CN103753885A - High-warranty PVDF (polyvinylidene fluoride) color coated steel sheet - Google Patents

High-warranty PVDF (polyvinylidene fluoride) color coated steel sheet Download PDF

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Publication number
CN103753885A
CN103753885A CN201310721716.6A CN201310721716A CN103753885A CN 103753885 A CN103753885 A CN 103753885A CN 201310721716 A CN201310721716 A CN 201310721716A CN 103753885 A CN103753885 A CN 103753885A
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CN
China
Prior art keywords
layer
pvdf
thickness
varnish
basic unit
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Pending
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CN201310721716.6A
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Chinese (zh)
Inventor
陈正国
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YEHUI (CHINA) TECHNOLOGY MATERIALS Co Ltd
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YEHUI (CHINA) TECHNOLOGY MATERIALS Co Ltd
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Priority to CN201310721716.6A priority Critical patent/CN103753885A/en
Publication of CN103753885A publication Critical patent/CN103753885A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a high-warranty PVDF (polyvinylidene fluoride) color coated steel sheet. The high-warranty PVDF color coated steel sheet comprises a base layer (1), wherein the front of the base layer (1) is sequentially provided with a pretreatment layer (2), a primer layer (3), a finish coat layer (4) and a varnish layer (5) from inward to outward; the back of the base layer (1) is sequentially provided with a pretreatment layer (6), a primer layer (7), a finish coat layer (8) from inward to outward; the pretreatment layers (2 and 6) of the front and the back of the base layer (1) are formed by coating passivation liquid; the primer layer (3) of the front of the base layer (1) has the thickness of 65-70 mu m, and is made of the polyurethane primer; the finish paint layer (4) has the thickness of 35-40 mu m, and is made of the PVDF finish coat; the varnish layer (5) has the thickness of 10-15mu m, and is made of the PVDF varnish. According to the invention, the combination of the thicknesses of the layers of the front of the base layer and the material selection is designed, so that the high-warranty PVDF color coated steel sheet has higher weather fastness and abrasion resistance, and is longer in warranty period which achieves above 25 years.

