CN103751943B - Fire extinguishing composition containing nitrogen-containing organic compound - Google Patents
Fire extinguishing composition containing nitrogen-containing organic compound Download PDFInfo
- Publication number
- CN103751943B CN103751943B CN201410012973.7A CN201410012973A CN103751943B CN 103751943 B CN103751943 B CN 103751943B CN 201410012973 A CN201410012973 A CN 201410012973A CN 103751943 B CN103751943 B CN 103751943B
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- CN
- China
- Prior art keywords
- fire extinguishing
- composition
- organic compound
- nitrogen
- containing organic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims abstract description 60
- -1 nitrogen-containing organic compound Chemical class 0.000 title claims abstract description 56
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 33
- 238000002485 combustion reaction Methods 0.000 claims abstract description 18
- 239000002245 particle Substances 0.000 claims abstract description 15
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 18
- 235000019359 magnesium stearate Nutrition 0.000 claims description 9
- LTWIBTYLSRDGHP-HCURTGQUSA-N 1,2-bis[(e)-(4-chlorophenyl)methylideneamino]guanidine;hydrochloride Chemical compound [Cl-].C=1C=C(Cl)C=CC=1\C=N\N=C(/N)N\[NH+]=C\C1=CC=C(Cl)C=C1 LTWIBTYLSRDGHP-HCURTGQUSA-N 0.000 claims description 3
- 229960005445 robenidine hydrochloride Drugs 0.000 claims description 3
- SPSSULHKWOKEEL-UHFFFAOYSA-N 2,4,6-trinitrotoluene Chemical compound CC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O SPSSULHKWOKEEL-UHFFFAOYSA-N 0.000 claims description 2
- XSXYESVZDBAKKT-UHFFFAOYSA-N 2-hydroxybenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1O XSXYESVZDBAKKT-UHFFFAOYSA-N 0.000 claims description 2
- 239000005983 Maleic hydrazide Substances 0.000 claims description 2
- BGRDGMRNKXEXQD-UHFFFAOYSA-N Maleic hydrazide Chemical compound OC1=CC=C(O)N=N1 BGRDGMRNKXEXQD-UHFFFAOYSA-N 0.000 claims description 2
- FULZLIGZKMKICU-UHFFFAOYSA-N N-phenylthiourea Chemical compound NC(=S)NC1=CC=CC=C1 FULZLIGZKMKICU-UHFFFAOYSA-N 0.000 claims description 2
- 239000004954 Polyphthalamide Substances 0.000 claims description 2
- SWRGUMCEJHQWEE-UHFFFAOYSA-N ethanedihydrazide Chemical compound NNC(=O)C(=O)NN SWRGUMCEJHQWEE-UHFFFAOYSA-N 0.000 claims description 2
- PLHJDBGFXBMTGZ-WEVVVXLNSA-N furazolidone Chemical compound O1C([N+](=O)[O-])=CC=C1\C=N\N1C(=O)OCC1 PLHJDBGFXBMTGZ-WEVVVXLNSA-N 0.000 claims description 2
- 229960001625 furazolidone Drugs 0.000 claims description 2
- NDEMNVPZDAFUKN-UHFFFAOYSA-N guanidine;nitric acid Chemical compound NC(N)=N.O[N+]([O-])=O.O[N+]([O-])=O NDEMNVPZDAFUKN-UHFFFAOYSA-N 0.000 claims description 2
- 229960003350 isoniazid Drugs 0.000 claims description 2
- QRXWMOHMRWLFEY-UHFFFAOYSA-N isoniazide Chemical compound NNC(=O)C1=CC=NC=C1 QRXWMOHMRWLFEY-UHFFFAOYSA-N 0.000 claims description 2
- 229920006375 polyphtalamide Polymers 0.000 claims description 2
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- 239000001913 cellulose Substances 0.000 claims 8
- 229920002678 cellulose Polymers 0.000 claims 8
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims 6
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims 4
- 235000019270 ammonium chloride Nutrition 0.000 claims 3
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims 2
- 239000004114 Ammonium polyphosphate Substances 0.000 claims 1
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- 230000000694 effects Effects 0.000 abstract description 8
- 230000005764 inhibitory process Effects 0.000 abstract 1
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- 239000003063 flame retardant Substances 0.000 description 6
