CN103725072B - A kind of promote pigment dyestuff be scattered in water-borne coatings band rust antirusting powder preparation method - Google Patents
A kind of promote pigment dyestuff be scattered in water-borne coatings band rust antirusting powder preparation method Download PDFInfo
- Publication number
- CN103725072B CN103725072B CN201210389165.3A CN201210389165A CN103725072B CN 103725072 B CN103725072 B CN 103725072B CN 201210389165 A CN201210389165 A CN 201210389165A CN 103725072 B CN103725072 B CN 103725072B
- Authority
- CN
- China
- Prior art keywords
- powder
- rust
- water
- antirusting
- band rust
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000843 powder Substances 0.000 title claims abstract description 55
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 239000000049 pigment Substances 0.000 title claims abstract description 16
- 238000000576 coating method Methods 0.000 title claims abstract description 13
- 239000000975 dye Substances 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title claims abstract description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 239000013008 thixotropic agent Substances 0.000 claims abstract description 13
- 229910052742 iron Inorganic materials 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims abstract description 10
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 7
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 13
- -1 hexafluorophosphoric acid calcium Chemical compound 0.000 claims description 12
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 6
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 6
- 239000003973 paint Substances 0.000 abstract description 17
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 5
- GFIKIVSYJDVOOZ-UHFFFAOYSA-L calcium;fluoro-dioxido-oxo-$l^{5}-phosphane Chemical compound [Ca+2].[O-]P([O-])(F)=O GFIKIVSYJDVOOZ-UHFFFAOYSA-L 0.000 abstract description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 2
- 238000004040 coloring Methods 0.000 abstract description 2
- 238000012986 modification Methods 0.000 abstract description 2
- 230000004048 modification Effects 0.000 abstract description 2
- 239000011574 phosphorus Substances 0.000 abstract description 2
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000003801 milling Methods 0.000 description 4
- 230000002265 prevention Effects 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000002401 inhibitory effect Effects 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000002131 composite material Substances 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- IXQWNVPHFNLUGD-UHFFFAOYSA-N iron titanium Chemical compound [Ti].[Fe] IXQWNVPHFNLUGD-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 241000276489 Merlangius merlangus Species 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229960004756 ethanol Drugs 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- 239000001053 orange pigment Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
The present invention relates to a kind of preparation method that pigment dyestuff is scattered in the band rust antirusting powder in water-borne coatings that promotes, to be rich in the phosphorus fine ore of calcium monofluorophosphate for carrier, with B216 thixotropic agent for properties-correcting agent, add iron rust changing agent D117, nano silicon and nano titanium oxide again, by certain modified technique, modification is carried out to calcium monofluorophosphate powder, prepare rust antirusting powder.Its advantage is: organic coloring pigments can be made to be evenly dispersed in water-miscible paint and do not occur flooding phenomenon, has both had band rust antirust function, can be applicable to again in oiliness, aqueous antirust paint.
Description
Technical field
The present invention relates to a kind of rust-inhibiting paint technical field, specifically a kind of with colored and have band rust antirust function, be not only applicable to oiliness (paint) but also be applicable to the antirusting powder of water-based (paint).
Background technology
As everyone knows, many pigment dyestuffs are directly used in aqueous industrial protective system, all there is dispersed bad problem, this is because when producing in coating, these organism are incompatible with water.As when producing " water-based lead free red lead rust-inhibiting paint ", just there is such problem in use red and the forever solid orange pigment dyestuff that waits.Rust-stabilising pigment composite iron-titanium powder mainly contains antirust function, but can not promote the dispersion of pigment dyestuff in water-based anticorrosive paint.Therefore, for a long time, in this technology kind that composite iron-titanium powder just can only be used for can not being used for water-miscible paint in solvent-thinned paint does not also have " band rust is antirust ".
Summary of the invention
The object of the invention is development one and can promote that pigment dyestuff is well-dispersed in water-based system coating, there is again band rust antirust function, and the antirusting powder in oiliness, aqueous antirust paint can be applicable to.
The present invention is a kind of promotes that the preparation method of the band rust antirusting powder that pigment dyestuff is scattered in water-borne coatings is realized by following scheme:
To be rich in the natural phosphorus fine ore of calcium monofluorophosphate for carrier, be properties-correcting agent with B216 thixotropic agent (production of Wuhan Shuo Li get scientific & technical corporation), carry out modification to hexafluorophosphoric acid calcium powder: be sprayed on hexafluorophosphoric acid calcium powder by the B216 thixotropic agent after diluting (1:1) with dehydrated alcohol, pulverizing in pulverizer and mixing (ethanol automatically volatilizees in milling process) B216 consumption is simultaneously 2% of calcium monofluorophosphate total amount.In the end pulverize in milling process and add iron rust changing agent D117 and a small amount of nano silicon oxide and nano-titanium oxide in order, obtain band rust antirusting powder.
