CN103710468B - A kind of cane sugar manufacture defecation method using ozone decolorization technology - Google Patents

A kind of cane sugar manufacture defecation method using ozone decolorization technology Download PDF

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CN103710468B
CN103710468B CN201310461957.1A CN201310461957A CN103710468B CN 103710468 B CN103710468 B CN 103710468B CN 201310461957 A CN201310461957 A CN 201310461957A CN 103710468 B CN103710468 B CN 103710468B
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ozone
juice
sugar
sulphitation
liquid separation
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CN103710468A (en
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李凯
黄福
韦武林
谢彩锋
周军宏
陆海勤
杭方学
黄斌
张雷
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CHINA CAMC ENGINEERING Co Ltd
GUANGXI NANNING HUAXIN SUGAR INDUSTRY TECHNOLOGY Co Ltd
Guangxi University
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CHINA CAMC ENGINEERING Co Ltd
GUANGXI NANNING HUAXIN SUGAR INDUSTRY TECHNOLOGY Co Ltd
Guangxi University
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Abstract

The invention provides a kind of cane sugar manufacture defecation method using ozone decolorization technology, adopt traditional clarification process, after a heat treated, before a described solid-liquid separation process, or, after a described heat treated, before described Sulphitation and Neutralization process, described method also comprises: sugar cane juice being entered under stress ozone concn is that the Ozone Absorption device of 200mg/L ~ 600mg/L absorbs ozone, and enters reaction box and carry out decoloring reaction 3min ~ 30min after absorption ozone; In described decoloring reaction, make the pH value of described sugar cane juice remain on 6.5 ~ 8.5 by adding milk of lime, the temperature of described decoloring reaction is 50 DEG C ~ 90 DEG C; Described ozone using air through denitrogenation processing or pure oxygen as source of the gas, use Used in Surface Discharging Ozone Generator to produce, described ozonizer generation is 500g/h ~ 2000g/h.

Description

A kind of cane sugar manufacture defecation method using ozone decolorization technology
Technical field
The present invention relates to cane sugar manufacture technology field, particularly relate to a kind of cane sugar manufacture defecation method using ozone decolorization technology.
Background technology
China is third place in the world Chan Tang big country, sugar annual production in recent years more than 1,000 ten thousand tons, is wherein raw material with sugarcane more than 90%.Current China cane sugar manufacture is produced more than 95% and is used sulfurous method clarification process, namely uses SO 2as primary clarifying agent, at the Ca of clarifying process and milk of lime 2+reaction generates the CaSO with strong adsorption-edulcoration 3precipitation, will be had the non-saccharide such as colloid, pigment to adsorb coprecipitation, then they removed by solid-liquid separation technique, improve sugarcane juice purity and reduce sugarcane juice colour in sugarcane juice; SO simultaneously 2also can cause color substance generation addition reaction with sugarcane juice phenol sulfonate, reducing sugar alkaline decomposition intermediate product etc. with unsaturated link(age), play bleaching, suppress new pigment nucleus formation.
In general, SO 2removal of impurities decolorization in sugarcane juice is strengthened with the increase of its consumption.Therefore SO 2in sulfurous method Closed Circulation in Sugar Production, be in irreplaceable position, since in October, 2006, China implemented white sugar new nation standard, vast sugar enterprise is by improving SO always 2consumption (intensity of sulfitation) comes to realize reducing white sugar colour object.
But due at traditional clarifying process, whole process control is at neutral range, and SO 2the H that dissolved water generates 2sO 3be weak diacid, be difficult to this understanding completely secondary ionization and Ca occur 2+generate CaSO 3precipitation, therefore unavoidably has part SO 2in a variety of manners in residual clear juice; Meanwhile, because sugarcane juice itself is a complicated component and the very strong system of variability, contained colloidalmaterial can hinder SO 2with Ca 2+reaction, make SO in juice clearly 2content increases.Remain in juice sulfurous gas clearly, in syrup boiling process, White Sugar Crystal inside can be entered into by sucrose crystal absorption, parcel, increase white sugar SO 2content.
