CN103757168A - Iron making rotary kiln and iron making technology - Google Patents

Iron making rotary kiln and iron making technology Download PDF

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CN103757168A
CN103757168A CN201310747865.XA CN201310747865A CN103757168A CN 103757168 A CN103757168 A CN 103757168A CN 201310747865 A CN201310747865 A CN 201310747865A CN 103757168 A CN103757168 A CN 103757168A
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gas
rotary kiln
regenerator
air
tail
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CN103757168B (en
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李苏翔
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Abstract

The invention relates to an iron making rotary kiln and an iron making technology. The iron making technology comprises the following steps of (1) preheating burning gas; (2) heating the rotary kiln; (3) making iron, wherein the iron making rotary kiln comprises a regenerative chamber, a rotary kiln and a tail gas recovery device, and the regenerative chamber comprises a coal gas regenerative chamber and an air regenerative chamber. By rising the temperature in the rotary kiln up to 1700 DEG C, the purpose of making iron by the rotary kiln is realized, the traditional blast furnace iron making technology is changed, pellets are reduced, coal consumption is saved by adopting the sintering technology, iron making process links are reduced, iron making production links are reduced, and then the cost and environment pollution are lowered.

Description

A kind of ironmaking rotary kiln and iron-smelting process thereof
Technical field
The present invention relates to a kind of ironmaking rotary kiln and iron-smelting process thereof.
Background technology
Existing rotary kiln is used coal dust and warm air burning, in kiln, top temperature is 1100 ℃, temperature does not reach ironmaking temperature, existing iron smelting method is used blast furnace ironmaking, but blast furnace ironmaking cost is high, power consumption is large, does not depart from group's ball, sintering process, and blast furnace ironmaking equipment is huge covers an area of, operation is various, and the environmental pressure causing is serious.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of rotary kiln that can smelt iron and iron-smelting process thereof.
The present invention adopts following technical scheme:
A kind of ironmaking rotary kiln comprises regenerator, rotary kiln, device for recovering tail gas;
Described regenerator comprises gas regenerator and air regenerator;
Described gas regenerator is provided with gas entry, gas exit, gas chamber gas inlet and the outlet of gas chamber tail gas, described gas entry is connected with cooled coal gas pipe by cooled coal gas arm, described cooled coal gas pipe is connected with coal-gas producer, described gas exit is connected with bocca by hot gas pipe, described gas chamber gas inlet is connected with offgas duct by tail gas arm, described offgas duct is connected with device for recovering tail gas, and described gas chamber tail gas outlet is connected with tail gas recycle pipe by tail gas recycle arm;
Described air regenerator is provided with gas inlet, air vout, wind box gas inlet and the outlet of wind box tail gas, described gas inlet is connected with cold air pipe by freezing air arm, described cold air pipe is connected with gas blower, described air vout is connected with bocca by warm-air pipe, described wind box gas inlet is connected with offgas duct by tail gas arm, and described wind box tail gas outlet is connected with tail gas recycle pipe by tail gas recycle arm;
Described rotary kiln is tilting on pedestal, and the kiln hood of described rotary kiln is lower than kiln tail, and described kiln tail is provided with raw material powder entrance, and described kiln hood is provided with molten iron outlet;
Described device for recovering tail gas comprises offgas duct, tail gas recycle pipe and is arranged on the tail gas gas blower in offgas duct, described offgas duct one end is fixedly installed on kiln tail, the other end is connected with wind box gas inlet and gas chamber gas inlet by tail gas arm, and described tail gas recycle pipe is connected with the outlet of wind box tail gas and the outlet of gas chamber tail gas by offgas duct;
Described hot gas pipe and warm-air pipe converge to bocca, and described bocca is corresponding with rotary kiln end;
Described gas entry, gas exit, gas chamber gas inlet, the outlet of gas chamber tail gas, gas inlet, air vout, wind box gas inlet and the outlet of wind box tail gas are respectively arranged with air door.
Described gas regenerator and air regenerator arrange more than two being used in conjunction with.
Described rotary kiln end inwall is built zircon corundum brick, and described rotary kiln inwall is built magnesite chrome brick, and described bocca inwall is built zircon corundum brick.
