CN103741517B - Stone wallpaper gold printing printing paste and preparation method - Google Patents
Stone wallpaper gold printing printing paste and preparation method Download PDFInfo
- Publication number
- CN103741517B CN103741517B CN201310743257.1A CN201310743257A CN103741517B CN 103741517 B CN103741517 B CN 103741517B CN 201310743257 A CN201310743257 A CN 201310743257A CN 103741517 B CN103741517 B CN 103741517B
- Authority
- CN
- China
- Prior art keywords
- printing
- acrylic acid
- association type
- rheological agent
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Paints Or Removers (AREA)
- Paper (AREA)
Abstract
Stone wallpaper gold printing printing paste of the present invention and preparation method, by dimethacrylate 1.4 butanediol ester 2.0-2.2, itaconic acid 1.0-1.1, ethyl acrylate 130-140, butyl acrylate 31-32, hydroxyethyl methylacrylate 6.4-6.6, methyl methacrylate 27-28, acetoacetoxyethyl methacrylate 4.0-4.2, styrene 32-33, fatty alcohol-polyoxyethylene ether 23E9 is 2-2.3, deionized water 230-250, through Over emulsfication, after initiated polymerization, the mixed liquor 20-25 of composite sorbierite and phenylpropyl alcohol triazole, association type levelling rheological agent 20-22, acrylic acid dispersant 10-15, mixing is obtained, its transparency is good, and glossiness is high, and fastness is good, resistance to air oxidation.
Description
Technical field
What the present invention relates to is a kind of stone wallpaper gold printing printing paste, namely for the printing paste of the color patterned pattern use of stone wallpaper bronze printing.
Background technology
Stone wallpaper take calcium carbonate as main raw material, and macromolecular material and multiple inorganic matter are that auxiliary material is made.
The printing paste that prior art does not have stone wallpaper special, all replaces printing paste to use with adhesive, as the adhesives I T with BASF, adds thickener, water, print paste mixing, does stone wallpaper printing paste and use.The pattern glossiness printed, elasticity, feel do not comply with one's wishes, and concave-convex sense is not strong.Particularly during gold printing, above-mentioned shortcoming is more obvious, and resistance to atmospheric oxidising bad, easily loses the magnificent gloss of bronze.
Stone wallpaper gold printing printing paste, is not shown in have special product and technology openly at present.
Summary of the invention
The object of this invention is to provide a kind of stone wallpaper gold printing printing paste and preparation method,
This printing paste adds bronze and carries out stamp, has bronze good dispersion, and gold printing transparency, glossiness, fastness are good, and concave-convex sense is strong, and feel is soft, and the magnificent polish retention of the bronze of resistance to air oxidation is good.And product processes is simple.
The present invention
stone wallpaper gold printing printing paste;
Raw material weight compares:
Dimethacrylate 1.4 butanediol ester 2.0-2.2, itaconic acid 1.0-1.1, ethyl acrylate 130-140, butyl acrylate 31-32, hydroxyethyl methylacrylate 6.4-6.6, methyl methacrylate 27-28, acetoacetoxyethyl methacrylate 4.0-4.2, styrene 32-33, fatty alcohol-polyoxyethylene ether 23E9 are 2-2.3, deionized water 230-250, after Over emulsfication, initiated polymerization, the mixed liquor 20-25 of composite sorbierite and phenylpropyl alcohol triazole, association type levelling rheological agent 20-22, acrylic acid dispersant 10-15, mixing is obtained;
Product chemical index is as follows:
Outward appearance: oyster white thick liquid
Ionic: cloudy
PH value: 7 ± 0.5
Solid content: >=50%.
Association type levelling rheological agent: be DS modest Shanghai Chemical Co., Ltd. product association type levelling rheological agent WT-203.
Acrylic acid dispersant: be Henkel chemical company product acrylic acid dispersant 5040.
