CN103703010B - 制备双(全氟烷基)次膦酸酐的方法 - Google Patents

制备双(全氟烷基)次膦酸酐的方法 Download PDF

Info

Publication number
CN103703010B
CN103703010B CN201280036598.9A CN201280036598A CN103703010B CN 103703010 B CN103703010 B CN 103703010B CN 201280036598 A CN201280036598 A CN 201280036598A CN 103703010 B CN103703010 B CN 103703010B
Authority
CN
China
Prior art keywords
acid
perfluoroalkyl
phospho acid
pentafluoroethyl group
phospho
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201280036598.9A
Other languages
English (en)
Chinese (zh)
Other versions
CN103703010A (zh
Inventor
N·(M)·伊格纳季耶夫
W·维贝尔
H·维尔纳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Merck Patent GmbH
Original Assignee
Merck Patent GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Merck Patent GmbH filed Critical Merck Patent GmbH
Publication of CN103703010A publication Critical patent/CN103703010A/zh
Application granted granted Critical
Publication of CN103703010B publication Critical patent/CN103703010B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/26—Drying gases or vapours
    • B01D53/28—Selection of materials for use as drying agents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
    • C07F9/301—Acyclic saturated acids which can have further substituents on alkyl
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
    • C07F9/308—Pyrophosphinic acids; Phosphinic acid anhydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
    • C07F9/32—Esters thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
    • C07F9/32—Esters thereof
    • C07F9/3258—Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/3294—Compounds containing the structure R2P(=X)-X-acyl, R2P(=X)-X-heteroatom, R2P(=X)-X-CN (X = O, S, Se)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
    • C07F9/34—Halides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/44—Amides thereof
    • C07F9/4461—Amides thereof the amide moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4484—Compounds containing the structure C-P(=X)(N-acyl)-X, C-P(=X)(N-heteroatom)-X or C-P(=X)(N-CN)-X (X = O, S, Se)
    • C07F9/4492—Compounds containing the structure P(=X)(N-C(=X)-) (X = O, S, Se)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
    • C07F9/5337—Phosphine oxides or thioxides containing the structure -C(=X)-P(=X) or NC-P(=X) (X = O, S, Se)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/60—Inorganic bases or salts
    • B01D2251/61—Phosphates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/26—Drying gases or vapours
    • B01D53/261—Drying gases or vapours by adsorption

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Molecular Biology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Fireproofing Substances (AREA)
CN201280036598.9A 2011-07-25 2012-07-06 制备双(全氟烷基)次膦酸酐的方法 Expired - Fee Related CN103703010B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102011108324.7 2011-07-25
DE102011108324A DE102011108324A1 (de) 2011-07-25 2011-07-25 Verfahren zur Herstellung von Bis(perfluoralkyl)phosphinsäureanhydriden
PCT/EP2012/002843 WO2013013766A1 (de) 2011-07-25 2012-07-06 Verfahren zur herstellung von bis(perfluoralkyl)phosphinsäureanhydriden

Publications (2)

Publication Number Publication Date
CN103703010A CN103703010A (zh) 2014-04-02
CN103703010B true CN103703010B (zh) 2016-01-06

Family

ID=46582652

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201280036598.9A Expired - Fee Related CN103703010B (zh) 2011-07-25 2012-07-06 制备双(全氟烷基)次膦酸酐的方法

Country Status (6)

Country Link
US (1) US9163039B2 (US20040106767A1-20040603-C00005.png)
EP (1) EP2736913B1 (US20040106767A1-20040603-C00005.png)
JP (1) JP5926797B2 (US20040106767A1-20040603-C00005.png)
CN (1) CN103703010B (US20040106767A1-20040603-C00005.png)
DE (1) DE102011108324A1 (US20040106767A1-20040603-C00005.png)
WO (1) WO2013013766A1 (US20040106767A1-20040603-C00005.png)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3454683A (en) * 1964-10-28 1969-07-08 Hoechst Ag Process for the manufacture of neutral polyphosphoric ester anhydrides
CN100387606C (zh) * 2003-07-21 2008-05-14 齐明药化 环状膦酸酐的制备方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10216997A1 (de) 2002-04-16 2003-10-30 Merck Patent Gmbh Verfahren zur Herstellung von Bis(perfluoralkyl)phosphinsäuren und deren Salze
DE102008035174A1 (de) 2008-07-28 2010-02-11 Merck Patent Gmbh Verfahren zur Herstellung von Bis(fluoralkyl)-phosphinsäure oder Fluoralkylphosphonsäure

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3454683A (en) * 1964-10-28 1969-07-08 Hoechst Ag Process for the manufacture of neutral polyphosphoric ester anhydrides
CN100387606C (zh) * 2003-07-21 2008-05-14 齐明药化 环状膦酸酐的制备方法