SO in white sugar 2mainly exist with sulphite form, slowly can be transformed into sulfurous gas in storage and edible process, the Digestive tract of infringement human respiratory tract, eyes, human body, hepatic tissue and lymphsystem etc., therefore white sugar SO 2content height relates to sugar security, and there is strict demand in man of China to this index, if white sugar SO 2content is forbidden dispatching from the factory more than 30mg/kg.Domestic and international famous brand name food and drink are to white sugar SO simultaneously 2content requirement is very harsh (SO always 2content higher than 15mg/kg, even can not contain SO 2), therefore China's white sugar major part cannot enter this great market at present, largely weakens China's white sugar market competitiveness, affects China's sugar industry development.
Therefore, how to reduce its SO in reduction white sugar colour simultaneously 2content is one of China's sugaring circle study hotspot always.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of new cane sugar manufacture defecation method, to realize reducing SO while reduction white sugar colour 2content.
In order to solve the problem, the invention discloses a kind of cane sugar manufacture defecation method using ozone decolorization technology, adopt traditional clarification process, comprise pre-ash process, heat treated, second-heating process, a solid-liquid separation process, Sulphitation and Neutralization process and the process of secondary solid-liquid separation, after a described heat treated, before a described solid-liquid separation process, or after a described heat treated, before described Sulphitation and Neutralization process, described method also comprises:
Sugar cane juice being entered under stress ozone concn is that the Ozone Absorption device of 200mg/L ~ 600mg/L absorbs ozone, and enters reaction box and carry out decoloring reaction 3min ~ 30min after absorption ozone;
In described decoloring reaction, make the pH value of described sugar cane juice remain on 6.5 ~ 8.5 by adding milk of lime, the temperature of described decoloring reaction is 50 DEG C ~ 90 DEG C;
Described ozone using air through denitrogenation processing or pure oxygen as source of the gas, use Used in Surface Discharging Ozone Generator to produce, described ozonizer generation is 500g/h ~ 2000g/h.
Preferably, in a described heat treated, Heating temperature is 50 DEG C ~ 90 DEG C.
Preferably, in described second-heating process, Heating temperature is 55 DEG C ~ 70 DEG C.
Preferably, in described Sulphitation and Neutralization process, the consumption of sulfurous gas is 0.4g/L ~ 1.2g/L.
Preferably, in described Sulphitation and Neutralization process, the pH value of described sugar cane juice is made to remain on 6.8 ~ 7.4 by adding milk of lime.
Preferably, after described Sulphitation and Neutralization process, be first heated to boiling, then carry out the process of secondary solid-liquid separation.
Preferably, described pre-ash process comprises: in described mixing juice, add phosphoric acid, obtain the sugar cane juice of pre-ash by the pH value of milk of lime to mixing juice after regulating.
Compared with prior art, the present invention includes following advantage:
Pass through the embodiment of the present invention, when adopting traditional clarification process to carry out cane sugar manufacture clarification, after once heating, use ozonize mixing juice, sugarcane juice coloring matter is oxidized to small molecules colorless substance, reach the effect of removing pigment in sugarcane juice, the embodiment of the present invention adopts ozone Some substitute SO 2clarify and decolorize process is carried out, compared to SO to sugarcane juice 2cane sugar manufacture clarifying process decolorizing effect can be improved; SO when carrying out Sulphitation and Neutralization 2consumption can reduce, and can reduce production cost on the one hand, the SO that another aspect uses due to Sulphitation and Neutralization process 2amount reduces, therefore SO in white sugar 2residual quantity can greatly reduce, sugar security can be improved.
Accompanying drawing explanation
Fig. 1 is the schema using the cane sugar manufacture defecation method of ozone decolorization technology in an example of the embodiment of the present invention.
Embodiment
For enabling above-mentioned purpose of the present invention, feature and advantage become apparent more, and below in conjunction with the drawings and specific embodiments, the present invention is further detailed explanation.
Because most sulfurous method sugar enterprises of current China custom is by improving SO 2consumption reduces white sugar colour, but SO 2the increase of consumption may cause SO in juice clearly 2content increases, thus causes white sugar SO 2content raises, and affect white sand confectionery safety, cartogram understands granulated sugar colour and SO 2exceeding standard is the large factor of China's White Sugar Quality underproof two.
In view of this, one of core idea of the embodiment of the present invention is, uses ozone Some substitute SO 2clarify and decolorize process is carried out to sugarcane juice, thus can SO be reduced 2consumption, reduces white sugar SO 2content.
