CN103772810A - High-temperature resistant ultrathin isotactic polypropylene metallized film for capacitor and preparation method thereof - Google Patents
High-temperature resistant ultrathin isotactic polypropylene metallized film for capacitor and preparation method thereof Download PDFInfo
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- CN103772810A CN103772810A CN201410001704.0A CN201410001704A CN103772810A CN 103772810 A CN103772810 A CN 103772810A CN 201410001704 A CN201410001704 A CN 201410001704A CN 103772810 A CN103772810 A CN 103772810A
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- capacitor
- temperature resistant
- isotatic polypropylene
- film
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- -1 polypropylene Polymers 0.000 title claims abstract description 24
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 23
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 23
- 239000011104 metalized film Substances 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims description 7
- 239000003990 capacitor Substances 0.000 title abstract description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 21
- CCJAYIGMMRQRAO-UHFFFAOYSA-N 2-[4-[(2-hydroxyphenyl)methylideneamino]butyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCCCN=CC1=CC=CC=C1O CCJAYIGMMRQRAO-UHFFFAOYSA-N 0.000 claims abstract description 7
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims abstract description 5
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 claims abstract description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 4
- 229920000728 polyester Polymers 0.000 claims abstract description 4
- 239000012752 auxiliary agent Substances 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 235000002918 Fraxinus excelsior Nutrition 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- 240000007313 Tilia cordata Species 0.000 claims description 6
- 230000032683 aging Effects 0.000 claims description 6
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 6
- 239000002956 ash Substances 0.000 claims description 6
- 150000003951 lactams Chemical class 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 6
- 230000008018 melting Effects 0.000 claims description 6
- 229920001526 metallocene linear low density polyethylene Polymers 0.000 claims description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 6
- 229920002554 vinyl polymer Polymers 0.000 claims description 6
- 241000628997 Flos Species 0.000 claims description 3
- CGSLYBDCEGBZCG-UHFFFAOYSA-N Octicizer Chemical compound C=1C=CC=CC=1OP(=O)(OCC(CC)CCCC)OC1=CC=CC=C1 CGSLYBDCEGBZCG-UHFFFAOYSA-N 0.000 claims description 3
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000003851 corona treatment Methods 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 229940033355 lauric acid Drugs 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- DCEMCPAKSGRHCN-UHFFFAOYSA-N oxirane-2,3-dicarboxylic acid Chemical compound OC(=O)C1OC1C(O)=O DCEMCPAKSGRHCN-UHFFFAOYSA-N 0.000 claims description 3
- 238000005096 rolling process Methods 0.000 claims description 3
- 238000007493 shaping process Methods 0.000 claims description 3
- WEAPVABOECTMGR-UHFFFAOYSA-N triethyl 2-acetyloxypropane-1,2,3-tricarboxylate Chemical compound CCOC(=O)CC(C(=O)OCC)(OC(C)=O)CC(=O)OCC WEAPVABOECTMGR-UHFFFAOYSA-N 0.000 claims description 3
- 238000007738 vacuum evaporation Methods 0.000 claims description 3
- 239000010408 film Substances 0.000 abstract description 11
- 238000005516 engineering process Methods 0.000 abstract description 2
- 239000004698 Polyethylene Substances 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 229920001529 polyepoxysuccinic acid Polymers 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
- B29C48/08—Flat, e.g. panels flexible, e.g. films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/001—Combinations of extrusion moulding with other shaping operations
- B29C48/0018—Combinations of extrusion moulding with other shaping operations combined with shaping by orienting, stretching or shrinking, e.g. film blowing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/002—Details
- H01G4/005—Electrodes
- H01G4/008—Selection of materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/002—Details
- H01G4/005—Electrodes
- H01G4/015—Special provisions for self-healing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Power Engineering (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Fixed Capacitors And Capacitor Manufacturing Machines (AREA)
Abstract
The invention discloses a high-temperature resistant ultrathin isotactic polypropylene metallized film for a capacitor, which is characterized by being prepared from the following raw materials in parts by weight: 200 parts of isotactic polypropylene, 1-2 parts of aluminum hydroxide, 2-3 parts of polyethylene amide, 1-2 parts of N-hydroxymethyl acrylamide, 1-2 parts of ethylene glycol, 2-3 parts of dicyclopentadiene, 1-2 parts of polyepoxysuccinic acid, 2-3 parts of dodecanoic acid, 1-2 parts of polyester acrylate and 5-6 parts of auxiliary. In the invention, the processing technology is simple, and the prepared film capacitor has low contact resistance so that the product features are good; the film disclosed by the invention is uniform in thickness and is not separated easily while the cost is low; the prepared capacitor is relatively small in volume and has the characteristics of low heat shrinkage and stable performance at high temperature, namely, relatively good high-temperature stability.
Description
Technical field
The present invention relates to field of capacitor manufacture, particularly high temperature resistant ultrathin isotatic polypropylene metalized film and preparation method thereof for a kind of electrical condenser.