Stone wallpaper gold printing printing paste preparation method of the present invention:
Raw material is by weight ratio:
(1) emulsification mix monomer: add dimethacrylate 1.4 butanediol ester 2.0-2.2 in stainless steel still, itaconic acid 1.0-1.1, ethyl acrylate 130-140, butyl acrylate 31-32, hydroxyethyl methylacrylate 6.4-6.6, methyl methacrylate 27-28, acetoacetoxyethyl methacrylate 4.0-4.2, styrene 32-33, fatty alcohol-polyoxyethylene ether 23E9 be 2-2.3, deionized water 210-230, emulsion is made in stirring, stand-by;
(2) initiated polymerization: get above-mentioned emulsion gross weight 30% adds in reactor, be warming up to 80-82 DEG C, add the mixed liquor of initiator ammonium persulfate 1.27 and deionized water 10, cause, at 80-82 DEG C of temperature, then drip remaining emulsion, drip ammonium persulfate 0.63-0.83 and deionized water 10 mixed liquor simultaneously, within 1-2 hour, dropwise, at 80-82 DEG C of insulation 2-3 hour, being then cooled to 30-40 DEG C, be 20% ammoniacal liquor adjust pH is 7 ± 0.5 with mass percent concentration;
(3) composite: sorbierite and phenylpropyl alcohol triazole to be added in above-mentioned polymer by 1:1 mixed dissolution liquid 20-25 and stirs, add acrylic acid dispersant 10-15 to stir, then add association type levelling rheological agent 20-22, stirring thickening is even, filter discharging, obtain stone wallpaper gold printing printing paste.
Association type levelling rheological agent: be DS modest Shanghai Chemical Co., Ltd. product association type levelling rheological agent WT-203.
Acrylic acid dispersant: be Henkel chemical company product acrylic acid dispersant 5040.
Product using method of the present invention:
Get the said goods add bronze 15% stir to obtain gold printing slurry.
Stamp bronze is Cu-Zn alloy powder, color and luster is divided into blue or green bronze, red bronze, gold powder etc.Cu-Zn alloy powder fineness can carry out choice for use as required.
The present invention selects methacrylic acid 1.4 butanediol ester, itaconic acid, ethyl acrylate, butyl acrylate, hydroxyethyl methylacrylate, methyl methacrylate, acetoacetoxyethyl methacrylate, styrene monomer copolymerization.
Wherein methyl methacrylate monomer vitrification point is high, and clarity in polymers can be made strong, and gloss is high.Methacrylic acid 1.4 butanediol ester, hydroxyethyl methylacrylate with the use of, polymerizate can be made crosslinked between linear macromolecule, make it to form network structure, polymerizate can be made to have very strong crosslinking ability.Acetoacetoxyethyl methacrylate, is more suitable for the synthesis of large arch dam acrylic emulsions, polymer film formation at low temp can be made good, and have outstanding elasticity and weatherability, makes polymer film forming continuous, soft.
Adding acrylic acid dispersant 5040 in composite can make polymer adding in bronze process, more easily disperses, and what powdery bronze was disperseed is more even, thus makes the pattern of printing more plentiful beautiful.Antioxidant phenylpropyl alcohol triazole, in gold printing, antioxidant effect is best, and it is the special corrosion inhibitor of copper, insoluble mixture can be produced with copper, can prevent bronze oxidation stain in atmosphere, therefore the wallpaper gold printing of gained is starched, transparency is good, glossiness is high, fastness is good, and feel is soft, adds bronze and easily disperses, resistance to air oxidation, the gloss that Long contact time air bronze is magnificent is unaffected.
Detailed description of the invention
Embodiment 1
Raw material weight compares:
(1) emulsification mix monomer: add dimethacrylate 1.4 butanediol ester 2.0 parts in stainless steel still, itaconic acid 1.0 parts, ethyl acrylate 130 parts, butyl acrylate 31 parts, hydroxyethyl methylacrylate 6.4 parts, methyl methacrylate 27 parts, acetoacetoxyethyl methacrylate 4.0 parts, styrene 32 parts, fatty alcohol-polyoxyethylene ether 23E9 be 2 parts, deionized water 210 parts, emulsion is made in stirring, stand-by;
(2) initiated polymerization: get above-mentioned emulsion gross weight 30% adds in reactor, be warming up to 80-82 DEG C, add the mixed liquor of initiator ammonium persulfate 1.27 parts and deionized water 10 parts, cause, at 80-82 DEG C of temperature, then drip remaining emulsion, drip ammonium persulfate 0.63 part and deionized water 10 portions of mixed liquors simultaneously, within 1 hour, dropwise, at 80-82 DEG C of insulation 2-3 hour, being then cooled to 30-40 DEG C, be 20% ammoniacal liquor adjust pH is 7 ± 0.5 with mass percent concentration;
(3) composite: sorbierite 10 parts and phenylpropyl alcohol triazole 10 parts of mixed dissolution liquid to be added in polymer and stirs, add acrylic acid dispersant 10 parts stirring, then add association type levelling rheological agent 20 parts, stir, filter discharging, obtain stone wallpaper gold printing printing paste.
