CN103710974B - A kind of preparation method of fabric dedicated optical solidification phosphate purification of air finishing agent - Google Patents
A kind of preparation method of fabric dedicated optical solidification phosphate purification of air finishing agent Download PDFInfo
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- CN103710974B CN103710974B CN201310724182.2A CN201310724182A CN103710974B CN 103710974 B CN103710974 B CN 103710974B CN 201310724182 A CN201310724182 A CN 201310724182A CN 103710974 B CN103710974 B CN 103710974B
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Abstract
The present invention relates to the preparation method of a kind of fabric dedicated optical solidification phosphate purification of air finishing agent, comprising: be deionized water, biological surface activating agent, cage modle polyhedral oligomeric silsesquioxane, the anatase type nano BiPO of 1: 0.01-0.05: 0.05-0.15: 0.02-0.1: 0.001-0.003 by mass ratio
4particle and silver nitrate mixing, add ammoniacal liquor after stirring, be obtained by reacting functional response liquid; Heated up by above-mentioned functions reactant liquor, be added dropwise to urethane acrylate monomer pre-emulsification, cooling, adds sodium azide and propylene glycol block polyether, and be heated to 60 DEG C of reaction 2-4 hour, adjust ph to 7 ~ 8, to obtain final product.Finishing agent of the present invention has good dispersion stabilization, and application has good air purification effect on the textile; And preparation method is simple, is suitable for suitability for industrialized production.
Description
Technical field
The invention belongs to the preparation field of purification of air finishing agent, particularly a kind of preparation method of fabric dedicated optical solidification phosphate purification of air finishing agent.
Background technology
According to WHO Report, the whole world causes 1,600,000 people dead due to room air pollution every year, on average within every 20 seconds, just has 1 people dead.The death toll that exceeds the quata that the annual room air pollution of China causes has reached 11.1 ten thousand people, and the emergency treatment number that exceeds the quata reaches 4,300,000 person-times, and direct and indirect economic loss reaches 10,700,000,000 dollars.
In recent years, photocatalysis technology and the continuous Cross slot interference of Techniques for Indoor Air Purification, photocatalytic method administers room air technology can not produce the particular advantages such as poisonous, harmful intermediate product owing to having in good purification, simple to operate, processing procedure, and at home and abroad room air deep purifying field obtains and applies in large quantities.Because nano-photocatalyst particle is minimum, after when high velocity flow of process air, easily cause dust pollution, need to be carried on certain carrier or preparation film forming.Load carriers is divided into inorganic carrier and organic carrier.Although inorganic carrier can solve the problem of nano titanium dioxide photocatalyst load, because its use is inconvenient, long-lasting catalytic uses the problems such as easy poison deactivation to be difficult to solve, have a strong impact on its serviceability.In order to solve the problem, start photocatalyst both at home and abroad to the research on fiber base material, breach the restriction that nano-photocatalyst support materials is confined to the inorganic material such as pottery, glass and metal for a long time, and utilize porous and the capillary performance of fibrous material, make fiber surface adsorption and enrichment pollutant, for nano-photocatalyst provides high concentration reactant environment, this accelerates photocatalytic degradation reaction rate to a great extent.The suction-operated of this outer fiber also may make photocatalytic degradation react issuable intermediate by-products to be adsorbed when generating and be further oxided and be degraded to simple inorganic matter, as carbon dioxide and water.Such fiber can not only condensed gaseous pollutant, acceleration photocatalytic degradation reacts, and can reduce intermediate by-products, timely releasing product, continuous propelling degradation reaction, this is to photocatalysis technology being applied to indoor air purification and pollution abatement thing is in demand.Research is fewer both at home and abroad at present, processing due to textiles is be processed as master with hygrometric state mostly, and current processing method has padding method, low-temperature in-site method and coating, wherein pad method due to technique simple, can continuous prodution, become the main method preparing air purified functional textile.And padding method key is the purification of air finishing agent needing to prepare stability and high efficiency, and rarer people studies this technology both at home and abroad.On seminar's early-stage Study basis, for the current situation of current air-cleaning function finishing agent, the present inventor's creativeness has prepared photocuring air-cleaning function finishing agent, high, active high, the Green-pollution of the finishing agent stability of preparation, and do not need hot setting, under light illumination just can crosslinking curing, reach the object of energy-saving and emission-reduction.
Summary of the invention
Technical problem to be solved by this invention is to provide the preparation method of a kind of fabric dedicated optical solidification phosphate purification of air finishing agent, and the method is simple, cost is low, non-secondary pollution, is easy to suitability for industrialized production.
The preparation method of a kind of fabric dedicated optical solidification phosphate purification of air finishing agent of the present invention, comprising:
(1) by mass ratio be the mixing of the deionized water of 1:0.01-0.05:0.05-0.15:0.02-0.1:0.001-0.003, biological surface activating agent, cage modle polyhedral oligomeric silsesquioxane, anatase type nano BiPO4 particle and silver nitrate, add ammoniacal liquor after stirring and regulate pH9-11, be obtained by reacting functional response liquid;
(2) above-mentioned functions reactant liquor is heated up, urethane acrylate monomer pre-emulsification 30-60min is added dropwise to while intensification, cooling, add sodium azide and propylene glycol block polyether, be heated to 60 DEG C of reaction 2-4 hour, adjust ph to 7 ~ 8, obtain fabric dedicated optical solidification phosphate purification of air finishing agent.
