CN103739915B - Synthetic wood material containing reinforcement and manufacture method thereof - Google Patents
Synthetic wood material containing reinforcement and manufacture method thereof Download PDFInfo
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- CN103739915B CN103739915B CN201310713304.8A CN201310713304A CN103739915B CN 103739915 B CN103739915 B CN 103739915B CN 201310713304 A CN201310713304 A CN 201310713304A CN 103739915 B CN103739915 B CN 103739915B
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- reinforcement
- pvc
- stabilizer
- tacryl
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The present invention relates to a kind of synthetic wood material containing reinforcement and method for production thereof, containing PVC be, PE, PEP, CPVC resin, acrylic acid, chlorinated polyethylene, tacryl, HBA 401A PVC, organotin complex stabilizer are, PVC complex stabilizer, ACR530, polyester, matter calcium carbonate, carbon fiber etc., and have reinforcement；By getting the raw materials ready, puddling, pelletize, composite molding make.The present invention uses high sub-modification technology to divide the component made, and is better than wood materials like wood materials, owing to containing reinforcement, further increasing the strength and stiffness of material.This material, have that integrated cost is low, intensity is big, low temperature flexible, lightweight, anticorrosive, high temperature resistant, order in service life long, heat conductivity is low, high-low temperature resistant, do not fade, do not fade, easily processing etc.；After the product rejection of this material, can be all as the products material recycling of the present invention.The present invention is applicable to manufacture the booth frame material of fruit and vegerable plantation, balustrade, outdoor sport apparatus, guardrail etc..
Description
Technical field
The present invention relates to macromolecular material and manufacturing technology thereof, specifically apply to a kind of new material of exterior product
And Industrialized processing technique.
Background technology
Be applied to all multi-products of outdoor, such as balustrade, outdoor sport apparatus, guardrail, refuse receptacle etc., multiplex timber or
Polrvinyl chloride, plastics, steel etc. are manufactured and are formed, although wood-based product----there is the advantage that heat conductivity is little, be easy to processing, but be subject to
The restriction in trees source, the most in short supply, and there is shortcoming perishable, the firmest, non-resistant；Although plastic product------has
Heat conductivity advantage little, lower-cost, but the most aging become fragile, intensity is low；Although steel material----there are intensity height, cost relatively
Low advantage, but there is the shortcomings such as big, the easy-to-rust of heat conductivity.
Summary of the invention
It is an object of the invention to, the shortcoming overcoming current material, it is desirable to provide one withstand expose to wind and rain, heat tight
The invasion and attack of cold, acid and alkali corrosion etc., it is adaptable to the new structural member material of exterior product and method for production thereof.
The present invention is achieved in that
One. the key component that the construction material of the present invention contains
PVC be 10-20, PE be 15-30, PEP be 15-30, CPVC resin be 7-10, acrylic acid be 7-9, chlorinated polyethylene
For 4-6, tacryl be 3-5, HBA-401A PVC be 1-3, organotin complex stabilizer be 3-4, PVC complex stabilizer 3-5,
ACR530 is 7-10, polyester is 5-10, matter calcium carbonate is 15-25, carbon fiber be 4-5, ABS be 8-10, PE wax be 2-3, Semen sojae atricolor
Oil 4-6；And containing reinforcement.
Described chlorinated polyethylene, for resin type chlorinated polyethylene CPE；
Described PVC complex stabilizer, including calcium stearate stabilizer or zinc stearate stabilizer；
Described ABS, for macromolecular material, including PE polyethylene, ABS engineering plastics, polyester slice, polypropylene, acrylic acid,
One or more in zinc oxide；
Described reinforcement, is intensity, the more preferable unlike material of toughness, such as steel plate strip, steel pipe etc..
The construction material of the present invention, its production technology and method for production be:
1) get the raw materials ready:
Silk material by component acryl fiber process growth 3-5cm；
Powder process: by other component beyond tacryl and liquid propene acid, soybean oil, be processed into powdery, granularity respectively
For 80-100 mesh.
