CN103749460B - Herbicidal composition for paddy fields - Google Patents

Herbicidal composition for paddy fields Download PDF

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Publication number
CN103749460B
CN103749460B CN201310722642.8A CN201310722642A CN103749460B CN 103749460 B CN103749460 B CN 103749460B CN 201310722642 A CN201310722642 A CN 201310722642A CN 103749460 B CN103749460 B CN 103749460B
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China
Prior art keywords
safener
herbicide
paddy fields
herbicidal composition
careless ether
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Expired - Fee Related
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CN201310722642.8A
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Chinese (zh)
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CN103749460A (en
Inventor
许网保
虞国新
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JIANGSU TIANRONG GROUP CO Ltd
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JIANGSU TIANRONG GROUP CO Ltd
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Abstract

The invention discloses a kind of Herbicidal composition for paddy fields, it is primarily of the two careless ether of active ingredient and herbicide-safener composition, and wherein the part by weight of the two careless ether of active ingredient and herbicide-safener is 10: 0.1 ~ 100.The present invention can be used for farmland and prevents and kill off multiple weeds, effectively raises two careless ether herbicide to the safety of crops.

Description

Herbicidal composition for paddy fields
Technical field
The present invention relates to the Herbicidal combinations that a kind of safety is good, owing to adding herbicide-safener, improve the safety to crops, decrease the generation of phytotoxicity accident, protect the interests of peasant, thus decrease the generation that social groups' property complains to the higher authorities about an injustice and request fair settlement event.The invention belongs to weed killer herbicide and manufacture field.
Background technology
Two careless ether, has another name called two KIH 6127, English general by name: bispyribac-sodium.It is a kind of herbicides for use in paddy, has special efficacy, can be used for the barnyard grass of preventing and kill off above the average age for marriage barnyard grass and other weed killer herbicide being produced to resistance to barnyard grass and Paspalum distichum (red mix root grass, Entada phaseoloides).
The former medicine low toxicity of two careless ether.Rat acute LD50 of passing through mouth >5000 mg/kg, acute through skin LD50>2000 mg/kg.Female 5840 mg/kg of preparation rat acute LD50 of passing through mouth, male 4300 mg/kg, acute through skin LD50>2000 mg/kg.Non-stimulated to skin, there is minimal irritation to eyes.
Two careless ether belongs to benzoic acid herbicide, it is highly active acetolactate synthestase (ALS) inhibitor, to rice varieties, there is excellent selectivity, be particularly useful for the rice direct seeding field that weed killer herbicide requirement is higher, grass family, sedge family and broad leaved weed can be prevented and kill off, have special efficacy to the barnyard grass removed difficult in paddy field.Can be absorbed by the cauline leaf of weeds very soon after this product dispenser, and conduct to whole plant, suppress the growth of plant meristematic tissue, thus kill weeds.Efficiently, wide spectrum, consumption are extremely low.
Two careless ether effectively can prevent and kill off barnyard grass and other grassy weeds, the double barnyard grass controlled most of broad leaved weed, some sedge weeds and other weed killer herbicide is produced to resistance.As: barnyard grass, Paspalum distichum, rice Leersia Sw, lady's-grass, agrostis stolonifera, amur foxtail, northeast Tian Mao, wolf tail grass, special-shaped nutgrass flatsedge, sunshine wooden dipper stroke common most weeds such as grass, cyperus iria, firefly Lin, Japanese grass, flat stalk grass, Monochoria vaginalis, Monochoria korsakowii, wild arrowhead, rhizoma alismatis, pondweed, pipewort, needle spikesedge herb, mexicana, Procumbent Falsepimpernel, triquetrousc murdannia herb, alternanthera philoxeroides, paddy field such as flower Lin etc.
But, two careless ether has a fatal weakness, it is poor to crop safety, comparatively responsive to Some Rice Varieties, be only recommended on rice variety at present and use, although range of application is strictly placed restrictions on, if but using method slightly mistake, also can produce phytotoxicity accident, cause the loss being difficult to retrieve to peasant, cause also to the reputation of manufacturer and have a strong impact on.
Summary of the invention
The object of the invention is, in order to overcome above defect, to provide the Herbicidal combinations that a kind of safety is good.We are found by research, add herbicide-safener, can improve the safety to crops, thus constitute the good Herbicidal combinations of safety in two careless ether formulation, decrease phytotoxicity accident and occur.
Object of the present invention can be reached by following measures:
A kind of Herbicidal composition for paddy fields, it is primarily of the two careless ether of active ingredient and herbicide-safener composition, and wherein the part by weight of the two careless ether of active ingredient and herbicide-safener is 10: 0.1 ~ 100.
Herbicide-safener in the present invention is mefenpyrdiethyl or fenchlorazole, and it effectively can alleviate the injury of weed killer herbicide to crops.The part by weight of the two careless ether of the active ingredient in the present invention and herbicide-safener is preferably 10: 1 ~ 10, and more preferably 10: 1 ~ 5.