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
Bis( trifluoromethyl) phosphoryl-μ-oxo-bis( trifluoromethy1)-phosphine. The Mixed Anhydride of a Phosphinous and Phosphinic Acid;Anton B. Burg;《Inorganic Chemistry》;19780831;第17卷(第8期);第2322-2324页 *
C6, C7, and C8 Perfluoroalkyl-Substituted Phosphinic Acids;Rajendra P. Singh et al;《Inorg. Chem.》;20000401;第39卷;第1787-1789页 *
Commercial Synthesis of Monoalkyl Phosphates;David J. Tracya et al;《Journal of Surfactants and Detergents》;20021231;第5卷(第2期);第169-172页 *
New Perfluoroalkylphosphonic and Bis( perfluoroalky1)phosphinic Acids and Their Precursors;Tariq Mahmood et al;《Inorg. Chem.》;19860831;第25卷;第3128-3131页 *
The Reaction of Tridluoromethylphosphino-compounds with Nitric Oxide;R. C. Dobbie et al;《J. Chem. SOC. (A)》;19711231;第2894-2897页 *

Also Published As

Publication number Publication date
WO2013013766A1 (de) 2013-01-31
CN103703010A (zh) 2014-04-02
US9163039B2 (en) 2015-10-20
JP2014521614A (ja) 2014-08-28
EP2736913B1 (de) 2015-08-26
US20140155649A1 (en) 2014-06-05
DE102011108324A1 (de) 2013-01-31
EP2736913A1 (de) 2014-06-04
JP5926797B2 (ja) 2016-05-25

Similar Documents

Publication Publication Date Title
Silvestru et al. Tetraorganodichalcogenoimidodiphosphorus acids and their main group metal derivatives
Hilliard et al. Synthesis, purification, and characterization of phosphine oxides and their hydrogen peroxide adducts
CN103080120B (zh) 制备镍磷配体配合物
Verat et al. Copper (I) complexes of N-thioacylamido (thio) phosphates and triphenylphosphine
CN103703010B (zh) 制备双(全氟烷基)次膦酸酐的方法
EP3296301A1 (en) A versatile process for the preparation of acylphosphines
US20220212177A1 (en) Complex compound and method for manufacturing the same
Perlikowska et al. Enantiomerically pure disulfides: key compounds in the kinetic resolution of chiral PIII-derivatives with stereogenic phosphorus
Goryunov et al. Reactions of Polyfluoroarenes with MenE‐MMe3 Reagents (MenE= Me2As, Me2P, Me2N, and MeS; M= Si, Sn): Synthesis of Polyfluoroaryl MenE Compounds
Kunnari et al. An unexpected tetrahydrofuran ring opening: synthesis and structural characterization of Ph 3 PO (CH 2) 4 TeBr 4
Calvo et al. A straightforward access to ruthenium-coordinated fluorophosphines from phosphorous oxyacids
Baldovino-Pantaleón et al. Reactivity of C6F5S-P (C6H5) 2 with [M3 (CO) 12](M= Fe, Ru, Os). The X-ray crystal structures of [Fe2 (μ-SC6F5)(μ-PPh2)(CO) 6],[Ru4 (μ3-SPPh2) 2 (μ-SC6F5) 2 (μ-PPh2) 2 (SC6F5) 2 (CO) 6] and [Os3 (η1-Ph2P-SC6F5)(CO) 11]
JP2014005214A (ja) アリールジクロロホスフィンの製造方法
Lebbe et al. Reactions of coordinated ligands. Part 19: Template synthesis of a macrocyclic secondary tetraphosphine by oxidative demetallation of crown phosphine Ni (II) complexes
Hatam et al. Phosphinic acid analogues of thiaproline and the related heterocyclic aminophosphinic acids
Brisdon et al. Perfluoropropenyl-containing phosphines from HFC replacements
Cea-Olivares et al. Synthesis and characterization of phenoxarsin-10-yl diorganodithiophosphinates. A folded phenoxarsine system in the first dimeric organoarsenic (III) 1, 1-dithiolate associated through As⋯ S secondary bonding
Malik et al. New phosphoroamidate compounds: Synthesis, structural characterization and studies on ZnCl2 assisted hydrolysis of the P–N bond
Coetzee et al. Phosphorus containing mixed anhydrides—their preparation, labile behaviour and potential routes to their stabilisation
Malysheva et al. Chemoselective Synthesis of Alkylphosphinic Acids from Red Phosphorus and Alkyl Bromides in the System KOH/H2O/Toluene/Micellar Catalyst
Wickemeyer et al. ortho-Phenylene-bridged phosphorus/silicon Lewis pairs
WO2024015263A1 (en) Process for preparing phosphonate esters
Zinov’eva et al. Synthesis and structure of tris (halo) alkyl phosphate complexes with metal chlorides
Ebrahim et al. Synthesis, spectra and crystal structures of zwitterionic mercury (II) complexes formed by the ligand,[Ph2PCH2PPh2CH2C (O) Ph]+
Ng et al. Di-and triorganotin (IV) derivatives of (diphenylphosphinyl)-and (diphenylthiophosphinyl) acetic acid

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160106

Termination date: 20170706

CF01 Termination of patent right due to non-payment of annual fee