CN103757612A - Environmental protection multifunction electric conduction film manufacturing method - Google Patents
Environmental protection multifunction electric conduction film manufacturing method Download PDFInfo
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- CN103757612A CN103757612A CN201310206271.8A CN201310206271A CN103757612A CN 103757612 A CN103757612 A CN 103757612A CN 201310206271 A CN201310206271 A CN 201310206271A CN 103757612 A CN103757612 A CN 103757612A
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 14
- 230000007613 environmental effect Effects 0.000 title abstract description 6
- 239000000463 material Substances 0.000 claims abstract description 16
- 239000007788 liquid Substances 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000758 substrate Substances 0.000 claims abstract description 10
- 238000002360 preparation method Methods 0.000 claims abstract description 9
- 230000032683 aging Effects 0.000 claims abstract description 7
- 238000000197 pyrolysis Methods 0.000 claims abstract description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000012153 distilled water Substances 0.000 claims abstract description 6
- NWFNSTOSIVLCJA-UHFFFAOYSA-L copper;diacetate;hydrate Chemical compound O.[Cu+2].CC([O-])=O.CC([O-])=O NWFNSTOSIVLCJA-UHFFFAOYSA-L 0.000 claims abstract description 4
- WCOATMADISNSBV-UHFFFAOYSA-K diacetyloxyalumanyl acetate Chemical compound [Al+3].CC([O-])=O.CC([O-])=O.CC([O-])=O WCOATMADISNSBV-UHFFFAOYSA-K 0.000 claims abstract description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 11
- 239000011787 zinc oxide Substances 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 6
- 239000011521 glass Substances 0.000 claims description 4
- 239000007921 spray Substances 0.000 claims description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims description 3
- 238000000889 atomisation Methods 0.000 claims description 3
- 210000003298 dental enamel Anatomy 0.000 claims description 3
- 239000000428 dust Substances 0.000 claims description 3
- 238000000605 extraction Methods 0.000 claims description 3
- 239000004744 fabric Substances 0.000 claims description 3
- 230000007062 hydrolysis Effects 0.000 claims description 3
- 238000006460 hydrolysis reaction Methods 0.000 claims description 3
- 229940071125 manganese acetate Drugs 0.000 claims description 3
- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 claims description 3
- 230000000873 masking effect Effects 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- 239000011490 mineral wool Substances 0.000 claims description 3
- 230000009467 reduction Effects 0.000 claims description 3
- 238000004062 sedimentation Methods 0.000 claims description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 239000008399 tap water Substances 0.000 claims description 3
- 235000020679 tap water Nutrition 0.000 claims description 3
- 150000003751 zinc Chemical class 0.000 claims description 3
- 239000004246 zinc acetate Substances 0.000 claims description 3
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 abstract description 5
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 abstract description 5
- 239000010949 copper Substances 0.000 abstract description 4
- 239000011701 zinc Substances 0.000 abstract description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052782 aluminium Inorganic materials 0.000 abstract description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 3
- 229910052802 copper Inorganic materials 0.000 abstract description 3
- 229960000935 dehydrated alcohol Drugs 0.000 abstract description 3
- 239000011572 manganese Substances 0.000 abstract description 3
- 229910001510 metal chloride Inorganic materials 0.000 abstract description 3
- 230000003287 optical effect Effects 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 3
- 239000002904 solvent Substances 0.000 abstract description 3
- 229910052725 zinc Inorganic materials 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- 230000036541 health Effects 0.000 abstract description 2
- 239000002019 doping agent Substances 0.000 abstract 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 1
- 150000001242 acetic acid derivatives Chemical class 0.000 abstract 1
- 239000012752 auxiliary agent Substances 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 abstract 1
- 239000013078 crystal Substances 0.000 abstract 1
- 230000002708 enhancing effect Effects 0.000 abstract 1
- DLINORNFHVEIFE-UHFFFAOYSA-N hydrogen peroxide;zinc Chemical compound [Zn].OO DLINORNFHVEIFE-UHFFFAOYSA-N 0.000 abstract 1
- 229910003437 indium oxide Inorganic materials 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 229940082328 manganese acetate tetrahydrate Drugs 0.000 abstract 1
- CESXSDZNZGSWSP-UHFFFAOYSA-L manganese(2+);diacetate;tetrahydrate Chemical compound O.O.O.O.[Mn+2].CC([O-])=O.CC([O-])=O CESXSDZNZGSWSP-UHFFFAOYSA-L 0.000 abstract 1
- 229910001887 tin oxide Inorganic materials 0.000 abstract 1
- YZYKBQUWMPUVEN-UHFFFAOYSA-N zafuleptine Chemical compound OC(=O)CCCCCC(C(C)C)NCC1=CC=C(F)C=C1 YZYKBQUWMPUVEN-UHFFFAOYSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 10
- 230000000694 effects Effects 0.000 description 4
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 4