Herbicidal composition for paddy fields of the present invention further can by the two careless ether of active ingredient and herbicide-safener, and insecticides adjuvant, makes various formulation, includes but not limited to wetting powder, water dispersible granules, aqueous emulsion or suspending agent etc.
Insecticides adjuvant in the present invention includes but not limited to one or more in dispersant, stabilizing agent, disintegrant, wetting agent, safener, binding agent, antifreeze, emulsifier, defoamer, thickener, filler.The mass content of insecticides adjuvant is 1% ~ 99%.
Filler of the present invention is including but not limited to white carbon, kaolin, diatomite, bentonite, precipitated calcium carbonate, gypsum, attapulgite, soluble starch, organic solvent, cosolvent, vegetable oil, mineral oil, water, nitrogen fertilizer, one or more of glucose, Anhydrous potassium carbonate, natrium carbonicum calcinatum, Carbon Dioxide hydrogen potassium, anhydrous sodium sulfate etc.
By adding herbicide-safener mefenpyrdiethyl or fenchlorazole to the two careless ether of the active component in foregoing invention, wetting powder is prepared into through formulations of pesticide Conventional processing methods, water dispersible granules, aqueous emulsion, suspending agent etc., through cold, heat stabilization test and storage at normal temperature stability test, filter out the formula that physicochemical property is stable, through biological activity determination, obtain preventive effect high, toxicity is low, environmental influence is little, the Herbicidal combinations that safety is good, result of the test shows, by two careless ether and herbicide-safener mefenpyrdiethyl or fenchlorazole mixture, in the biologically active of two careless ether, there will not be antagonism, poisoning situation is observed through biological test, result shows the safety of this Herbicidal combinations than the two careless ether not adding herbicide-safener and greatly improves.
The present invention is compared with background technology; this Herbicidal combinations improves greatly than the two careless ether safety not adding herbicide-safener; decrease the generation of phytotoxicity accident; protect interests and the crops of peasant; thus decrease the generation that social groups' property complains to the higher authorities about an injustice and request fair settlement event, guarantee the good harvest of agricultural production high yield.
Embodiment
Following examples further describe content of the present invention, but should not be construed as limitation of the scope of the invention.Number in all embodiments is parts by weight.
Embodiment 1. wetting powder:
The former medicine of two careless ethers: 20 parts;
Safener mefenpyrdiethyl: 5 parts;
Dispersant; 6 parts;
Stabilizing agent: 4 parts;
Filler-kaolin: complement to 100 parts.
By above herbicide active active ingredients, safener and insecticides adjuvant, carry out formulation according to the Conventional processing methods of pesticide wettable, obtain the two careless ether wetting powder of 100kg20%.
Embodiment 2, water dispersible granules:
The former medicine of two careless ethers: 50 parts;
Safener mefenpyrdiethyl: 10 parts;
Dispersant: 4 parts;
Disintegrant: 3 parts;
Stabilizing agent: 3 parts
Binding agent: 1 part
Soluble starch: complement to 100 parts.
By above herbicide active active ingredients, safener and various insecticides adjuvant, carry out formulation according to the Conventional processing methods of pesticide water dispersible granules, obtain the two careless ether water dispersible granules of 100kg50%.
Embodiment 3, aqueous emulsion:
The former medicine of two careless ethers: 10 parts;
Safener fenchlorazole: 2 parts;
Cosolvent: 10 parts
Emulsifier: 5 parts
Stabilizing agent: 3 parts
Dispersant: 5 parts
Antifreeze: 2 parts
Thickener: 5 parts
Defoamer: 3 parts
Water: complement to 100 parts
By above herbicide active active ingredients, safener and various insecticides adjuvant, carry out formulation according to the Conventional processing methods of pesticide emulsion in water, obtain the two careless ether aqueous emulsion of 100kg10%.
Embodiment 4, suspending agent:
The former medicine of two careless ethers: 25 parts;
Safener fenchlorazole: 3 parts;
Cosolvent: 5 parts
Emulsifier: 12 parts
Dispersant: 5 parts
Thickener: 5 parts
Anti-agglomerating agent: 3 parts
Antifreezing agent: 4 parts
Water: complement to 100 parts.
By above herbicide active active ingredients, safener and various insecticides adjuvant, carry out formulation according to the Conventional processing methods of agricultural chemicals suspension agent, obtain the two careless ether suspending agent of 100kg25%.
Herbicidal composition for paddy fields of the present invention, the formulations of pesticide that can be processed into are including but not limited to above four kinds of formulations.
Effect experiment example:
Utilize Herbicidal combinations prepared by embodiment 1-4, carried out management of weeds at paddy field and tested and the degree of impairment observing rice shoot, and carried out comparative trial with the two careless ether wetting powder not adding herbicide-safener, investigation result is as follows:
(note: adopt spray-on process dispenser, 30 days investigation herbicidal effects after medicine, drug effect is with 0-9 classification, and 9 expressions are prevented and kill off completely, and 0 expression does not damage completely.While investigation herbicidal effect, investigate the degree of impairment to rice shoot, also with 0-9 classification, 9 represent that growth suppresses completely, and 0 represents that growth is not affected)
Above result shows, Herbicidal composition for paddy fields of the present invention, increases to the safety of paddy rice.