Specifically, embodiments provide a kind of cane sugar manufacture defecation method, have employed traditional sulfurous method clarification process, traditional sulfurous method clarification process comprises pre-ash process, heat treated, second-heating process, a solid-liquid separation process, Sulphitation and Neutralization process and the process of secondary solid-liquid separation, the embodiment of the present invention, after a heat treated, adds and adopts ozone to carry out the step of decolouring.
Tradition sulfurous method is mainly by SO 2sugarcane juice is decoloured, the embodiment of the present invention adopts ozone to decolour, ozone has strong oxidizing property, ozone and the pigment produced in Active Radicals Produced (OH) sugarcane juice thereof or cause unsaturated link(age) fracture contained by color substance in the solution, generate the colourless or light material of small molecules, reach decolorizing effect, compared to SO 2cane sugar manufacture clarifying process decolorizing effect can be improved; Further, after adding the step of ozone decolorization, SO when carrying out Sulphitation and Neutralization 2consumption can reduce, and can reduce production cost on the one hand, the SO that another aspect uses due to Sulphitation and Neutralization process 2amount reduces, SO in white sugar 2residual quantity can greatly reduce, sugar security can be improved.
The step of ozone decolorization process can perform after mixing juice heat treated before a solid-liquid separation process, can perform before Sulphitation and Neutralization process after mixing juice heat treated, also can perform before process of floating after syrup heating.Specifically, can perform between mixing juice heat treated and second-heating process, also can perform between the process of mixing juice second-heating and a solid-liquid separation process, also can perform between second-heating process and a solid-liquid separation process, can perform between a solid-liquid separation and Sulphitation and Neutralization process, specifically select to perform and can design according to concrete demand and applied environment between any two steps.
Specifically, the step adopting ozone to carry out decolouring comprises:
Sugar cane juice being entered under stress ozone concn is that the Ozone Absorption device of 200mg/L ~ 600mg/L absorbs ozone, and enters reaction box and carry out decoloring reaction 3min ~ 30min after absorption ozone.
Ozone Absorption device comprises the ozone that concentration is 200mg/L ~ 600mg/L, and sugar cane juice is pressed into Ozone Absorption device under a certain pressure, and in Ozone Absorption device, the ozone in sugar cane juice meeting absorbing environmental, after absorption, enters into reaction box and carry out decoloring reaction.
Wherein, in described decoloring reaction, the pH value of described sugar cane juice is made to remain on 6.5 ~ 8.5 by adding milk of lime, more preferably, prove through large quantity research and experiment, when the pH value of sugar cane juice is 7.5 ~ 8.5, ozone decolorization can obtain better effect, therefore, follow-up employing Sulphitation and Neutralization can adopt less SO 2, further SO 2residual quantity can be less, that is to say, when the pH value of sugar cane juice is 7.5 ~ 8.5, when being 6.5 ~ 7.5 compared to pH value, SO in prepared white sugar 2residual quantity can be less.
Preferably, the temperature of described decoloring reaction is 50 DEG C ~ 90 DEG C.
Described ozone can using air or air through denitrogenation processing or pure oxygen as source of the gas, use Used in Surface Discharging Ozone Generator to produce, described ozonizer generation is 500g/h ~ 2000g/h.
Further preferably, in a described heat treated, Heating temperature can be 50 DEG C ~ 90 DEG C.
Further preferably, in described second-heating process, Heating temperature can be 55 DEG C ~ 70 DEG C.
Further preferably, in described Sulphitation and Neutralization process, the pH value of described sugar cane juice is made to remain on 6.8 ~ 7.4 by adding milk of lime.
Further preferably, after described Sulphitation and Neutralization process, first can be heated to boiling, then carry out the process of secondary solid-liquid separation.
Further preferably, described pre-ash process can comprise: in described mixing juice, add phosphoric acid, obtain the sugar cane juice of pre-ash after regulating by the pH value of milk of lime to mixing juice, for as far as possible close to the pH value in ozone treating process, the pH value that pre-ash regulates can should be 6.5 ~ 8.5 mutually.
Give the schema using the cane sugar manufacture defecation method of ozone decolorization technology in an example of the embodiment of the present invention see Fig. 1, comprising:
Pre-grey 101: in described mixing juice, add phosphoric acid, obtain the sugar cane juice of pre-ash after regulating by the pH value of milk of lime to mixing juice.
Once heat 102: Heating temperature is 50 DEG C ~ 90 DEG C.
Ozone decolorization 103: sugar cane juice is entered under stress Ozone Absorption device and absorb ozone, ozone concn controls at 200mg/L ~ 600mg/L, and enter reaction box and carry out decoloring reaction 3min ~ 30min after absorption ozone, in reaction process in order to ensure that sugarcane juice pH value is between 6.5 ~ 8.5, need to add appropriate milk of lime continuously to reaction box, the temperature of described decoloring reaction is 50 DEG C ~ 90 DEG C
Second-heating 104: after question response terminates, sugar cane juice is carried out second-heating to 55 DEG C ~ 70 DEG C.
A solid-liquid separation 105: upper scum silica frost foam is carried out to sugar cane juice and is separated, obtain a clear juice.
Sulphitation and Neutralization 106: separating obtained one clear juice is carried out Sulphitation and Neutralization process, SO 2consumption is 0.4g/L ~ 1.2mg/L, in reaction process in order to ensure that sugarcane juice pH value is between 6.8 ~ 7.4, needs to add appropriate milk of lime continuously.
Secondary solid-liquid separation 107: be first heated to boiling, then carry out the process of secondary solid-liquid separation, obtain two clear juice;
Subsequent disposal 108: add that two clear juice that ozone decolorization technology obtains carry out evaporation concentration, boiling, purging can obtain white sugar through sulfurous method clarification process.
In order to make those skilled in the art understand the present invention better, be described below by way of the cane sugar manufacture defecation method of specific embodiment to use ozone decolorization technology of the present invention.
Embodiment 1
In the 1L mixing juice that crushing sugar cane obtains, pre-ash adds phosphoric acid, the pH value 7.0 of mixing juice is regulated with milk of lime, once be heated to 65 DEG C, Ozone Absorption device is entered under certain pressure effect, reaction box is entered after absorbing ozone, ozone concn controls at 350mg/L, stop reaction 25min, in reaction process, add appropriate milk of lime continuously ensure that sugarcane juice pH value is 7.0, by sugarcane juice second-heating to 65 DEG C after question response terminates, then carry out upper scum silica frost foam to be separated, separating obtained one clear juice is delivered to Sulphitation and Neutralization operation and carries out Sulphitation and Neutralization process, at Sulphitation and Neutralization process post-heating to boiling, SO 2consumption is 1.0g/L, and add appropriate milk of lime continuously and ensure that sugarcane juice pH value is between 7.0, is heated to boiling, then carries out solid-liquid separation process, test obtains SO 2residual quantity be 0.09g/L.
Embodiment 2
In the 2L mixing juice that crushing sugar cane obtains, pre-ash adds phosphoric acid, the pH value to 8.0 of mixing juice is regulated with milk of lime, once be heated to 55 DEG C, Ozone Absorption device is entered under certain pressure effect, reaction box is entered after absorbing ozone, ozone concn controls at 300mg/L, stop reaction 20min, in reaction process, add appropriate milk of lime continuously ensure that sugarcane juice pH value is 8.0, by sugarcane juice second-heating to 55 DEG C after question response terminates, then carry out upper scum silica frost foam to be separated, separating obtained one clear juice is delivered to Sulphitation and Neutralization operation and carries out Sulphitation and Neutralization process, at Sulphitation and Neutralization process post-heating to boiling, SO 2consumption is 0.6g/L, and add appropriate milk of lime continuously and ensure that sugarcane juice pH value is 7.2, is heated to boiling, then carries out solid-liquid separation process, test obtains SO 2residual quantity be 0.05g/L.
Embodiment 3
In the 1L mixing juice that crushing sugar cane obtains, pre-ash adds phosphoric acid, the pH value 7.5 of mixing juice is regulated with milk of lime, once be heated to 60 DEG C, Ozone Absorption device is entered under certain pressure effect, reaction box is entered after absorbing ozone, ozone concn controls at 500mg/L, stop reaction 30min, in reaction process, add appropriate milk of lime continuously ensure that sugarcane juice pH value is 7.5, by sugarcane juice second-heating to 60 DEG C after question response terminates, then carry out upper scum silica frost foam to be separated, separating obtained one clear juice is delivered to Sulphitation and Neutralization operation and carries out Sulphitation and Neutralization process, at Sulphitation and Neutralization process post-heating to boiling, SO 2consumption is 0.4g/L, and add appropriate milk of lime continuously and ensure that sugarcane juice pH value is 7.4, is heated to boiling, then carries out solid-liquid separation process, test obtains SO 2residual quantity be 0.03g/L.
As can be seen from above data, compared to SO in prior art 2for the consumption of 2.0-3.0g/L, and SO in corresponding white sugar 2be about the residual quantity of about 0.4g/L, present invention achieves SO 2sO in the minimizing of consumption and white sugar 2the minimizing of residual quantity, can find out, when the pH value of sugar cane juice is 7.5-8.5, and SO in white sugar 2content can be less.
Known by above-described embodiment, when the present invention adopts traditional sulfurous method clarification process to carry out cane sugar manufacture clarification, ozonize mixing juice is used after once heating, sugarcane juice coloring matter is oxidized to small molecules colorless substance, reach the effect of removing pigment in sugarcane juice, add that two clear juice that ozone decolorization technology obtains carry out evaporation concentration, boiling, purging can obtain white sugar through sulfurous method clarification process, use ozone Some substitute SO 2clarify and decolorize process is carried out to sugarcane juice, thus can SO be reduced 2consumption, reduces white sugar SO 2content, improves sugar security, widens China's sugar market; Obviously reducing the SO that sugarcane sulfurous method produces white sugar 2consumption simultaneously, can also improve clarifying process decolorizing effect, reduces production cost, thus can improve Closed Circulation in Sugar Production Business Economic Benefit further.
For embodiment of the method, in order to simple description, therefore it is all expressed as a series of combination of actions, but those skilled in the art should know, the present invention is not by the restriction of described sequence of operation, because according to the present invention, some step can adopt other orders or carry out simultaneously.Secondly, those skilled in the art also should know, the embodiment described in specification sheets all belongs to preferred embodiment, and involved action and parts might not be that the present invention is necessary.
Above a kind of cane sugar manufacture defecation method of ozone decolorization technology that uses provided by the present invention is described in detail, apply specific case herein to set forth principle of the present invention and embodiment, the explanation of above embodiment just understands method of the present invention and core concept thereof for helping; Meanwhile, for one of ordinary skill in the art, according to thought of the present invention, all will change in specific embodiments and applications, in sum, this description should not be construed as limitation of the present invention.

Claims (5)

1. one kind uses the cane sugar manufacture defecation method of ozone decolorization technology, adopt traditional clarification process, comprise pre-ash process, heat treated, second-heating process, a solid-liquid separation process, Sulphitation and Neutralization process and the process of secondary solid-liquid separation, it is characterized in that, after a described heat treated, before a described solid-liquid separation process, or after a described heat treated, before described Sulphitation and Neutralization process, described method also comprises:
Sugar cane juice being entered under stress ozone concn is that the Ozone Absorption device of 350mg/L ~ 500mg/L absorbs ozone, and enters reaction box and carry out decoloring reaction 3min ~ 30min after absorption ozone;
In described decoloring reaction, make the pH value of described sugar cane juice remain on 6.5 ~ 8.5 by adding milk of lime, the temperature of described decoloring reaction is 50 DEG C ~ 90 DEG C;
Described ozone using air through denitrogenation processing or pure oxygen as source of the gas, use Used in Surface Discharging Ozone Generator to produce, described ozonizer generation is 500g/h ~ 2000g/h;
In a described heat treated, Heating temperature is 55 DEG C ~ 65 DEG C;
In described second-heating process, Heating temperature is 55 DEG C.
2. the method for claim 1, is characterized in that, in described Sulphitation and Neutralization process, the consumption of sulfurous gas is 0.4g/L ~ 1.2g/L.
3. the method for claim 1, is characterized in that, in described Sulphitation and Neutralization process, make the pH value of described sugar cane juice remain on 6.8 ~ 7.4 by adding milk of lime.
4. the method for claim 1, is characterized in that, is first heated to boiling, then carries out the process of secondary solid-liquid separation after described Sulphitation and Neutralization process.
5. the method for claim 1, is characterized in that, described pre-ash process comprises: in the mixing juice that crushing sugar cane obtains, add phosphoric acid, obtain the sugar cane juice of pre-ash by the pH value of milk of lime to described mixing juice after regulating.
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