Described offgas duct and tail gas recycle inside pipe wall are built insulating brick.
Described rotary kiln and horizontal plane angle are 3-5 °.
it is above-mentioned that the present invention provides on the other handthe iron-smelting process of ironmaking rotary kiln carries out in the steps below when ironmaking:
(1) burning gas preheating
(1.1) high-temperature tail gas of rotary kiln imports gas regenerator and air regenerator;
(1.2) coal gas of being derived by coal-gas producer, import the gas regenerator that accumulation of heat completes, gas temperature behind gas regenerator gets a promotion, and gas blower is sent to air the air regenerator of accumulation of heat, and the air themperature after air regenerator gets a promotion;
(2) rotary kiln heating
Through the coal gas of high temperature and the spontaneous combustion after bocca converges of the air of high temperature of regenerator, kiln hood is heated;
(3) ironmaking
Raw material powder enters rotary kiln from kiln tail, and under the continuous rotation of tilting rotary kiln, raw material powder moves to the high-temperature zone of rotary kiln, forms molten iron, through stream material mouthful, flows out and obtains molten iron.
In above-mentioned steps (1.1), described rotary kiln exhaust gas temperature is 1100-1200 ℃,
In above-mentioned steps (1.1), the temperature after described regenerator heating is 950-1000 ℃,
In above-mentioned steps (2), the temperature of the coal gas of described high temperature and the air of high temperature is 800-900 ℃,
In above-mentioned steps (2), described kiln hood flame temperature is 1500-1700 ℃;
The composition of the mass percent of above-mentioned raw materials powder:
Powdered iron ore 68-75%,
Coal dust 15-17%,
Wingdale 10-17%;
Furtherly, the high-temperature tail gas that flows out regenerator passes through tail gas recycle pipe again, and tail gas is delivered to raw material powder heating unit, and raw material powder is preheated.
Furtherly, raw material powder is preheated to 200-300 ℃.
Positively effect of the present invention is as follows:
The present invention can be by the temperature increase to 1700 in kiln ℃, can realize and smelt iron object with rotary kiln, change like this technique of traditional blast furnace ironmaking, reduce group's ball, sintering process saving coal consumption, reduce the process procedure of ironmaking, reduce the production link of ironmaking, thereby reduce costs and the pollution to environment.
Accompanying drawing explanation
Accompanying drawing 1 is structural representation of the present invention;
Accompanying drawing 2 is regenerator internal structure schematic diagram of the present invention;
Accompanying drawing 3 is bocca structural representation of the present invention;
Accompanying drawing 4 is two groups of regenerator material flow schematic diagram of the present invention;
Accompanying drawing 5 is two groups of regenerator Two-ports structure schematic diagram of the present invention;
In the accompanying drawings: 1 gas regenerator, 11 gas entries, 12 gas exits, 13 gas chamber gas inlets, 14 gas chamber tail gas outlets, 2 air regenerators, 21 gas inlets, 22 air vouts, 23 wind box gas inlets, 24 wind box tail gas outlets, 3 cooled coal gas pipes, 31 cooled coal gas arms, 32 hot gas pipes, 4 rotary kilns, 41 kiln hoods, 42 kiln tails, 5 boccas, 6 offgas duct, 61 tail gas arms, 62 tail gas recycle arms, 63 tail gas recycle pipes, 7 cold air pipes, 71 freezing air arms, 72 warm-air pipes, 8 tail gas gas blowers, 9 air doors, 10 regenerator.
Embodiment
Embodiment 1: as described in accompanying drawing 2, a kind of ironmaking rotary kiln, comprises regenerator 10, rotary kiln 4, device for recovering tail gas;
Described regenerator comprises gas regenerator 1 and air regenerator 2:
Described gas regenerator 1 is provided with gas entry 11, gas exit 12, gas chamber gas inlet 13 and gas chamber tail gas outlet 14, described gas entry 11 is connected with cooled coal gas pipe 3 by cooled coal gas arm 31, described cooled coal gas pipe 3 is connected with coal-gas producer, described gas exit 12 is connected with bocca 5 by hot gas pipe 32, described gas chamber gas inlet 13 is connected with offgas duct 6 by tail gas arm 61, described offgas duct 6 is connected with device for recovering tail gas, described gas chamber tail gas outlet 14 is connected with tail gas recycle pipe 63 by tail gas recycle arm 62,
Described air regenerator is provided with gas inlet 21, air vout 22, wind box gas inlet 23 and wind box tail gas outlet 24, described gas inlet 21 is connected with cold air pipe 7 by freezing air arm 71, described cold air pipe 7 is connected with gas blower, described air vout 22 is connected with bocca 5 by warm-air pipe 72, described wind box gas inlet 23 is connected with offgas duct 6 by tail gas arm 61, and described wind box tail gas outlet 24 is connected with tail gas recycle pipe 63 by tail gas recycle arm 62.