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- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 4
- JRNVZBWKYDBUCA-UHFFFAOYSA-N N-chlorosuccinimide Chemical compound ClN1C(=O)CCC1=O JRNVZBWKYDBUCA-UHFFFAOYSA-N 0.000 description 4
- FZERHIULMFGESH-UHFFFAOYSA-N N-phenylacetamide Chemical compound CC(=O)NC1=CC=CC=C1 FZERHIULMFGESH-UHFFFAOYSA-N 0.000 description 4
- ISAKRJDGNUQOIC-UHFFFAOYSA-N Uracil Chemical compound O=C1C=CNC(=O)N1 ISAKRJDGNUQOIC-UHFFFAOYSA-N 0.000 description 4
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- 239000002253 acid Substances 0.000 description 4
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- 150000002894 organic compounds Chemical class 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- QYNUQALWYRSVHF-OLZOCXBDSA-N (6R)-5,10-methylenetetrahydrofolic acid Chemical compound C([C@H]1CNC=2N=C(NC(=O)C=2N1C1)N)N1C1=CC=C(C(=O)N[C@@H](CCC(O)=O)C(O)=O)C=C1 QYNUQALWYRSVHF-OLZOCXBDSA-N 0.000 description 3
- UZJZIZFCQFZDHP-UHFFFAOYSA-N 3-nitrobenzene-1,2-dicarbonitrile Chemical compound [O-][N+](=O)C1=CC=CC(C#N)=C1C#N UZJZIZFCQFZDHP-UHFFFAOYSA-N 0.000 description 3
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 3
- OVBPIULPVIDEAO-UHFFFAOYSA-N N-Pteroyl-L-glutaminsaeure Natural products C=1N=C2NC(N)=NC(=O)C2=NC=1CNC1=CC=C(C(=O)NC(CCC(O)=O)C(O)=O)C=C1 OVBPIULPVIDEAO-UHFFFAOYSA-N 0.000 description 3
- ZRALSGWEFCBTJO-UHFFFAOYSA-N anhydrous guanidine Natural products NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 3
- 235000013877 carbamide Nutrition 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229960000304 folic acid Drugs 0.000 description 3
- 235000019152 folic acid Nutrition 0.000 description 3
- 239000011724 folic acid Substances 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
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- BEOOHQFXGBMRKU-UHFFFAOYSA-N sodium cyanoborohydride Chemical compound [Na+].[B-]C#N BEOOHQFXGBMRKU-UHFFFAOYSA-N 0.000 description 3
- GHOKWGTUZJEAQD-ZETCQYMHSA-N (D)-(+)-Pantothenic acid Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-ZETCQYMHSA-N 0.000 description 2
- IAKHMKGGTNLKSZ-INIZCTEOSA-N (S)-colchicine Chemical compound C1([C@@H](NC(C)=O)CC2)=CC(=O)C(OC)=CC=C1C1=C2C=C(OC)C(OC)=C1OC IAKHMKGGTNLKSZ-INIZCTEOSA-N 0.000 description 2
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 2
- LUBJCRLGQSPQNN-UHFFFAOYSA-N 1-Phenylurea Chemical compound NC(=O)NC1=CC=CC=C1 LUBJCRLGQSPQNN-UHFFFAOYSA-N 0.000 description 2
- BQMPGKPTOHKYHS-UHFFFAOYSA-N 1h-pyrrole-2-carbonitrile Chemical compound N#CC1=CC=CN1 BQMPGKPTOHKYHS-UHFFFAOYSA-N 0.000 description 2
- HZNVUJQVZSTENZ-UHFFFAOYSA-N 2,3-dichloro-5,6-dicyano-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(C#N)=C(C#N)C1=O HZNVUJQVZSTENZ-UHFFFAOYSA-N 0.000 description 2
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- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 2
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
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Landscapes
- Fire-Extinguishing Compositions (AREA)
Abstract
The present invention relates to a fire extinguishing composition containing a nitrogen-containing organic compound, which releases a large amount of effective fire extinguishing particles using heat generated by combustion of a pyrotechnic agent. The fire extinguishing composition containing the nitrogen-containing organic compound reacts at high temperature to generate free radicals, and the free radicals react with one or more of O, OH and H free radicals necessary for the chain combustion reaction, so that the chain combustion reaction is cut off, and the physical and chemical inhibition effects are generated to realize the fire extinguishing effect together.
