CN103698324B - Air formaldehyde self testing kit - Google Patents

Air formaldehyde self testing kit Download PDF

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Publication number
CN103698324B
CN103698324B CN201310611950.3A CN201310611950A CN103698324B CN 103698324 B CN103698324 B CN 103698324B CN 201310611950 A CN201310611950 A CN 201310611950A CN 103698324 B CN103698324 B CN 103698324B
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China
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formaldehyde
diluent
acidulant
absorbent
self testing
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CN201310611950.3A
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CN103698324A (en
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严滨
廖文超
程前
许美兰
叶茜
林君成
燕龙龙
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Xiamen University of Technology
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Xiamen University of Technology
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Abstract

The invention discloses a kind of air formaldehyde self testing kit, including absorbent, acidulant, diluent, developer and colorimetric card;Described absorbent is phenol reagent, and acidulant is phosphorus pentoxide, and described diluent is pure water, and described developer is ammonium ferric sulfate.The box of testing oneself is adapted to family and uses, and can be detected with content of formaldehyde economic, convenient, accurately and rapidly to interior.

Description

Air formaldehyde self testing kit
Technical field
The present invention relates to the technical field of air detection formaldehyde, espespecially a kind of air formaldehyde self testing kit.
Background technology
Formaldehyde is a kind of plasm poisonous substance for destroying biological cell protein, and at typical condition, pure formaldehyde is a kind of band There are the colourless gas of stinkpot, the skin of people, respiratory tract and internal organ can be caused damage, its extent of injury is with it in air In concentration it is closely related with the length of time of contact.Formaldehyde also has teratogenesis, carcinogenesis, and the people of Long Term Contact formaldehyde suffers from The probability of nasal cavity, oral cavity, nasopharynx, throat, skin and alimentary tract cancer is higher than common people, and mankind's Long Term Contact low amounts formaldehyde can be with Cause chronic respiratory disease, feminine menstrual disorder, pregnancy syndrome, cause neonate's constitution to reduce, chromosome abnormality, or even Cause nasopharyngeal carcinoma, the formaldehyde of high concentration is all toxic to nervous system, immune system, liver etc..Formaldehyde is the World Health Organization The teratogenesis of confirmation, carcinogen, Long Term Contact will cause gene mutation, be arranged in the list for being China's toxic chemical priority acccess control Second.
China《Indoor air quality-monitoring technical specification》(HJ/ T167- 2004)Recommend to use AHMT light splitting light Degree method, phenol reagent method, acetylacetone,2,4-pentanedione AAS, gas chromatography and electrochemical sensor method are used as formaldehyde Assay method.Wherein gas chromatography has the characteristics of selectivity is good, and disturbing factor is small, but gas chromatograph somewhat expensive; AHMT AAS strong antijamming capabilities, sensitivity is higher, but operation is required strictly;Acetylacetone,2,4-pentanedione AAS is to coexisting Phenol and noiseless, easy to operate, the favorable reproducibility such as ethanol, but sensitivity is relatively low;Electrochemical sensor method is easy to operate and fast Speed, but the price of formaldehyde sensor is universal more expensive.
The content of the invention
The technical problems to be solved by the invention are provide that a kind of suitable family uses economic, convenient, accurate, quick Air formaldehyde self testing kit, it passes through to reappear and optimize national standard Law《Public place method for determining formaldehyde in air phenol reagent AAS》(GB/T18204.26-2000), it is desirably to obtain the optimum proportioning of the constituent of box of testing oneself.
In order to solve the above technical problems, technical solution of the invention is:
A kind of air formaldehyde self testing kit, including absorbent, acidulant, diluent, developer and colorimetric card;Described absorption Agent is phenol reagent, and described acidulant is phosphorus pentoxide, and described diluent is pure water, and described developer is ferric sulfate Ammonium.
Described absorbent is 0.03mg/ml with the described mixed mass concentration of diluent pure water.
After the phosphorus pentoxide is mixed in the diluent, its mass concentration is 25g/L.
Described developer is ammonium ferric sulfate that mass concentration is 1.5%.
Acidulant is added with the phenol reagent, the acidulant is phosphorus pentoxide powder, while acidulant plays drying Agent is acted on, and keeps reagent to dry.
Described colorimetric card preparation process is:By the absorbent and acidulant by the dilution dilution agent, with difference The formaldehyde of concentration reacts with the absorbent after above-mentioned dilution, by reaction solution with the chromogenic reagent, is prepared according to colour developing degree Standard color comparison card.
After such scheme, the present invention, as absorbent, is acidified using phenol reagent using phosphorus pentoxide, is used Ammonium ferric sulfate prepares standard color comparison card as developer again by mentioned reagent, for indoor formaldehyde concentration detection more For accurate, quick, convenient.
More specifically, the invention has the advantages that:
1st, sensitivity is high:It is high with formaldehyde reaction sensitivity using the phenol reagent of optimum proportioning, acidulant, it is more beneficial for inspection Survey, more quickly, convenient.
2nd, low cost:Phenol reagent price most expensive in the detection process, compared to more published several kit patents Technology, the phenol reagent addition of this method is minimum.
