[summary of the invention]
Technical problem to be solved by this invention is for above-mentioned deficiency of the prior art; provide a kind of in, the treatment process for the treatment of of advanced stage landfill leachate; the method effectively will in, treatment of advanced stage landfill leachate processes discharging standards and discharges, and effectively protected environment.
For achieving the above object, the present invention has adopted following technical proposals:
In, the treatment process for the treatment of of advanced stage landfill leachate, it is characterized in that:
(1), by, late period rubbish produce leachate collection among equalizing tank.
(2), by the water pump being arranged at the bottom of described equalizing tank pond, the percolate among described equalizing tank is transferred to integration denitrification reactor, described denitrification reactor comprises nitrification zone and denitrification zone, hydrophilic group urethane filler is installed in nitrification zone, in denitrification zone, place slowly-releasing carbon source type macromolecular material, to the nitrification zone aeration of described integration denitrification reactor, the lift that utilizes aeration to produce moves upward the water of bottom, nitrification zone, and at top, produce the overflow of cleaving and enter denitrification zone, realized the backflow of nitrification and denitrification.
(3), will transfer to acid precipitation reaction device through the solution after denitrification reaction, solution among described acid precipitation reaction device adds sulfuric acid, the pH value of regulator solution is to acid out point, a large amount of throw outs are separated out floating, then through the mode of scraping slag, scum silica frost is removed, the mud producing in this process is transferred to landfill yard.
(4), to transfer to integrated Fenton reactor through the solution after acid precipitation reaction, to the solution aeration among described integrated Fenton reactor, and the solution among described integrated Fenton reactor adds hydrogen peroxide, described integrated Fenton reactor comprises scum silica frost disengaging zone, iron carbon hydrogen peroxide Fenton's reaction district, rear reaction zone, iron carbon produces micro-electrolysis reaction in acidic solution, and in Fenton's reaction, produce stronger oxygenizement, in the process of redox reaction, make organic macromolecule that fracture degraded occur, thereby eliminated the colourity of solution, improved the biodegradability of solution, under the powerful oxygenizement of hydroxyl radical free radical, chemical oxygen demand (COD) is able to more removal.
(5), among transferring to coagulating sedimentation device through the solution after Fenton's reaction, carry out coagulating sedimentation, among solution, add sodium hydroxide, flocculation agent, after flocculation reaction, enter settling tank solid-liquid separation.
(6), among transferring to activated sludge reactor through the solution after coagulating sedimentation, process, solution in described activated sludge reactor continues aeration, the sludge-like throw out forming because of aerobic microbial reproduction after certain hour, on it, perching take zoogloea as main micropopulation, by the effect of microorganism, organism in Decomposition Wastewater, by the effect of aerobic microbiological, further dispel the organism among solution, reduce chemical oxygen demand value, reach emission standard, the mud producing in this process is transferred to landfill yard.
(7), among transferring to filtering basin through the solution after active sludge treatment, carry out filtration treatment, greatly reduce the suspended substance among sewage, make suspended substance reach emission standard.
, by filter after clear water transfer among sterilization pool, the solution in described sterilization pool passes into dioxide peroxide disinfection, kills intestinal bacteria and again reduces chemical oxygen demand (COD).
(9), will be disposed to urban sewage pipe through the solution of disinfecting, reach emission standard.
Described above the, (2) among step, in described integration denitrification reactor denitrification zone, place slowly-releasing carbon source type macromolecular material for poly-β hydroxy fatty acid.
Described above the, (3) among step, among solution, add sulfuric acid, the pH value of regulator solution is 3~3.5.
Concentration at the described above the hydrogen peroxide (4) adding among step is 7.5%.
At the described above the flocculation agent (5) adding among step, it is polyacrylamide.
The invention has the beneficial effects as follows:
1, among the present invention, by a series of technical matters, combine, the first discharge standard of early stage percolate being processed to national regulation discharges.
2, among the present invention, denitrogenation has adopted integrated nitration denitrification denitrogenation device, denitrification filler has adopted slowly-releasing carbon source type macromolecular material-poly-β hydroxy fatty acid (PHA), this material be the ground of the parasitism of denitrifying microorganism be also the nutrition source that this microorganism is liked most--β hydroxy fatty acid; Chemical oxidation has adopted iron-carbon micro-electrolysis and hydrogen peroxide hybrid technique to reach micro-electrolysis and Fenton process is oxidized the efficient oxidation function of simultaneously carrying out.
3, the present invention has adopted acid out decolouring, the colloid being dissolved in the water is removed, thereby made the colourity in water have larger removal, and organism is minimized.
