CN103725418A - Method for extracting jack fruit aromatherapy oil from ionic liquid - Google Patents
Method for extracting jack fruit aromatherapy oil from ionic liquid Download PDFInfo
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- CN103725418A CN103725418A CN201310708249.3A CN201310708249A CN103725418A CN 103725418 A CN103725418 A CN 103725418A CN 201310708249 A CN201310708249 A CN 201310708249A CN 103725418 A CN103725418 A CN 103725418A
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- artocarpi heterophylli
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Abstract
The invention relates to a method for extracting jack fruit aromatherapy oil from ionic liquids, which belongs to the technical field of aromatherapy oil. The method comprises the following steps: weighing 50-100 parts of jack fruit pulp, pulping at -30 to -10 DEG C by a low-temperature liquid nitrogen pulping technique so as to obtain a jack fruit pulp liquid to ensure that the fragrance ingredients in the jack fruit are effectively prevented from volatilization loss, uniformly mixing the jack fruit pulp liquid with 20-40 parts of 1-ethyl-3-methylimidazole hexafluorophosphate ([Bmin]PF6), putting the mixture into an extraction liquid, extracting jack fruit volatile oil under the microwave power of 100-500 W and at 100-170 DEG C, condensing and recycling the volatile oil by an extractor for 30-50 minutes till that the volatile oil is completely extracted, collecting the volatile oil, drying by anhydrous sodium sulfate, and sealing, refrigerating and storing the volatile oil at 0-5 DEG C. The extraction method is high in extraction rate, the extracted medium ionic liquids can be recycled and circulated, and the method has environment-friendly and non-pollution effects and is applicable to industrial production.
Description
Technical field
The present invention relates to a kind of method with ionic liquid extract Fructus Artocarpi Heterophylli champignon oil, be specifically related to a kind of extraction yield high, extract medium ionic liquid recyclable, environment friendly and pollution-free, be applicable to the method for the extraction champignon oil of suitability for industrialized production, be a kind of novel Fructus Artocarpi Heterophylli champignon oil extracting method, belong to champignon oil extractive technique field.
Background technology
Volatile oil claims again essential oil, champignon oil, is a kind of activeconstituents being prevalent in plant, and component is comparatively complicated, and the comfortable beauty treatment of its energy, loosens decompression.By massage, suction, hot compress, immersion, steaming, smoke, volatile oil is incorporated in blood of human body and lymph liquid fast, can acceleration bodies intracellular metabolic, promote viable cell regeneration, strengthen body immunity, and then mediator's somatic nervous system, the recycle system, endocrine system, muscle tissue, Digestive tract and Excretory system etc.
The extraction of tradition champignon oil adopts the preparation of organic solvent high temperature extraction mostly, and the method extraction yield is not high, need to consume a large amount of organic solvents, and production cost is high, and organic solvent is difficult to recycle, to environment.At present, cause the upsurge that one adopts ionic liquid extract effective constituent abroad.
Ionic liquid (Ionic Liquid) claims again room temperature fused salt (Room Temperature Molten Salt), refer to the liquid being formed by yin, yang ion completely under room temperature or nearly room temperature, generally by specific, volume is relatively large, the asymmetric organic cation of structure and the relatively little inorganic anion of volume form [fgl.In ionic compound, the reactive force between zwitterion is Coulomb's force, and its size is relevant with amount of charge and the radius of zwitterion, and ionic radius is larger, and the reactive force between them is less, to such an extent as to fusing point approaches room temperature.Because many conventional solvent that ionic liquid itself has advantages of are incomparable, can set it as green solvent and be applied to extracts active ingredients.Utilize ionic liquid extract volatile oil, can avoid conventional organic solvents extraction method extraction yield low, cost is high, and high temperature destroys the shortcoming of aroma component.Therefore it is very significant, adopting ionic liquid extract champignon oil.
