Background technology
Asphalt, as a kind of heat-sink material, reaches 0.85 ~ 0.95 to sunlight heat specific absorption, and the high-absorbility of bituminous pavement to sunlight causes asphalt pavement warm to spend high major cause.Due to China's most area, the highest temperature in summer can reach 35 DEG C ~ 40 DEG C, and under sunlight prolonged exposure, amount of heat is absorbed by bituminous pavement and accumulates in bituminous pavement, the temperature of bituminous pavement can reach 63 DEG C ~ 68 DEG C, and makes bituminous pavement produce rut.High temperature is the most direct inducement that rut produces: high temperature makes the rheological property of pitch transform from visco-elasticity to plasticity, and stiffness modulus declines to a great extent, and its non-deformability sharply reduces, under the effect of vehicular load, just occur serious rut.Current pavement material circle extensively adopts modifying asphalt, uses high-quality to gather materials, adopts extruded aggregate grating, adds the high-temperature behavior that the measures such as anti-rut agent improve bituminous pavement, but due to the thermally sensitive intrinsic propesties of bituminous material, these measures fundamentally do not solve bituminous pavement high temperature rut problem yet.
Meanwhile, China's urban road mats formation form mainly based on bituminous pavement, and the amount of heat of bituminous pavement accumulation seriously exacerbates " tropical island effect " in city.And the current general measure solving city " tropical island effect " improves urban forest cover rate and expands meadow, water ground area, to change the state of city underlying surface, but city is a region that building height is intensive, road height is densely covered, the forest coverage in city etc. are extremely difficult to be improved.
And China's pavement of road mostly is grey or black, grey and the neural system of black to people have calm effect, but watching dull grey road surface for a long time attentively can make driver attention slow up, bring out fatigue, even drowsy, the danger of generation traffic accident is increased.
Therefore, for Bituminous Pavement Wheel Rut Question, " tropical island effect " in city and the single dull problem of pavement of road color, be necessary that exploitation one possesses heat reflectivity, the caloric receptivity of bituminous pavement can be reduced, greatly reduce bituminous pavement temperature, reduce asphalt pavement rut disease, alleviate city " tropical island effect ", aesthetic road view, improve the high-molecular compounded and modified color asphalt of heat-reflective of traffic safety, itself and certain graded aggregate compound are made heat-reflective chromatic bitumen mixture to pave in road surface, play reflection, radiation solar heat, reduce bituminous pavement temperature, prevent asphalt pavement rut from injuring, reduce the effect of urban heat land effect to a certain extent simultaneously.
Summary of the invention
The object of the invention is to overcome above-mentioned shortcoming, provide one significantly can reduce bituminous pavement temperature, reduce asphalt pavement rut disease, alleviate city " tropical island effect " and the high-molecular compounded and modified color emulsified asphalt of heat-reflective of aesthetic road view, raising traffic safety.
Another object of the present invention is to provide the high-molecular compounded and modified color emulsified asphalt compound of a kind of heat-reflective.
For reaching the object of the invention, the present invention adopts following technical scheme: the high-molecular compounded and modified color emulsified asphalt of a kind of heat-reflective, it is characterized in that: it comprises the raw material of following weight part: light colour resin emulsion 35 ~ 75 parts, resin aqueous emulsion 15 ~ 45 parts, near-infrared reflection pigment 1 ~ 5 part, sericite in powder 1 ~ 3.5 part, 1 ~ 3.5 part, nano-far-infrared radiation powder, dispersion agent 0.4 ~ 0.5 part and 2 ~ 10 parts, water, various starting material are weighed according to above-mentioned weight part, first light colour resin emulsion is added into stirring tank, resin aqueous emulsion and dispersion agent and water, open and stir, stir 3 minutes, then add near-infrared reflection pigment (IR pigment), sericite in powder, far-infrared powder to stirring tank, stir 5 minutes, stirring velocity is 1000rad/min, last testing product uniformity coefficient and stability, stop stirring.
The high-molecular compounded and modified color emulsified asphalt of above-mentioned heat-reflective, is characterized in that: described light colour resin emulsion is obtained by the light colour Resin adhesive ramming material emulsification possessing asphalt performance, is divided into cationic and anionic.