Described rotary kiln 4 is tilting on pedestal, the inclination angle of rotary kiln 4 be the kiln hood 41 of 4 ° of described rotary kilns 4 lower than kiln tail 42, described kiln tail 42 is provided with raw material powder entrance, described kiln hood 41 is provided with molten iron outlet;
Described device for recovering tail gas comprises offgas duct 6, tail gas recycle pipe 63 and is arranged on the tail gas gas blower 8 in offgas duct 6, described offgas duct 6 one end are fixedly installed on kiln tail 42, the other end is connected with wind box gas inlet 23 and gas chamber gas inlet 13 by tail gas arm 61, and described tail gas recycle pipe 63 is connected with the outlet 24 of wind box tail gas and gas chamber tail gas outlet 14 by offgas duct 62;
Described hot gas pipe 32 and warm-air pipe 72 converge to bocca 5, and described bocca 5 is corresponding with rotary kiln end 41;
Described gas entry 11, gas exit 12, gas chamber gas inlet 13, gas chamber tail gas outlet 14, gas inlet 21, air vout 22, wind box gas inlet 23 and wind box tail gas outlet 24 are respectively arranged with air door 9.
As described in accompanying drawing 1,4, the heat storage in regenerator is built into stereo grid shaped, and heat storage can be refractory brick, the form of piling up of three-dimensional hollow mesh structure is conducive to heat storage accumulation of heat and heat release, take regenerator as two groups as example, the hocket accumulation of heat and allow the heat, cycle be 30min of two groups of regenerator, wherein during one group of accumulation of heat, gas entry 11, gas inlet 21, the air door 9 of gas exit 12 and air vout 22 is closed, gas chamber gas inlet 13, gas chamber tail gas outlet 14, the air door 9 of wind box gas inlet 23 and wind box tail gas outlet 24 is opened, the high-temperature tail gas that now offgas duct 6 is dredged by kiln tail 42 sends into gas regenerator 1 by tail gas gas blower 8 and air regenerator 2 makes the heat storage in regenerator absorb the heat in tail gas, the tail gas that flows out the outlet 14 of gas chamber tail gas and wind box tail gas outlet 24 converges to tail gas recycle pipe 63 by tail gas recycle arm 62, tail gas recycle pipe 63 is sent to tail gas raw material powder primary heater unit again, improve the temperature that raw material powder enters rotary kiln, meanwhile, another group is being carried out heat release, when the regenerator that accumulation of heat completes is carried out heat release, gas chamber gas inlet 13, gas chamber tail gas outlet 14, the air door 9 of wind box gas inlet 23 and wind box tail gas outlet 24 is closed, gas entry 11, gas inlet 21, the air door 9 of gas exit 12 and air vout 22 is opened, the coal gas of the 300-500 now being transported by coal-gas producer ℃ can enter gas regenerator 1 by gas entry 11, the coal gas carrying out after heat exchange enters hot gas pipe 32 via gas exit 12, then be transported to bocca 5, by gas blower, being transported is that air enters after air regenerator heat exchange via gas inlet 21, through air vout 22, enters warm-air pipe 72, is then transported to bocca 5, the coal gas of high temperature and air are in bocca 5 spontaneous combustions, and the flame temperature of kiln hood 41 can reach 1650 ℃, and kiln hood just can keep optimum ironmaking temperature (1480-1520 ℃) like this.
Rotary kiln end 41 inwalls are built zircon corundum bricks, and described rotary kiln 42 inwalls are built magnesite chrome brick, and the temperature of bearing with kiln tail 42 due to kiln hood 41 is different can use different fire-proof and thermal-insulation insulating bricks, reduces costs, and also can better adapt to need of production.