Fructus Artocarpi Heterophylli (formal name used at school: Artocarpus heterophyllus), in Guangzhou, Hong Kong, Macao and other Guangdong language areas, Jack-fruit is commonly referred to as large artocarpus heterophyllus, on Guangxi and other places, is called Fructus Artocarpi Heterophylli, is that Moraceae Jack-fruit belongs to aiphyllium.Fructus Artocarpi Heterophylli is described as " tropical fruit queen ", is the heaviest in the world fruit, the plump softness of pulp, sweet and sour palatability, aromatic flavour. and there is multiple processing characteristics and pharmacological action, be therefore subject to many people's favor.In Fructus Artocarpi Heterophylli, contain abundant carbohydrate, protein, B1, B2, B6. vitamins C, mineral substance, fatty wet goods.In Fructus Artocarpi Heterophylli pulp, content of calcium and magnesium is high especially, and also containing beneficial elements such as more zinc, iron, sodium, manganese, and the harmful element content such as cadmium, lead, arsenic are very low same.Fructus Artocarpi Heterophylli is also rich in organic composition, carbohydrate containing 16.0%, 25.4%, protein 1.2%～1.9%, fat 0.1% ~ 0.4%, fiber 1.0%～1.5% in pulp.Fructus Artocarpi Heterophylli, containing unique aroma component, is the desirable feedstock that the present invention adopts.
China Patent Publication No.: CN1428408A discloses a kind of natural New method for extracting jasmine oil, the method at room temperature, without any solvent treatment process, with damp atmosphere, blow over the fresh Flower of Arabian Jasmine of layering placement, take the fragrance ingredient that Flower of Arabian Jasmine is distributed out of, and with special adsorbent trapping, then with supercritical carbon dioxide extraction, reclaim essential oil in sorbent material.The method needs a large amount of damp atmospheres to blow Flower of Arabian Jasmine, and power consumption is large, and depends merely on air and blow aroma component, and the aroma component amount that sorbent material is collected is fewer, and yield is low, and essential oil cost prepared by the method is high.
The invention provides a kind of ionic liquid extract Fructus Artocarpi Heterophylli champignon oil, the recycling capable of circulation of this ionic liquid, environmental protection, environment is not worked the mischief, this extracting method champignon oil yield is high, is applicable to large-scale industrialization and produces, and this ionic liquid extract Fructus Artocarpi Heterophylli champignon oil patent has not yet to see at home.
Summary of the invention
The object of this invention is to provide a kind of method with ionic liquid extract Fructus Artocarpi Heterophylli champignon oil; This this extracting method extraction yield is high, extracts medium ionic liquid recyclable, environment friendly and pollution-free, is applicable to suitability for industrialized production.
In order to address the above problem, the technical solution adopted in the present invention is:
A kind of method with ionic liquid extract Fructus Artocarpi Heterophylli champignon oil:
Take 50-100 part Fructus Artocarpi Heterophylli pulp, utilize low temperature liquid nitrogen making beating technology, under-30--10 ℃ of conditions, pull an oar, obtain Fructus Artocarpi Heterophylli slurries, effectively prevent Fructus Artocarpi Heterophylli fragrance ingredient volatilization loss, by Fructus Artocarpi Heterophylli slurries and 20-40 part 1-base-3-Methylimidazole hexafluorophosphate ([Bmim] PF
6) mix, put into extraction flask, at microwave power 100-500W, under temperature 100-170 ℃ of condition, extract Fructus Artocarpi Heterophylli volatile oil, volatile oil reclaims through extractor condensation, and extraction time is 30-50min, guarantees that volatile oil extracts completely, accept volatile oil and use anhydrous sodium sulfate drying, 0-5 ℃ of lower seal stored refrigerated;
The present invention with respect to the beneficial effect of prior art is:
1. the present invention adopts liquid nitrogen making beating technology to the making beating of Fructus Artocarpi Heterophylli pulp, keeps to greatest extent the aroma component of Fructus Artocarpi Heterophylli, prevents the volatilization loss of its effective constituent, improves product recovery utilization rate, saves production cost;
2. the present invention adopts ionic liquid extract Fructus Artocarpi Heterophylli champignon oil, ionic liquid is as the novel extraction medium of one, there is recycle, it is convenient to reclaim, environmental protection feature, ionic liquid extract method not only can improve the extraction yield of champignon oil, can also keep to greatest extent the aroma component of Fructus Artocarpi Heterophylli, improves the quality of products.
3. the present invention extracts champignon oil method, and technique is simple, and convenient operation is applicable to large-scale industrialization and produces.
Embodiment
Below by embodiment, the present invention is described in further details, these embodiment are only used for illustrating the present invention, do not limit the scope of the invention.