3) puddle；
A. by above-mentioned steps 1) each component of getting ready and acrylic acid, soybean oil load in blender, stir and heat
(but except organotin complex stabilizer, calcium stearoyl zinc stabilizer, ACR530 foaming control agent and HBA-401A PVC, PE wax)；
B. when temperature rises to 50-70 DEG C, adding organotin complex stabilizer and calcium stearoyl zinc stabilizer, stirring 3-5 divides
Clock；
C., when temperature rises to 80-90 DEG C, tacryl, ACR530 foaming control agent and HBA-401A PVC foam are added
Agent, stirs 3-5 minute；
D., when temperature rises to 95-100 DEG C, add PE wax, stir 3-5 minute；
E. when temperature rises to 110-140 DEG C, after stirring 3-5 minute, discharging；
3) pelletize: prilling temperature is at 170-200 DEG C；The granule of φ 3.5mm-4.5mm is made by comminutor；
4) composite molding: carry out in forming machine, is provided with six thermals treatment zone before and after this forming machine, temperature is respectively 100-
110℃、120-130℃、130-140℃、140-160℃、180-190℃、190-200℃。
Its program is:
(1) intensity, toughness more preferable foreign peoples reinforcement are insert molded in machine；
(2) by abovementioned steps 3) semi-finished stock, send in forming machine.
During the semi-finished stock six thermal treatment zone reaches in forming machine, with reinforcement synchronizing moving.Through adding
Heat, extruding----pressure is every square centimeter 6-10 kilogram, and reinforcement is wrapped among raw material, finally cooling molding therewith
It is brought out the thermal treatment zone, becomes final products.
The present invention uses the structure material and production technology thereof that macromolecule modified technology makes, and can be made into containing reinforcement
Synthesis wood new material, reinforcement further increases the strength and stiffness of material.This material, is better than wooden like wood materials
Material, have that integrated cost is low, intensity is big, flexible, lightweight, anticorrosive, high-low temperature resistant, order in service life long, and have
Nontoxic, mothproof, the most water funk, the most inflammable, anti-ultraviolet, heat conductivity outdoor high/low temperature low, resistance to, do not fade, the advantage such as do not fade；
After the product rejection of this material, can recycle as the products material of the present invention.The present invention is applicable to manufacture fruit and vegerable plantation
Booth frame material, balustrade, outdoor sport apparatus, guardrail, refuse receptacle etc..
Accompanying drawing explanation
Fig. 1. there is the component generalized section of the synthetic wood material of reinforcement
In figure, 1 is cylindrical component, and 2 is resistance to compression cap；3 vertical steel tubes.
Detailed description of the invention
Below in conjunction with drawings and Examples, the present invention is described further.
Fig. 1 shows the profile of cylindrical component, and this component uses the component of the present invention to make.Cylindrical component 1 vertical
Reinforcement it is enclosed with at azimuth axis.This reinforcement, is the two ends at a vertical steel tube 3, is fixed with resistance to compression cap 2, so as to entering
One step improves the intensity of component.
Embodiment 1, the construction material of a kind of balustrade and manufacture method thereof
The component and the shared weight portion that contain in this framework material be: PVC is 10, PE is 30, PEP is 15, CPVC tree
Fat is 10, thermoplasticity bright alkene resin is 4, chlorinated polyethylene is 6, tacryl is 3, HBA-401A PVC is 3, organotin is combined
Stabilizer is 3, PVC complex stabilizer (calcium stearate stabilizer) 5, ACR530 are 7, glass fibre cotton is 18, poly-carbon is 5, matter
Calcium carbonate is 25, carbon fiber is 4, ABS (PE polyethylene) is 10, PE wax is 2, soybean oil 4；And containing reinforcement.
The production method of the present embodiment structure material:
1) get the raw materials ready:
By component acryl fiber, glass fibre cotton, the silk material of processing growth 3-5cm；
Powder process: by other component beyond tacryl and liquid propene acid, soybean oil, be processed into powdery, granularity respectively
80-100 mesh.
4) puddle；
A. by 1) get ready each component of material and acrylic acid, soybean oil (organotin complex stabilizer, calcium stearoyl zinc stabilizer,
Except ACR530 foaming control agent and HBA-401A PVC, PE wax), load and blender stirs and heats；
B., when temperature rises to 50-70 DEG C, add organotin complex stabilizer and calcium stearoyl zinc stabilizer, be sufficiently stirred for；
C., when temperature rises to 80-90 DEG C, tacryl, ACR530 foaming control agent and HBA-401A PVC foam are added
Agent, is sufficiently stirred for；
D., when temperature rises to 95-100 DEG C, add PE wax and stir.
E., when temperature rises to 110-120 DEG C, complete discharging is stirred.
