CN103696225A - Textile oxygen bleaching stabilizer - Google Patents
Textile oxygen bleaching stabilizer Download PDFInfo
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- CN103696225A CN103696225A CN201310610433.4A CN201310610433A CN103696225A CN 103696225 A CN103696225 A CN 103696225A CN 201310610433 A CN201310610433 A CN 201310610433A CN 103696225 A CN103696225 A CN 103696225A
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- hydrogen peroxide
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Abstract
The invention relates to a textile oxygen bleaching stabilizer, and belongs to the technical field of textile auxiliaries. The stabilizer comprises the following components by weight: 8-10 parts of tartaric acid, 2-5 parts of polymalic acid, 6-8 parts of polyacrylamide, 20-40 parts of a chelating agent, 2-5 parts of a surfactant and 60-80 parts of water. The textile oxygen bleaching stabilizer provided by the invention has strong pigment adsorption effect and good bleaching effect, and can effectively prevent deposition and adhesion of silicon scale on the fabric surface, and the bleached textile does not gain rough or hard hand feel; at the same time, the stabilizer can effectively control the decomposition rate of hydrogen peroxide, and effectively avoid local holes on fiber and damage to the fiber.
Description
Technical field
The invention belongs to textile auxiliary technical field, be specifically related to a kind of textile hydrogen peroxide bleaching stabilizer.
Background technology
H
2o
2classical chemical products, hydrogen peroxide bleaching agent is because of its good stability, etching apparatus not, pollution-free, and be widely used in the bleaching process of cellulose fibre and other fiber, it is a kind of good bleaching agent, product whiteness good stability, environmentally safe, because of but a kind of rising bleaching agent.In bleaching process, H
2o
2decomposition often uncontrolled, cause H
2o
2waste, occur that whiteness is poor, the decline of fibre strength, problems such as occurring broken hole bleaches cloth.For hydrogen peroxide evenly, is effectively decomposed in bleaching process, avoid fabric to suffer violent damage, in bleaching liquor, must add a certain amount of stabilizing agent, i.e. hydrogen peroxide bleaching stabilizer.
Hydrogen peroxide bleaching stabilizer claims again hydrogen peroxide stabilizer, is mainly in the market silicon class hydrogen peroxide bleaching stabilizer, and its main component is sodium metasilicate, it is obvious that it absorbs pigment effect, and bleaching effect is outstanding, but it is prone to silicon dirt, silicon dirt deposition, on fabric, causes that fabric is coarse to harden, and is difficult to especially rinsing.Therefore research staff mainly researches and develops towards the direction of non-silicon class hydrogen peroxide bleaching stabilizer at present, although some non-silicon class hydrogen peroxide bleaching stabilizers that occur on market, their adsorpting pigment ability, after bleaching, product whiteness is low.Therefore how overcoming the deficiencies in the prior art is problems that current textile auxiliary technical field is needed solution badly.
Summary of the invention
The object of the invention is, in order to solve the deficiencies in the prior art, provides a kind of textile hydrogen peroxide bleaching stabilizer, and this hydrogen peroxide bleaching stabilizer not only bleaching effect is good, and can effectively stop silicon dirt deposition to stick to fabric face.
The technical solution used in the present invention is as follows:
A textile hydrogen peroxide bleaching stabilizer, comprises the following component according to parts by weight meter: 8 ~ 10 parts, tartaric acid, 2 ~ 5 parts of polymalic acids, 6 ~ 8 parts of poly amic acids, 20 ~ 40 parts of chelating agents, 2 ~ 5 parts, surfactant, 60 ~ 80 parts, water.
Further preferably described chelating agent is gluconic acid sodium salt or sodium tartrate.
Further preferably described surfactant is polyoxyethylene carboxylate.
The preparation method of above-mentioned textile hydrogen peroxide bleaching stabilizer mixes the raw material of aforementioned proportion and is stirred to mix to make by physical method.
compared with prior art, its beneficial effect is in the present invention:product adsorpting pigment of the present invention effect is strong, and bleaching effect is good, can effectively stop silicon dirt deposition to stick to fabric face, and the textiles feel of bleaching is hardened without coarse; This textile hydrogen peroxide bleaching stabilizer can effectively be controlled the decomposition rate of hydrogen peroxide, has effectively avoided the local broken hole of fiber, without fiber damaged phenomenon.
Specific embodiment
Below in conjunction with embodiment, the present invention is described in further detail.
Embodiment 1
A textile hydrogen peroxide bleaching stabilizer, comprises the following component according to parts by weight meter: 8 parts, tartaric acid, 2 parts of polymalic acids, 6 parts of poly amic acids, 20 parts of gluconic acid sodium salts, 2 parts of polyoxyethylene carboxylates, 60 parts, water.
The preparation method of the present embodiment textile hydrogen peroxide bleaching stabilizer mixes the raw material of aforementioned proportion and is stirred to mix to make by physical method.
Embodiment 2
A textile hydrogen peroxide bleaching stabilizer, comprises the following component according to parts by weight meter: 10 parts, tartaric acid, 5 parts of polymalic acids, 8 parts of poly amic acids, 40 parts of gluconic acid sodium salts, 5 parts of polyoxyethylene carboxylates, 80 parts, water.
The preparation method of the present embodiment textile hydrogen peroxide bleaching stabilizer mixes the raw material of aforementioned proportion and is stirred to mix to make by physical method.
Embodiment 3
A textile hydrogen peroxide bleaching stabilizer, comprises the following component according to parts by weight meter: 8 ~ 10 parts, tartaric acid, 3 parts of polymalic acids, 7 parts of poly amic acids, 30 parts of gluconic acid sodium salts, 4 parts of polyoxyethylene carboxylates, 70 parts, water.