Embodiment 1
A kind of method with ionic liquid extract Fructus Artocarpi Heterophylli champignon oil:
Take 80 parts of Fructus Artocarpi Heterophylli pulp, utilize low temperature liquid nitrogen making beating technology, under-20 ℃ of conditions, pull an oar, obtain Fructus Artocarpi Heterophylli slurries, effectively prevent Fructus Artocarpi Heterophylli fragrance ingredient volatilization loss, by Fructus Artocarpi Heterophylli slurries and 25 parts of 1-base-3-Methylimidazole hexafluorophosphate ([Bmim] PF
6) mix, put into extraction flask, at microwave power 120W, under 100 ℃ of conditions of temperature, extract Fructus Artocarpi Heterophylli volatile oil, volatile oil reclaims through extractor condensation, and extraction time is 48min, guarantee that volatile oil extracts completely, accept volatile oil and use anhydrous sodium sulfate drying, 1 ℃ of lower seal stored refrigerated.
Embodiment 2
A kind of method with ionic liquid extract Fructus Artocarpi Heterophylli champignon oil:
Take 90 parts of Fructus Artocarpi Heterophylli pulp, utilize low temperature liquid nitrogen making beating technology, under-30 ℃ of conditions, pull an oar, obtain Fructus Artocarpi Heterophylli slurries, effectively prevent Fructus Artocarpi Heterophylli fragrance ingredient volatilization loss, by Fructus Artocarpi Heterophylli slurries and 35 parts of 1-base-3-Methylimidazole hexafluorophosphate ([Bmim] PF
6) mix, put into extraction flask, at microwave power 150W, under 130 ℃ of conditions of temperature, extract Fructus Artocarpi Heterophylli volatile oil, volatile oil reclaims through extractor condensation, and extraction time is 35min, guarantee that volatile oil extracts completely, accept volatile oil and use anhydrous sodium sulfate drying, 0 ℃ of lower seal stored refrigerated.
Embodiment 3
A kind of method with ionic liquid extract Fructus Artocarpi Heterophylli champignon oil:
Take 50 parts of Fructus Artocarpi Heterophylli pulp, utilize low temperature liquid nitrogen making beating technology, under-17 ℃ of conditions, pull an oar, obtain Fructus Artocarpi Heterophylli slurries, effectively prevent Fructus Artocarpi Heterophylli fragrance ingredient volatilization loss, by Fructus Artocarpi Heterophylli slurries and 21 parts of 1-base-3-Methylimidazole hexafluorophosphate ([Bmim] PF
6) mix, put into extraction flask, at microwave power 140W, under 150 ℃ of conditions of temperature, extract Fructus Artocarpi Heterophylli volatile oil, volatile oil reclaims through extractor condensation, and extraction time is 45min, guarantee that volatile oil extracts completely, accept volatile oil and use anhydrous sodium sulfate drying, 3 ℃ of lower seal stored refrigerated.
Embodiment 4
A kind of method with ionic liquid extract Fructus Artocarpi Heterophylli champignon oil:
Take 100 parts of Fructus Artocarpi Heterophylli pulp, utilize low temperature liquid nitrogen making beating technology, under-30 ℃ of conditions, pull an oar, obtain Fructus Artocarpi Heterophylli slurries, effectively prevent Fructus Artocarpi Heterophylli fragrance ingredient volatilization loss, by Fructus Artocarpi Heterophylli slurries and 30 parts of 1-base-3-Methylimidazole hexafluorophosphate ([Bmim] PF
6) mix, put into extraction flask, at microwave power 400W, under 140 ℃ of conditions of temperature, extract Fructus Artocarpi Heterophylli volatile oil, volatile oil reclaims through extractor condensation, and extraction time is 40min, guarantee that volatile oil extracts completely, accept volatile oil and use anhydrous sodium sulfate drying, 4 ℃ of lower seal stored refrigerated.
