CN103772810A - High-temperature resistant ultrathin isotactic polypropylene metallized film for capacitor and preparation method thereof - Google Patents

High-temperature resistant ultrathin isotactic polypropylene metallized film for capacitor and preparation method thereof Download PDF

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Publication number
CN103772810A
CN103772810A CN201410001704.0A CN201410001704A CN103772810A CN 103772810 A CN103772810 A CN 103772810A CN 201410001704 A CN201410001704 A CN 201410001704A CN 103772810 A CN103772810 A CN 103772810A
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parts
capacitor
temperature resistant
isotatic polypropylene
film
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CN201410001704.0A
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荚朝辉
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TONGLING QILI ELECTRONIC MATERIALS CO Ltd
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TONGLING QILI ELECTRONIC MATERIALS CO Ltd
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Priority to CN201410001704.0A priority Critical patent/CN103772810A/en
Publication of CN103772810A publication Critical patent/CN103772810A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07Flat, e.g. panels
    • B29C48/08Flat, e.g. panels flexible, e.g. films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • B29C48/0018Combinations of extrusion moulding with other shaping operations combined with shaping by orienting, stretching or shrinking, e.g. film blowing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/92Measuring, controlling or regulating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G4/00Fixed capacitors; Processes of their manufacture
    • H01G4/002Details
    • H01G4/005Electrodes
    • H01G4/008Selection of materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G4/00Fixed capacitors; Processes of their manufacture
    • H01G4/002Details
    • H01G4/005Electrodes
    • H01G4/015Special provisions for self-healing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/92704Temperature
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92819Location or phase of control
    • B29C2948/92857Extrusion unit
    • B29C2948/92876Feeding, melting, plasticising or pumping zones, e.g. the melt itself
    • B29C2948/92895Barrel or housing
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10Homopolymers or copolymers of propene
    • C08J2323/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04Homopolymers or copolymers of ethene
    • C08J2423/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Power Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Fixed Capacitors And Capacitor Manufacturing Machines (AREA)

Abstract

The invention discloses a high-temperature resistant ultrathin isotactic polypropylene metallized film for a capacitor, which is characterized by being prepared from the following raw materials in parts by weight: 200 parts of isotactic polypropylene, 1-2 parts of aluminum hydroxide, 2-3 parts of polyethylene amide, 1-2 parts of N-hydroxymethyl acrylamide, 1-2 parts of ethylene glycol, 2-3 parts of dicyclopentadiene, 1-2 parts of polyepoxysuccinic acid, 2-3 parts of dodecanoic acid, 1-2 parts of polyester acrylate and 5-6 parts of auxiliary. In the invention, the processing technology is simple, and the prepared film capacitor has low contact resistance so that the product features are good; the film disclosed by the invention is uniform in thickness and is not separated easily while the cost is low; the prepared capacitor is relatively small in volume and has the characteristics of low heat shrinkage and stable performance at high temperature, namely, relatively good high-temperature stability.