Embodiment 2
(1) emulsification mix monomer: add dimethacrylate 1.4 butanediol ester 2.1 parts in stainless steel still, itaconic acid 1.05 parts, ethyl acrylate 135 parts, butyl acrylate 31.5 parts, hydroxyethyl methylacrylate 6.5 parts, methyl methacrylate 27.5 parts, acetoacetoxyethyl methacrylate 4.1 parts, styrene 32.5 parts, fatty alcohol-polyoxyethylene ether 23E9 be 2.2 parts, deionized water 220 parts, emulsion is made in stirring, stand-by;
(2) initiated polymerization: get above-mentioned emulsion gross weight 30% adds in reactor, be warming up to 80-82 DEG C, add the mixed liquor of initiator ammonium persulfate 1.27 parts and deionized water 10 parts, cause, then at 80-82 DEG C of temperature, drip remaining emulsion, drip ammonium persulfate 0.73 part and deionized water 10 portions of mixed liquors simultaneously, within 1.5 hours, dropwise, at 80-82 DEG C of insulation 2-3 hour, then being cooled to 30-40 DEG C, be 20% ammoniacal liquor adjust pH is 7 ± 0.5 with mass percent concentration;
(3) composite: sorbierite 12 parts and phenylpropyl alcohol triazole 12 parts of mixed dissolution liquid to be added in polymer and stirs, add acrylic acid dispersant 12.5 parts stirring, then add association type levelling rheological agent 21 parts, stirring thickening is even, filter discharging, obtain stone wallpaper gold printing printing paste.
Embodiment 3
(1) emulsification mix monomer: add dimethacrylate 1.4 butanediol ester 2.2 parts in stainless steel still, itaconic acid 1.1 parts, ethyl acrylate 140 parts, butyl acrylate 32 parts, hydroxyethyl methylacrylate 6.6 parts, methyl methacrylate 28 parts, acetoacetoxyethyl methacrylate 4.2 parts, styrene 33 parts, fatty alcohol-polyoxyethylene ether 23E9 be 2.3 parts, deionized water 230 parts, emulsion is made in stirring, stand-by;
(2) initiated polymerization: get above-mentioned emulsion gross weight 30% adds in reactor, be warming up to 80-82 DEG C, add the mixed liquor of initiator ammonium persulfate 1.27 parts and deionized water 10 parts, cause, at 80-82 DEG C of temperature, then drip remaining emulsion, drip ammonium persulfate 0.83 part and deionized water 10 portions of mixed liquors simultaneously, within 2 hours, dropwise, at 80-82 DEG C of insulation 2-3 hour, being then cooled to 30-40 DEG C, be 20% ammoniacal liquor adjust pH is 7 ± 0.5 with mass percent concentration;
(3) composite: sorbierite 12.5 parts and phenylpropyl alcohol triazole 12.5 parts of mixed dissolution liquid to be added in polymer and stirs, add acrylic acid dispersant 15 parts stirring, then add association type levelling rheological agent 22 grams, stirring thickening is even, filter discharging, obtain stone wallpaper gold printing printing paste.
Association type levelling rheological agent described in above-described embodiment: be DS modest Shanghai Chemical Co., Ltd. product association type levelling rheological agent WT-203.
Acrylic acid dispersant described in above-described embodiment: be Henkel chemical company product acrylic acid dispersant 5040.
Experimental example:
Get embodiment of the present invention 1-3 product, the bronze adding 15% weight respectively stirs, and obtains stone wallpaper gold printing slurry.
Adopt rotary screen printing machines stamp in stone paper wallpaper, dry 3 minutes for 70-80 DEG C.
Testing result is as follows afterwards for experimental example product and printing:
Project | Experimental example 1 | Experimental example 2 | Experimental example 3 |
Fine and smooth degree | Fine and smooth | Fine and smooth | Fine and smooth |
Transparency | Good | Good | Good |
Glossiness | Magnificent gloss | Magnificent gloss | Magnificent gloss |
Oxidative resistance | Nondiscolouring | Nondiscolouring | Nondiscolouring |
Feel elasticity | Soft good springiness | Soft good springiness | Soft good springiness |
Dispersed | Easy dispersion | Easy dispersion | Easy dispersion |
Dry fastness | 5 grades | 5 grades | 5 grades |
Fastness to wet rubbing | 5 grades | 5 grades | 5 grades |
Dry fastness to wet rubbing test is pressed GB/3920 and is performed.