Claims (6)

1. a Herbicidal composition for paddy fields, it is characterized in that it is primarily of the two careless ether of active ingredient and herbicide-safener mefenpyrdiethyl or fenchlorazole composition, wherein the part by weight of the two careless ether of active ingredient and herbicide-safener is 10: 1 ~ 10.
2. Herbicidal composition for paddy fields according to claim 1, is characterized in that the part by weight of the two careless ether of active ingredient and herbicide-safener is 10: 1 ~ 5.
3. Herbicidal composition for paddy fields according to claim 1, is characterized in that said composition is by the two careless ether of active ingredient and herbicide-safener, and insecticides adjuvant, makes various formulation.
4. Herbicidal composition for paddy fields according to claim 3, is characterized in that described formulation comprises wetting powder, water dispersible granules, aqueous emulsion or suspending agent.
5. Herbicidal composition for paddy fields according to claim 3, is characterized in that one or more that described insecticides adjuvant is selected from dispersant, stabilizing agent, disintegrant, wetting agent, safener, binding agent, antifreeze, emulsifier, defoamer, thickener, filler.
6. Herbicidal composition for paddy fields according to claim 3, is characterized in that the mass content of described insecticides adjuvant is 1% ~ 99%.
CN201310722642.8A 2013-12-24 2013-12-24 Herbicidal composition for paddy fields Expired - Fee Related CN103749460B (en)

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CN103749460B true CN103749460B (en) 2015-11-11

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1309533A (en) * 1998-07-16 2001-08-22 阿温提斯作物科学有限公司 Herbicide composition
US20020004457A1 (en) * 1998-11-10 2002-01-10 Nevill David John Herbicidal composition
CN101115389A (en) * 2005-02-04 2008-01-30 辛根塔参与股份公司 Process for the control of undesired plant growth in rice

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1309533A (en) * 1998-07-16 2001-08-22 阿温提斯作物科学有限公司 Herbicide composition
US20020004457A1 (en) * 1998-11-10 2002-01-10 Nevill David John Herbicidal composition
CN101115389A (en) * 2005-02-04 2008-01-30 辛根塔参与股份公司 Process for the control of undesired plant growth in rice

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
农美利等除草剂对水稻药害的研究;赵学平 等;《浙江农业学报》;20001125;第12卷(第6期);参见第368-373页,第372-373页2.2.7部分 *

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