The preparation method of the present embodiment textile hydrogen peroxide bleaching stabilizer mixes the raw material of aforementioned proportion and is stirred to mix to make by physical method.
Embodiment 4
A textile hydrogen peroxide bleaching stabilizer, comprises the following component according to parts by weight meter: 9 parts, tartaric acid, 4 parts of polymalic acids, 7 parts of poly amic acids, 35 parts of sodium tartrates, 3 parts of polyoxyethylene carboxylates, 66 parts, water.
The preparation method of the present embodiment textile hydrogen peroxide bleaching stabilizer mixes the raw material of aforementioned proportion and is stirred to mix to make by physical method.
According to following bleaching prescription and technique, oxygenation bleaching stibilizer carries out bleaching to cotton, and bleaching effect is measured.Pure cotton grey fabric is first passed through to kiering, then bleach.
Bleaching prescription: 30% hydrogen peroxide 15g/L
Caustic soda 6g/L
Bleeding agent 4g/L
Hydrogen peroxide bleaching stabilizer 8g/L
Bleaching process: two enter two rolls, through washing, oven dry, detects according to GB/T8424.2-2001, and test result is shown in Table 1.
Table 1 test result
| ? | Fabric whiteness | Have or not the coarse feel of hardening | Have or not broken hole or damage phenomenon | Have or not silicon dirt |
| Embodiment 1 | 92.2 | Nothing | Nothing | Nothing |
| Embodiment 2 | 90.1 | Nothing | Nothing | Nothing |
| Embodiment 3 | 94.3 | Nothing | Nothing | Nothing |
| Embodiment 4 | 93.8 | Nothing | Nothing | Nothing |
Claims (3)
1. a textile hydrogen peroxide bleaching stabilizer, is characterized in that comprising the following component according to parts by weight meter: 8 ~ 10 parts, tartaric acid, 2 ~ 5 parts of polymalic acids, 6 ~ 8 parts of poly amic acids, 20 ~ 40 parts of chelating agents, 2 ~ 5 parts, surfactant, 60 ~ 80 parts, water.
2. textile hydrogen peroxide bleaching stabilizer according to claim 1, is characterized in that described chelating agent is gluconic acid sodium salt or sodium tartrate.
3. textile hydrogen peroxide bleaching stabilizer according to claim 1, is characterized in that described surfactant is polyoxyethylene carboxylate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310610433.4A CN103696225A (en) | 2013-11-27 | 2013-11-27 | Textile oxygen bleaching stabilizer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310610433.4A CN103696225A (en) | 2013-11-27 | 2013-11-27 | Textile oxygen bleaching stabilizer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103696225A true CN103696225A (en) | 2014-04-02 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310610433.4A Withdrawn CN103696225A (en) | 2013-11-27 | 2013-11-27 | Textile oxygen bleaching stabilizer |
Country Status (1)
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| CN (1) | CN103696225A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104532541A (en) * | 2014-12-30 | 2015-04-22 | 四川益欣科技有限责任公司 | Efficient alkali-resistant non-silicone oxidation bleaching stabilizer as well as preparation method and application thereof |
| CN105019270A (en) * | 2015-07-28 | 2015-11-04 | 山东黄河三角洲纺织科技研究院有限公司 | Hydrogen peroxide bleaching stabilizer for cotton fabrics |
| CN105625013A (en) * | 2016-01-25 | 2016-06-01 | 苏州印丝特纺织数码科技有限公司 | Polyacrylic acid type hydrogen peroxide stabilizer for weaving and preparation method thereof |
| CN108951097A (en) * | 2018-07-20 | 2018-12-07 | 郦璋 | A kind of textile hydrogen peroxide bleaching stabilizer |
| CN109989260A (en) * | 2019-04-20 | 2019-07-09 | 潍坊军涛化工有限公司 | A kind of hydrogen peroxide bleaching stabilizer and its preparation method and application |
| CN111560768A (en) * | 2019-02-14 | 2020-08-21 | 柳州煜华科技有限公司 | Phosphorus-free and silicon-oxygen-free bleaching stabilizer and preparation method thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104532541A (en) * | 2014-12-30 | 2015-04-22 | 四川益欣科技有限责任公司 | Efficient alkali-resistant non-silicone oxidation bleaching stabilizer as well as preparation method and application thereof |
| CN104532541B (en) * | 2014-12-30 | 2016-07-13 | 四川益欣科技有限责任公司 | A kind of efficient alkaline-resisting non-silicone oxidation blkeach Stabilizer and its preparation method and application |
| CN105019270A (en) * | 2015-07-28 | 2015-11-04 | 山东黄河三角洲纺织科技研究院有限公司 | Hydrogen peroxide bleaching stabilizer for cotton fabrics |
| CN105625013A (en) * | 2016-01-25 | 2016-06-01 | 苏州印丝特纺织数码科技有限公司 | Polyacrylic acid type hydrogen peroxide stabilizer for weaving and preparation method thereof |
| CN108951097A (en) * | 2018-07-20 | 2018-12-07 | 郦璋 | A kind of textile hydrogen peroxide bleaching stabilizer |
| CN108951097B (en) * | 2018-07-20 | 2020-11-20 | 浙江鹿达科技有限公司 | Textile oxygen bleaching stabilizer |
| CN111560768A (en) * | 2019-02-14 | 2020-08-21 | 柳州煜华科技有限公司 | Phosphorus-free and silicon-oxygen-free bleaching stabilizer and preparation method thereof |
| CN109989260A (en) * | 2019-04-20 | 2019-07-09 | 潍坊军涛化工有限公司 | A kind of hydrogen peroxide bleaching stabilizer and its preparation method and application |
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Application publication date: 20140402 |