Description
Technical Field
The invention belongs to the technical field of aerosol fire extinguishing, and particularly relates to a hot aerosol fire extinguishing composition.
Background
Since the specific goal of replacing the fire extinguishing agent with the dragon fire extinguishing agent is provided by the Montreal convention in Canada in 1987, all countries in the world are dedicated to research on new fire extinguishing technologies, and the efforts of people are directed to the fire extinguishing technologies which have high fire extinguishing efficiency and are free of environmental pollution.
Gas fire extinguishing systems, dry powder fire extinguishing systems, water system fire extinguishing systems and the like are widely used as substitutes of Halon fire extinguishing agents due to no harm to the environment. Carbon dioxide, inert gas fire extinguishing systems such as IG 541's the mechanism of putting out a fire is mainly for physics is put out a fire, through reducing the oxygen concentration in the district of catching a fire and stifle the fire, this kind of mode of putting out a fire threatens human safety easily, dry powder fire extinguishing system is then through the powder of blowout and flame contact under the pressurized gas effect, take place the physical chemistry inhibitory action and put out a fire, water smoke fire extinguishing system is through the cooling of thin water smoke, stifle and isolated thermal radiation's triple action down reach the control conflagration, suppress the conflagration and put out the purpose of conflagration.
However, these fire extinguishing systems require high-pressure storage, not only are large in volume, but also have the risk of physical explosion during storage, and the document "safety analysis of gas fire extinguishing systems" (fire science and technology 200221 (5)) analyzes the risk of the gas fire extinguishing systems and enumerates the safety accidents caused by the use of the pressure-storage type gas fire extinguishing systems.
The existing hot aerosol fire extinguishing agent mainly comprises S-type and K-type fire extinguishing agents, and the performance characteristics of the existing hot aerosol fire extinguishing agent are comprehensively analyzed, wherein the fire extinguishing mechanism is that the hot aerosol fire extinguishing agent utilizes the burning of agents to generate oxidation-reduction reaction to release a large amount of gas and active particles, and the coverage of the large amount of gas is choked through the chain scission reaction of the active particles, so that the fire extinguishing purpose of combining chemistry and physics is realized. Its weak point is in the hot aerosol fire extinguishing agent when taking place combustion reaction release hot aerosol, can release a large amount of heats, can cause the postcombustion, for effectively reducing the temperature of device and aerosol, avoid taking place the secondary fire, need increase cooling system, the cooling temperature material of current hot aerosol fire extinguishing device though can reduce the temperature of product, the fire extinguishing performance of product has also been weakened greatly simultaneously, in order to compensate the loss on the fire extinguishing performance that cooling system brought, many products have either reduced the rank of putting out a fire, or continue to increase the quality of actual fire extinguishing agent, make the product volume increase, the availability factor descends, this leads to the complicated heavy of device structure, the process flow is complicated, and is with high costs, and the spout temperature is higher, easily cause the injury to the personnel of putting out a fire.
Disclosure of Invention
In view of the current state of the art fire extinguishing devices, and in particular the inherent drawbacks of aerosol fire extinguishing systems, it is an object of the present invention to provide a safer, more efficient fire extinguishing composition.
The technical scheme adopted by the invention is as follows:
a fire extinguishing composition containing a nitrogen-containing organic compound, characterized in that: the fire extinguishing composition contains a nitrogen-containing organic compound; the fire extinguishing composition utilizes the combustion of a pyrotechnic agent to release a plurality of effective fire extinguishing particles.
Furthermore, the mass percentage of the nitrogen-containing organic compound in the fire extinguishing composition is more than or equal to 35%.
Further, the nitrogen-containing organic compound comprises one or more of nitro compounds, amines, amides, (azo) diazo compounds, (iso) nitriles, isonitrile acid esters, guanidines, ureas, hydrazines, hydrazones and oximes.
Further, the nitro compound includes: furazolidone, 2,4, 6-tris (trinitromethyl) -1,3, 5-triazine, 2, 4-dinitrophenol, 3- [ (4-nitrophenyl) carbamoylamino ] propionic acid, nilvadipine, nimesulide, 5-nitro-2-propoxyaniline, trinitrotoluene, m-nitroaniline, trimethylolnitromethane, hexanitroethane, p-nitrophenol, clonazepam, roxarsone, nitroguanidine, nitrosobenzene.