The present invention is a kind of promotes that pigment dyestuff is scattered in the band rust antirusting powder in water-borne coatings: its method is:
(1) the composition weight percent of band rust antirusting powder is:
(2) thixotropic agent B216 and iron rust changing agent D117 is pressed 1:1 with dehydrated alcohol respectively to dilute;
(3) according to the above ratio hexafluorophosphoric acid calcium powder (moisture is less than 1%) is added in powder modifying machine, start powder modifying machine and stir hexafluorophosphoric acid calcium powder 7 ~ 9min, powder is heated up;
(4) by said ratio and thixotropic agent B216 premix, then under temperature is 80-110 DEG C of condition, by modifying machine (1400 revs/min) stirring 10 ~ 15min at a high speed;
(5) according to the above ratio, successively add iron rust changing agent D117, nano silicon oxide and nano-titanium oxide, (1400 revs/min) stir 10 ~ 30min mixing at a high speed finally; Pulverize together with pulverizer again; In the process, dehydrated alcohol all volatilizees, and prepares the antirust powder of band rust; Smashing fineness >=500 order.
The present invention is a kind of promotes the preparation method that pigment dyestuff is scattered in the band rust antirusting powder in water-borne coatings, its advantage is: organic coloring pigments can be made to be evenly dispersed in water-miscible paint and do not occur flooding phenomenon, both there is band rust antirust function, can be applicable to again in oiliness, aqueous antirust paint.
Embodiment
Embodiment one:
The present invention is a kind of promotes that pigment dyestuff is scattered in the band rust antirusting powder in water-borne coatings: its method is:
(1) the composition weight percent of band rust antirusting powder is:
(2) thixotropic agent B216 and iron rust changing agent D117 is pressed 1:1 with dehydrated alcohol respectively to dilute;
(3) according to the above ratio hexafluorophosphoric acid calcium powder (moisture is less than 1%) is added in powder modifying machine, start powder modifying machine and stir hexafluorophosphoric acid calcium powder 7 ~ 9min, powder is heated up;
(4) by said ratio and thixotropic agent B216 premix, then under temperature is 80-110 DEG C of condition, by modifying machine (1400 revs/min) stirring 10 ~ 15min at a high speed;
(5) according to the above ratio, successively add iron rust changing agent D117, nano silicon oxide and nano-titanium oxide, (1400 revs/min) stir 10 ~ 30min mixing at a high speed finally; Pulverize together with pulverizer again; In the process, dehydrated alcohol all volatilizees, and prepares the antirust powder of band rust; Smashing fineness >=500 order.
Embodiment two
The present invention is a kind of promotes that pigment dyestuff is scattered in the band rust antirusting powder in water-borne coatings: its method is:
(1) the composition weight percent of band rust antirusting powder is:
(2) thixotropic agent B216 and iron rust changing agent D117 is pressed 1:1 with dehydrated alcohol respectively to dilute;
(3) according to the above ratio hexafluorophosphoric acid calcium powder (moisture is less than 1%) is added in powder modifying machine, start powder modifying machine and stir hexafluorophosphoric acid calcium powder 7 ~ 9min, powder is heated up;
(4) by said ratio and thixotropic agent B216 premix, then under temperature is 80-110 DEG C of condition, by modifying machine (1400 revs/min) stirring 10 ~ 15min at a high speed;
(5) according to the above ratio, successively add iron rust changing agent D117, nano silicon oxide and nano-titanium oxide, (1400 revs/min) stir 10 ~ 30min mixing at a high speed finally; Pulverize together with pulverizer again; In the process, dehydrated alcohol all volatilizees, and prepares the antirust powder of band rust; Smashing fineness >=500 order.
Embodiment three
The present invention is a kind of promotes that pigment dyestuff is scattered in the band rust antirusting powder in water-borne coatings: its method is:
(1) the composition weight percent of band rust antirusting powder is:
(2) thixotropic agent B216 and iron rust changing agent D117 is pressed 1:1 with dehydrated alcohol respectively to dilute;
(3) according to the above ratio hexafluorophosphoric acid calcium powder (moisture is less than 1%) is added in powder modifying machine, start powder modifying machine and stir hexafluorophosphoric acid calcium powder 7 ~ 9min, powder is heated up;
(4) by said ratio and thixotropic agent B216 premix, then under temperature is 80-110 DEG C of condition, by modifying machine (1400 revs/min) stirring 10 ~ 15min at a high speed;
(5) according to the above ratio, successively add iron rust changing agent D117, nano silicon oxide and nano-titanium oxide, (1400 revs/min) stir 10 ~ 30min mixing at a high speed finally; Pulverize together with pulverizer again; In the process, dehydrated alcohol all volatilizees, and prepares the antirust powder of band rust; Smashing fineness >=500 order.
