CN103695641A - High-calcium consolidation agent for cold-solidifying ball-pressing process and using method of high-calcium consolidation agent - Google Patents
High-calcium consolidation agent for cold-solidifying ball-pressing process and using method of high-calcium consolidation agent Download PDFInfo
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- CN103695641A CN103695641A CN201310655560.6A CN201310655560A CN103695641A CN 103695641 A CN103695641 A CN 103695641A CN 201310655560 A CN201310655560 A CN 201310655560A CN 103695641 A CN103695641 A CN 103695641A
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- Prior art keywords
- calcium
- solidifying agent
- consolidation agent
- consolidation
- high calcium
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 39
- 238000000034 method Methods 0.000 title claims abstract description 25
- 239000011575 calcium Substances 0.000 title claims abstract description 21
- 229910052791 calcium Inorganic materials 0.000 title claims abstract description 21
- 238000007596 consolidation process Methods 0.000 title abstract description 17
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 50
- 229910052742 iron Inorganic materials 0.000 claims abstract description 25
- 239000000463 material Substances 0.000 claims abstract description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 18
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims abstract description 16
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims abstract description 13
- 239000000428 dust Substances 0.000 claims abstract description 9
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 9
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 9
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims abstract description 8
- 235000019341 magnesium sulphate Nutrition 0.000 claims abstract description 8
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 10
- 150000002500 ions Chemical class 0.000 claims description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- 229960001866 silicon dioxide Drugs 0.000 claims description 5
- 238000010298 pulverizing process Methods 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
- 239000005864 Sulphur Substances 0.000 claims description 2
- 235000011132 calcium sulphate Nutrition 0.000 claims description 2
- 239000000843 powder Substances 0.000 abstract description 10
- HGUFODBRKLSHSI-UHFFFAOYSA-N 2,3,7,8-tetrachloro-dibenzo-p-dioxin Chemical compound O1C2=CC(Cl)=C(Cl)C=C2OC2=C1C=C(Cl)C(Cl)=C2 HGUFODBRKLSHSI-UHFFFAOYSA-N 0.000 abstract description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 239000011499 joint compound Substances 0.000 description 7
- 239000011230 binding agent Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 238000003723 Smelting Methods 0.000 description 4
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 3
- 230000004523 agglutinating effect Effects 0.000 description 3
- 229910052925 anhydrite Inorganic materials 0.000 description 3
- 239000003245 coal Substances 0.000 description 3
- 229910052681 coesite Inorganic materials 0.000 description 3
- 229910052906 cristobalite Inorganic materials 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 238000005272 metallurgy Methods 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 239000010802 sludge Substances 0.000 description 3
- 229910052682 stishovite Inorganic materials 0.000 description 3
- 229910052905 tridymite Inorganic materials 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- 241000370738 Chlorion Species 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 239000003546 flue gas Substances 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- MAZPIOPHRNWBNG-UHFFFAOYSA-N [Cl-].Cl[NH3+].[Na] Chemical compound [Cl-].Cl[NH3+].[Na] MAZPIOPHRNWBNG-UHFFFAOYSA-N 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009851 ferrous metallurgy Methods 0.000 description 1
- 239000003500 flue dust Substances 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
Landscapes
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The invention provides a high-calcium consolidation agent for a cold-solidifying ball-pressing process. The high-calcium consolidation agent comprises the following components in parts by mass: 30-75 parts of calcium sulfate, 8-35 parts of magnesium sulfate, 0-1 part of silicon dioxide and 0-0.5 part of aluminum oxide, wherein dosing amount of a high-calcium consolidation agent accounts for 3%-7% of the total weight of the materials. The novel consolidation agent has consolidation strength as high as 1500N-3000N, is wide in scope of application, not only is suitable for various iron-containing dust mud materials, but also is applicable to iron sheet oxide type large particles or metallurgical powder with cohesiveness, so that a dioxin pollution problem caused by a chlorine-containing consolidation agent is solved; moreover, the consolidation agent is wide in material resource and low in price.
Description
Technical field
The present invention relates to ferrous metallurgy field, particularly a kind of cold fixed ball press technique high calcium solidifying agent and using method.
Background technology
In metallurgical industry production process, can produce a large amount of flue dust, mud, iron scale and other powdery regenerants, the iron-holder of these powdery regenerants up to 45% and more than, utilize cold-consolidation pellet process to process these pulverulent materials, have that technique is simple, a less investment, instant effect, the saving energy, low cost and other advantages.The annual production of China's iron and steel is 3.5 hundred million tons according to statistics, the iron content secondary iron-containing resource of association approximately produces more than ten million ton every year, generally adopt wilkinite, water glass, cement as binding agent, mostly have the problem that green-ball Pulverization ratio is high, rate of drying is slow, intensity is low, ferrous grade reduces.
200510026046.1 disclose a kind of adhesive for fast consolidation of cold solidified pellet, and its component comprises calcium oxide, silicon-dioxide, magnesium oxide, aluminium sesquioxide, ferric oxide and manganese oxide.Its solidifying agent is applied in cold fixed ball press technique that ion dust mud contaning or ion dust mud contaning contain.Yet this binding agent is smelted for metallurgical, has certain material limitation, is not suitable for the cold fixed ball press technique of the poor material of the macrobeads such as iron scale or agglutinating value(of coal).