Background technology
Electrical condenser has higher mechanical property and electric property with BiOriented Polypropylene Films, compared with the electrical condenser making with coventional type film, the electrical condenser making with polypropylene film is low with its percent thermal shrinkage, stable performance, high temperature resistant, high pressure resistant, the remarkable advantage such as prevent from puncturing, make the use range of the electrical condenser that polypropylene film makes more and more wider.
Existing polypropylene capactive film, shrinking percentage is relatively bigger than normal, temperature tolerance is poor, with the electrical condenser that the forms lengthening along with its working hour of reeling of this film, its internal temperature rise is very fast, cause the stability of electrical condenser sharply to decline, even cause electrical condenser to lose efficacy, bring serious potential safety hazard to electrical equipment complete machine or electrical network.Therefore the heat resistance as dielectric polypropylene film is had higher requirement.
Summary of the invention
The object of this invention is to provide a kind of electrical condenser high temperature resistant ultrathin isotatic polypropylene metalized film and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
High temperature resistant ultrathin isotatic polypropylene metalized film for a kind of electrical condenser, is made up of the raw material of following weight part: isotatic polypropylene 200, aluminium hydroxide 1-2, polyvinyl lactam 2-3, N hydroxymethyl acrylamide 1-2, ethylene glycol 1-2, dicyclopentadiene 2-3, poly-epoxy succinic acid 1-2, laurostearic acid 2-3, polyester acrylate 1-2, auxiliary agent 5-6;
Described auxiliary agent is made up of the raw material of following weight part: metallocene linear-low density polyethylene 12-15, acetyl triethyl citrate 14-18, propionate 3-4, linden ashes 1-2, linking agent TAC1-2,2-ethylhexyl diphenyl phosphate 5-6, polyvinyl alcohol 2-3, Flos Rosae Rugosae quintessence oil 0.1-0.2; Metallocene linear-low density polyethylene is heated to molten state by preparation method, then, adds polyvinyl alcohol, linden ashes to stir 10-15 minute, finally adds other composition, and dispersed with stirring is even, cooling, and granulation to obtain final product.
High temperature resistant ultrathin isotatic polypropylene metalized film for electrical condenser of the present invention, made by following concrete steps:
(1) by isotatic polypropylene, aluminium hydroxide, polyvinyl lactam, N hydroxymethyl acrylamide, the melting of ethylene glycol Hybrid Heating, add again auxiliary agent and all the other remaining components fully to stir, send into forcing machine melting, filtration, and then by forcing machine extruding sheet melt, filter >1200 order, the temperature of described forcing machine is 220-260 ℃;
(2) the sheet melt of step (1) being made makes slab after by sharp cooling roll and air raining chamber cooling and shaping, carries out successively longitudinal stretching, cross directional stretch, alligatoring face corona treatment;
(3) rolling, ageing treatment, ageing treatment for the second time for the first time;
(4) vacuum-evaporation metalized film, alligatoring face forms metal layer.
Complete processing of the present invention is simple, and little with the film capacitor contact resistance of its making, thereby makes product performance good; Film thickness of the present invention is even, is not easy to throw off, and cost is low, and the small volume of the electrical condenser of making has at high temperature percent thermal shrinkage low and stable performance, the i.e. good feature of high-temperature stability.
Embodiment
Below by specific examples, the present invention is described in detail.
High temperature resistant ultrathin isotatic polypropylene metalized film for a kind of electrical condenser, by following weight part (kilogram) raw material make: isotatic polypropylene 200, aluminium hydroxide 1, polyvinyl lactam 2, N hydroxymethyl acrylamide 1, ethylene glycol 1, dicyclopentadiene 2, poly-epoxy succinic acid 1, laurostearic acid 2, polyester acrylate 1, auxiliary agent 5;
Described auxiliary agent by following weight part (kilogram) raw material make: metallocene linear-low density polyethylene 12, acetyl triethyl citrate 14, propionate 3, linden ashes 2, linking agent TAC1,2-ethylhexyl diphenyl phosphate 5, polyvinyl alcohol 2, Flos Rosae Rugosae quintessence oil 0.1; Metallocene linear-low density polyethylene is heated to molten state by preparation method, then, adds polyvinyl alcohol, linden ashes to stir 10-15 minute, finally adds other composition, and dispersed with stirring is even, cooling, and granulation to obtain final product.
High temperature resistant ultrathin isotatic polypropylene metalized film for electrical condenser of the present invention, made by following concrete steps:
(1) by isotatic polypropylene, aluminium hydroxide, polyvinyl lactam, N hydroxymethyl acrylamide, the melting of ethylene glycol Hybrid Heating, add again auxiliary agent and all the other remaining components fully to stir, send into forcing machine melting, filtration, and then by forcing machine extruding sheet melt, filter >1200 order, the temperature of described forcing machine is 220-260 ℃;
(2) the sheet melt of step (1) being made makes slab after by sharp cooling roll and air raining chamber cooling and shaping, carries out successively longitudinal stretching, cross directional stretch, alligatoring face corona treatment;
(3) rolling, ageing treatment, ageing treatment for the second time for the first time;
(4) vacuum-evaporation metalized film, alligatoring face forms metal layer.
