 orders.
beneficial effect:cotton clothes is after arranging through finishing agent of the present invention, and it is after washing of drum type washing machine 30 times, and shrinkage factor only has 0.3% to 0.5%.Its colibacillary inhibiting rate is 75% to 79%, and the inhibiting rate of staphylococcus aureus is 82% to 84%.
Detailed description of the invention
Embodiment 1
(1) vacuum reaction still temperature is adjusted to 75 DEG C, maintaining in reactor is vacuum state; (2) in vacuum reaction still, dropped into by the window that feeds intake that 1,3-PD is 40kg, water is 180kg, Brij-35 is 12kg, ethylene glycol diglycidylether is 3kg, stir with the paddle that vacuum reaction still carries; (3) again add that zeolite powder is 3kg, gelatin is 4kg, Tea Polyphenols is 2kg, potassium metaphosphate is 6kg by the vacuum reaction still window that feeds intake, under vacuum state, stir 30min; (4) after stirring, reactor is recovered normal pressure, dressing liquid Homogenizing pump is carried out homogeneous, homogenization pressure is 25Mpa, and homogenizing time is 10min; (5), after homogeneous terminates, finishing agent is carried out sealing rear low-temperature preservation.
Embodiment 2
(1) vacuum reaction still temperature is adjusted to 73 DEG C, maintaining in reactor is vacuum state; (2) in vacuum reaction still, dropped into by the window that feeds intake that 1,3-PD is 50kg, water is 200kg, Brij-35 is 8kg, ethylene glycol diglycidylether is 4kg, stir with the paddle that vacuum reaction still carries; (3) again add that zeolite powder is 4kg, gelatin is 3kg, Tea Polyphenols is 3kg, potassium metaphosphate is 2kg by the vacuum reaction still window that feeds intake, under vacuum state, stir 30min; (4) after stirring, reactor is recovered normal pressure, dressing liquid Homogenizing pump is carried out homogeneous, homogenization pressure is 20Mpa, and homogenizing time is 7min; (5), after homogeneous terminates, finishing agent is carried out sealing rear low-temperature preservation.
Embodiment 3
(1) vacuum reaction still temperature is adjusted to 70 DEG C, maintaining in reactor is vacuum state; (2) in vacuum reaction still, dropped into by the window that feeds intake that 1,3-PD is 60kg, water is 190kg, Brij-35 is 10kg, ethylene glycol diglycidylether is 6kg, stir with the paddle that vacuum reaction still carries; (3) again add that zeolite powder is 5kg, gelatin is 3kg, Tea Polyphenols is 2kg, potassium metaphosphate is 4kg by the vacuum reaction still window that feeds intake, under vacuum state, stir 30min; (4) after stirring, reactor is recovered normal pressure, dressing liquid Homogenizing pump is carried out homogeneous, homogenization pressure is 25Mpa, and homogenizing time is 5min; (5), after homogeneous terminates, finishing agent is carried out sealing rear low-temperature preservation.
Soak 40min by the finishing agent being dipped into embodiment 1, embodiment 2, embodiment 3 under textile overcoat room temperature, dry at 65 DEG C after immersion.Determine the bacteriostasis rate of overcoat, bioassay standard is FZ/T73023-2006, more separately rounds the embodiment 1 after reason, embodiment 2, embodiment 3, and measure its shrinkage factor after cleaning 30 times, result is as following table.
| Embodiment 1 | Embodiment 2 | Embodiment 3 | |
| Escherichia coli inhibiting rate | 76% | 75% | 79% |
| Staphylococcus aureus inhibiting rate | 84% | 82% | 82% |
| Wash 30 post-shrinkage ratios | 0.3% | 0.5% | 0.4% |
Textile overcoat, after arranging, is provided with the significant effect suppressing Escherichia coli and staphylococcus aureus, also has the performance of good resisted shrinkage simultaneously.