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 4
- 238000012271 agricultural production Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000004065 semiconductor Substances 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000005660 chlorination reaction Methods 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052738 indium Inorganic materials 0.000 description 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 210000002345 respiratory system Anatomy 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 235000019633 pungent taste Nutrition 0.000 description 1
- 238000005118 spray pyrolysis Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
Abstract
The invention relates to an environmental protection multifunction electric conduction film manufacturing method, which is characterized in that the film-forming liquid formula comprises: 100 g of zinc acetate dihydrate adopted as a main material, 47 g of aluminum triacetate adopted as a dopant, 2.4 g of manganese acetate tetrahydrate, 1.9 g of copper acetate monohydrate adopted as an enhancing dopant, a proper amount of acetic acid adopted as an auxiliary agent, and 100-500 g of distilled water adopted as a solvent. The preparation process comprises: film-forming liquid preparation, substrate cleaning, pyrolysis film forming, electrode preparation and wire leading, and impact aging. Compared with the manufacturing method in the prior art, the manufacturing method of the present invention has the following advantages that: acetates of zinc, aluminum, manganese and copper are adopted to replace the commonly-used metal chloride formula so as to provide characteristics of environmental protection and energy saving; according to the electric conduction film, zinc dioxide is adopted to replace tin oxide and indium oxide so as to be adopted as the main crystal phase, and distilled water is adopted to replace dehydrated alcohol so as to be adopted the solvent; and the environmental protection multifunction electric conduction film has characteristics of low cost, easily-available raw material and low price, and can be used for piezoelectric materials, optical sensors, solar cells, military coating, and electric conduction films in the health field.
Description
Technical field
The ohmic resistance conductive film that material or material property be feature is take in the present invention, especially relates to a kind of manufacture method of environment protection type multifunctional conducting film.
Background technology
Metal conductive oxide material is the important member in semi-conductor family, and because it has good electrical property and energy-saving effect, recent decades, widely people paid close attention to.Numerous scientific and technical personnel's unremitting effort, technical progress is remarkable, and Application Areas is constantly widened, the planar electro-conductive material of film-type particularly, because its thermal response is fast, electric conversion efficiency is high, and energy-saving effect is remarkable, and in heating, be used widely in the aspects such as water-heater.
At present, conventional metal conductive oxide film mainly contains tindioxide, indium trioxide, zinc oxide and indium acid cadmium and doping system thereof.Mostly they are to adopt the muriate of respective metal to be dissolved in dehydrated alcohol, are formulated as film forming liquid, at high temperature through spray pyrolysis or other method, form metal conductive oxide film, then through the utmost point processed elementization production that gone between.Problem is the ethanolic soln of these metal chlorides, and a large amount of chlorine and the hydrogen chloride gas that in pyrolytic coating pyrolytic process, produce, cause severe contamination to atmosphere.Chlorination has rank smell, poisonous! In the air of general operation place, content must not surpass 0.001mg/ liter, and the moisture in respiratory tract is that the former is extremely unstable, and then is decomposed into oxygen and hydrogenchloride so that chlorination intense reaction generates hypochlorous acid and hydrochloric acid.Hydrogenchloride is very easily water-soluble and generate hydrochloric acid.Hydrochloric acid is one of strong acid, has extremely strong corrodibility, to skin, can cause burn, and respiratory system is had to pungency damage.
China has put into effect the rules of " environmental protection right of veto by one vote " in recent years, and importance, urgency and national great attention in China environmental protection have been described.The old road that Yu Qizou developed country " pollutes century-old improvement for 1 year ", not as beginning from myself,, does everything possible to reduce or stop and pollutes to power from source.
Summary of the invention
The object of the invention is to propose a kind of manufacture method of environment protection multifunctional conducting film, in accordance with the old maxim of " enhance agricultural production and economize expenses ", from protection of the environment, the starting material prescription that the rich inexpensive pollution of candidate is little, reaching can be cost-saving, can treat again the object of environment kindly.