Description

The high PVDF color coated steel sheet admittedly of protecting
Technical field
The present invention relates to a kind of color coated steel sheet, specifically the solid PVDF color coated steel sheet of a kind of high guarantor.
Background technology
Day by day serious along with environmental problem, various pollutions are more and more serious to the corrosion of construction material, and in order to extend service life, the serious factory of some environmental corrosions need to be used high weather-proof construction material as power plant, chemical plant and some Important Project.
PVDF color coating coil of strip is used the color coating coil of strip product of PVDF (polyvinylidene fluoride) production of resins, and generally producing thickness is 20 μ m, and Bao Gunian is limited to 15~20 years.In order to increase the weatherability of PVDF color coating coil of strip, need to guarantee that in paint film, PVDF resin content needs more than 70%, and use inorganic ceramic pigment, just can reach certain weatherability, protect the solid time limit and can reach at most 20 years.
At present, produce high weather-proof, the high PVDF product of protecting the solid time limit and need use high weather-proof high-end PVDF resin as KYNAR500 or HYLAR5000, guarantee that paint thickness is more than 18 μ m, and need to use inorganic ceramic pigment.Coating price costliness and color are limited.
Summary of the invention
Technical problem to be solved by this invention is to provide the solid PVDF color coated steel sheet of a kind of high guarantor.This color coated steel sheet has stronger weatherability, wear resistence, protects the solid time limit more of a specified duration.
In order to solve the problems of the technologies described above, technical scheme of the present invention is:
The solid PVDF color coated steel sheet of a kind of high guarantor, comprise basic unit, the front of described basic unit is followed successively by preprocessing layer, prime coat, top coat layer and layer of varnish from inside to outside, the back side of described basic unit is followed successively by preprocessing layer, prime coat and top coat layer from inside to outside, preprocessing layer outside described basic unit positive and negative is that passivating solution applies formation, the prime coat thickness in described basic unit front is 65~70 μ m, and its material is polyurethane primer; Described top coat layer thickness is 35~40 μ m, and its material is PVDF finish paint; Described layer of varnish thickness is 10~15 μ m, and its material is PVDF varnish.
Wherein, the polyurethane priming paint of 65~70 μ m has good corrosion resistance.
The PVDF of 35~40 μ m (polyvinylidene fluoride) finish paint has good weatherability.
The PVDF of 10~15 μ m (polyvinylidene fluoride) varnish, has good wearability.
In order to obtain the solid time limit of more excellent guarantor, the gross thickness of prime coat, top coat layer and the layer of varnish in described basic unit front is less than 120 μ m, and the prime coat thickness that preferred scheme is basic unit front is 65 μ m, and top coat layer thickness is 40 μ m, and layer of varnish thickness is 10 μ m.
Described basic unit is galvanized sheet or aluminium plating zinc plate.
The polyurethane primer relating in the present invention, PVDF finish paint and PVDF varnish are application known materials for a long time in industry.Wherein, polyurethane primer is comprised of the polyurethane resin of isocyanato group containing, wear-and corrosion-resistant pigment, solvent, auxiliary agent, curing agent etc.; PVDF finish paint is mainly comprised of PVDF resin, acrylic resin, weather-proof pigment, solvent, auxiliary agent etc.As polyurethane primer is selected the polyurethane primer of selling outside Nippon Paint (China) Co., Ltd.; PVDF finish paint selects note forever to make the polyvinylidene fluoride resin finish paint of selling outside paint industry (Kunshan) Co., Ltd; PVDF varnish selects note forever to make the polyvinylidene fluoride resin varnish of selling outside paint industry (Kunshan) Co., Ltd.
Creativeness of the present invention is the combination that the positive thickness at all levels of the basic unit of design and material are selected, and makes it have stronger weatherability, wear resistence, protects the solid time limit more of a specified duration, protects the solid time limit and reaches more than 25 years.Product of the present invention is through salt spray test, and compared with common product, experiment parameter is increased to 260% left and right.
Accompanying drawing explanation
Below in conjunction with the drawings and specific embodiments, the present invention is further detailed explanation.
Fig. 1 is structural representation of the present invention.
The specific embodiment
Embodiment 1
The high PVDF color coated steel sheet basic unit 1 admittedly of protecting adopts galvanized sheet or aluminium plating zinc plate, basic unit 1 front is followed successively by preprocessing layer 2, prime coat 3, top coat layer 4 and layer of varnish 5 from inside to outside, preprocessing layer 2 forms for the passivating solution containing Cr VI phosphate composition applies, prime coat 3 thickness in basic unit 1 front are 65 μ m, and its material is for forever remembering and make the polyurethane primer of selling outside paint industry (Kunshan) Co., Ltd; Top coat layer 4 thickness are 35 μ m, and its material is for forever remembering and make the polyvinylidene fluoride Trees fat finish paint of selling outside paint industry (Kunshan) Co., Ltd; Layer of varnish 5 thickness are 10 μ m, and its material is for forever remembering and make the polyvinylidene fluoride Trees fat varnish of selling outside paint industry (Kunshan) Co., Ltd.
The back side of basic unit 1 is followed successively by preprocessing layer 6, prime coat 7 and top coat layer 8 from inside to outside, and preprocessing layer 6 forms for the passivating solution containing Cr VI phosphate composition applies, and thickness and the material of prime coat 7 and top coat layer 8 adopt common solution of the prior art.
The said goods can reach 2600 hours through salt mist experiment, 1000 hours experimental results of more general PVDF product, and performance significantly improves.
Embodiment 2
Prime coat 3 thickness in basic unit 1 front are 65 μ m, and its material is the polyurethane primer of selling outside Li Bang Tu material (middle Country) Co., Ltd; Top coat layer 4 thickness are 40 μ m, and its material is the polyvinylidene fluoride Trees fat finish paint of selling outside Li Bang Tu material (middle Country) Co., Ltd; Layer of varnish 5 thickness are 15 μ m, and its material is the polyvinylidene fluoride Trees fat varnish of selling outside Li Bang Tu material (middle Country) Co., Ltd.
All the other schemes are identical with embodiment 1.
The said goods can reach 2500 hours through salt mist experiment, 1000 hours experimental results of more general PVDF product, and performance significantly improves.
Embodiment 3
Prime coat 3 thickness in basic unit 1 front are 65 μ m, and its material is for forever remembering and make the polyurethane primer of selling outside paint industry (Kunshan) Co., Ltd; Top coat layer 4 thickness are 40 μ m, and its material is for forever remembering and make the polyvinylidene fluoride Trees fat finish paint of selling outside paint industry (Kunshan) Co., Ltd; Layer of varnish 5 thickness are 10 μ m, and its material is for forever remembering and make the polyvinylidene fluoride Trees fat varnish of selling outside paint industry (Kunshan) Co., Ltd.
All the other schemes are identical with embodiment 1.
The said goods can reach 2650 hours through salt mist experiment, 1000 hours experimental results of more general PVDF product, and performance significantly improves.
Above-described embodiment does not limit the present invention in any way, and every employing is equal to replaces or technical scheme that the mode of equivalent transformation obtains all drops in protection scope of the present invention.