200610031958.2 disclose a kind of adhesive for fast consolidation of cold solidified pellet, and its component comprises magnesium chloride, calcium chloride, iron(ic) chloride, sodium-chlor, ammonium chloride.Binding agent with addition of amount, be the 1.5-2.0% of raw material gross weight.Yet this binding agent is under the metallurgical smelting process condition of high temperature, chlorion enters flue gas, pipeline and fume treatment auxiliary is worked the mischief, and use this binding agent, and chlorion enters in atmosphere with flue gas, also can increase the generation of toxicant dioxin.
Summary of the invention
The object of the invention be to provide a kind of use range more extensively, cost is lower and meet solidifying agent and the using method of the cold consolidation technique service requirements of metallurgy powder, and solves the chloride difficult problem of cold fixed pressure ball solidifying agent.
A kind of cold fixed ball press technique high calcium solidifying agent of realizing the object of the invention, comprises calcium sulfate, magnesium sulfate, silicon-dioxide, aluminium sesquioxide and sulphur, and in mass parts, each component concentration is as follows:
A high calcium solidifying agent, in mass parts, each component concentration is as follows:
A high calcium solidifying agent, in mass parts, each component concentration is as follows:
Calcium sulfate 30.8
Magnesium sulfate 33.3
Silicon-dioxide 0.4
A high calcium solidifying agent, in mass parts, each component concentration is as follows:
The using method of above-mentioned any one high calcium solidifying agent, the amount of allocating into of described high calcium solidifying agent is the 3-7wt% of material total mass.
After described material and described high calcium solidifying agent mix, the moisture of controlling mixture is 2-8wt%.
Described material is ion dust mud contaning and iron scale, and wherein said iron scale pulverizing and jevigating is less than 5mm to granularity, and the quality proportioning of ion dust mud contaning and iron scale is greater than 1/3.
This novel solidifying agent utilizes raw material itself to meet the feature of water fast solidifying, easy electrolysis, not only guaranteed finished ball falling and stacking intensity at pelletizing initial stage, and along with the degree of consolidation of time lapse ferrous material own deepens to have guaranteed falling and ultimate compression strength of its later stage, consolidation strength is up to 1500-3000N.Applied widely, be not only applicable to all kinds of ion dust mud contaning materials, be also applicable to the poor metallurgy powder of iron scale class macrobead or agglutinating value(of coal); And can solve chloride solidifying agent and bring the pollution problem of dioxin.And this solidifying agent raw material drawing is extensive, cheap.
Embodiment
For better explanation the present invention, below the technical scheme in the embodiment of the present invention is clearly and completely described.
Embodiment 1
(1) become granularity to be less than the powder of 5mm iron scale crushing grinding;
(2) prepare novel solidifying agent, meter is got CaSO4 content 59.0kg, MgSO4 content 17.2kg, SiO2 content 0.7kg, Al2O3 content 0.1kg;
(3) under normal temperature and pressure conditions, by solidifying agent, by outer dosage 4Wt%, join in the powder of iron containing sludge and iron scale (proportioning is greater than 1:3), material is mixed, guarantee mixture moisture 2-8%;
(4) by conveyor, will mix material and be delivered to ball press feed bin, pressure ball is transported to smelting furnace after balling-up after stacking 12-24h under finished ball normal temperature and pressure, uses.
Embodiment 2
(1) become granularity to be less than the powder of 5mm iron scale crushing grinding;
(2) prepare novel solidifying agent, meter is got CaSO4 content 30.8kg, MgSO4 content 33.3kg, SiO2 content 0.4kg;
(3) under normal temperature and pressure conditions, solidifying agent joins in the powder of iron containing sludge and iron scale (proportioning is greater than 1:3) by outer dosage 5Wt%, and material is mixed, and guarantees mixture moisture 2-8%;
(4) by conveyor, will mix material and be delivered to ball press feed bin, pressure ball is transported to smelting furnace after balling-up after stacking 12-24h under finished ball normal temperature and pressure, uses.
Embodiment 3
(1) become granularity to be less than the powder of 5mm iron scale crushing grinding;
(2) prepare novel solidifying agent, meter is got CaSO4 content 38.3kg, MgSO4 content 28.7kg, SiO2 content 0.5kg, Al2O3 content 0.1kg;
(3) under normal temperature and pressure conditions, solidifying agent joins in the powder of iron containing sludge and iron scale (proportioning is greater than 1:3) by outer dosage 6Wt%, and material is mixed, and guarantees mixture moisture 2-8%;
(4) by conveyor, will mix material and be delivered to ball press feed bin, pressure ball is transported to smelting furnace after balling-up after stacking 12-24h under finished ball normal temperature and pressure, uses.