3rd, using acidulant:The need of detection process make solution keep acidifying state.In published detection method, typically make It is acidified with sulfuric acid, nitric acid or hydrochloric acid etc., process is complicated.This method is mixed using phenol reagent with phosphorus pentoxide, five oxidations Two phosphorus can ensure phenol reagent stabilization during usually storing, and serve as drier;It is dissolved in absorption process and process color After water, solution acidifying makes that absorption process is rapid, chromogenic reaction stabilization is carried out.Above procedure causes kit medicament of the invention Reasonable mixture ratio, process is simple, favorable reproducibility.
Brief description of the drawings
Fig. 1 is the schematic diagram of standard color comparison card of the present invention.
Specific embodiment
The invention will be further described with specific embodiment below in conjunction with the accompanying drawings.
Disclosed is a kind of air formaldehyde self testing kit, it includes absorbent, acidulant, diluent, developer And colorimetric card.The principle of the box of testing oneself is using the formaldehyde and MBTH in air(Abbreviation phenol reagent) Reaction generation piperazine, piperazine aoxidizes to form blue-green compound by ferric ion in an acidic solution, the shade of the compound with The content of formaldehyde is directly proportional, after developing time 30min, by colorimetric assay.The principle is according to national standard Law《Public place Method for determining formaldehyde in air phenol reagent method》(GB/T18204.26-2000).
Described absorbent selects phenol reagent, in order to prevent the moisture in air from influenceing measurement result, can be to absorbent Phosphorus pentoxide is added in phenol reagent as drier, and is positioned over simultaneously in a box, and sealing preserve.
Described acidulant is phosphorus pentoxide, and it shows acidity after being dissolved in water.
Described diluent selects pure water.
The phenol reagent of configuration is 0.3mg in described testing cassete, and diluent pure water is 10ml, and mixed solution is matter during test Amount concentration is the phenol reagent solution of 0.03mg/ml.
The determination of the acidulant, developer:The piperazine generated according to formaldehyde and phenol reagent in an acidic solution by high ferro from Son oxidation forms blue-green compound, and respectively with acidified ammonium ferric sulfate solution, sulphation ammonium ferric sulfate, nitrification ferric sulfate Ammonium and phosphorus pentoxide solution acidifying ammonium ferric sulfate, according to color developing effect, it is determined that optimal color condition is phosphorus pentoxide quality Concentration is 25g/L, and ammonium ferric sulfate is mass concentration 1.5%..
Acidulant uses phosphorus pentoxide 250mg in kit, is dissolved in 10ml water.
Developer uses the ammonium ferric sulfate of mass concentration 1.5%
The preparation of the colorimetric card:Determine standard ratio using above-mentioned selected absorbent, acidulant, diluent, developer Colour atla.Described absorbent and acidulant are first diluted to mass concentration for 0.03mg/ml by the diluent, it is dense with formaldehyde Degree respectively 0.05,0.10,0.20,0.40,0.60,0.80,1.20mg/m3Formaldehyde it is anti-with absorbent after above-mentioned dilution Should, by reaction solution with the chromogenic reagent, standard color comparison card is prepared according to colour developing degree, as shown in Figure 1.
Detection process of the invention is:Absorbent, acidulant are first carried out into a certain proportion of dilution with diluent, is then put In the interior to be detected, a period of time is placed, the formaldehyde in phenol reagent absorption air, reaction generation piperazine is added colour developing afterwards Agent, developing time is 30min or so, observes color and is contrasted with colorimetric card, judges indoor formaldehyde content.It is common according to the Chinese people With state's national standard《The sanitary standard of formaldehyde in indoor air》(GB/T 18883-2002)Regulation:Formaldehyde in indoor air Maximum permissible concentration is 0.08 mg/m3.If colour developing exceedes colorimetric card left side secondary series, it is believed that formaldehyde in room.
Air formaldehyde self testing kit test result of the present invention and the test result of GB phenol reagent method are entered Row contrast experiment:
The air formaldehyde self testing kit formula for being worked out with GB phenol reagent method and the present invention respectively, between three In the room of different concentration of formaldehyde, the measurement of air formaldehyde concentration is synchronously carried out.
Test oneself result that box obtains of formaldehyde compares reading and obtains the concentration of formaldehyde in three rooms and is respectively according to colorimetric card: 0.05 mg/m3、0.2~0.4 mg/m3、0.2 mg/m3
And the absorbance of chromophoric solution between three rooms is measured according to National Standard Method, calculate public further according to air formaldehyde concentration Formula C=A*T/V0Conversion is obtained, and the concentration of formaldehyde in three rooms is respectively 0.05mg/m3, 0.242 mg/m3, 0.218 mg/m3
Contrast the result of two methods, it is seen then that the result of air formaldehyde self testing kit, meet the requirement of half-quantitative detection, its Result is close with the measurement result of National Standard Method, scientific with it.This method provide a kind of relatively simple self-testing method.
The above, is only presently preferred embodiments of the present invention, and not technical scope of the invention is imposed any restrictions, Therefore the change or modification that claim under this invention and specification are done in every case, should all belong to the scope that patent of the present invention covers Within.