Bocca 5 inwalls are built zircon corundum brick, so very high-temperature heat insulating refractory material is reliability and durability because bocca 5 will bear.
Offgas duct 6 and tail gas recycle pipe 63 inwalls are built insulating brick, need insulation when tail gas is carried, and the one, reduce thermosteresis, the 2nd, reduce the infringement of high temperature to surrounding devices and personnel.
Hot gas pipe 32 diameters are 1200mm, and finishing building effective diameter after insulating brick is 750mm, and warm-air pipe 72 diameters are 1600mm, and finishing building effective diameter after insulating brick is 1150mm; Bocca 5 is built into by the refractory brick of zircon corundum material, and as described in accompanying drawing 3, on bocca 5, top is arc, and arc top maximum height is 1000mm, and width is 700mm; Rotary kiln length 64000mm, external diameter is 3200mm, and the 12000mm of kiln hood place builds zircon corundum brick, and rest part is built chromium magnesium zirconia block, and after block fire proofing tile, the effectively interior warp of rotary kiln is 2700mm; The spiral tube that offgas duct 6 diameters that kiln tail 42 arranges are 1500mm, the inside and outside block of spiral tube has light-weight insulating brick.
Powdered iron ore and coal dust, raw material powder after the raw materials such as Wingdale mix is entered in kiln body by kiln tail 42, because tilting kiln body constantly rotates, along with the rotation of rotary kiln, material slowly and is uniformly pushed to kiln hood 41, raw material powder is advanced to kiln hood 41 gradually, due to high temperature anoxic in kiln body, the carbon monoxide that carbon in coal dust forms in the hot environment of anoxic, by the 2+ in iron ore, 3+, the iron of 4+ is reduced into iron simple substance, when arriving kiln hood 41 high-temperature area, the fe being reduced is at high temperature fused into liquid state, Wingdale in raw material powder plays desulfurization and catalysis, the effect of slag making, the molten iron of high temperature flows out by flowing material mouthful, because residue light specific gravity can float on above molten iron, finally by slag-drip opening, discharged, through separator, obtain molten iron.
Gas regenerator 1 and air regenerator 2 arrange more than two being used in conjunction with, produce and just can carry out continuously like this, the coal gas of preheating and air can continually be carried in kiln, to produce continual carrying out, with two groups of regenerator, are optimum settings, when more than three groups regenerator coordinates, be applicable to large-scale ironmaking rotary kiln.
As described in accompanying drawing 1,2,4, above-mentioned a kind of iron-smelting process of smelting iron rotary kiln, carries out in the steps below:
(1) burning gas preheating
(1.1) high-temperature tail gas of rotary kiln importing gas regenerator and air regenerator will store in regenerator;
(1.2) coal gas of being derived by coal-gas producer, import the gas regenerator that accumulation of heat completes, gas temperature behind gas regenerator gets a promotion, and by gas blower, air is sent to the air regenerator of accumulation of heat, and the air themperature after air regenerator gets a promotion;
(2) rotary kiln heating
Through the coal gas of high temperature and the spontaneous combustion after bocca converges of the air of high temperature of regenerator, kiln hood is heated;
(3) ironmaking
Raw material powder enters rotary kiln from kiln tail, and under the continuous rotation of tilting rotary kiln, raw material powder moves to the high-temperature zone of rotary kiln, forms molten iron, through stream material mouthful, flows out and obtains molten iron.
In described step (1.1), described rotary kiln exhaust gas temperature is 1150 ℃,
In described step (1.1), the temperature after described regenerator heating is 980 ℃,
In described step (2), the temperature of the coal gas of described high temperature and the air of high temperature is 850 ℃,
In described step (2), described kiln hood is heated by the flame 1650 ℃.
The composition of the mass percent of described raw material powder:
Powdered iron ore 72%,
Coal dust 16%,
Wingdale 12%.
The high-temperature tail gas that flows out regenerator passes through tail gas recycle pipe again, and tail gas is delivered to raw material powder heating unit, and raw material powder is preheated.
Tail gas is preheated to 200-300 ℃ by raw material powder.
