CN103739261A - Chimney white mud lime bamboo fiber-reinforced calcium silicate plate - Google Patents
Chimney white mud lime bamboo fiber-reinforced calcium silicate plate Download PDFInfo
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- CN103739261A CN103739261A CN201310677200.6A CN201310677200A CN103739261A CN 103739261 A CN103739261 A CN 103739261A CN 201310677200 A CN201310677200 A CN 201310677200A CN 103739261 A CN103739261 A CN 103739261A
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- calcium silicate
- lime
- chimney white
- white mud
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Abstract
A chimney white mud lime bamboo fiber-reinforced calcium silicate plate is prepared mainly by the following raw materials by weight: 6%-12% of lime bamboo fibers; 1%-3% of glass fibers; 20%-30% of chimney white mud; 25%-40% of quartz; 25%-35% of ordinary portland cement; and 1%-2% of expanded perlite. The advantages of the chimney white mud lime bamboo fiber-reinforced calcium silicate plate are that: the chimney white mud fiber-reinforced calcium silicate plate is prepared through effective study of Ca+ in chimney white mud and by making full use of the characteristics of gypsum at different temperatures; the strength is high; the appearance is beautiful; the cost is low; the raw material price is low; the impurities are few; waste water recovered through vacuum dehydration in the production process is recycled, and Ca+ in the waste water is completely used, which solves the problem of comprehensive utilization of industrial desulfurized gypsum, reduces the production cost of calcium silicate plates, and meets the requirements of circular economy.
Description
Technical field
The present invention relates to a kind of material of construction, particularly a kind of chimney white clay lime bamboo fiber reinforcement calcium silicate board.
Background technology
Density is low because having for fiber reinforced calcium silicate board, fire prevention, strong, the anticorrosion protection against the tide of sound-proofing, intensity advantages of higher, is therefore widely used in all kinds of buildings, in traditional method, take lime effective Ca in prepared using lime
+with SiO
2in Si
+produce calcium silicate board under certain condition, wherein unslaked lime CaO has certain influence to production environment.
Because the calcareous raw material cost that adopts lime to strengthen calcium silicate board as producd fibers is excessive, how to reduce production costs, be urgent problem always.
Summary of the invention
Object of the present invention is just to provide a kind of a kind of chimney white clay of industrial waste (being chimney white clay) replacement lime production lime bamboo fiber reinforcement calcium silicate board that adopts chimney white clay to form desulfurization.
Solution of the present invention is such:
The industrial residue that desulfurizing industrial fume forms, its major ingredient is calcium sulfite powder (being desulfurated plaster), there is identical rule with the physical and chemical performance of the plaster of paris, but the byproduct thing as a kind of flue gas desulfurization, general character matter is by flue gas desulfurization technique, make it there is some feature of reclaimed gypsum, have different with the plaster of paris, be mainly manifested in the aspects such as appearance property, particle characteristics, chemical composition, stability.
Chimney white clay main component is calcium sulfite, its unstable properties, and under certain temperature and humidity, wherein 30% ~ 35% Ca+ can separate out, with Si
+in conjunction with generating calcium silicate board.
By the systems analysis to desulfurated plaster (the being chimney white clay) component of chimney desulfurization formation, and effective Ca under High Temperature High Pressure
+formation ratio research, utilize under 150 ° of-200 ° of C part Ca in desulfurated plaster (CaSO4)
+separate out, with Si
+hydrothermal synthesis reaction occurs, generate hydrated calcium silicate gum material, other material adhesive is formed to integral body, effectively improve the strength characteristics of calcium silicate board, the sheet material of production is harder, attractive in appearance, smooth surface is fine and smooth, cost is low.
Solution of the present invention is such: a kind of chimney white clay lime bamboo fiber reinforcement calcium silicate board, mainly by containing following raw materials by weight, make: lime bamboo pulp fiber 6 % mono-12 %; Glass fibre 1 % mono-3 %; Chimney white clay 20 % mono-30 %; Quartzy 25 % mono-40%; Ordinary Portland cement 25 % mono-35 %; Pearlstone l % mono-2 %; Above-mentioned former wood pulp cellulose is added and appropriate water mill slurry after, then add other material slurrying, through stream slurry, vacuum hydro-extraction, moulding, rest, make finished product after the demoulding, steam pressure, oven dry.