Sophistication, glossiness ocular estimate.
Oxidative resistance adopts the test of solarization climate test instrument: be divided into nondiscolouring, light discolouration, serious discoloration.
Feel, elasticity hand touching test.
Dispersed employing range estimation adds bronze and stirs rear uniformity coefficient test.
Known by above result, this product is applied on environment-friendly type stone wallpaper has that transparency is good, glossiness is high, fastness is good, feel is soft, add bronze easily to disperse, resistance to air oxidation, the gloss that Long contact time air bronze is magnificent is unaffected, production technology is simple, and meets the feature of environmental requirement.
Claims (4)
1. stone wallpaper gold printing printing paste, is characterized in that;
Raw material weight compares:
Dimethacrylate-1,4-butanediol ester 2.0-2.2, itaconic acid 1.0-1.1, ethyl acrylate 130-140, butyl acrylate 31-32, hydroxyethyl methylacrylate 6.4-6.6, methyl methacrylate 27-28, acetoacetoxyethyl methacrylate 4.0-4.2, styrene 32-33, fatty alcohol-polyoxyethylene ether 23E9 are 2-2.3, deionized water 230-250, after Over emulsfication, initiated polymerization, the mixed liquor 20-25 of composite sorbierite and phenylpropyl alcohol triazole, association type levelling rheological agent 20-22, acrylic acid dispersant 10-15, mixing is obtained;
Product chemical index is as follows:
Outward appearance: oyster white thick liquid
Ionic: cloudy
PH value: 7 ± 0.5
Solid content: >=50%;
Association type levelling rheological agent: be DS modest Shanghai Chemical Co., Ltd. product association type levelling rheological agent WT-203;
Acrylic acid dispersant: be Henkel chemical company product acrylic acid dispersant 5040.
2. the preparation method that starches with gold printing of stone wallpaper, is characterized in that:
Raw material is by weight ratio:
(1) emulsification mix monomer: add dimethacrylate-1 in stainless steel still, 4-butanediol ester 2.0-2.2, itaconic acid 1.0-1.1, ethyl acrylate 130-140, butyl acrylate 31-32, hydroxyethyl methylacrylate 6.4-6.6, methyl methacrylate 27-28, acetoacetoxyethyl methacrylate 4.0-4.2, styrene 32-33, fatty alcohol-polyoxyethylene ether 23E9 are 2-2.3, deionized water 210-230, emulsion is made in stirring, stand-by;
(2) initiated polymerization: get above-mentioned emulsion gross weight 30% adds in reactor, be warming up to 80-82 DEG C, add the mixed liquor of initiator ammonium persulfate 1.27 and deionized water 10, cause, at 80-82 DEG C of temperature, then drip remaining emulsion, drip ammonium persulfate 0.63-0.83 and deionized water 10 mixed liquor simultaneously, within 1-2 hour, dropwise, at 80-82 DEG C of insulation 2-3 hour, being then cooled to 30-40 DEG C, be 20% ammoniacal liquor adjust pH is 7 ± 0.5 with mass percent concentration;
(3) composite: sorbierite and phenylpropyl alcohol triazole to be added in above-mentioned polymer by 1:1 mixed dissolution liquid 20-25 and stirs, add acrylic acid dispersant 10-15 to stir, then add association type levelling rheological agent 20-22, stirring thickening is even, filter discharging, obtain stone wallpaper gold printing printing paste.
3. the preparation method of stone wallpaper gold printing slurry according to claim 2, is characterized in that:
Association type levelling rheological agent is DS modest Shanghai Chemical Co., Ltd. product association type levelling rheological agent WT-203;
Acrylic acid dispersant is Henkel chemical company product acrylic acid dispersant 5040.