In described step (1), biological surface activating agent is the one in living beings glycosyl surfactant active, living beings cardanol sulfonate surfactant, the two carboxylate gemini surfactant of abietyl.
In described step (1), stir speed (S.S.) is 800-1500r/min, and mixing time is 30-60min.
In described step (2), heating rate is 2-3 DEG C/min, and be warming up to 50-80 DEG C, chilling temperature is to 20-25 DEG C.
Urethane acrylate and the middle BiPO of step (1) in described step (2)
4mass ratio 1:8-1:20.
Sodium azide and the middle BiPO of step (1) in described step (2)
4mass ratio 1:10-1:30.
Propylene glycol block polyether and the middle BiPO of step (1) in described step (2)
4mass ratio 1:15-1:30.
In described step (1), (2), reaction is carried out in a kettle..
beneficial effect
(1) preparation method of the present invention is simple, cost is low, does not increase new equipment, is easy to suitability for industrialized production;
(2) the good and good air purification effect of the finishing agent stability of preparation of the present invention, baking is saved in use procedure, directly just can be effective by photocuring, energy-saving and emission-reduction, be applicable to various textile fabric and fabric, can Long-Time Service, can be applicable to the interior decoration fields such as submarine, hospital ward, automotive interior trim, interior of aircraft decoration, have broad application prospects and market prospects.
Detailed description of the invention
Below in conjunction with specific embodiment, set forth the present invention further.Should be understood that these embodiments are only not used in for illustration of the present invention to limit the scope of the invention.In addition should be understood that those skilled in the art can make various changes or modifications the present invention, and these equivalent form of values fall within the application's appended claims limited range equally after the content of having read the present invention's instruction.
Embodiment 1
(1) to add mass ratio be in a kettle. mass ratio is 1:0.05:0.15:0.1:0.001 deionized water, biomass sugar based surfactants, cage modle polyhedral oligomeric silsesquioxane, anatase type nano BiPO
4particle and silver nitrate, add ammoniacal liquor after 800r/min high-speed stirred 60min, regulates pH to 9, be obtained by reacting functional response liquid;
(2) heating rate is 2 DEG C/min, is warming up to 50 DEG C, continues slowly to be added dropwise to urethane acrylate monomer pre-emulsification 30min while intensification, be cooled to 25 DEG C, add sodium azide and propylene glycol block polyether, be heated to 60 DEG C of reactions 2 hours, adjust ph to 7.The wherein urethane acrylate described in step (2) and the middle BiPO of step (1)
4mass ratio 1:8; Sodium azide described in step (2) and the middle BiPO of step (1)
4mass ratio 1:10; Propylene glycol block polyether described in step (2) and the middle BiPO of step (1)
4mass ratio 1:15, the finishing agent of preparation is in relative humidity 30%, and at temperature 25 DEG C, initial concentration of formaldehyde 10.2ppm, under visible ray, the clearance of PARA FORMALDEHYDE PRILLS(91,95) reaches 95.3%.
Embodiment 2
(1) to add mass ratio be in a kettle. mass ratio is 1:0.01:0.05:0.02:0.003 deionized water, living beings cardanol sulfonate surfactant, cage modle polyhedral oligomeric silsesquioxane, anatase type nano BiPO
4particle and silver nitrate, add ammoniacal liquor after 1150r/min high-speed stirred 45min, regulates pH to 10, be obtained by reacting functional response liquid;
(2) heating rate is 2.5 DEG C/min, be warming up to 65 DEG C, continue slowly to be added dropwise to urethane acrylate monomer pre-emulsification 45min in intensification simultaneously, cool 20 DEG C, add sodium azide and propylene glycol block polyether, be heated to 60 DEG C of reactions 4 hours, adjust ph to 7.5, wherein the urethane acrylate described in step (2) and the middle BiPO of step (1)
4mass ratio 1:20; Sodium azide described in step (2) and the middle BiPO of step (1)
4mass ratio 1:30; Propylene glycol block polyether described in step (2) and the middle BiPO of step (1)
4mass ratio 1:30.The finishing agent of preparation is in relative humidity 30%, and at temperature 25 DEG C, initial concentration of formaldehyde 9.8ppm, under visible ray, the clearance of PARA FORMALDEHYDE PRILLS(91,95) reaches 97.3%.