Technical scheme also comprises more specifically: mainly by containing following raw materials by weight, make: lime bamboo fibers 7%; Glass fibre 2%; Chimney white clay 17%; Quartzy 46%; Ordinary Portland cement 25%; Pearlstone 1.6%.
Advantage of the present invention is:
(1), pass through Ca in chimney white clay
+effectively research, makes full use of the characteristic under gypsum differing temps, manufactures chimney white clay fiber reinforced calcium silicate board;
(2), intensity is high;
(3), appearance looks elegant;
(4), cost is low, realization utilizes integrated mill, the chimney waste residue desulfurated plaster (FGD) that enterprise's chimney dust removal desulfurization such as power plant precipitate substitutes CaO and as producd fibers, strengthens the calcareous raw material of calcium plate, greatly reduce raw materials cost, press CaO360 yuan/ton of calculating, chimney white clay reclaims 45 yuan/ton of prices, through high temperature, under high pressure, process the CaO that obtains 32.6%, only this item, per tonly cut down expenses 222 yuan, solved the comprehensive utilization of industrially desulfurized gypsum, reduced again the production cost of calcium silicate board, for flue gas desulfurization comprehensive utilization of waste material, to have opened up a technology reliable, economically viable approach, obtained the doulbe-sides' victory of environment and economy benefit,
(5), vacuum hydro-extraction is reclaimed in process of production cycling utilization of wastewater, the Ca in waste water
+arrived completely and utilized, cost is low, meets recycling economy requirement.
Accompanying drawing explanation
Fig. 1 is process flow sheet of the present invention.
Embodiment
A kind of chimney white clay lime bamboo fiber reinforcement calcium silicate board of the present invention, mainly makes by containing following raw materials by weight: lime bamboo fibers 6 % mono-12 %; Glass fibre 1 % mono-3 %; Chimney white clay 20 % mono-30 %; Quartzy 25 % mono-40%; Ordinary Portland cement 25 % mono-35 %; Pearlstone l % mono-2 %; By above-mentioned, add after appropriate water mill slurry, then add other material slurrying, through stream slurry, vacuum hydro-extraction, moulding, rest, make finished product after the demoulding, steam pressure, oven dry, finishing.
Specific embodiment is as following table:
Embodiment | Lime bamboo fibers | Glass fibre | Chimney white clay | Quartzy | Ordinary Portland cement | Pearlstone |
1 | 7 | 2 | 20 | 25 | 25 | 1.6 |
2 | 6 | 1 | 30 | 40 | 30 | 2 |
3 | 12 | 3 | 25 | 30 | 235 | 1 |
4 | 10 | 2 | 28 | 28 | 28 | 1 |
5 | 9 | 3 | 23 | 38 | 23 | 2 |
In above-described embodiment, surplus is water.
The making method of above-described embodiment is: after above-mentioned raw materials is mixed with water, drop in stirrer and stir formation mixed slurry, then through overcurrent, starch the vacuum hydro-extraction one moulding one demoulding one steam pressure reaction one of resting and dry edging one finished product.Can form chimney white clay lime bamboo fiber reinforcement calcium silicate board of the present invention.When the vacuum hydro-extraction of stream slurry, collected waste water is for chimney white clay lime bamboo fibers next time and the supplementary water cycle of using of mixed slurry.Leftover bits during moulding reclaim again and stir and use.
Chimney white clay lime bamboo fiber reinforcement calcium silicate board (specification be 2240 * 1220mm * 10 mm) the physical and mechanical property index detected result of following table l for making by above-mentioned raw materials proportioning.
Table l: physical and mechanical property index detected result
As can be seen from the above data, folding strength, water ratio, bulking factor, thermal conductivity, percent thermal shrinkage, fire endurance and the oise insulation factor etc. of chimney white clay lime bamboo fiber reinforcement calcium silicate board of the present invention are all better than general common calcium silicate board.