Further, the amine compound includes: dinitrophenol sodium, nitrosamine, carbodiimide, N-dimethyl-5-methoxytryptamine, 5-methoxydimethyltryptamine, dimethyltryptamine, dephosphorylated gymnocytocybine, bufotoxin, serotonin, 5-hydroxytryptophan, tranylcypromine, methylphenidate, salbutamol, thiamphenicol, octopamoate, folic acid, 5, 10-methylenetetrahydrofolic acid, N-chlorosuccinimide, N-bromosuccinimide, polyvinylpyrrolidone, caronic acid, solanine, o-phenylenediamine, trimethylamine oxide, galactosamine, glucosamine, N-acetylglucosamine, hygromycin B, streptomycin sulfate, sodium hyaluronate, N-formylmethionine, methionine, cystine, homocysteine, gamma-aminobutyric acid, N-acetylglutamic acid, Aspartame, ornithine, methionine, pyruvic acid, alpha-ketoglutaric acid, oxaloacetic acid, succinyl-coenzyme A, fumaric acid, phosphoenolpyruvic acid, ketogenic amino acid, arginosuccinic acid, N-phosphonoacetyl-L-aspartic acid, beta-methylamino-L-alanine, pyrrolysine, citrulline, levoglutaminic acid, betaine, selenocysteine, methylselenine, N-methylglycine, aminomethylene glutamic acid, theanine, citrulline, amanitic acid, glutamic acid-1-semialdehyde, asymmetric dimethylarginine, methyl red, methyl blue, methyl violet, flutamide, 4-aminobiphenyl, 4-aminosalicylic acid, 4' -diaminodiphenyl ether, diethylamino hydroxybenzoyl hexyl benzoate, Xylene blue, fast green FCF, sulfamethoxazole, crystal violet, chlorambucil, catecholamine, 2-aminophenol, 4-aminophenol, diphenylamine, dequalinium chloride, p-aminobenzoic acid, anthranilic acid, m-aminobenzoic acid, p-aminobenzoic acid, benzidine, o-phenylenediamine, m-phenylenediamine, p-phenylenediamine, 1, 4-diazabicyclo [2.2.2] octane, 4-dimethylaminopyridine, tris (hydroxymethyl) aminomethane, melamine, ethylenediaminetetraacetic acid, xylenol orange, calcium cyanamide, p-toluidine, thiamine, cytosine, glyphosate, glufosinate, formamidine, pyrazole, benzimidazole, methamidophos, saccharin, 4-chloroaniline, 4' -diaminodiphenylmethane, 3-dichlorobenzidine, dimethoxybenzidine.
Further, the amide-based organic compound includes: acephate, alfafomethylthiofentanyl, acetanilide, acetamide, zolpidem, chitin, colchicine, folic acid, 5, 10-methylenetetrahydrofolic acid, acephate, uracil, uridine diphosphate, 5-bromo-2-deoxyuridine, thymidine, thymine, alloxan, caprolactam, diltiazem, oxindole, isonicotinamide, sulfonamide, acetazolamide, cyclamate, polyphthalamide, polyisophthaloylimide, m-phenyleneisophthalamide, N-chlorosuccinimide, N-bromosuccinimide, phthalimide, buspirone hydrochloride, tetramethrin, acrylamide, ethanediamide, acetanilide, N ', N' -triethylenethiophosphoramide, aspartame, acetaminophen, salicylamide, nicotinamide, isonicotinamide, nicotinamide, trexofenamide, folic acid, 5, 10-methylenetetrahydrofolic acid, 5-methyltetrahydrofolic acid, uracil, uridine, N-bromosuccinimide, thioprochloraz, and mixtures thereof, Cyclophosphamide, thioacetamide, piperine, hippuric acid, pantothenic acid.
Further, the (azo) diazo organic compounds include: 1- ((p-nitrophenyl) azo) -2-naphthol, azobisisobutyronitrile, azobenzene, chloroazido mycin, 4-aminoazobenzene, azobisisobutyronitrile, diazo-benzene chloride, diazoaminobenzene, azobenzene, p-hydroxyazobenzene, p-dimethylaminoazobenzene, p-aminoazobenzene, azoformamide, sudan red, 2 '-dichlorohydrazobenzene, 4' -dihydroxyazobenzene, azobiscyclohexylcarbonitrile, azobisisoheptonitrile.