This novel solidifying agent utilizes raw material itself to meet the feature of water fast solidifying, easy electrolysis, not only guaranteed finished ball falling and stacking intensity at pelletizing initial stage, and along with the degree of consolidation of time lapse ferrous material own deepens to have guaranteed falling and ultimate compression strength of its later stage, consolidation strength is up to 1500-3000N.Applied widely, be not only applicable to all kinds of ion dust mud contaning materials, be also applicable to the poor metallurgy powder of iron scale class macrobead or agglutinating value(of coal); And can solve chloride solidifying agent and bring the pollution problem of dioxin.And this solidifying agent raw material drawing is extensive, cheap.
The above; be only the present invention's embodiment preferably, but protection scope of the present invention is not limited to this, is anyly familiar with in technical scope that those skilled in the art disclose in the present invention; the variation that can expect easily or replacement, within all should being encompassed in protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain of claims.
Claims (7)
1. a cold fixed ball press technique high calcium solidifying agent, is characterized in that, comprises calcium sulfate, magnesium sulfate, silicon-dioxide, aluminium sesquioxide and sulphur, and in mass parts, each component concentration is as follows:
。
2. knot ball press technique high calcium solidifying agent according to claim 1, is characterized in that, in mass parts, each component concentration is as follows:
。
3. knot ball press technique high calcium solidifying agent according to claim 1, is characterized in that, in mass parts, each component concentration is as follows:
Calcium sulfate 30.8
Magnesium sulfate 33.3
Silicon-dioxide 0.4.
4. knot ball press technique high calcium solidifying agent according to claim 1, is characterized in that, in mass parts, each component concentration is as follows:
5. the using method of high calcium solidifying agent for the knot ball press technique described in claim 1-4 any one, is characterized in that, the amount of allocating into of described high calcium solidifying agent is the 3-7wt% of material total mass.
6. using method according to claim 5, is characterized in that, after described material and described high calcium solidifying agent mix, the moisture of controlling mixture is 2-8wt%.
7. using method according to claim 6, is characterized in that, described material is ion dust mud contaning and iron scale, and wherein said iron scale pulverizing and jevigating is less than 5mm to granularity, and the quality proportioning of ion dust mud contaning and iron scale is greater than 1/3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310655560.6A CN103695641B (en) | 2013-12-06 | 2013-12-06 | One freezes off knot ball press technique high calcium consolidating agent and using method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310655560.6A CN103695641B (en) | 2013-12-06 | 2013-12-06 | One freezes off knot ball press technique high calcium consolidating agent and using method |
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| Publication Number | Publication Date |
|---|---|
| CN103695641A true CN103695641A (en) | 2014-04-02 |
| CN103695641B CN103695641B (en) | 2016-08-17 |
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| Application Number | Title | Priority Date | Filing Date |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105219956A (en) * | 2015-10-30 | 2016-01-06 | 兰州大学 | A kind of preparation method of iron powder coal-pressing ball compound binding agent |
| CN114605131A (en) * | 2022-02-16 | 2022-06-10 | 南阳师范学院 | Magnesium oxide acetate adhesive for cold consolidation forming of solid powder |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11285777A (en) * | 1998-04-02 | 1999-10-19 | Nissan Motor Co Ltd | Casting mold and manufacture of casting mold |
| CN1778976A (en) * | 2004-11-21 | 2006-05-31 | 黄志勇 | Pyrolusite blocks and production thereof |
| CN1865459A (en) * | 2005-05-20 | 2006-11-22 | 上海盘龙实业有限公司 | Novel binding agent for normal temperature pelletized and cured iron-containing mud cold-cured pellet |
| CN1888095A (en) * | 2006-07-14 | 2007-01-03 | 中南大学 | Adhesive for fast consolidation of cold solidified pellet |
-
2013
- 2013-12-06 CN CN201310655560.6A patent/CN103695641B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11285777A (en) * | 1998-04-02 | 1999-10-19 | Nissan Motor Co Ltd | Casting mold and manufacture of casting mold |
| CN1778976A (en) * | 2004-11-21 | 2006-05-31 | 黄志勇 | Pyrolusite blocks and production thereof |
| CN1865459A (en) * | 2005-05-20 | 2006-11-22 | 上海盘龙实业有限公司 | Novel binding agent for normal temperature pelletized and cured iron-containing mud cold-cured pellet |
| CN1888095A (en) * | 2006-07-14 | 2007-01-03 | 中南大学 | Adhesive for fast consolidation of cold solidified pellet |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105219956A (en) * | 2015-10-30 | 2016-01-06 | 兰州大学 | A kind of preparation method of iron powder coal-pressing ball compound binding agent |
| CN114605131A (en) * | 2022-02-16 | 2022-06-10 | 南阳师范学院 | Magnesium oxide acetate adhesive for cold consolidation forming of solid powder |
| CN114605131B (en) * | 2022-02-16 | 2023-11-14 | 南阳师范学院 | Magnesium oxide acetate adhesive for cold consolidation molding of solid powder |
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| CN103695641B (en) | 2016-08-17 |
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Denomination of invention: High-calcium consolidation agent for cold-solidifying ball-pressing process and using method of high-calcium consolidation agent Effective date of registration: 20180327 Granted publication date: 20160817 Pledgee: Tianfeng Securities Co.,Ltd. Pledgor: Shenwu Technology Group Co.,Ltd. Registration number: 2018990000229 |
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