Claims (4)
1. the finishing agent that a resisted shrinkage is antibacterial, it is characterized in that the antibacterial finishing agent of resisted shrinkage is made up of according to weight ratio following composition: Brij-35 is 8 ~ 12 parts, zeolite powder is 3 ~ 5 parts, gelatin is 3 ~ 4 parts, Tea Polyphenols is 2 ~ 3 parts, ethylene glycol diglycidylether is 3 ~ 6 parts, potassium metaphosphate is 2 ~ 6 parts, 1,3-PD is 40 ~ 60 parts, water is 180 ~ 200 parts;
The preparation method of the finishing agent that described a kind of resisted shrinkage is antibacterial, comprises the following steps: vacuum reaction still temperature is adjusted to 70 DEG C ~ 75 DEG C by (1), and maintaining in reactor is vacuum state; (2) in vacuum reaction still, 1 is dropped into by the window that feeds intake, ammediol is 40 ~ 60 parts, water is 180 ~ 200 parts, Brij-35 is 8 ~ 12 parts, ethylene glycol diglycidylether is 3 ~ 6 parts, stirs with the paddle that vacuum reaction still carries; (3) again add that zeolite powder is 3 ~ 5 parts, gelatin is 3 ~ 4 parts, Tea Polyphenols is 2 ~ 3 parts, potassium metaphosphate is 2 ~ 6 parts by the vacuum reaction still window that feeds intake, under vacuum state, stir 30min; (4) after stirring, reactor is recovered normal pressure, dressing liquid Homogenizing pump is carried out homogeneous, homogenization pressure is 20 ~ 25MPa, and homogenizing time is 5min ~ 10min; (5), after homogeneous terminates, finishing agent is carried out sealing rear low-temperature preservation.
2. the finishing agent that a kind of resisted shrinkage according to claim 1 is antibacterial, is characterized in that the Tea Polyphenols added is 3 parts.
3. the finishing agent that a kind of resisted shrinkage according to claim 1 is antibacterial, when it is characterized in that homogeneous, homogenization pressure is 25MPa.
4. the finishing agent that a kind of resisted shrinkage according to claim 1 is antibacterial, is characterized in that the zeolite powder added is 300 orders.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310749263.8A CN103774416B (en) | 2013-12-31 | 2013-12-31 | Finishing agent that a kind of resisted shrinkage is antibacterial and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310749263.8A CN103774416B (en) | 2013-12-31 | 2013-12-31 | Finishing agent that a kind of resisted shrinkage is antibacterial and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103774416A CN103774416A (en) | 2014-05-07 |
| CN103774416B true CN103774416B (en) | 2016-01-20 |
Family
ID=50567133
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310749263.8A Active CN103774416B (en) | 2013-12-31 | 2013-12-31 | Finishing agent that a kind of resisted shrinkage is antibacterial and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103774416B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104695214B (en) * | 2015-03-05 | 2016-09-07 | 苏州经贸职业技术学院 | A kind of real silk polyphenol finishing agent and preparation method thereof |
| CN105332096A (en) * | 2015-10-19 | 2016-02-17 | 耿云花 | Preparation method of functional non-woven fabric, and non-woven fabric prepared via preparation method |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2800094B2 (en) * | 1994-07-13 | 1998-09-21 | 富士紡績株式会社 | Method for improving strikethrough of polynosic fiber fabric |
| CN1730804A (en) * | 2005-08-26 | 2006-02-08 | 上海汽车集团股份有限公司 | Antibacterial fabric and its preparation method |
| CN101324027A (en) * | 2008-07-22 | 2008-12-17 | 浙江理工大学 | Preparation of environment-friendly type antibiotic and odor removing textile |
| CN102965760B (en) * | 2012-11-26 | 2014-12-03 | 荣盛石化股份有限公司 | Manufacturing method of antibacterial deodorizing polyester fiber |
| CN103451927B (en) * | 2013-08-02 | 2015-05-20 | 苏州爱立方服饰有限公司 | Anti-shrinkage antibacterial woolen sweater treatment liquid containing capric triglyceride |
| CN103469330B (en) * | 2013-09-13 | 2016-03-02 | 句容市后白镇迎瑞印花厂 | A kind of production method of bamboo charcoal tea fiber |
-
2013
- 2013-12-31 CN CN201310749263.8A patent/CN103774416B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN103774416A (en) | 2014-05-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101768869B (en) | No-iron treatment method for cotton shirt | |
| CN103668955B (en) | Padding-process antibacterial polyester fabric and preparation method thereof | |
| CN104452273B (en) | The antibacterial non-ironing processing method of a kind of cowboy's vest | |
| CN104278527B (en) | A kind of antibacterial fabric inorganic agent and preparation method thereof | |
| CN104452293A (en) | Formaldehyde-free anti-bacterial noniron finish liquid of shirt and finish method | |
| CN103774416B (en) | Finishing agent that a kind of resisted shrinkage is antibacterial and preparation method thereof | |
| CN103882689A (en) | Method for processing cotton fabric by chitosan derivative | |