Further, the (iso) nitrile organic compounds include: isonitrile, 2, 3-dichloro-5, 6-dicyano-p-benzoquinone, dicyandiamide, cyanamide, sodium cyanoborohydride, hexachlorocyclotriphosphazene, 1-naphthonitrile, 3-indoxynitrile, pyrrole-2-carbonitrile, 5-nitrothiophene-2-carbonitrile, benzofuran-2-carbonitrile, 3-amino-5-chloropyrazine-2-carbonitrile, 3-indoxynitrile, 4-biphenylacetonitrile, cyanamide hydrochloride, methyleneaminoacetonitrile, 1,2,4, 5-benzenetetracarbonitrile, fenbuconazole, 2-hydroxybenzonitrile, terephthalonitrile, phthalonitrile, isophthalonitrile, 4-nitrophthalonitrile, 3-nitrophthalonitrile, p-trifluoromethylbenzonitrile, tetrachloroterephthalonitrile, tetrachlorophthalonitrile, sodium cyanoborohydride, hexachlorocyclotriphosphazene, 1-naphthonitrile, 3-nitrophthalonitrile, p-trifluoromethylbenzonitrile, tetrachlorophthalonitrile, sodium cyanoborohydride, and mixtures thereof, Tetrachloroisophthalonitrile, 3-nitrophthalonitrile, 4-bromoacetylbenzonitrile, 2-amino-5-methylbenzonitrile, 3,4,5, 6-tetrafluorophthalonitrile, 2,3,5, 6-tetrafluoroterephthalonitrile, 3, 5-diiodo-4-octanoyloxybenzonitrile, benzylallyldinitrile, o-chlorobenzonitrile, cis-bis (benzonitrile) dichloroplatinum, diaminomaleonitrile, fumarodinitrile, azobisisovaleronitrile, 2, 3-dichlorobenzonitrile, 2, 6-dichlorobenzonitrile.
Further, the guanidine organic compounds include: guanidine, guanidine nitrate, guanidine carbonate, moroxydine, guanidinoacetic acid, guanidine thiocyanate, nitrosoguanidine, dodecaguanidine, robenidine hydrochloride, biguanide, dicyandiamide, sulfaguanidine, guanidine phenylacetate, aminoguanidine, acetoguanidine, guanidine phosphate, guanidine chlorophenol, guanidine sulfate, methylguanamine, aminoguanidine sulfate, hydroxyguanidine sulfate, 1-methyl-3-nitroguanidine, aminoguanidine nitrate, robenidine hydrochloride, guanidineacetic acid, diphenylguanidine, phenylguanidine carbonate, dodine, butaneguanidine, aminoguanidine hydrochloride, vinylguanamine.
Further, the urea-based organic compound includes: urea, ethylenethiourea, dichlorophenyldimethylurea, urethaneurea, acetohexylurea, chlorpropamide, tolbutamide, tolazamide, carbutamide, glimepiride, hydantoin, phenylthiourea, forchlorfenuron, urea phosphate, semicarbazide, propylurea, benzylurea, urea sulfate, sulfonylureas, forchlorfenuron, tert-butylurea, vinylurea, acetylurea, oxaleurea, methylurea, glycoluril, cyclohexylurea, selenourea, phenylurea, urea phosphate, hydroxyurea sulfate, urea formaldehyde, cyanoacetourea, novaluron, cyanoacetylurea, imidazolidinyl urea, methylnitrosourea, cucurbituril.
Further, the hydrazine-based organic compound includes: 1, 2-diphenyl hydrazine, indazole, semicarbazide, phthalazine, hydralazine, luminol, hydrazine sulfate, phenylhydrazine, isoniazid, dimethylhydrazine, benzylhydrazine, benzoyl hydrazine, oxamyl hydrazide, 4-hydroxybutyric acid hydrazine, lauroyl hydrazide, nicotinic acid hydrazide, hydrazine formate, hydrazine bromide, hydrazine hydrochloride, hydrazine yellow, malonyl hydrazine, phenylhydrazide, succinyl hydrazine, formyl hydrazine, hydrazophthalazine, nifurohydrazide, 2-thiophenecarboxylic acid hydrazine, thiocarbamohydrazide, oxalyl dihydrazide, perchloric acid hydrazide, phenylacetyl hydrazide, maleic hydrazide, bishydrazide, salicyloyl hydrazide, cyanoacetic hydrazide, methyl carbazate, vanillyl hydrazine.