4, among the present invention in integration denitrification reactor, the lift that the nitrification zone of integration denitrification reactor utilizes aeration to produce moves upward the solution of bottom, and at top, produce the overflow of cleaving and enter denitrification zone, thereby realized the backflow of nitrification and denitrification, the effect refluxing has: the one, and the nitric acid nitrite anions that aerobic nitrification is produced is transported to denitrification zone, for denitrification provides nutrition source and nitric acid nitrite anions is converted into nitrogen, removes; The 2nd, the acid group that aerobic nitrification produces is transported to denitrification zone, with the hydroxide radical neutralization reaction that denitrification produces, has saved the interpolation of acid with alkali.Above function has not only been saved refluxing unit but also saved medicament, the electricity charge; The removal efficiency that has improved nitrate is used in the application of denitrification slowly-releasing carbon source type macromolecular material, has solved available organic carbon source in this waste water and has lacked the poky difficult problem of denitrifying bacteria.
[embodiment]
Below in conjunction with accompanying drawing, the present invention is done to further detailed description.
As shown in Figure 1, in a kind of, the treatment process for the treatment of of advanced stage landfill leachate:
(1), by, late period rubbish produce leachate collection among equalizing tank 1.
(2), by the water pump 2 being arranged at the bottom of described equalizing tank 1 pond, the percolate among described equalizing tank 1 is transferred to integration denitrification reactor 3, described denitrification reactor 3 comprises nitrification zone and denitrification zone, hydrophilic group urethane filler is installed in nitrification zone, in denitrification zone, place slowly-releasing carbon source type macromolecular material, slowly-releasing carbon source type macromolecular material is preferably poly-β hydroxy fatty acid, to the nitrification zone aeration of described integration denitrification reactor 3, the lift that utilizes aeration to produce moves upward the water of bottom, nitrification zone, and at top, produce the overflow of cleaving and enter denitrification zone, realized the backflow of nitrification and denitrification, the effect refluxing has: the one, and the nitric acid nitrite anions that aerobic nitrification is produced is transported to denitrification zone, for providing nutrition source and nitric acid nitrite anions is converted into nitrogen, removes denitrification, the 2nd, the acid group that aerobic nitrification produces is transported to denitrification zone, with the hydroxide radical neutralization reaction that denitrification produces, has saved the interpolation of acid with alkali.Above function has not only been saved refluxing unit but also saved medicament, the electricity charge; The removal efficiency that has improved nitrate is used in the application of denitrification slowly-releasing carbon source type macromolecular material, has solved available organic carbon source in this waste water and has lacked the poky difficult problem of denitrifying bacteria.
(3), will transfer to acid precipitation reaction device 4 through the solution after denitrification reaction, solution among described acid precipitation reaction device 4 adds sulfuric acid, the pH value of regulator solution is to acid out point, the pH value of regulator solution is preferably 3~3.5, a large amount of throw outs are separated out floating, then through the mode of scraping slag, scum silica frost is removed, the mud producing in this process is transferred to landfill yard.
(4), to transfer to integrated Fenton reactor 5 through the solution after acid precipitation reaction, to the solution aeration among described integrated Fenton reactor 5, and the solution among described integrated Fenton reactor 5 adds hydrogen peroxide, the concentration of hydrogen peroxide is preferably 7.5%, described integrated Fenton reactor 5 comprises scum silica frost disengaging zone, iron carbon hydrogen peroxide Fenton's reaction district, rear reaction zone, iron carbon produces micro-electrolysis reaction in acidic solution, and in Fenton's reaction, produce stronger oxygenizement, in the process of redox reaction, make organic macromolecule that fracture degraded occur, thereby eliminated the colourity of solution, improved the biodegradability of solution, under the powerful oxygenizement of hydroxyl radical free radical, chemical oxygen demand (COD) is able to more removal.
(5), among transferring to coagulating sedimentation device 6 through the solution after Fenton's reaction, carry out coagulating sedimentation, among solution, add sodium hydroxide, flocculation agent, flocculation agent is preferably polyacrylamide, after flocculation reaction, enters settling tank solid-liquid separation.
(6), among transferring to activated sludge reactor 7 through the solution after coagulating sedimentation, process, solution in described activated sludge reactor 7 continues aeration, the sludge-like throw out forming because of aerobic microbial reproduction after certain hour, on it, perching take zoogloea as main micropopulation, by the effect of microorganism, organism in Decomposition Wastewater, by the effect of aerobic microbiological, further dispel the organism among solution, reduce chemical oxygen demand value, reach emission standard, the mud producing in this process is transferred to landfill yard.
(7), among transferring to filtering basin 8 through the solution after active sludge treatment, carry out filtration treatment, greatly reduce the suspended substance among sewage, make suspended substance reach emission standard.
, by filter after clear water transfer among sterilization pool 9, the solution in described sterilization pool 9 passes into dioxide peroxide disinfection, kills intestinal bacteria and again reduces chemical oxygen demand (COD).
(9), will be disposed to urban sewage pipe through the solution of disinfecting, reach emission standard.