The technical indicator of the metallized film of the embodiment of the present invention is as follows:
(1) lateral shrinkage≤0.2%, longitudinal contraction rate≤2.5%
(2) transverse tensile strength >=10Mpa, longitudinal tensile strength >=16Mpa;
(3) minimum break-down voltage 597Vv/um.
Claims (2)
1. a high temperature resistant ultrathin isotatic polypropylene metalized film for electrical condenser, it is characterized in that, made by the raw material of following weight part: isotatic polypropylene 200, aluminium hydroxide 1-2, polyvinyl lactam 2-3, N hydroxymethyl acrylamide 1-2, ethylene glycol 1-2, dicyclopentadiene 2-3, poly-epoxy succinic acid 1-2, laurostearic acid 2-3, polyester acrylate 1-2, auxiliary agent 5-6;
Described auxiliary agent is made up of the raw material of following weight part: metallocene linear-low density polyethylene 12-15, acetyl triethyl citrate 14-18, propionate 3-4, linden ashes 1-2, linking agent TAC1-2,2-ethylhexyl diphenyl phosphate 5-6, polyvinyl alcohol 2-3, Flos Rosae Rugosae quintessence oil 0.1-0.2; Metallocene linear-low density polyethylene is heated to molten state by preparation method, then, adds polyvinyl alcohol, linden ashes to stir 10-15 minute, finally adds other composition, and dispersed with stirring is even, cooling, and granulation to obtain final product.
2. high temperature resistant ultrathin isotatic polypropylene metalized film for electrical condenser according to claim 1, is characterized in that, is made up of following concrete steps:
(1) by isotatic polypropylene, aluminium hydroxide, polyvinyl lactam, N hydroxymethyl acrylamide, the melting of ethylene glycol Hybrid Heating, add again auxiliary agent and all the other remaining components fully to stir, send into forcing machine melting, filtration, and then by forcing machine extruding sheet melt, filter >1200 order, the temperature of described forcing machine is 220-260 ℃;
(2) the sheet melt of step (1) being made makes slab after by sharp cooling roll and air raining chamber cooling and shaping, carries out successively longitudinal stretching, cross directional stretch, alligatoring face corona treatment;
(3) rolling, ageing treatment, ageing treatment for the second time for the first time;
(4) vacuum-evaporation metalized film, alligatoring face forms metal layer.
Priority Applications (1)
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CN201410001704.0A CN103772810A (en) | 2014-01-03 | 2014-01-03 | High-temperature resistant ultrathin isotactic polypropylene metallized film for capacitor and preparation method thereof |
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CN201410001704.0A CN103772810A (en) | 2014-01-03 | 2014-01-03 | High-temperature resistant ultrathin isotactic polypropylene metallized film for capacitor and preparation method thereof |
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CN201410001704.0A Pending CN103772810A (en) | 2014-01-03 | 2014-01-03 | High-temperature resistant ultrathin isotactic polypropylene metallized film for capacitor and preparation method thereof |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104774377A (en) * | 2015-03-26 | 2015-07-15 | 安徽海纳川塑业科技有限公司 | Lightweight and environmental-protection polypropylene composite material |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5392190A (en) * | 1991-12-18 | 1995-02-21 | Merlin Gerin | Manufacturing process of a capacitor with delayed ageing and a capacitor manufactured according to this process |
CN102543432A (en) * | 2011-12-28 | 2012-07-04 | 宁波大东南万象科技有限公司 | Preparation method of double-side metallized polypropylene capacitor film |
CN102964679A (en) * | 2012-10-31 | 2013-03-13 | 安徽省易达电子有限公司 | Capacitor film containing modified talc and preparation method thereof |
CN103102582A (en) * | 2012-11-13 | 2013-05-15 | 铜陵亿亨达电子有限责任公司 | Capacitor thin film containing modified nano-titanium dioxide and preparation method thereof |
CN103112169A (en) * | 2013-01-28 | 2013-05-22 | 宁波绿海电子材料有限公司 | Preparation method of metalized film of induction cooker capacitor |
-
2014
- 2014-01-03 CN CN201410001704.0A patent/CN103772810A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5392190A (en) * | 1991-12-18 | 1995-02-21 | Merlin Gerin | Manufacturing process of a capacitor with delayed ageing and a capacitor manufactured according to this process |
CN102543432A (en) * | 2011-12-28 | 2012-07-04 | 宁波大东南万象科技有限公司 | Preparation method of double-side metallized polypropylene capacitor film |
CN102964679A (en) * | 2012-10-31 | 2013-03-13 | 安徽省易达电子有限公司 | Capacitor film containing modified talc and preparation method thereof |
CN103102582A (en) * | 2012-11-13 | 2013-05-15 | 铜陵亿亨达电子有限责任公司 | Capacitor thin film containing modified nano-titanium dioxide and preparation method thereof |
CN103112169A (en) * | 2013-01-28 | 2013-05-22 | 宁波绿海电子材料有限公司 | Preparation method of metalized film of induction cooker capacitor |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104774377A (en) * | 2015-03-26 | 2015-07-15 | 安徽海纳川塑业科技有限公司 | Lightweight and environmental-protection polypropylene composite material |
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