Further, the hydrazone-based organic compound includes: phenylhydrazone, metaflumizone, dithizone, salicylaldohydrazone, diphenylcarbazone, acetonylphenylhydrazone, benzisoylhydrazone, benzophenonehydrazone, hydramethylhydrazone, salicylaldohydrazone, benzophenonehydrazone, diflufenzopyr, acetophenone tosylhydrazones, bicyclohexanoneoxalyldihydrazone, 2-methyl-4-dibenzylaminobenzaldehyde-1, 1-diphenylhydrazone, propimidylhydrazone, pyrimidinehydrazone, cyclohexanone-2, 4-dinitrophenylhydrazone, pyridine-2-carboxaldehyde-2-quinolinylhydrazone.
Further, the oxime organic compound includes: acetaldoxime, camphor oxime, acetoxime, cyclohexanone oxime, benzamidoxime, erythromycin oxime, dimethylglyoxime, salicylamidoxime, benzoin oxime, diacetyl monoxime, nifuroxime, cinnamaldehyde oxime, oxadiazon, glyoxime, trifloxystrobin, acetophenone oxime, 9-fluorenone oxime, aminothiaximeacetic acid, n-heptanoaldoxime, fluorooxime ammonia, fatty ether bacteria amine, pyruvaldehyde-1-oxime, pyribenzoxim, diacetyl monoxime, cyclohexanone oxime, ethyl aminothiazoloxime, benzohydroxamic acid, p-benzoquinone dioxime, acetoxyhydroxamic acid, methyltripropyrone oximidosilane.
Further, the fire-extinguishing composition also includes a secondary fire-extinguishing material.
Further, the secondary fire extinguishing material includes: bromine-based flame retardants, chlorine-based flame retardants, organic phosphorus-based flame retardants, phosphorus-halogen-based flame retardants, nitrogen-based flame retardants, phosphorus-nitrogen-based flame retardants, inorganic flame retardants, or any combination thereof.
Further, the fire extinguishing composition also comprises an additive, and the content of the additive is 0.1-10%.
Further, the additive is one or more of stearate, graphite, or water glass, phenolic resin, shellac, starch, dextrin, rubber, epoxy resin, acetal gum and hydroxypropyl methyl cellulose. In addition to the above-listed materials, other organic or inorganic materials capable of performing the above-described functions may be substituted for the additives in the fire-fighting composition of the present invention.
Further, the fire extinguishing composition comprises the following components in percentage by mass:
35 to 96 percent of nitrogen-containing organic compound
3 to 60 percent of auxiliary fire extinguishing material
1 to 10 percent of additive
Further, the fire extinguishing composition comprises the following components in percentage by mass:
50 to 90 percent of nitrogen-containing organic compound
5 to 45 percent of auxiliary fire extinguishing material
3 to 8 percent of additive
The mechanism of flame suppression of the fire extinguishing composition of the present invention is as follows:
when the fire extinguishing agent is used, the pyrotechnical agent is used as a heat source and a power source, the pyrotechnical agent is ignited to burn and release heat, so that the nitrogen-containing organic compound reacts at high temperature to generate effective fire extinguishing particles such as alkyl (or aryl) free radicals, acyl free radicals, carbonyl free radicals, N, hydroxyl free radicals and the like, and the effective fire extinguishing particles react with one or more of O, OH and H free radicals which are necessary for the chain type combustion reaction, so that the chain type combustion reaction is cut off, and meanwhile, the fire extinguishing agent and the pyrotechnical agent generate a synergistic effect, the fire extinguishing efficiency of the fire extinguishing agent is further improved, and the effective fire extinguishing time is greatly shortened.
Compared with the existing hot aerosol fire extinguishing agent, the fire extinguishing composition has the following advantages:
1. the nitrogen-containing compound in the fire extinguishing composition reacts at high temperature to generate a large amount of nano-scale effective fire extinguishing particles and various free radicals, and the fire extinguishing effect is achieved together with the reaction product of the hot aerosol generating agent by cutting off a combustion reaction chain, so that the fire extinguishing efficiency of the fire extinguishing agent is further improved, and the effective fire extinguishing time is shortened.