3) pelletize: prilling temperature is at 170-200 DEG C.The granule of φ 3.5mm-4.5mm is made by comminutor
4) composite molding: in forming machine before and after be provided with six thermals treatment zone, temperature be respectively 100-110 DEG C, 120-130 DEG C,
130-140℃、140-160℃、180-190℃。
(1) by reinforcement----vertical steel tube 3 two ends are fixed with resistance to compression cap 2, are insert molded in machine；
(2) by abovementioned steps 3) semi-finished stock, send in forming machine.
Semi-finished stock during six thermals treatment zone, with reinforcement steel pipe synchronizing moving, passes through before and after forming machine
Heat, extruding----pressure is every square centimeter 6-8 kilogram, and reinforcement steel pipe is wrapped among raw material, finally cools down molding
And it is brought out the thermal treatment zone therewith, become final products.
Embodiment 2, the construction material of a kind of outdoor exercising apparatus and manufacture method thereof
The component and the shared weight portion that contain in this framework material be:
PVC is 20, PE is 15, PEP is 30, CPVC resin is 7, thermoplasticity bright alkene resin is 6, chlorinated polyethylene is 4, third
Alkene fiber is 5, HBA-401A PVC is 1, organotin complex stabilizer is 4, PVC complex stabilizer (zinc stearate stabilizer) 3,
ACR530 is 10, glass fibre cotton is 12, poly-carbon is 10, matter calcium carbonate is 15, carbon fiber is 5, ABS (ABS engineering plastics) is
8, PE wax be 3, soybean oil 6, and containing reinforcement.
The production method of the structure material of the present embodiment
1) get the raw materials ready:
By component acryl fiber, glass fibre cotton, the silk material of processing growth 3-5cm；
Powder process: by other component beyond tacryl and liquid propene acid, soybean oil, be processed into powdery, granularity respectively
80-100 mesh.
5) puddle；
A. by 1) get each component and acrylic acid, soybean oil (tacryl, organotin complex stabilizer, the calcium stearoyl of material ready
Except zinc stabilizer, ACR530 foaming control agent and HBA-401A PVC, PE wax), load in blender and stir also
Heating；
B., when temperature rises to 50-70 DEG C, add organotin complex stabilizer and calcium stearoyl zinc stabilizer, be sufficiently stirred for；
C., when temperature rises to 80-90 DEG C, tacryl, ACR530 foaming control agent and HBA-401A PVC foam are added
Agent, is sufficiently stirred for；
D., when temperature rises to 95-100 DEG C, add PE wax and stir.
E., when temperature rises to 110-120 DEG C, complete discharging is stirred.
3) pelletize: prilling temperature is at 170-200 DEG C.The granule of φ 3.5mm-4.5mm is made by comminutor
4) composite molding: carry out in forming machine, is successively provided with six thermals treatment zone in this forming machine, and temperature is respectively 100-
110℃、120-130℃、130-140℃、140-160℃、180-190℃。
(1) by reinforcement----steel plate strip is insert molded in machine；
(2) by abovementioned steps 3) semi-finished stock, send in forming machine.
Semi-finished stock before and after forming machine during six thermals treatment zone, and reinforcement synchronizing moving, through heating,
Extruding----pressure is every square centimeter 8-10 kilogram, and reinforcement is wrapped among raw material, finally cooling molding and therewith by
Draw the thermal treatment zone, become final products.
The synthesis wood construction material of the present invention, has the advantage that timber is easily processed----lightweight, can saw, follow closely, dig, viscous
Patch, screw is firm, high-low temperature resistant, heat conductivity aldehyde of having no way of low, nontoxic, do not fade, do not fade, integrated cost is low, have simultaneously
Have that intensity is high, good toughness, anticorrosive, order in service life is long, mothproof, the most water funk, the most inflammable, do not ftracture, indeformable advantage, can
Replace the timber of traditional product, plastic-steel, aluminium and part steel etc., it is adaptable to manufacture the booth frame material of fruit and vegerable plantation, building
Ladder rail, outdoor sport apparatus, guardrail etc.；If after product is scrapped, can all reclaim----use as one of the raw material of the present invention
Make product.Owing to construction material is contained within reinforcement, further improve the intensity of construction material, rigidity.