Description

High temperature resistant ultrathin isotatic polypropylene metalized film and preparation method thereof for a kind of electrical condenser
Technical field
The present invention relates to field of capacitor manufacture, particularly high temperature resistant ultrathin isotatic polypropylene metalized film and preparation method thereof for a kind of electrical condenser.
Background technology
Electrical condenser has higher mechanical property and electric property with BiOriented Polypropylene Films, compared with the electrical condenser making with coventional type film, the electrical condenser making with polypropylene film is low with its percent thermal shrinkage, stable performance, high temperature resistant, high pressure resistant, the remarkable advantage such as prevent from puncturing, make the use range of the electrical condenser that polypropylene film makes more and more wider.
Existing polypropylene capactive film, shrinking percentage is relatively bigger than normal, temperature tolerance is poor, with the electrical condenser that the forms lengthening along with its working hour of reeling of this film, its internal temperature rise is very fast, cause the stability of electrical condenser sharply to decline, even cause electrical condenser to lose efficacy, bring serious potential safety hazard to electrical equipment complete machine or electrical network.Therefore the heat resistance as dielectric polypropylene film is had higher requirement.
Summary of the invention
The object of this invention is to provide a kind of electrical condenser high temperature resistant ultrathin isotatic polypropylene metalized film and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
High temperature resistant ultrathin isotatic polypropylene metalized film for a kind of electrical condenser, is made up of the raw material of following weight part: isotatic polypropylene 200, aluminium hydroxide 1-2, polyvinyl lactam 2-3, N hydroxymethyl acrylamide 1-2, ethylene glycol 1-2, dicyclopentadiene 2-3, poly-epoxy succinic acid 1-2, laurostearic acid 2-3, polyester acrylate 1-2, auxiliary agent 5-6;
Described auxiliary agent is made up of the raw material of following weight part: metallocene linear-low density polyethylene 12-15, acetyl triethyl citrate 14-18, propionate 3-4, linden ashes 1-2, linking agent TAC1-2,2-ethylhexyl diphenyl phosphate 5-6, polyvinyl alcohol 2-3, Flos Rosae Rugosae quintessence oil 0.1-0.2; Metallocene linear-low density polyethylene is heated to molten state by preparation method, then, adds polyvinyl alcohol, linden ashes to stir 10-15 minute, finally adds other composition, and dispersed with stirring is even, cooling, and granulation to obtain final product.
High temperature resistant ultrathin isotatic polypropylene metalized film for electrical condenser of the present invention, made by following concrete steps:
(1) by isotatic polypropylene, aluminium hydroxide, polyvinyl lactam, N hydroxymethyl acrylamide, the melting of ethylene glycol Hybrid Heating, add again auxiliary agent and all the other remaining components fully to stir, send into forcing machine melting, filtration, and then by forcing machine extruding sheet melt, filter >1200 order, the temperature of described forcing machine is 220-260 ℃;
(2) the sheet melt of step (1) being made makes slab after by sharp cooling roll and air raining chamber cooling and shaping, carries out successively longitudinal stretching, cross directional stretch, alligatoring face corona treatment;
(3) rolling, ageing treatment, ageing treatment for the second time for the first time;
(4) vacuum-evaporation metalized film, alligatoring face forms metal layer.
Complete processing of the present invention is simple, and little with the film capacitor contact resistance of its making, thereby makes product performance good; Film thickness of the present invention is even, is not easy to throw off, and cost is low, and the small volume of the electrical condenser of making has at high temperature percent thermal shrinkage low and stable performance, the i.e. good feature of high-temperature stability.
Embodiment
Below by specific examples, the present invention is described in detail.
High temperature resistant ultrathin isotatic polypropylene metalized film for a kind of electrical condenser, by following weight part (kilogram) raw material make: isotatic polypropylene 200, aluminium hydroxide 1, polyvinyl lactam 2, N hydroxymethyl acrylamide 1, ethylene glycol 1, dicyclopentadiene 2, poly-epoxy succinic acid 1, laurostearic acid 2, polyester acrylate 1, auxiliary agent 5;
Described auxiliary agent by following weight part (kilogram) raw material make: metallocene linear-low density polyethylene 12, acetyl triethyl citrate 14, propionate 3, linden ashes 2, linking agent TAC1,2-ethylhexyl diphenyl phosphate 5, polyvinyl alcohol 2, Flos Rosae Rugosae quintessence oil 0.1; Metallocene linear-low density polyethylene is heated to molten state by preparation method, then, adds polyvinyl alcohol, linden ashes to stir 10-15 minute, finally adds other composition, and dispersed with stirring is even, cooling, and granulation to obtain final product.
High temperature resistant ultrathin isotatic polypropylene metalized film for electrical condenser of the present invention, made by following concrete steps:
(1) by isotatic polypropylene, aluminium hydroxide, polyvinyl lactam, N hydroxymethyl acrylamide, the melting of ethylene glycol Hybrid Heating, add again auxiliary agent and all the other remaining components fully to stir, send into forcing machine melting, filtration, and then by forcing machine extruding sheet melt, filter >1200 order, the temperature of described forcing machine is 220-260 ℃;
(2) the sheet melt of step (1) being made makes slab after by sharp cooling roll and air raining chamber cooling and shaping, carries out successively longitudinal stretching, cross directional stretch, alligatoring face corona treatment;
(3) rolling, ageing treatment, ageing treatment for the second time for the first time;
(4) vacuum-evaporation metalized film, alligatoring face forms metal layer.
The technical indicator of the metallized film of the embodiment of the present invention is as follows:
(1) lateral shrinkage≤0.2%, longitudinal contraction rate≤2.5%
(2) transverse tensile strength >=10Mpa, longitudinal tensile strength >=16Mpa;
(3) minimum break-down voltage 597Vv/um.