2. The fire extinguishing composition disclosed by the invention utilizes heat generated by combustion of the aerosol generating agent, absorbs heat quickly to react, absorbs heat released by combustion of the pyrotechnic agent, reduces the temperature of a nozzle of a fire extinguishing device, is better in safety, cannot cause harm to fire extinguishers, and also avoids secondary fire.
3. The aerosol fire extinguishing device adopting the fire extinguishing composition does not need to add a cooling system with a complex structure and a large volume, so that the aerosol fire extinguishing device has the characteristics of light structure, simple process flow, good economy and the like.
Detailed Description
The following are specific examples of the present disclosure, which are used to illustrate technical solutions to be solved in the present disclosure and help those skilled in the art understand the present disclosure, but the present disclosure is not limited to these examples.
The fire extinguishing composition is added with additive, water is used as solvent, after sieving and granulation, the release agent is added, after mixing, sieving is carried out, and the mixture can be formed into spheres, sheets, strips, blocks and honeycombs by adopting the processes of pelleting, mould pressing, extrusion and the like.
The fire extinguishing composition has the advantages that the effectiveness of the fire extinguishing composition is obviously superior to that of the existing fire extinguishing agent, and the fire extinguishing time is greatly shortened.
The composition is tested by adopting the following mixture ratio, and the specific test result is as follows:
examples
In examples 1 to 100, a certain mass percentage of a nitrogen-containing organic compound, a certain mass percentage of an auxiliary fire extinguishing material, a certain mass percentage of an additive, water as a solvent, are granulated by using a 20-mesh sieve, a certain mass percentage of magnesium stearate is added as a release agent, the mixture is uniformly mixed and then is sieved by a 15-mesh sieve, and the mixture is flaked, 50g of the mixture is added into a fire extinguishing device filled with a 50g K type aerosol generating agent, and the fire extinguishing effect is shown in tables 1 to 20.
Comparative example 1:
the fire extinguishing device sample using the 50gK salt type aerosol fire extinguishing agent is used for carrying out fire extinguishing experiments according to a fire extinguishing experiment model, and the fire extinguishing effect is shown in the table.
Comparative example 2:
the fire extinguishing device sample using the 50g S type aerosol fire extinguishing agent is used for carrying out fire extinguishing experiments according to the fire extinguishing experiment model, and the fire extinguishing effect is shown in the table.
Fire extinguishing experimental model: fire extinguishing experiment for oil pan
The formula of the fire extinguishing composition is as follows GA86-2009<Simple fire extinguisher>6.3.2.1 in Standard, Experimental method implementation area 25m2And the 93# gasoline 8B fire extinguishing experiment, carrying out three experiments on each group of formula, and recording the fire extinguishing effect and the fire extinguishing time. The results of the experiments are shown in the following table.
TABLE 1 comparison of the ingredients of the various components and the results of the fire extinguishing experiments
TABLE 2 comparison of the ingredients of the various components and results of the fire extinguishing experiments
TABLE 3 comparison of the ingredients of the various components and the results of the fire extinguishing experiments
Table 4 comparison of the ingredients of the various components and comparison of the results of the fire extinguishing experiments
TABLE 5 comparison of the ingredients of the various components and results of the fire extinguishing experiments
TABLE 6 comparison of the ingredients of the various components and results of the fire extinguishing experiments
TABLE 7 comparison of the ingredients of the various components and results of the fire extinguishing experiments
TABLE 8 comparison of the ingredients of the various components and results of the fire extinguishing experiments
TABLE 9 comparison of the ingredients of the various components and results of the fire extinguishing experiments
TABLE 10 comparison of the ingredients of the various components and results of the fire extinguishing experiments
TABLE 11 comparison of the ingredients of the various components and results of the fire extinguishing experiments
TABLE 12 comparison of the ingredients of the various components and results of the fire extinguishing experiments
TABLE 13 comparison of the ingredients of the various components and results of the fire extinguishing experiments
TABLE 14 comparison of the ingredients of the various components and results of the fire extinguishing experiments
TABLE 15 comparison of the ingredients of the various components and results of the fire extinguishing experiments
TABLE 16 comparison of the ingredients of the various components and results of the fire extinguishing experiments
TABLE 17 comparison of the ingredients of the various components and results of the fire extinguishing experiments
TABLE 18 comparison of the ingredients of the various components and results of the fire extinguishing experiments
TABLE 19 comparison of the ingredients of the various components and results of the fire extinguishing experiments
TABLE 20 comparison of the ingredients of the various components and results of the fire extinguishing experiments
The above examples are merely illustrative of the preferred embodiments of the present invention and do not limit the present invention. Changes and modifications of the above-described embodiments within the spirit and scope of the present invention should fall within the scope of the claims of the present application.