Claims (2)
1. a chimney white clay lime bamboo fiber reinforcement calcium silicate board, is characterized in that: mainly by containing following raw materials by weight, make: lime bamboo fibers 6 % mono-12 %; Chimney white clay 20 % mono-30 %; Quartzy 25% one 40%; Ordinary Portland cement 25 % mono-35 %; Pearlstone l % mono-2 %; Above-mentioned former wood pulp cellulose is added and appropriate water mill slurry after, then add other material slurrying, through stream slurry, vacuum hydro-extraction, moulding, rest, make finished product after the demoulding, steam pressure, oven dry.
2. chimney white clay lime bamboo fiber reinforcement calcium silicate board according to claim 1, is characterized in that: mainly by containing following raw materials by weight, make: lime bamboo fibers 7%; Glass fibre 2%; Chimney white clay 17%; Quartzy 46%; Ordinary Portland cement 25%; Pearlstone 1.6%.
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CN201310677200.6A CN103739261A (en) | 2013-12-13 | 2013-12-13 | Chimney white mud lime bamboo fiber-reinforced calcium silicate plate |
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CN201310677200.6A CN103739261A (en) | 2013-12-13 | 2013-12-13 | Chimney white mud lime bamboo fiber-reinforced calcium silicate plate |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103964786A (en) * | 2014-05-07 | 2014-08-06 | 山东建筑大学 | Method for producing calcium silicate board by utilizing papermaking white clay and quartz stone wastes |
CN103964785A (en) * | 2014-05-07 | 2014-08-06 | 山东建筑大学 | Method for producing calcium silicate board from artificial stone plate wastes and quartz stone plate wastes |
CN106927777A (en) * | 2017-04-13 | 2017-07-07 | 贵州联和新型建材有限公司 | A kind of combined wall board calcium silicate board and preparation method thereof |
CN111620650A (en) * | 2020-05-22 | 2020-09-04 | 贵州开磷磷石膏综合利用有限公司 | Fire-resistant light gypsum flue and preparation method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009034828A (en) * | 2007-07-31 | 2009-02-19 | Hymo Corp | Method for producing inorganic article |
CN101863650A (en) * | 2010-06-10 | 2010-10-20 | 柳州市桂人建材有限公司 | Lime bamboo pulp fiber reinforced calcium silicate board |
CN103319118A (en) * | 2013-05-21 | 2013-09-25 | 内蒙古科技大学 | Method for making heat insulation plates through utilizing industrial solid wastes |
-
2013
- 2013-12-13 CN CN201310677200.6A patent/CN103739261A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009034828A (en) * | 2007-07-31 | 2009-02-19 | Hymo Corp | Method for producing inorganic article |
CN101863650A (en) * | 2010-06-10 | 2010-10-20 | 柳州市桂人建材有限公司 | Lime bamboo pulp fiber reinforced calcium silicate board |
CN103319118A (en) * | 2013-05-21 | 2013-09-25 | 内蒙古科技大学 | Method for making heat insulation plates through utilizing industrial solid wastes |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103964786A (en) * | 2014-05-07 | 2014-08-06 | 山东建筑大学 | Method for producing calcium silicate board by utilizing papermaking white clay and quartz stone wastes |
CN103964785A (en) * | 2014-05-07 | 2014-08-06 | 山东建筑大学 | Method for producing calcium silicate board from artificial stone plate wastes and quartz stone plate wastes |
CN103964785B (en) * | 2014-05-07 | 2015-10-21 | 山东建筑大学 | A kind of method of producing calcium silicon plate with artificial stone plate and quartz slate waste |
CN106927777A (en) * | 2017-04-13 | 2017-07-07 | 贵州联和新型建材有限公司 | A kind of combined wall board calcium silicate board and preparation method thereof |
CN111620650A (en) * | 2020-05-22 | 2020-09-04 | 贵州开磷磷石膏综合利用有限公司 | Fire-resistant light gypsum flue and preparation method thereof |
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Application publication date: 20140423 |