Claims (2)

1. a high temperature resistant ultrathin isotatic polypropylene metalized film for electrical condenser, it is characterized in that, made by the raw material of following weight part: isotatic polypropylene 200, aluminium hydroxide 1-2, polyvinyl lactam 2-3, N hydroxymethyl acrylamide 1-2, ethylene glycol 1-2, dicyclopentadiene 2-3, poly-epoxy succinic acid 1-2, laurostearic acid 2-3, polyester acrylate 1-2, auxiliary agent 5-6;
Described auxiliary agent is made up of the raw material of following weight part: metallocene linear-low density polyethylene 12-15, acetyl triethyl citrate 14-18, propionate 3-4, linden ashes 1-2, linking agent TAC1-2,2-ethylhexyl diphenyl phosphate 5-6, polyvinyl alcohol 2-3, Flos Rosae Rugosae quintessence oil 0.1-0.2; Metallocene linear-low density polyethylene is heated to molten state by preparation method, then, adds polyvinyl alcohol, linden ashes to stir 10-15 minute, finally adds other composition, and dispersed with stirring is even, cooling, and granulation to obtain final product.
2. high temperature resistant ultrathin isotatic polypropylene metalized film for electrical condenser according to claim 1, is characterized in that, is made up of following concrete steps:
(1) by isotatic polypropylene, aluminium hydroxide, polyvinyl lactam, N hydroxymethyl acrylamide, the melting of ethylene glycol Hybrid Heating, add again auxiliary agent and all the other remaining components fully to stir, send into forcing machine melting, filtration, and then by forcing machine extruding sheet melt, filter >1200 order, the temperature of described forcing machine is 220-260 ℃;
(2) the sheet melt of step (1) being made makes slab after by sharp cooling roll and air raining chamber cooling and shaping, carries out successively longitudinal stretching, cross directional stretch, alligatoring face corona treatment;
(3) rolling, ageing treatment, ageing treatment for the second time for the first time;
(4) vacuum-evaporation metalized film, alligatoring face forms metal layer.
CN201410001704.0A 2014-01-03 2014-01-03 High-temperature resistant ultrathin isotactic polypropylene metallized film for capacitor and preparation method thereof Pending CN103772810A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104774377A (en) * 2015-03-26 2015-07-15 安徽海纳川塑业科技有限公司 Lightweight and environmental-protection polypropylene composite material

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5392190A (en) * 1991-12-18 1995-02-21 Merlin Gerin Manufacturing process of a capacitor with delayed ageing and a capacitor manufactured according to this process
CN102543432A (en) * 2011-12-28 2012-07-04 宁波大东南万象科技有限公司 Preparation method of double-side metallized polypropylene capacitor film
CN102964679A (en) * 2012-10-31 2013-03-13 安徽省易达电子有限公司 Capacitor film containing modified talc and preparation method thereof
CN103102582A (en) * 2012-11-13 2013-05-15 铜陵亿亨达电子有限责任公司 Capacitor thin film containing modified nano-titanium dioxide and preparation method thereof
CN103112169A (en) * 2013-01-28 2013-05-22 宁波绿海电子材料有限公司 Preparation method of metalized film of induction cooker capacitor

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5392190A (en) * 1991-12-18 1995-02-21 Merlin Gerin Manufacturing process of a capacitor with delayed ageing and a capacitor manufactured according to this process
CN102543432A (en) * 2011-12-28 2012-07-04 宁波大东南万象科技有限公司 Preparation method of double-side metallized polypropylene capacitor film
CN102964679A (en) * 2012-10-31 2013-03-13 安徽省易达电子有限公司 Capacitor film containing modified talc and preparation method thereof
CN103102582A (en) * 2012-11-13 2013-05-15 铜陵亿亨达电子有限责任公司 Capacitor thin film containing modified nano-titanium dioxide and preparation method thereof
CN103112169A (en) * 2013-01-28 2013-05-22 宁波绿海电子材料有限公司 Preparation method of metalized film of induction cooker capacitor

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104774377A (en) * 2015-03-26 2015-07-15 安徽海纳川塑业科技有限公司 Lightweight and environmental-protection polypropylene composite material

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