Claims (8)
1. A fire extinguishing composition containing a nitrogen-containing organic compound, characterized in that: the fire extinguishing composition comprises the following components in percentage by mass:
93% of robenidine hydrochloride, 5% of magnesium stearate and 2% of carboxymethyl propyl cellulose, said composition releasing a large amount of effective fire extinguishing particles by combustion of the pyrotechnic agent.
2. A fire extinguishing composition containing a nitrogen-containing organic compound, characterized in that: the fire extinguishing composition comprises the following components in percentage by mass: 94% salicyloyl hydrazine, 4% magnesium stearate, 2% carboxymethyl propyl cellulose, said composition utilizing the combustion of the pyrotechnic agent to release a large number of effective fire extinguishing particles.
3. A fire extinguishing composition containing a nitrogen-containing organic compound, characterized in that: the fire extinguishing composition comprises the following components in percentage by mass: 94% maleic hydrazide, 4% magnesium stearate, 2% carboxymethyl propyl cellulose, said composition releasing a large amount of effective fire extinguishing particles by combustion of the pyrotechnic agent.
4. A fire extinguishing composition containing a nitrogen-containing organic compound, characterized in that: the fire extinguishing composition comprises the following components in percentage by mass: 33% of trinitrotoluene, 40% of furazolidone, 12% of sodium bicarbonate, 5% of aluminum hydroxide, 5% of magnesium stearate and 5% of carboxymethyl propyl cellulose, and the composition releases a large amount of effective fire extinguishing particles by utilizing the combustion of the pyrotechnic composition.
5. A fire extinguishing composition containing a nitrogen-containing organic compound, characterized in that: the fire extinguishing composition comprises the following components in percentage by mass: 80% of polyphthalamide, 11.9% of ammonium chloride, 8% of sodium bicarbonate, 0.05% of magnesium stearate and 0.05% of carboxymethyl propyl cellulose, wherein the composition releases a large amount of effective fire extinguishing particles by utilizing the combustion of a pyrotechnic composition.
6. A fire extinguishing composition containing a nitrogen-containing organic compound, characterized in that: the fire extinguishing composition comprises the following components in percentage by mass: 50% of guanidine nitrate, 30% of ammonium polyphosphate, 16% of aluminum hydroxide, 2% of magnesium stearate and 2% of carboxymethyl propyl cellulose, wherein the composition releases a large amount of effective fire extinguishing particles by utilizing the combustion of the pyrotechnic composition.
7. A fire extinguishing composition containing a nitrogen-containing organic compound, characterized in that: the fire extinguishing composition comprises the following components in percentage by mass: phenylthiourea 50%, ammonium chloride 25%, aluminum hydroxide 21%, magnesium stearate 2%, carboxymethyl propyl cellulose 2%, said composition utilizing the combustion of the pyrotechnic agent to release a large number of effective fire extinguishing particles.
8. A fire extinguishing composition containing a nitrogen-containing organic compound, characterized in that: the fire extinguishing composition comprises the following components in percentage by mass: 20% of isoniazid, 50% of oxalyl dihydrazide, 7% of ammonium chloride, 13% of aluminum hydroxide, 5% of magnesium stearate and 5% of carboxymethyl propyl cellulose, wherein the composition releases a large amount of effective fire extinguishing particles by utilizing the combustion of the pyrotechnic composition.
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| CN103170082A (en) * | 2011-12-20 | 2013-06-26 | 陕西坚瑞消防股份有限公司 | Fire-extinguishing composition containing amino acid compounds |
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| CN102949802B (en) * | 2011-08-16 | 2016-04-06 | 西安坚瑞安全应急设备有限责任公司 | A kind of fire-extinguishing composite containing organic acid compound |
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