Embodiment 3
(1) to add mass ratio be in a kettle. mass ratio is 1:0.03:0.10:0.07:0.002 deionized water, abietyl two carboxylate gemini surfactant, cage modle polyhedral oligomeric silsesquioxane, anatase type nano BiPO
4particle and silver nitrate, add ammoniacal liquor after 1500r/min high-speed stirred 30min, regulates pH to 11, be obtained by reacting functional response liquid;
(2) heating rate is 2.5 DEG C/min, is warming up to 80 DEG C, continues slowly to be added dropwise to urethane acrylate monomer pre-emulsification 60min in intensification simultaneously, cool 25 DEG C, add sodium azide and propylene glycol block polyether, be heated to 60 DEG C of reactions 3 hours, adjust ph to 8.The wherein urethane acrylate described in step (2) and the middle BiPO of step (1)
4mass ratio 1:20; Sodium azide described in step (2) and the middle BiPO of step (1)
4mass ratio 1:20; Propylene glycol block polyether described in step (2) and the middle BiPO of step (1)
4mass ratio 1:25.The finishing agent of preparation is in relative humidity 30%, and at temperature 25 DEG C, initial concentration of formaldehyde 6.8ppm, under visible ray, the clearance of PARA FORMALDEHYDE PRILLS(91,95) reaches 98.3%.
Claims (7)
1. a preparation method for fabric dedicated optical solidification phosphate purification of air finishing agent, comprising:
(1) by mass ratio be deionized water, biological surface activating agent, cage modle polyhedral oligomeric silsesquioxane, the anatase type nano BiPO of 1:0.01-0.05:0.05-0.15:0.02-0.1:0.001-0.003
4particle and silver nitrate mixing, add ammoniacal liquor and regulate pH 9-11, be obtained by reacting functional response liquid after stirring;
(2) above-mentioned functions reactant liquor is heated up, urethane acrylate monomer pre-emulsification 30-60min is added dropwise to while intensification, cooling, add sodium azide and propylene glycol block polyether, be heated to 60 DEG C of reaction 2-4 hour, adjust ph to 7 ~ 8, obtain fabric dedicated optical solidification phosphate purification of air finishing agent;
Wherein sodium azide and the middle BiPO of step (1) in step (2)
4mass ratio 1:10-1:30.
2. the preparation method of a kind of fabric dedicated optical solidification phosphate purification of air finishing agent according to claim 1, is characterized in that: in described step (1), biological surface activating agent is the one in living beings glycosyl surfactant active, living beings cardanol sulfonate surfactant, the two carboxylate gemini surfactant of abietyl.
3. the preparation method of a kind of fabric dedicated optical solidification phosphate purification of air finishing agent according to claim 1, is characterized in that: in described step (1), stir speed (S.S.) is 800-1500r/min, and mixing time is 30-60min.
4. the preparation method of a kind of fabric dedicated optical solidification phosphate purification of air finishing agent according to claim 1, it is characterized in that: in described step (2), heating rate is 2-3 DEG C/min, be warming up to 50-80 DEG C, chilling temperature is to 20-25 DEG C.
5. the preparation method of a kind of fabric dedicated optical solidification phosphate purification of air finishing agent according to claim 1, is characterized in that: urethane acrylate and the middle BiPO of step (1) in described step (2)
4mass ratio 1:8-1:20.
6. the preparation method of a kind of fabric dedicated optical solidification phosphate purification of air finishing agent according to claim 1, is characterized in that: propylene glycol block polyether and the middle BiPO of step (1) in described step (2)
4mass ratio 1:15-1:30.
7. the preparation method of a kind of fabric dedicated optical solidification phosphate purification of air finishing agent according to claim 1, is characterized in that: in described step (1), (2), reaction is carried out in a kettle..
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| CN201310724182.2A CN103710974B (en) | 2013-12-24 | 2013-12-24 | A kind of preparation method of fabric dedicated optical solidification phosphate purification of air finishing agent |
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| CN103710974B true CN103710974B (en) | 2015-08-12 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1275600A (en) * | 1968-09-25 | 1972-05-24 | Bayer Ag | Process for finishing fibre materials |
| CN102182069A (en) * | 2010-12-30 | 2011-09-14 | 洪桂焕 | Silver-carried antibacterial finishing agent and preparation method thereof |
| CN103194886A (en) * | 2013-04-17 | 2013-07-10 | 东华大学 | Preparation method of multi-phase heterogeneous visible light catalysis functional fabric |
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2013
- 2013-12-24 CN CN201310724182.2A patent/CN103710974B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1275600A (en) * | 1968-09-25 | 1972-05-24 | Bayer Ag | Process for finishing fibre materials |
| CN102182069A (en) * | 2010-12-30 | 2011-09-14 | 洪桂焕 | Silver-carried antibacterial finishing agent and preparation method thereof |
| CN103194886A (en) * | 2013-04-17 | 2013-07-10 | 东华大学 | Preparation method of multi-phase heterogeneous visible light catalysis functional fabric |
Non-Patent Citations (4)
| Title |
|---|
| Informatics》.2012,第5卷(第2期),181-190. * |
| Yang Zhou et al.Photocatalytic Activity of Hierarchically Nanoporous BiVO4/TiO2 Hollow Microspheres.《Journal of Fiber Bioengineering & * |
| 空气净化功能织物研究进展;王振华等;《印染助剂》;20111031;第28卷(第10期);1-4 * |
| 钒酸铋负载功能织物的制备及其光催化性能;陆洋等;《印染》;20130101(第1期);5-8 * |
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