The present invention relates to the relevant device of ironmaking, the associated production line equipment such as coal-gas producer, ore powder processing units, temperature controlling system are identical with existing installation.
Embodiment 2: in the process of ironmaking, the temperature in step 1 and step 2 can also be on the basis of embodiment 1:
In described step (1.1), described rotary kiln exhaust gas temperature is 1200 ℃,
In described step (1.1), the temperature after described regenerator heating is 1000 ℃,
In described step (2), the temperature of the coal gas of described high temperature and the air of high temperature is 900 ℃,
In described step (2), described kiln hood flame temperature is 1700 ℃.
The composition of the mass percent of described raw material powder furtherly:
Powdered iron ore 68%,
Coal dust 17%,
Wingdale 15%.
The inclination angle of rotary kiln 4 is 3 °.
Embodiment 3: in the process of ironmaking, the temperature in step 1 and step 2 can also be on the basis of embodiment 1:
In described step (1.1), described rotary kiln exhaust gas temperature is 1100 ℃,
In described step (1.1), the temperature after described regenerator heating is 950 ℃,
In described step (2), the temperature of the coal gas of described high temperature and the air of high temperature is 800 ℃,
In described step (2), described kiln hood is heated by the flame 1500 ℃.
The composition of the mass percent of described raw material powder:
Powdered iron ore 75%,
Coal dust 15%,
Wingdale 10%.
The inclination angle of rotary kiln 4 is 5 °.
Embodiment 4: as shown in Figure 2, each regenerator has 4 import and export in embodiment 1, corresponding outlet connecting pipe road arranges respectively air door on pipeline, and regenerator opening is too much.On the basis of said structure, as shown in Figure 5, play the exhaust pipe opening of pre-heat effect, can directly be opened in that corresponding (heating air flow is conventionally contrary with coal gas, air draught, adopt adverse currents heating more) coal gas or the duct wall of air turnover regenerator on, offer the position of mouth in being offered the air door middle part of pipeline regenerator opening and this pipeline, the air-flow of each pipeline can be controlled and be independent of each other separately like this, control identically with primary structure, such improvement can reduce the opening of regenerator half.

Claims (10)

1. an ironmaking rotary kiln, is characterized in that: it comprises regenerator (10), rotary kiln (4), device for recovering tail gas;
Described regenerator (10) comprises gas regenerator (1) and air regenerator (2);
Described gas regenerator (1) is provided with gas entry (11), gas exit (12), gas chamber gas inlet (13) and gas chamber tail gas outlet (14), described gas entry (11) is connected with cooled coal gas pipe (3) by cooled coal gas arm (31), described cooled coal gas pipe (3) is connected with coal-gas producer, described gas exit (12) is connected with bocca (5) by hot gas pipe (32), described gas chamber gas inlet (13) is connected with offgas duct (6) by tail gas arm (61), described offgas duct (6) is connected with device for recovering tail gas, described gas chamber tail gas outlet (14) is connected with tail gas recycle pipe (63) by tail gas recycle arm (62),
Described air regenerator is provided with gas inlet (21), air vout (22), wind box gas inlet (23) and wind box tail gas outlet (24), described gas inlet (21) is connected with cold air pipe (7) by freezing air arm (71), described cold air pipe (7) is connected with gas blower, described air vout (22) is connected with bocca (5) by warm-air pipe (72), described wind box gas inlet (23) is connected with offgas duct (6) by tail gas arm (61), described wind box tail gas outlet (24) is connected with tail gas recycle pipe (63) by tail gas recycle arm (62),
Described rotary kiln (4) is tilting on pedestal, and the kiln hood (41) of described rotary kiln (4) is lower than kiln tail (42), and described kiln tail (42) is provided with raw material powder entrance, and described kiln hood (41) is provided with molten iron outlet;
Described device for recovering tail gas comprises offgas duct (6), tail gas recycle pipe (63) and is arranged on the tail gas gas blower (8) in offgas duct (6), described offgas duct (6) one end is fixedly installed on kiln tail (42), the other end is connected with wind box gas inlet (23) and gas chamber gas inlet (13) by tail gas arm (61), and described tail gas recycle pipe (63) is connected with wind box tail gas outlet (24) and gas chamber tail gas outlet (14) by offgas duct (62);
Described hot gas pipe (32) and warm-air pipe (72) converge to bocca (5), and described bocca (5) is corresponding with rotary kiln end (41);
Described gas entry (11), gas exit (12), gas chamber gas inlet (13), the outlet of gas chamber tail gas (14), gas inlet (21), air vout (22), wind box gas inlet (23) and wind box tail gas outlet (24) are respectively arranged with air door (9).