| CN108708160A (en) | A kind of antibacterial blended yarn weaved fabric | |
| CN103741452B (en) | A kind of shirt dressing liquid and preparation method thereof | |
| CN104389161B (en) | A kind of preparation method of crease-shedding real silk composite material | |
| CN103696266A (en) | Antibacterial finishing process of fabric | |
| CN104805697A (en) | Novel antibacterial finishing agent composition for cotton fabric | |
| CN103938396B (en) | Press finishing process exempted from by clothes | |
| CN105586771A (en) | Anti-wrinkle finishing method for hemp fabric | |
| CN105421057A (en) | Dyeing and finishing process of knitted fabric | |
| CN103668958A (en) | Impregnation-process antibacterial polyester fabric and preparation method thereof | |
| CN104213403B (en) | A kind of fabric insect protected antibacterial finishing agent and preparation method thereof | |
| CN103174015A (en) | Antibiotic finish method for chitosan quaternary ammonium salt of pure-cotton jean | |
| CN106480705A (en) | A kind of wool fabric antibacterial finishing process | |
| CN110952330A (en) | Antibacterial and soil-release finishing process for silk fabric | |
| CN103741448B (en) | Cotton clothes treatment fluid that a kind of resisted shrinkage is fungi-proofing and preparation method thereof | |
| CN104264482A (en) | Antibacterial and anti-wrinkle fabric care agent and preparation method thereof | |
| CN105568676A (en) | Pillowcase fabric | |
| CN104278516A (en) | Mildew-proof and anti-bacterial finishing agent for fabric and preparation method of mildew-proof and anti-bacterial finishing agent | |
| CN103882682A (en) | Production method of antimicrobial wool fabric |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20191223 Address after: 224414 No.3, national entrepreneurship cluster, Lupu Town, Funing County, Yancheng City, Jiangsu Province (x) Patentee after: FUNING RONGTAI TEXTILE Co.,Ltd. Address before: 7 groups of friendship village Songling town of Wujiang District of Suzhou City, Jiangsu province 215200 split eight community Patentee before: SUZHOU XUANDE TEXTILE SCIENCE & TECHNOLOGY Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20210119 Address after: No. 100, Beihuan West Road, Hede Town, Sheyang County, Yancheng City, Jiangsu Province Patentee after: Yancheng Silk Road Information Technology Service Co.,Ltd. Address before: 224414 No.3 (x), national entrepreneurship cluster, Lupu Town, Funing County, Yancheng City, Jiangsu Province Patentee before: FUNING RONGTAI TEXTILE Co.,Ltd. |
|
| EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20140507 Assignee: Yancheng Nuohao Xinxiang Technology Co.,Ltd. Assignor: Yancheng Silk Road Information Technology Service Co.,Ltd. Contract record no.: X2023980043986 Denomination of invention: A finishing agent with anti shrinkage and antibacterial properties and its preparation method Granted publication date: 20160120 License type: Common License Record date: 20231024 |
|
| EE01 | Entry into force of recordation of patent licensing contract | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20140507 Assignee: Jiangsu Jiezhimeng New Energy Technology Co.,Ltd.|Yancheng Yuanshun Environmental Protection Technology Co.,Ltd.|Jiangsu Xingneng Environmental Protection Technology Co.,Ltd.|Tianneng carbon (Jiangsu) Co.,Ltd. Assignor: Yancheng Silk Road Information Technology Service Co.,Ltd. Contract record no.: X2023980047304 Denomination of invention: A finishing agent with anti shrinkage and antibacterial properties and its preparation method Granted publication date: 20160120 License type: Common License Record date: 20231118 |
|
| EE01 | Entry into force of recordation of patent licensing contract | ||
| EC01 | Cancellation of recordation of patent licensing contract |
Assignee: Jiangsu Jiezhimeng New Energy Technology Co.,Ltd.|Yancheng Yuanshun Environmental Protection Technology Co.,Ltd.|Jiangsu Xingneng Environmental Protection Technology Co.,Ltd.|Tianneng carbon (Jiangsu) Co.,Ltd. Assignor: Yancheng Silk Road Information Technology Service Co.,Ltd. Contract record no.: X2023980047304 Date of cancellation: 20240425 Assignee: Yancheng Nuohao Xinxiang Technology Co.,Ltd. Assignor: Yancheng Silk Road Information Technology Service Co.,Ltd. Contract record no.: X2023980043986 Date of cancellation: 20240425 |
|
| EC01 | Cancellation of recordation of patent licensing contract | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240831 Address after: 224400 Group 5, Gaoyang Village, Lupu Town, Funing County, Yancheng City, Jiangsu Province (X) Patentee after: Yancheng Haoyu Travel Products Co.,Ltd. Country or region after: China Address before: No. 100, Beihuan West Road, Hede Town, Sheyang County, Yancheng City, Jiangsu Province Patentee before: Yancheng Silk Road Information Technology Service Co.,Ltd. Country or region before: China |
|
| TR01 | Transfer of patent right |