Claims (2)
1. contain the synthetic wood material of reinforcement, it is characterised in that the key component and the shared weight portion that contain be: PVC is 10-
20, PE be 15-30, PEP be 15-30, CPVC resin be 7-10, acrylic acid be 7-9, chlorinated polyethylene be 4-6, tacryl be
3-5, HBA-401A PVC foam agent is 1-3, organotin complex stabilizer be 3-4, PVC complex stabilizer 3-5, ACR530 be 7-
10, polyester be 5-10, matter calcium carbonate be 15-25, carbon fiber be 4-5, ABS be 8-10, PE wax be 2-3, soybean oil 4-6；And contain
There is reinforcement；
Described chlorinated polyethylene, for resin type chlorinated polyethylene CPE；
Described PVC complex stabilizer, including calcium stearate stabilizer or zinc stearate stabilizer；
Described ABS, for macromolecular material, including the one or many in PE polyethylene, ABS engineering plastics, polyester slice, polypropylene
Kind；
Described reinforcement is wrapped among synthetic wood material.
Contain the synthetic wood material of reinforcement the most according to claim 1, it is characterised in that its production technology and method for production
It is:
1) get the raw materials ready:
Silk material by component acryl fiber process growth 3-5cm；
Powder process: by other component beyond tacryl and liquid propene acid, soybean oil, being processed into powdery respectively, granularity is 80-
100 mesh；
2) puddle；
A. except tacryl, organotin complex stabilizer, calcium stearoyl zinc stabilizer, ACR530 foaming control agent and HBA-401A
Except PVC, PE wax, by above-mentioned steps 1) remaining component of getting ready and acrylic acid, soybean oil load in blender, stir also
Heating；
B., when temperature rises to 50-70 DEG C, add organotin complex stabilizer and calcium stearoyl zinc stabilizer, stir 3-5 minute；
C., when temperature rises to 80-90 DEG C, tacryl, ACR530 foaming control agent and HBA-401A PVC foam agent are added,
Stir 3-5 minute；
D., when temperature rises to 95-100 DEG C, add PE wax, stir 3-5 minute；
E. when temperature rises to 110-140 DEG C, after stirring 3-5 minute, discharging；
3) pelletize: prilling temperature is at 170-200 DEG C；The granule of φ 3.5mm-4.5mm is made by comminutor；
4) composite molding: carry out in forming machine, is provided with six thermals treatment zone before and after this forming machine, temperature be respectively 100-110 DEG C,
120-130℃、130-140℃、140-160℃、180-190℃、190-200℃；
Its technological process is:
(1) reinforcement is insert molded in machine；
(2) by abovementioned steps 3) semi-finished stock, send in forming machine；
Semi-finished stock during six thermals treatment zone, with reinforcement synchronizing moving, through heating, squeezes before and after forming machine
Pressure, reinforcement is wrapped among raw material, and finally cooling molding is also brought out the thermal treatment zone therewith, becomes final products.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310713304.8A CN103739915B (en) | 2013-12-23 | 2013-12-23 | Synthetic wood material containing reinforcement and manufacture method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310713304.8A CN103739915B (en) | 2013-12-23 | 2013-12-23 | Synthetic wood material containing reinforcement and manufacture method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103739915A CN103739915A (en) | 2014-04-23 |
| CN103739915B true CN103739915B (en) | 2016-08-17 |
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| CN201310713304.8A Active CN103739915B (en) | 2013-12-23 | 2013-12-23 | Synthetic wood material containing reinforcement and manufacture method thereof |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106167595A (en) * | 2016-07-29 | 2016-11-30 | 无锡市凯达来塑胶有限公司 | A kind of polrvinyl chloride heat-insulated floorboard |
| CN107236174A (en) * | 2017-07-19 | 2017-10-10 | 合肥申沃园艺有限公司 | A kind of plastic greenhouse framework material and preparation method thereof |
| CN111234419A (en) * | 2020-03-25 | 2020-06-05 | 湖南翰坤实业有限公司 | Steel core composite PVC material prepared fence material for building |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101858190A (en) * | 2010-06-23 | 2010-10-13 | 杨华 | Method for producing liquid wood integral door |
| CN102558716A (en) * | 2012-03-06 | 2012-07-11 | 鹰自达装饰材料有限公司 | Method for manufacturing plastic-wooden composite section bar |
-
2013
- 2013-12-23 CN CN201310713304.8A patent/CN103739915B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101858190A (en) * | 2010-06-23 | 2010-10-13 | 杨华 | Method for producing liquid wood integral door |
| CN102558716A (en) * | 2012-03-06 | 2012-07-11 | 鹰自达装饰材料有限公司 | Method for manufacturing plastic-wooden composite section bar |
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