2. a kind of ironmaking rotary kiln according to claim 1, is characterized in that described gas regenerator (1) and air regenerator (2) arrange more than two being used in conjunction with.
3. a kind of ironmaking rotary kiln according to claim 1 and 2, is characterized in that: described rotary kiln end (41) inwall is built zircon corundum brick, and described rotary kiln (42) inwall is built magnesite chrome brick, and described bocca (5) inwall is built zircon corundum brick.
4. a kind of ironmaking rotary kiln according to claim 1 and 2, is characterized in that: described offgas duct (6) and tail gas recycle pipe (63) inwall are built insulating brick.
5. a kind of ironmaking rotary kiln according to claim 1 and 2, is characterized in that: described rotary kiln (4) is 3-5 ° with horizontal plane angle.
6. an iron-smelting process for ironmaking rotary kiln as claimed in claim 1, is characterized in that: when ironmaking, carry out in the steps below:
(1) burning gas preheating
(1.1) high-temperature tail gas of rotary kiln imports gas regenerator and air regenerator;
(1.2) coal gas of being derived by coal-gas producer, import the gas regenerator that accumulation of heat completes, gas temperature behind gas regenerator gets a promotion, and gas blower is sent to air the air regenerator of accumulation of heat, and the air themperature after air regenerator gets a promotion;
(2) rotary kiln heating
Through the coal gas of high temperature and the spontaneous combustion after bocca converges of the air of high temperature of regenerator, kiln hood is heated;
(3) ironmaking
Raw material powder enters rotary kiln from kiln tail, and under the continuous rotation of tilting rotary kiln, raw material powder moves to the high-temperature zone of rotary kiln, forms molten iron, through stream material mouthful, flows out and obtains molten iron.
7. a kind of iron-smelting process of smelting iron rotary kiln according to claim 6, is characterized in that:
In described step (1.1), described rotary kiln exhaust gas temperature is 1100-1200 ℃,
In described step (1.1), the temperature after described regenerator heating is 950-1000 ℃,
In described step (2), the temperature of the coal gas of described high temperature and the air of high temperature is 800-900 ℃,
In described step (2), described kiln hood flame temperature is 1500-1700 ℃.
8. the iron-smelting process of a kind of rotary kiln according to claim 6, is characterized in that:
The composition of the mass percent of described raw material powder:
Powdered iron ore 68-75%,
Coal dust 15-17%,
Wingdale 10-17%.
9. the iron-smelting process of a kind of rotary kiln according to claim 6, is characterized in that: the high-temperature tail gas that flows out regenerator passes through tail gas recycle pipe again, and tail gas is delivered to raw material powder heating unit, and raw material powder is preheated.
10. the iron-smelting process of a kind of rotary kiln according to claim 9, is characterized in that: raw material powder is preheated to 200-300 ℃.
CN201310747865.XA 2013-12-31 2013-12-31 A kind of ironmaking rotary kiln and iron-smelting process thereof Expired - Fee Related CN103757168B (en)

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Publication number Priority date Publication date Assignee Title
CN106636519A (en) * 2016-10-12 2017-05-10 唐竹胜 Whole-body two-sided flame separating type heating rotary kiln and method for producing direct reduction iron co-production carbon base fertilizer
CN107843110A (en) * 2017-11-29 2018-03-27 浙江大东吴集团建设新材料有限公司 A kind of heated air circulation type Expanded Clay Rotary Kilns

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Publication number Priority date Publication date Assignee Title
CN106636519A (en) * 2016-10-12 2017-05-10 唐竹胜 Whole-body two-sided flame separating type heating rotary kiln and method for producing direct reduction iron co-production carbon base fertilizer
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CN107843110A (en) * 2017-11-29 2018-03-27 浙江大东吴集团建设新材料有限公司 A kind of heated air circulation type Expanded Clay Rotary Kilns

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