Technical scheme of the present invention is following realization, a kind of manufacture method of environment protection multifunctional conducting film, and its film forming liquid formula weight ratio is:
A manufacture method for environment protection multifunctional conducting film, its processing step comprises: preparation film forming liquid, cleaned base material, pyrolysis film forming, the utmost point processed lead-in wire, impact aging, specifically:
1, preparation film forming liquid: first with acetic acid by distilled water acidifying, in case zinc salt hydrolysis; By formula, take each component again, under stirring, slowly add successively zinc acetate two water, aluminium acetate, manganese acetate four water, neutralized verdigris one water, stir to dissolving completely, build, standby.
2, cleaned base material: the hard temperature resistant substrates such as glass, pottery, silicon carbide, enamel are cleaned with tap water, wiped steam, dry, prevent dust, standby; Slim temperature resistant substrate is as mica, and mineral wool cloth etc., wipe clean with alcohol swab if desired.
3, pyrolysis masking: clean dry and comfortable base material is loaded onto to clamping apparatus, along track, push film forming stove, at 250～300 ℃, adopt ultra low volume spray (utilize special equipment and shower nozzle, make the droplet of ejection be less than 100 microns) that the atomization of film forming liquid is sprayed in stove, pass through series of chemical, generate corresponding metal conductive oxide particulate, sedimentation embeds in substrate surface lattice, and long-pending generate be take the conductive doped film that zinc oxide is principal crystalline phase.
(CH
3COO)
2Zn·2H
2O+4O
2＝ZnO+4CO
2+5H
2O
2(CH
3COO)
3Al+12O
2＝Al
2O
3+12CO
2+9H
2O
2(CH
3COO)
2Mn·4H
2O+9O
2＝2MnO
2+8CO
2+14H
2O
(CH
3COO)
2Cu·H
2O+4O
2＝CuO+4CO
2+4H
2O
CuO+MnO
2＝CuMnO
3
Copper Mn oxide is good semiconductor material, is entrained in zinc oxide crystalline phase, has improved capacitive character and the stability of rete.
4, the utmost point processed lead-in wire: according to product needed, coat conductive silver paste in the appropriate location of rete, after about 100 ℃ oven dry, send in 250～300 ℃ of reduction furnaces reductase 12 0～30 minute, cause electrode to be even compact, smooth silvery white is qualified.
5, impact aging: from electrode extraction electrode line, use higher than the voltage of 1～25 times of operating voltage and take each second after interval break-make 10～20 times, logical 3～10 minutes continuously, make rete Ordering lattice, allow the product of defectiveness fully expose problem simultaneously, screen out in time, to guarantee quality product.
Advantage of the present invention: 1; reduce and pollute; kind treatment environment; the present invention adopt zinc, aluminium, manganese, copper, acetate substitute conventional metal chloride prescription; in reactor off-gas, stopped obnoxious flavour chlorine and hydrogenchloride, the substitute is oxygen, the necessary useful gases of animals and plants existence such as carbonic acid gas and aqueous vapor; to reducing, pollute, protection of the environment plays a role.2, raw material is easy to get, and low price has data introduction: " metal average content indium in the earth's crust: tin: zinc is 0.1: 40: 132ppm ", and conducting film of the present invention is to using zinc oxide to replace tindioxide and Indium sesquioxide as principal crystalline phase, with distilled water, replaces dehydrated alcohol and make solvent.With how, for few, with low-priced Dai Gui, not only raw material is easy to get, and price advantage is obvious.3, enhance agricultural production and economize expenses, reduces energy consumption, and the present invention adopts ultra low volume spray film forming, because thing is rich, does not economize, and or not because of inexpensive not thrifty, medication is not few, and effect is fast, and number of dropouts is little, meets the old maxim of " enhance agricultural production and economize expenses ".Film-forming temperature, not as good as half of prior art, greatly reduces film forming energy consumption.4, performance is various, is widely used, and that zinc oxide electro-conductive material has is optical, electrical, piezoelectricity and the characteristic such as ferroelectric.As a kind of piezoelectric, zinc oxide percentage coupling is larger, and synergistic effect, can strengthen its task performance mutually, at modern electronic technology, acousto-optic and Radio Physics molecular engineering technical elements, is widely used.Aspect photoconductive property, because its induction force is strong, response is used to optical sensor soon; The doping of aluminium has improved the light transmission of rete, electroconductibility and stability and be used to solar cell, and flat-panel monitor and heating glass etc., the doping of copper Mn oxide, has strengthened electric conductivity and the stability of rete; 90% infrared reflectance, has widened the application aspect military application and health care.As a kind of inexpensive multi-functional semiconductor material, zinc chloride conducting film and doping system thereof have wide Prospect of R & D.