The high-molecular compounded and modified color emulsified asphalt of above-mentioned heat-reflective, is characterized in that: described resin aqueous emulsion is the macromolecule resin emulsion with light colour resin emulsion compatibility.
The high-molecular compounded and modified color emulsified asphalt of above-mentioned heat-reflective, it is characterized in that: described near-infrared reflection pigment adopts U.S. Xue Te (Shepherd) company, Jiangsu good fortune Lu (Ferro) company or Japanese many agates to obtain the near-infrared reflection serial pigment of (Tomatec) company, has another name called cold pigment.Through more than 1000 DEG C high-temperature calcinations after described near-infrared reflection pigment is mixed by Multimetal oxide, raw material solid itself starts to react, metal ion in raw material and oxonium ion rearrange, formed and more stable be similar to spinel structure or rutile-type structure, the pigment formed is made to have larger reflection potential in infrared region, to the near infrared ray accounting for 50% in solar radiation, there is higher reflectivity, solar radiant heat directly can be reflected away, reduce the thermal absorption of brea bed, reduce high temperature to the injury of pitch.
The high-molecular compounded and modified color emulsified asphalt of above-mentioned heat-reflective, it is characterized in that: described sericite in powder has high radius-thickness ratio (up to more than 80), high temperature resistant, acid-proof alkaline, maskable uv-radiation, has excellent weather resistance, and can promote the resistance of aging of bituminous material.
The high-molecular compounded and modified color emulsified asphalt of above-mentioned heat-reflective, it is characterized in that: the infrared emittance under described nano-far-infrared radiation powder normal temperature within the scope of wavelength 2-18 μm is up to more than 92%, the solar radiation that bituminous pavement absorbs can be exhaled, reduce pavement temperature, reduce high temperature to the solarization of pitch and rut phenomenon; Preferred Shandong Origine Nanomaterial Engineering Co., Ltd., Shanghai Huzheng Nano-Tech Co., Ltd. and Shanghai nanotechnology and the nano-far-infrared powder applying National Engineering Research Centre company limited.
The high-molecular compounded and modified color emulsified asphalt of above-mentioned heat-reflective, is characterized in that: described dispersion agent to make color stuffing be dispersed in auxiliary agent in water, and the dispersion agent of preferred water resistant type, as NopcosantK, SN5040 and BYK190.
The high-molecular compounded and modified color emulsified asphalt compound of a kind of heat-reflective, it is characterized in that: it comprises the raw material of following weight part: the high-molecular compounded and modified color emulsified asphalt of heat-reflective 25 ~ 45 parts, pH adjusting agent 0.08 part, thickening material 0.10 ~ 0.30 part, grating building stones 50 ~ 70 parts and 5 parts, water, various starting material are weighed according to above-mentioned weight part, first in stirring tank, the high-molecular compounded and modified emulsified bitumen of heat-reflective and pH adjusting agent is added, open and stir, stir 3 minutes, stirring velocity is 600rad/min, system pH is surveyed in sampling, hierarchy of control pH value is 12.50 ± 1.00, then add thickening material to stirring tank, stir 5 minutes, system pH is surveyed in sampling, and hierarchy of control pH value is 12.00 ± 1.00, add grating building stones to stirring tank again, stir 3 minutes, system pH is surveyed in sampling, and the pH value of the hierarchy of control is 11.00 ± 1.00, finally stop stirring, package encapsulation stores.
The high-molecular compounded and modified color emulsified asphalt compound of above-mentioned heat-reflective, is characterized in that: described pH adjusting agent is the auxiliary agent that system can be made to present alkalescence, as NaOH, KOH and AMP-95 etc., and the pH adjusting agent of preferred water tolerance.
The high-molecular compounded and modified color emulsified asphalt compound of above-mentioned heat-reflective, is characterized in that: described thickening material is the auxiliary agent that system can be made to keep storage and the required viscosity of construction, as alkali swelling type thickening material TT-935, TH-300A and A600.
Compared with prior art, the present invention possesses following beneficial effect:
(1) the high-molecular compounded and modified color emulsified asphalt mixture pavement of heat-reflective of the present invention can reduce bituminous pavement surface temperature more than 7 DEG C in summer under the highest temperature.