Embodiment 5
A kind of method with ionic liquid extract Fructus Artocarpi Heterophylli champignon oil:
Take 80 parts of Fructus Artocarpi Heterophylli pulp, utilize low temperature liquid nitrogen making beating technology, under-20 ℃ of conditions, pull an oar, obtain Fructus Artocarpi Heterophylli slurries, effectively prevent Fructus Artocarpi Heterophylli fragrance ingredient volatilization loss, by Fructus Artocarpi Heterophylli slurries and 30 parts of 1-base-3-Methylimidazole hexafluorophosphate ([Bmim] PF
6) mix, put into extraction flask, at microwave power 340W, under 120 ℃ of conditions of temperature, extract Fructus Artocarpi Heterophylli volatile oil, volatile oil reclaims through extractor condensation, and extraction time is 40min, guarantee that volatile oil extracts completely, accept volatile oil and use anhydrous sodium sulfate drying, 4 ℃ of lower seal stored refrigerated.
Claims (5)
1. by a method for ionic liquid extract Fructus Artocarpi Heterophylli champignon oil, it is characterized in that: comprise the steps:
Take 50-100 part Fructus Artocarpi Heterophylli pulp, utilize the making beating of low temperature liquid nitrogen methods of beating, obtain Fructus Artocarpi Heterophylli slurries, effectively prevent Fructus Artocarpi Heterophylli fragrance ingredient volatilization loss, by Fructus Artocarpi Heterophylli slurries and 20-40 part 1-base-3-Methylimidazole hexafluorophosphate [Bmim] PF
6mix, put into extraction flask, microwave-assisted extracts Fructus Artocarpi Heterophylli volatile oil, volatile oil reclaims through extractor condensation, and extraction time is 30-50min, guarantees that volatile oil extracts completely, receive volatile oil and use anhydrous sodium sulfate drying, 0-5 ℃ of lower seal stored refrigerated.
2. a kind of method with ionic liquid extract Fructus Artocarpi Heterophylli champignon oil according to claim 1, is characterized in that: described liquid nitrogen conditions of beating is-30 ~-10 ℃.
3. a kind of method with ionic liquid extract Fructus Artocarpi Heterophylli champignon oil according to claim 1, is characterized in that: described Fructus Artocarpi Heterophylli slurry and 1-base-3-Methylimidazole hexafluorophosphate [Bmim] PF
6ratio be 1:1.2 ~ 1:5.
4. a kind of method with ionic liquid extract Fructus Artocarpi Heterophylli champignon oil according to claim 1, is characterized in that: described microwave extraction condition is microwave power 100-500W, temperature 100-170 ℃.
5. a kind of method with ionic liquid extract Fructus Artocarpi Heterophylli champignon oil according to claim 1, is characterized in that: the method is applicable to the orange, the pineapple that contain fragrant volatile oil.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104450185A (en) * | 2014-10-27 | 2015-03-25 | 茂名市德威圣科技有限责任公司 | Method for extracting and preparing passion fruit flavor |
| CN105176673A (en) * | 2015-10-22 | 2015-12-23 | 河南行知专利服务有限公司 | Method for extracting fat oil in croton by using ionic liquid |
| CN108485818A (en) * | 2018-05-25 | 2018-09-04 | 西南石油大学 | A kind of method of microwave radiation technology ionic liquid extract kitchen garbage solid phase waste oil |
| CN108671582A (en) * | 2018-06-21 | 2018-10-19 | 东北林业大学 | Method that is a kind of while extracting Fructus Schisandrae Polysaccharide and Schisandra chinensis essential oil |
| CN108977279A (en) * | 2018-07-25 | 2018-12-11 | 鹰潭中投科技有限公司 | It can be reduced the extracting method of fragrance diffusion |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104450185A (en) * | 2014-10-27 | 2015-03-25 | 茂名市德威圣科技有限责任公司 | Method for extracting and preparing passion fruit flavor |
| CN105176673A (en) * | 2015-10-22 | 2015-12-23 | 河南行知专利服务有限公司 | Method for extracting fat oil in croton by using ionic liquid |
| CN108485818A (en) * | 2018-05-25 | 2018-09-04 | 西南石油大学 | A kind of method of microwave radiation technology ionic liquid extract kitchen garbage solid phase waste oil |
| CN108671582A (en) * | 2018-06-21 | 2018-10-19 | 东北林业大学 | Method that is a kind of while extracting Fructus Schisandrae Polysaccharide and Schisandra chinensis essential oil |
| CN108977279A (en) * | 2018-07-25 | 2018-12-11 | 鹰潭中投科技有限公司 | It can be reduced the extracting method of fragrance diffusion |
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Application publication date: 20140416 |