Embodiment
A manufacture method for environment protection multifunctional conducting film, its film forming liquid formula weight ratio is:
A manufacture method for environment protection multifunctional conducting film, its processing step comprises: preparation film forming liquid, cleaned base material, pyrolysis film forming, the utmost point processed lead-in wire, impact aging, specifically:
1, preparation film forming liquid: first with acetic acid by distilled water acidifying, in case zinc salt hydrolysis; By formula, take each component again, under stirring, slowly add successively zinc acetate two water, aluminium acetate, manganese acetate four water, neutralized verdigris one water, stir to dissolving completely, build, standby.
2, cleaned base material: the hard temperature resistant substrates such as glass, pottery, silicon carbide, enamel are cleaned with tap water, wiped steam, dry, prevent dust, standby; Slim temperature resistant substrate is as mica, and mineral wool cloth etc., wipe clean with alcohol swab if desired.
3, pyrolysis masking: clean dry and comfortable base material is loaded onto to clamping apparatus, along track, push film forming stove, at 250～300 ℃, adopt ultra low volume spray (utilize special equipment and shower nozzle, make the droplet of ejection be less than 100 microns) that the atomization of film forming liquid is sprayed in stove, pass through series of chemical, generate corresponding metal conductive oxide particulate, sedimentation embeds in substrate surface lattice, and long-pending generate be take the conductive doped film that zinc oxide is principal crystalline phase.
4, the utmost point processed lead-in wire: according to product needed, coat conductive silver paste in the appropriate location of rete, after about 100 ℃ oven dry, send in 250～300 ℃ of reduction furnaces reductase 12 0～30 minute, cause electrode to be even compact, smooth silvery white is qualified.
5, impact aging: from electrode extraction electrode line, use higher than the voltage of 1～25 times of operating voltage and take each second after interval break-make 10～20 times, logical 3～10 minutes continuously, make rete Ordering lattice, allow the product of defectiveness fully expose problem simultaneously, screen out in time, to guarantee quality product.
Claims (2)
1. a manufacture method for environment protection multifunctional conducting film, is characterized in that film forming liquid formula weight ratio is:
2. the manufacture method of a kind of environment protection multifunctional conducting film as claimed in claim 1, is characterized in that processing step comprises: preparation film forming liquid, cleaned base material, pyrolysis film forming, the utmost point processed go between, impact aging, specifically:
Preparation film forming liquid: first with acetic acid by distilled water acidifying, in case zinc salt hydrolysis; By formula, take each component again, under stirring, slowly add successively zinc acetate two water, aluminium acetate, manganese acetate four water, neutralized verdigris one water, stir to dissolving completely, build, standby;
Cleaned base material: the hard temperature resistant substrates such as glass, pottery, silicon carbide, enamel are cleaned with tap water, wiped steam, dry, prevent dust, standby; Slim temperature resistant substrate is as mica, and mineral wool cloth, wipes clean with alcohol swab;
Pyrolysis masking: clean dry and comfortable base material is loaded onto to clamping apparatus, along track, push film forming stove, at 250～300 ℃, adopt ultra low volume spray that the atomization of film forming liquid is sprayed in stove, pass through series of chemical, generate corresponding metal conductive oxide particulate, sedimentation embeds in substrate surface lattice, and long-pending generate be take the conductive doped film that zinc oxide is principal crystalline phase;
The utmost point processed lead-in wire: the appropriate location at rete coats conductive silver paste, after about 100 ℃ oven dry, sends in 250～300 ℃ of reduction furnaces reductase 12 0～30 minute, causes electrode to be even compact, and smooth silvery white is qualified;
Impact aging: from electrode extraction electrode line, use higher than the voltage of 1～25 times of operating voltage and take each second after interval break-make 10～20 times, logical 3～10 minutes continuously, make rete Ordering lattice, to guarantee quality product.
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| CN201310206271.8A CN103757612B (en) | 2013-05-30 | 2013-05-30 | The manufacture method of Environmental protection multifunction electric conduction film |
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| CN103757612B CN103757612B (en) | 2016-04-20 |
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| JP2012172200A (en) * | 2011-02-22 | 2012-09-10 | National Institute Of Advanced Industrial Science & Technology | Method for manufacturing transparent conductive film, and transparent conductive film |
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| JP2013030399A (en) * | 2011-07-29 | 2013-02-07 | Shimane Univ | Creation method of transparent conductive film, and transparent conductive film material |
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2013
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| US20070036914A1 (en) * | 2001-12-03 | 2007-02-15 | Konica Corporation | Transparent conductive layer forming method, transparent conductive layer formed by the method, and material comprising the layer |
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| CN103757612B (en) | 2016-04-20 |
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