Claims (4)

1. a high guarantor consolidates PVDF color coated steel sheet, comprise basic unit (1), the front of described basic unit (1) is followed successively by preprocessing layer (2), prime coat (3), top coat layer (4) and layer of varnish (5) from inside to outside, the back side of described basic unit (1) is followed successively by preprocessing layer (6), prime coat (7) and top coat layer (8) from inside to outside, preprocessing layer (2 outside described basic unit (1) positive and negative, 6) for applying, passivating solution forms, it is characterized in that: positive prime coat (3) thickness of described basic unit (1) is 65~70 μ m, and its material is polyurethane primer; Described top coat layer (4) thickness is 35~40 μ m, and its material is PVDF finish paint; Described layer of varnish (5) thickness is 10~15 μ m, and its material is PVDF varnish.
2. the high solid PVDF color coated steel sheet of protecting according to claim 1, is characterized in that: the gross thickness of prime coat (3), top coat layer (4) and layer of varnish (5) that described basic unit (1) is positive is less than 120 μ m.
3. the high solid PVDF color coated steel sheet of protecting according to claim 2, is characterized in that: positive prime coat (3) thickness of described basic unit (1) is 65 μ m, and top coat layer (4) thickness is 40 μ m, and layer of varnish (5) thickness is 10 μ m.
4. according to the height described in claim 1,2 or 3, protect solid PVDF color coated steel sheet, it is characterized in that: described basic unit (1) is galvanized sheet or aluminium plating zinc plate.
CN201310721716.6A 2013-12-24 2013-12-24 High-warranty PVDF (polyvinylidene fluoride) color coated steel sheet Pending CN103753885A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104004420A (en) * 2014-06-11 2014-08-27 江苏标榜装饰新材料股份有限公司 Sidewall panel for train carriage
CN104015436A (en) * 2014-05-15 2014-09-03 合肥禾盛新型材料有限公司 Front-rear-surface dual-coated matte panel and manufacturing method thereof
CN105437659A (en) * 2015-12-22 2016-03-30 苏州兴禾源复合材料有限公司 High-strength PCM colored steel plate
CN107060198A (en) * 2017-04-24 2017-08-18 董晶龙 A kind of shockproof building panel of environmental protection and its prepare installation method

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04203156A (en) * 1990-11-30 1992-07-23 Dainippon Printing Co Ltd Manufacture for facing decorative sheet
JP2000280402A (en) * 1999-03-30 2000-10-10 Nisshin Steel Co Ltd Fluoroplastic film laminated metal plate and production thereof
CN101235240A (en) * 2008-03-10 2008-08-06 常州新刚高丽化工有限公司 Fluorocarbon dope and producing method thereof
CN101664734A (en) * 2009-09-02 2010-03-10 苏州扬子江新型材料股份有限公司 Preparation method of scratch-resistant and wear-resistant color coat steel plate
CN102501458A (en) * 2011-10-19 2012-06-20 珠海拾比佰彩图板股份有限公司 Highlight triple-coating and triple-baking color coated steel sheet and preparation method thereof
CN203623059U (en) * 2013-12-24 2014-06-04 烨辉(中国)科技材料有限公司 High-warranty PVDF (Polyvinylidene Fluoride) color pre-coated steel plate

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04203156A (en) * 1990-11-30 1992-07-23 Dainippon Printing Co Ltd Manufacture for facing decorative sheet
JP2000280402A (en) * 1999-03-30 2000-10-10 Nisshin Steel Co Ltd Fluoroplastic film laminated metal plate and production thereof
CN101235240A (en) * 2008-03-10 2008-08-06 常州新刚高丽化工有限公司 Fluorocarbon dope and producing method thereof
CN101664734A (en) * 2009-09-02 2010-03-10 苏州扬子江新型材料股份有限公司 Preparation method of scratch-resistant and wear-resistant color coat steel plate
CN102501458A (en) * 2011-10-19 2012-06-20 珠海拾比佰彩图板股份有限公司 Highlight triple-coating and triple-baking color coated steel sheet and preparation method thereof
CN203623059U (en) * 2013-12-24 2014-06-04 烨辉(中国)科技材料有限公司 High-warranty PVDF (Polyvinylidene Fluoride) color pre-coated steel plate

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
孙玉福: "《金属材料规格及重量手册》", 30 September 2012, article "钢板和钢带", pages: 373-381 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104015436A (en) * 2014-05-15 2014-09-03 合肥禾盛新型材料有限公司 Front-rear-surface dual-coated matte panel and manufacturing method thereof
CN104004420A (en) * 2014-06-11 2014-08-27 江苏标榜装饰新材料股份有限公司 Sidewall panel for train carriage
CN105437659A (en) * 2015-12-22 2016-03-30 苏州兴禾源复合材料有限公司 High-strength PCM colored steel plate
CN107060198A (en) * 2017-04-24 2017-08-18 董晶龙 A kind of shockproof building panel of environmental protection and its prepare installation method
CN107060198B (en) * 2017-04-24 2018-05-08 深圳市广胜达建设有限公司 A kind of environmentally protective shockproof building panel and its prepare installation method

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Application publication date: 20140430