Claims (4)

1. a kind of air formaldehyde self testing kit, it is characterised in that:Including absorbent, acidulant, diluent, developer and colorimetric card; Described absorbent is phenol reagent, and described acidulant is phosphorus pentoxide powder, and described diluent is pure water, and described is aobvious Toner is ammonium ferric sulfate;Described acidulant, and sealing preserve simultaneously are added with the phenol reagent;
After the phosphorus pentoxide is mixed in the diluent, its mass concentration is 25g/L.
2. air formaldehyde self testing kit according to claim 1, it is characterised in that:Described absorbent and described diluent The mixed mass concentration of pure water is 0.03mg/mL.
3. air formaldehyde self testing kit according to claim 1, it is characterised in that:Described developer is for mass concentration 1.5% ammonium ferric sulfate.
4. air formaldehyde self testing kit according to claim 1, it is characterised in that:Described colorimetric card preparation process is:Will The absorbent and acidulant are diluted simultaneously by the diluent, with the absorbent after the formaldehyde of various concentrations and above-mentioned dilution Reaction, by reaction solution with the chromogenic reagent, standard color comparison card is prepared according to colour developing degree.
CN201310611950.3A 2013-11-27 2013-11-27 Air formaldehyde self testing kit Expired - Fee Related CN103698324B (en)

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Publication number Priority date Publication date Assignee Title
CN105021597A (en) * 2014-04-30 2015-11-04 张晓咪 Air formaldehyde detection device
CN104390959A (en) * 2014-11-06 2015-03-04 常熟市苏常工程质量检测有限公司 Method for detecting content of formaldehyde in house
CN104436985A (en) * 2014-11-18 2015-03-25 苏州东辰林达检测技术有限公司 Formaldehyde absorbing material and preparation method thereof
CN105352950A (en) * 2015-10-24 2016-02-24 佛山市奥朗科技有限公司 Detection medicament and method for rapid detection of formaldehyde content in air
CN107525801A (en) * 2017-07-17 2017-12-29 贵州金洋检测工程有限公司 A kind of formaldehyde in air content assaying method
CN108514867B (en) * 2018-04-18 2020-09-22 北京化工大学 Preparation of sodium alginate gel beads for detecting formaldehyde
CN111504991A (en) * 2020-04-30 2020-08-07 军事科学院军事医学研究院环境医学与作业医学研究所 Kit for detecting formaldehyde gas
CN113884482A (en) * 2020-07-02 2022-01-04 海南光宇生物科技有限公司 Formaldehyde self-testing box with biological cellulose membrane as reagent carrier
CN112858279A (en) * 2021-02-04 2021-05-28 江苏中烟工业有限责任公司 Method for rapidly determining residual amount of formaldehyde in water-based adhesive
CN113125426A (en) * 2021-04-07 2021-07-16 山西工程职业学院 Use method of portable accurate formaldehyde analysis box

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JPWO2004111635A1 (en) * 2003-06-12 2006-07-27 株式会社東洋発酵 Composition for aldehyde detection
CN1661360A (en) * 2004-02-27 2005-08-31 上海塞艾生物科技有限公司 One-off simple rapid test kit for color matching formaldehyde and preparation method
CN101029870A (en) * 2006-02-28 2007-09-05 张佃志 Methanal fast-inspecting reagent unit and its production
CN102565043A (en) * 2011-12-16 2012-07-11 邯郸派瑞电器有限公司 Kit capable of quickly detecting formaldehyde in air

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