Here is the embodiment making the rust-inhibiting paint of band rust of band rust antirusting powder:
Example one:
Water-based bottom surface unification orange conversion and prevention paint of rust, its percentage composition is:
| Title | Consumption (unit: %) |
| Emulsion 1001-A | 60 |
| Band rust antirusting powder | 13.2 |
| Titanium dioxide | 4.8 |
| Coarse whiting | 12 |
| Red | 1.2 |
| Forever solid orange | 1.8 |
| Anti-sudden strain of a muscle rust agent ZT708 | 0.5 |
| Defoamer 090 | 0.2 |
| Water | 6.3 |
Above-mentioned component obtains water-based lead free red lead (orange) conversion and prevention paint of rust through coating sand mill sand milling, and its salient features is as follows after testing:
Example two:
Pale blue bottom surface unification conversion and prevention paint of rust, its percentage composition is:
| Title | Consumption (unit: %) |
| Emulsion 1001-A | 64 |
| Band rust antirusting powder | 14.9 |
| Titanium dioxide | 8.6 |
| Lemon yellow | 1.7 |
| Pthalocyanine blue | 0.4 |
| Defoamer 090 | 0.4 |
| Water | 10 |
Above component is through sand milling, and obtain the unification of pale blue bottom surface conversion and prevention paint of rust, after testing its salient features, except gloss reaches 68, other technologies index is identical with embodiment two.In addition, the old rust on test plate (panel) can be transformed.
Claims (1)
1. promote that pigment dyestuff is scattered in a preparation method for the band rust antirusting powder in water-borne coatings, it is characterized in that:
(1) the composition weight percent of band rust antirusting powder is:
Component total weight percent is absolutely
(2) thixotropic agent B216 and iron rust changing agent D117 is pressed 1:1 with dehydrated alcohol respectively to dilute, by weight percentage;
(3) according to the above ratio natural hexafluorophosphoric acid calcium powder is added in powder modifying machine, start powder modifying machine and stir natural hexafluorophosphoric acid calcium powder 7 ~ 9min, powder is heated up;
(4) by said ratio and thixotropic agent B216 premix, then under temperature is 80-110 DEG C of condition, modifying machine is stirred 10 ~ 15min with the speed of 1400 revs/min;
(5) according to the above ratio, successively add iron rust changing agent D117, nano silicon oxide and nano-titanium oxide finally, stir 10 ~ 30min mixing with the speed of 1400 revs/min; Pulverize together with pulverizer again; In the process, dehydrated alcohol all volatilizees, and prepares the antirust powder of band rust; Smashing fineness >=500 order.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210389165.3A CN103725072B (en) | 2012-10-15 | 2012-10-15 | A kind of promote pigment dyestuff be scattered in water-borne coatings band rust antirusting powder preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210389165.3A CN103725072B (en) | 2012-10-15 | 2012-10-15 | A kind of promote pigment dyestuff be scattered in water-borne coatings band rust antirusting powder preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103725072A CN103725072A (en) | 2014-04-16 |
| CN103725072B true CN103725072B (en) | 2016-03-02 |
Family
ID=50449380
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210389165.3A Active CN103725072B (en) | 2012-10-15 | 2012-10-15 | A kind of promote pigment dyestuff be scattered in water-borne coatings band rust antirusting powder preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103725072B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104073053A (en) * | 2014-06-15 | 2014-10-01 | 安徽奥邦新材料有限公司 | Novel orange antirust composite pigment and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101182398A (en) * | 2006-11-14 | 2008-05-21 | 武汉市大汉科技发展有限公司 | Fluorapatite long-acting precoated primer |
| CN101182417A (en) * | 2006-11-14 | 2008-05-21 | 武汉市大汉科技发展有限公司 | Calcium monofluorophosphate rust-proofing powder |
| CN101182396A (en) * | 2006-11-14 | 2008-05-21 | 武汉市大汉科技发展有限公司 | Fluorapatite fluorine-carbon rust-inhibiting paint |
| CN101182397A (en) * | 2006-11-14 | 2008-05-21 | 武汉市大汉科技发展有限公司 | Fluorapatite acrylic rust-inhibiting paint |
| CN101182400A (en) * | 2006-11-14 | 2008-05-21 | 武汉市大汉科技发展有限公司 | Fluorapatite alkyd rust-inhibiting paint |
-
2012
- 2012-10-15 CN CN201210389165.3A patent/CN103725072B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101182398A (en) * | 2006-11-14 | 2008-05-21 | 武汉市大汉科技发展有限公司 | Fluorapatite long-acting precoated primer |
| CN101182417A (en) * | 2006-11-14 | 2008-05-21 | 武汉市大汉科技发展有限公司 | Calcium monofluorophosphate rust-proofing powder |
| CN101182396A (en) * | 2006-11-14 | 2008-05-21 | 武汉市大汉科技发展有限公司 | Fluorapatite fluorine-carbon rust-inhibiting paint |