4. as stone wallpaper gold printing printing paste that claim 2 method obtains.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310743257.1A CN103741517B (en) | 2013-12-30 | 2013-12-30 | Stone wallpaper gold printing printing paste and preparation method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310743257.1A CN103741517B (en) | 2013-12-30 | 2013-12-30 | Stone wallpaper gold printing printing paste and preparation method |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103741517A CN103741517A (en) | 2014-04-23 |
CN103741517B true CN103741517B (en) | 2015-10-28 |
Family
ID=50498577
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310743257.1A Active CN103741517B (en) | 2013-12-30 | 2013-12-30 | Stone wallpaper gold printing printing paste and preparation method |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103741517B (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103965395B (en) * | 2014-05-21 | 2016-01-13 | 辽宁恒星精细化工有限公司 | Modification acrylate intumescent coating emulsion and preparation method |
CN110904701B (en) * | 2019-12-17 | 2022-02-01 | 辽宁恒星精细化工有限公司 | Printing paste for polyvinyl chloride material handicraft leaves and preparation method thereof |
CN112694561B (en) * | 2020-12-23 | 2022-07-26 | 辽宁恒星精细化工有限公司 | Preparation method and application of water-based acrylate adhesive cement |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6331598B1 (en) * | 1998-08-25 | 2001-12-18 | Korea Chemical Co., Ltd. | Emulsion polymer having a vesiculated structure and the process for preparing the same |
CN101942771A (en) * | 2010-08-17 | 2011-01-12 | 辽宁恒星精细化工有限公司 | Cotton-polyester fabric burn-out printing gum and preparation method thereof |
CN102619102A (en) * | 2012-04-06 | 2012-08-01 | 辽宁恒星精细化工有限公司 | Embossed printing paste for velvet fabric and preparation method thereof |
CN103088674A (en) * | 2012-12-26 | 2013-05-08 | 辽宁恒星精细化工有限公司 | Bright film printing paste and preparation method thereof |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009084709A (en) * | 2007-09-27 | 2009-04-23 | Chuo Rika Kogyo Corp | Aqueous resin dispersion for textile processing |
-
2013
- 2013-12-30 CN CN201310743257.1A patent/CN103741517B/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6331598B1 (en) * | 1998-08-25 | 2001-12-18 | Korea Chemical Co., Ltd. | Emulsion polymer having a vesiculated structure and the process for preparing the same |
CN101942771A (en) * | 2010-08-17 | 2011-01-12 | 辽宁恒星精细化工有限公司 | Cotton-polyester fabric burn-out printing gum and preparation method thereof |
CN102619102A (en) * | 2012-04-06 | 2012-08-01 | 辽宁恒星精细化工有限公司 | Embossed printing paste for velvet fabric and preparation method thereof |
CN103088674A (en) * | 2012-12-26 | 2013-05-08 | 辽宁恒星精细化工有限公司 | Bright film printing paste and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
CN103741517A (en) | 2014-04-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101748617B (en) | Anti-sticking soft dope printing adhesive and preparation method | |
CN102619103B (en) | Pigment printing imitated reactive printing adhesive and preparation method thereof | |
NO794228L (en) | METACRYLIC ACID EMULSION COPOLYMES FOR THICKNESS FORM | |
CN104672403A (en) | Environment-friendly silicon-acrylate emulsion and preparation method thereof | |
CN106758392B (en) | A kind of new dye stamp synthetic thickening agent and preparation method thereof, application | |
JPS5989313A (en) | Tackifying alkylacrylamide-containing emulsion copolymer | |
CN103756601B (en) | Metal(lic)powder tackiness agent and preparation method thereof and wallpaper, textiles | |
CN102619102B (en) | Embossed printing paste for velvet fabric and preparation method thereof | |
CN103088674B (en) | Bright film printing paste and preparation method thereof | |
CN103741517B (en) | Stone wallpaper gold printing printing paste and preparation method | |
DE1570312A1 (en) | Process for the preparation of polymer dispersions | |
CN102154852A (en) | Textile machinery printing pigment binding agent and manufacturing method thereof | |
CN101457499B (en) | Surface sizing agent and its production method | |
CN107163761A (en) | A kind of colorful base paint emulsion of excellent performance and preparation method thereof | |
CN103030914A (en) | Acrylic ester composition, preparation method of acrylic ester composition, and adhesive tape applying composition | |
CN103232566B (en) | Preparation method of high-solid-content low-viscosity acrylate emulsion for sealing gum | |
CN105884962B (en) | A kind of lacquer lotion and using the lotion as the lacquer of film forming matter | |
CN103215825A (en) | Printing adhesive of stone paper wallpaper and preparation method of printing adhesive | |
JP3722397B2 (en) | Water-based ink binder | |
CN101581045B (en) | Elastic colorized printing paste and production method thereof | |
JPH05295048A (en) | Aqueous resin composition | |
CN106750039B (en) | A kind of rosin/acrylate nuclear-shell emulsion and the preparation method and application thereof | |
CN102382509A (en) | Water-based ink, elastic emulsion used for water-based ink and preparation method of elastic emulsion | |
CN102050932B (en) | Water-based alkali swelling rheological agent and production method thereof | |
CN109776739B (en) | Macromolecular anti-cross-color builder |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant |