CN103706630B - 一种利用矿物纳米复合材料修复土壤中有机污染物的方法 - Google Patents

一种利用矿物纳米复合材料修复土壤中有机污染物的方法 Download PDF

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CN103706630B
CN103706630B CN201310726410.XA CN201310726410A CN103706630B CN 103706630 B CN103706630 B CN 103706630B CN 201310726410 A CN201310726410 A CN 201310726410A CN 103706630 B CN103706630 B CN 103706630B
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CN103706630A (zh
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程功弼
温涛
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JIANGSU GAIYA ENVIRONMENTAL SCIENCE AND TECHNOLOGY CO., LTD.
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Abstract

本发明公开了一种利用矿物纳米复合材料修复土壤中有机污染物的方法,将晶质镁铝硅酸盐与纳米碳酸盐按照摩尔比1:1进行配比,充分搅拌使其混合物均匀;将TiO2负载坡缕石置入土质稳定剂溶液中,使其达到絮凝状态;加Fe-RE交联蒙脱石到水质稳定剂溶液中,充分搅拌使其混合物均匀;将以上三种混合物按照质量比1:1:2进行混合,完成整个制备过程。将最终的混合物播散到存在有机污染物的土壤中去,以达到修复的目的。采用本发明技术方案,设计简单,操作方便;无需复杂的处理设备,成本低;处理彻底,无二次污染。

Description

一种利用矿物纳米复合材料修复土壤中有机污染物的方法
技术领域
本发明涉及土壤修复技术领域,具体而言,涉及一种利用矿物纳米复合材料修复土壤中有机污染物的方法。
背景技术
化工厂生产过程中排放的多种有机污染物,对人体和生物都具有高毒性,且很难被生物降解,因此被列于世界“环境优先控制有毒污染物”的名单。一旦大量进入土壤及地下水中,将会造成难以修复的环境危害。
近年来,纳米颗粒因具有高的比表面积、多级比表面和高表面能而倍受人们关注。纳米材料是指三维空间尺度至少有一维处于纳米量级(1-100 nm)的材料,它是由尺寸介于原子、分子和宏观体系之间的纳米颗粒所组成的新一代材料。当颗粒尺寸处于纳米量级时,量子效应开始影响到物质的性能和结构,而表现出特殊的理化性质如小尺寸效应、界面(表面)效应、量子尺寸效应以及量子隧道效应等。纳米材料的特殊理化性质取决于其颗粒大小(比表面积和分布)、化学构成(纯度),因此, 纳米材料在物理性能如磁、光、电、热等方面与普通材料有很大不同,具有吸附、催化、辐射、吸收等新特性。纳米颗粒由于其大量的微界面及微孔性,可以强化各种界面反应,如对污染物的表面及专性吸附反应等,在污染土壤治理及污水净化中正发挥越来越显著的作用。
矿物纳米材料可以直接从自然界中提取,来源方便简单,并且能够还原去除环境中多种污染物,利用矿物纳米复合材料进行污染土壤和地下水的修复成为国内外较为关注的研究方向。在20世纪80年代末,纳米零价铁颗粒作为一种有效的脱卤还原剂受到人们关注。近年来研究发现,纳米铁可以催化还原多种有机卤化物,如卤代烷烃、卤代烯烃、卤代芳香烃、有机氯农药等难降解有机污染物。但是,目前其他矿物纳米材料在土壤修复方面的研究较少。
发明内容
本发明的目的是提供一种利用矿物纳米复合材料修复土壤中有机污染物的方法。
为实现上述技术目的,达到上述技术效果,本发明通过以下技术方案实现:
一种利用矿物纳米复合材料修复土壤中有机污染物的方法,包括以下步骤:
步骤1)将晶质镁铝硅酸盐与纳米碳酸盐按照摩尔比1:1进行配比,充分搅拌使其混合物均匀;
步骤2)将TiO2负载坡缕石置入土质稳定剂溶液中,使其达到絮凝状态;
步骤3)加Fe-RE交联蒙脱石到水质稳定剂溶液中,充分搅拌使其混合物均匀;
步骤4)将以上三种混合物按照质量比1:1:2进行混合,完成整个制备过程。
步骤5)将最终的混合物播散到存在有机污染物的土壤中去,以达到修复的目的。
本发明的有益效果是:
采用本发明技术方案,设计简单,操作方便;无需复杂的处理设备,成本低;处理彻底,无二次污染。
具体实施方式
下面将结合实施例来详细说明本发明。
一种利用矿物纳米复合材料修复土壤中有机污染物的方法,包括以下步骤:
步骤1)将晶质镁铝硅酸盐与纳米碳酸盐按照摩尔比1:1进行配比,充分搅拌使其混合物均匀;
步骤2)将TiO2负载坡缕石置入土质稳定剂溶液中,使其达到絮凝状态;
步骤3)加Fe-RE交联蒙脱石到水质稳定剂溶液中,充分搅拌使其混合物均匀;
步骤4)将以上三种混合物按照质量比1:1:2进行混合,完成整个制备过程。
步骤5)将最终的混合物播散到存在有机污染物的土壤中去,以达到修复的目的。

Claims (1)

1.一种利用矿物纳米复合材料修复土壤中有机污染物的方法,其特征在于:包括以下步骤:
步骤1)将晶质镁铝硅酸盐与纳米碳酸盐按照摩尔比1:1进行配比,充分搅拌使其混合物均匀;
步骤2)将TiO2负载坡缕石置入土质稳定剂溶液中,使其达到絮凝状态;
步骤3)加Fe-RE交联蒙脱石到水质稳定剂溶液中,充分搅拌使其混合物均匀;
步骤4)将以上三种混合物按照质量比1:1:2进行混合,完成整个制备过程;步骤5)将最终的混合物播散到存在有机污染物的土壤中去,以达到修复的目的。
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