| CN101182397A (en) * | 2006-11-14 | 2008-05-21 | 武汉市大汉科技发展有限公司 | Fluorapatite acrylic rust-inhibiting paint |
| CN101182400A (en) * | 2006-11-14 | 2008-05-21 | 武汉市大汉科技发展有限公司 | Fluorapatite alkyd rust-inhibiting paint |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103725072A (en) | 2014-04-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103468077B (en) | A kind of steel construction use rust-inhibiting paint and production technique thereof | |
| CN103468092B (en) | A kind of aqueous coating for engineering goods surface | |
| CN106833299A (en) | A kind of single-component water-based container intermediate coat and its preparation technology | |
| CN103305062A (en) | Environment-friendly general color paste and preparation method thereof | |
| CN107841234A (en) | A kind of silicon-modified epoxy acrylic acid allochroic paint and preparation method thereof | |
| CN103725072B (en) | A kind of promote pigment dyestuff be scattered in water-borne coatings band rust antirusting powder preparation method | |
| CN104277609A (en) | Heat insulation, sterilization and waterproof coating and preparation method thereof | |
| CN103342939A (en) | Water-soluble epoxy ester antirust paint | |
| CN103572617A (en) | Water-based anti-settling non-laminated fluorescent pigment paste | |
| CN102876156A (en) | Low-cost high-temperature-resistant coating | |
| CN102746789A (en) | High temperature resistant low temperature quick-drying hammer paint | |
| CN109749522B (en) | Cation color paste and preparation method thereof | |
| CN105348866A (en) | Iron oxide red pigment for compound paint and preparation method thereof | |
| CN103541272A (en) | Waterproof coating for carton box | |
| CN104277656A (en) | Synthesis process of water-soluble phenolic resin antirust coating | |
| CN109517459A (en) | A kind of preparation method from dry acrylic acid anti-corrosion reflective heat-insulation paint | |
| CN102101956A (en) | Preparation method of low-carbon light reflecting energy-saving coating | |
| CN105348916B (en) | A kind of polymolecularity high thixotropic Neutral writing ink and preparation method thereof | |
| CN104194491A (en) | Method for preparing novel aqueous ink | |
| CN105505011B (en) | Preparation method of aqueous environment-friendly nano color paste for synthetic leather coating | |
| CN103819939A (en) | Iron oxide red pigment containing wool fat | |
| CN103232761A (en) | High-stability neutral ink | |
| CN103666094B (en) | A kind of printing-ink and its preparation method | |
| CN103289435B (en) | A kind of liquid crystal display pigment derivative and manufacture method thereof | |
| CN104194487A (en) | Novel aqueous ink |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170519 Address after: Lake Management District 433115 Hubei city of Qianjiang province after the Han Yi Lake Industrial Park No. 1 high iron Patentee after: Hubei branch of Sino new Mstar Technology Ltd. Address before: 430043 Hubei Province in Qiaokou District of Wuhan city Gutian five road No. 17, room 216 Patentee before: Hubei Zhongke Boze New Materials Research Institute |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20210409 Address after: No.c7-7, building 16, enterprise accelerator, No.23, Changchun Road, high tech Industrial Development Zone, Zhengzhou City, Henan Province, 450000 Patentee after: Zhengzhou Qishan new material technology Research Institute Address before: No.1 South of Hanyi high speed railway, Houhu Industrial Park, Houhu management zone, Qianjiang City, Hubei Province, 433115 Patentee before: Hubei branch of Sino new Mstar Technology Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20220308 Address after: 450000 56 duqin street, Mazhai Town, Erqi District, Zhengzhou City, Henan Province Patentee after: Zhengzhou Qishan anti corrosion protection new material Technology Research Institute Co.,Ltd. Address before: No.c7-7, building 16, enterprise accelerator, No.23, Changchun Road, high tech Industrial Development Zone, Zhengzhou City, Henan Province, 450000 Patentee before: Zhengzhou Qishan new material technology Research Institute |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20221221 Address after: 476600 320 meters north of the intersection of Xishan Road and South Outer Ring Road, Yongcheng Industrial Cluster District, Shangqiu City, Henan Province Patentee after: Yongcheng Qingshan Environmental Protection Technology Co.,Ltd. Address before: 450000 56 duqin street, Mazhai Town, Erqi District, Zhengzhou City, Henan Province Patentee before: Zhengzhou Qishan anti corrosion protection new material Technology Research Institute Co.,Ltd. |
|
| TR01 | Transfer of patent right |