(2) high temperature makes pitch deliquescing, causes the supporting capacity of bituminous concrete to decline.Data shows, when road table temperature is lower than 55 DEG C, rut can be limited in the scope of several millimeters.When road, table temperature is in the scope of 55 ~ 65 DEG C, and rut will develop with the speed of centimetre-sized.Pitch raises along with temperature, and particularly when pavement temperature reaches about 50 DEG C time, dynamic stability sharply declines.China's most area generally can reach 36 ~ 38 DEG C at the highest temperature in summer, bituminous pavement in this section of high-temperature time is very easy to produce rut, temperature often rises 5 DEG C to have source investigation to show, dynamic stability is by reduction 800 ~ 1000 times/mm, the present invention at least improves dynamic stability 1350 ~ 1650 times/mm of asphalt, significantly improves the high-temperature stability of bituminous pavement and reduces asphalt pavement rut harm.
(3) the present invention is down to 0.25 from 0.9, according to .Pomerantz bituminous pavement to sunlight heat specific absorption
Study known Deng people, this measure can reduce urban atmosphere temperature 1.5 DEG C.As can be seen from above-mentioned data, the present invention reduces urban atmosphere temperature, alleviates city " tropical island effect " effect obviously.
(4) the heat-reflective Colorful Asphalt Pavement of making of the present invention has beautified road landscape, alleviate the eye strain of officer, improve Road safety performance, the traffic capacity of guide and instruct management traffic flow, increase road, red heat reflection type asphalt pavement can remind that officer is careful, enhancing your vigilance property, green heat reflection type asphalt pavement represents quiet, officer can be reminded to put light machine sound and not ring loudspeaker.
(5) the antiskid pendulum value on the high-molecular compounded and modified color emulsified asphalt road surface of heat-reflective of the present invention is greater than 5BPN, and the frictional behaviour impact of road pavement is less.
In sum, bituminous pavement high temperature rut disease significantly can be reduced in the high-molecular compounded and modified color emulsified asphalt road surface of heat-reflective of the present invention, extend bituminous pavement work-ing life, alleviate city " tropical island effect ", aesthetic road view, improve Road safety performance, comprehensive cost be low, formula is simple simultaneously, produce, easy construction.
Embodiment
1, the embodiment of the high-molecular compounded and modified emulsified bitumen of heat-reflective of the present invention
The formula table (unit, kg) of the high-molecular compounded and modified emulsified bitumen embodiment of table 1 heat-reflective of the present invention
The preparation method of the high-molecular compounded and modified color emulsified asphalt embodiment of above-mentioned heat-reflective:
(1) require to weigh various starting material according to above-described embodiment formulating of recipe;
(2) under normal temperature, be added into light colour resin emulsion, resin aqueous emulsion and dispersion agent and water to stirring tank, open and stir, stir 3 minutes;
(3) add near-infrared reflection pigment (IR pigment), sericite in powder, far-infrared powder to stirring tank, stir 5 minutes, stirring velocity is 1000rad/min;
(4) testing product uniformity coefficient and stability, stops stirring.
2, the embodiment of the high-molecular compounded and modified Emulsified Asphalt Mixture of heat-reflective of the present invention
The formula table (unit, kg) of the high-molecular compounded and modified Emulsified Asphalt Mixture embodiment of table 2 heat-reflective of the present invention
The preparation method of above-mentioned heat-reflective high-molecular compounded and modified color emulsified asphalt compound embodiment:
(1) various starting material are weighed according to above-described embodiment formulating of recipe;
(2) under normal temperature, add the high-molecular compounded and modified emulsified bitumen of heat-reflective and pH adjusting agent in stirring tank, open and stir, stir 3 minutes, stirring velocity is 600rad/min, and system pH is surveyed in sampling, and hierarchy of control pH value is 12.50 ± 1.00;
(3) add thickening material to stirring tank, stir 5 minutes, system pH is surveyed in sampling, and hierarchy of control pH value is 12.00 ± 1.00;
(4) add graded aggregate to stirring tank, stir 3 minutes, system pH is surveyed in sampling, and the pH value of the hierarchy of control is 11.00 ± 1.00;
(5) stop stirring, package encapsulation stores, and cleans stirring tank.